EP0114592B1 - Verfahren zur Metallverarbeitung unter Verwendung von Matrizen - Google Patents
Verfahren zur Metallverarbeitung unter Verwendung von Matrizen Download PDFInfo
- Publication number
- EP0114592B1 EP0114592B1 EP83890233A EP83890233A EP0114592B1 EP 0114592 B1 EP0114592 B1 EP 0114592B1 EP 83890233 A EP83890233 A EP 83890233A EP 83890233 A EP83890233 A EP 83890233A EP 0114592 B1 EP0114592 B1 EP 0114592B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tube
- process according
- jacket tube
- alloy
- compressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 14
- 239000002184 metal Substances 0.000 title claims description 11
- 229910052751 metal Inorganic materials 0.000 title claims description 11
- 150000002739 metals Chemical class 0.000 title 1
- 239000000463 material Substances 0.000 claims abstract description 20
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 5
- 239000010959 steel Substances 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 239000007769 metal material Substances 0.000 claims description 4
- 229910000531 Co alloy Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000003754 machining Methods 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000012254 powdered material Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 238000005242 forging Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 abstract description 2
- 239000010941 cobalt Substances 0.000 abstract description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 2
- 238000012856 packing Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000002775 capsule Substances 0.000 description 4
- 238000001513 hot isostatic pressing Methods 0.000 description 4
- 229910000746 Structural steel Inorganic materials 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000915 Free machining steel Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/1208—Containers or coating used therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/062—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools involving the connection or repairing of preformed parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/08—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41A—FUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
- F41A21/00—Barrels; Gun tubes; Muzzle attachments; Barrel mounting means
- F41A21/02—Composite barrels, i.e. barrels having multiple layers, e.g. of different materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12063—Nonparticulate metal component
- Y10T428/12097—Nonparticulate component encloses particles
Definitions
- the invention relates to a method for metal processing using matrices which have a shaping inner part and at least one shell part partially encasing this, made of different, metallic materials.
- Matrices be they extrusion dies for pipes made of high-alloy steels, copper, plastic, drawing dies for wires, cold-forming dies for screws, dies for hot or cold forming of plastic masses are subject to a double load.
- the shaping parts are subjected to a highly abrasive stress, which is directly attributable to the deformation of the material to be molded, and, on the other hand, a compressive stress occurs because the material to be molded offers resistance to deformation. This resistance causes pressure and tensile stress on the die.
- matrices are also manufactured in several parts, with an inner part that is used for shaping being produced from a different material than a part surrounding this part, which is intended to absorb forces. Precondition that a tool divided in this way can bring the desired advantage is precise manufacture, since only then can the shaping part be prevented from breaking.
- a method is described which is suitable for lining cavities, including pipes.
- a gap is created in a casing tube, for example made of steel, by introducing a thin-walled metal part, into which metal powder is filled, the gap is then evacuated and then the body with the metal part and powder contained therein at approx. 1150 ° C. and 103 N / mm 2 is compressed. A final post-processing is possible.
- No. 4,327,154 shows a method for producing tubular parts, a composite part being produced by applying a powder component to a tubular metal shell using hot isostatic pressing between 1000 ° and 1400 ° C. and pressures from 10 to 1000 bar.
- the invention has for its object to provide a method for metal processing using dies, which allows a die to be used which is constructed from two different materials, and a combination of material pairs can be used.
- the method according to the invention essentially consists in that the die is manufactured in such a way that a filling made of a powdery, highly wear-resistant or corrosion-resistant material and having a bulk density of at least 60% of the density of the compact material is inserted into a casing tube made of a tough alloy is inserted with a recess in a central hollow area of the casing tube, the hollow area being cut out by a filler made of free-cutting steel, then compressed and closed at the ends of the casing tube, whereupon the pipe is closed and evacuated at 900 ° C, but below the melting point of the metallic materials and a pressure of at least 900 bar is pressed, and that the composite body thus obtained, which has a full-surface mechanical bond between the casing tube and the compressed material, before its shaping further processing into a die of a hot deformation with an at least subjected to at least 1.3-fold deformation, processed to give shape.
- a tube can also be used as a packing, in which case e.g. over a mandrel that can be forged.
- a sleeve tube made of an alloy of the following composition in wt .-% C 0.36, Si 1.1, Cr 5.0, Mo 1.1, V 0.40 and remainder iron with an outer diameter of 120 mm and an inner diameter of 60 mm and a length of 1200 mm.
- Degassing was carried out at 360 ° C., whereupon an upper cover with a suction opening was welded onto the capsule tube. Then it was evacuated and the suction opening was closed.
- the encapsulated body was hot-isostatically pressed for 3 hours in an argon atmosphere at 1150 ° C. and at a pressure of 1020 bar.
- This composite body was then forged on a long forging machine to an outer diameter of approximately 80 mm, which corresponds to approximately 2.5 times the deformation. After the forging, annealing was carried out, after which an extrusion die for the production of copper pipes was produced by mechanical processing, cutting to length, turning.
- a hollow cylinder made of steel with the following composition C 0.03, Mo 5.0, Ni 18.5, Co 9 , 0, Ti 0.6 introduced with an outer diameter of 210 mm and an inner diameter of 120 mm and a length of 500 mm.
- a cylindrical rod made of free-cutting steel with an outside diameter of 100 mm and a length of 500 mm was inserted in the center of the casing tube.
- the hollow cylindrical space was filled with a powder of a cobalt-based alloy of the following composition in% by weight C 0.25, Cr 28.0, Mo 5.4, Ni 3.0, rest Co, a density of 6.8 g being obtained by shaking / cm 3 was reached.
- Degassing was carried out at 360 ° C., whereupon an upper cover with suction openings was welded on. It was then evacuated and hot-isostatically pressed according to Example 2.
- the composite body thus obtained was forged on a long forging machine with a fourfold deformation. Further processing was carried out after solution annealing as in Example 2 to give a hot-drawing die.
- a 100 mm long sleeve tube of 70 mm outside diameter and a wall of 20 mm made of the material 25CrMo4 was made entirely of a spherical alloy powder of the composition in% by weight 0.9 C to produce a cold impact die for gate screws.
- the hot isostatic pressing was carried out at 1050 ° C. and a gas pressure of 1100 bar for three hours.
- the recess intended for the specified purpose and corresponding to the screw shape was produced by EDM machining.
- the sleeve tube can also be welded directly to the lids, since in some cases no pressure can act on the powder in the radial direction due to the material thickness of the sleeve tube.
- the core can also be formed by a hollow cylinder, in which case a mandrel can be used for forging.
- a cladding tube can also be used which has an inner coating, e.g. Electrolytically deposited from nickel or the like., which can occur as an adhesion promoter between the material of the cladding tube and the powder.
- an inner coating e.g. Electrolytically deposited from nickel or the like., which can occur as an adhesion promoter between the material of the cladding tube and the powder.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Forging (AREA)
- Powder Metallurgy (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Coating With Molten Metal (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Semiconductor Lasers (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT467982 | 1982-12-23 | ||
AT4679/82 | 1982-12-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0114592A1 EP0114592A1 (de) | 1984-08-01 |
EP0114592B1 true EP0114592B1 (de) | 1988-03-30 |
Family
ID=3567024
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83890233A Expired EP0114592B1 (de) | 1982-12-23 | 1983-12-22 | Verfahren zur Metallverarbeitung unter Verwendung von Matrizen |
EP83890234A Withdrawn EP0114593A1 (de) | 1982-12-23 | 1983-12-22 | Verfahren zur Herstellung eines Maschinenhohlzylinders für Kunststoffverarbeitungsmaschinen |
EP83890232A Expired EP0114591B1 (de) | 1982-12-23 | 1983-12-22 | Verfahren zur Herstellung von Waffenrohren |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83890234A Withdrawn EP0114593A1 (de) | 1982-12-23 | 1983-12-22 | Verfahren zur Herstellung eines Maschinenhohlzylinders für Kunststoffverarbeitungsmaschinen |
EP83890232A Expired EP0114591B1 (de) | 1982-12-23 | 1983-12-22 | Verfahren zur Herstellung von Waffenrohren |
Country Status (6)
Country | Link |
---|---|
US (1) | US4747225A (cs) |
EP (3) | EP0114592B1 (cs) |
AT (2) | ATE33218T1 (cs) |
DE (2) | DE3376100D1 (cs) |
ES (2) | ES8501657A1 (cs) |
GR (2) | GR79748B (cs) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT385227B (de) * | 1984-01-24 | 1988-03-10 | Ver Edelstahlwerke Ag | Verfahren zur herstellung von kraftuebertragenden, insbesondere drehmomentuebertragenden elementen |
US4640814A (en) * | 1985-10-17 | 1987-02-03 | Crucible Materials Corporation | Method for producing clad tubular product |
EP0283877B1 (en) * | 1987-03-25 | 1993-06-23 | Nippon Steel Corporation | Method of producing clad metal tubes. |
AT391105B (de) * | 1988-10-07 | 1990-08-27 | Boehler Gmbh | Vormaterial fuer die erzeugung von verbundwerkstoffen |
US5277228A (en) * | 1990-11-02 | 1994-01-11 | Usui Kokusai Sangyo Kaisha Limited | Welded pipe with excellent corrosion resistance inner surface |
US5290507A (en) * | 1991-02-19 | 1994-03-01 | Runkle Joseph C | Method for making tool steel with high thermal fatigue resistance |
US5341719A (en) * | 1992-12-14 | 1994-08-30 | General Electric Company | Multi-layer composite gun barrel |
US5357842A (en) * | 1993-07-09 | 1994-10-25 | Reynolds Charles E | Recoil reducing device |
US6218026B1 (en) | 1995-06-07 | 2001-04-17 | Allison Engine Company | Lightweight high stiffness member and manufacturing method thereof |
US5724643A (en) * | 1995-06-07 | 1998-03-03 | Allison Engine Company, Inc. | Lightweight high stiffness shaft and manufacturing method thereof |
US5856631A (en) * | 1995-11-20 | 1999-01-05 | Nitinol Technologies, Inc. | Gun barrel |
DE19834394A1 (de) * | 1998-07-30 | 2000-02-03 | Rheinmetall W & M Gmbh | Waffenrohr mit einer verschleißmindernden Hartchromschicht |
SE516130C2 (sv) * | 1999-03-15 | 2001-11-19 | Damasteel Ab | Ämne för metallprodukt, förfarande för framställning av metallprodukt samt metallprodukt |
RU2167742C2 (ru) * | 1999-03-31 | 2001-05-27 | Курский государственный технический университет | Способ армирования металлических изделий твердосплавным слоем |
DE19926246A1 (de) * | 1999-06-09 | 2000-12-14 | Rheinmetall W & M Gmbh | Verfahren zur Innenbeschichtung eines Waffenrohres |
US6594936B1 (en) * | 2002-10-03 | 2003-07-22 | Gary Sniezak | Method for lining a gun barrel |
US20040226211A1 (en) * | 2003-05-16 | 2004-11-18 | Ra Brands. L.L.C. | Composite receiver for firearms |
US20040244254A1 (en) * | 2003-06-09 | 2004-12-09 | Barfield Christopher A.. | Firearm safety device |
US7922065B2 (en) | 2004-08-02 | 2011-04-12 | Ati Properties, Inc. | Corrosion resistant fluid conducting parts, methods of making corrosion resistant fluid conducting parts and equipment and parts replacement methods utilizing corrosion resistant fluid conducting parts |
US7963202B1 (en) * | 2005-09-21 | 2011-06-21 | The United States Of America As Represented By The Secretary Of The Army | Superalloy mortar tube |
US7921590B2 (en) | 2006-02-23 | 2011-04-12 | Strum, Ruger & Company, Inc. | Composite firearm barrel reinforcement |
US20100236122A1 (en) * | 2006-07-26 | 2010-09-23 | Fonte Matthew V | Flowforming Gun Barrels and Similar Tubular Devices |
BRPI0621189A2 (pt) * | 2006-08-01 | 2011-12-06 | Afl Telecommunications Llc | tubo metálico, método para a criação de um tubo metálico e método para a criação de um produto de tubo metálico |
US8910409B1 (en) | 2010-02-09 | 2014-12-16 | Ati Properties, Inc. | System and method of producing autofrettage in tubular components using a flowforming process |
US8869443B2 (en) | 2011-03-02 | 2014-10-28 | Ati Properties, Inc. | Composite gun barrel with outer sleeve made from shape memory alloy to dampen firing vibrations |
US10118259B1 (en) | 2012-12-11 | 2018-11-06 | Ati Properties Llc | Corrosion resistant bimetallic tube manufactured by a two-step process |
US9279633B2 (en) | 2014-01-21 | 2016-03-08 | Richard R. Hayes | Multi-caliber weapon |
US9796057B2 (en) * | 2015-01-15 | 2017-10-24 | Saeilo Enterprises, Inc. | Gun barrel assembly |
SE2300011A1 (sv) * | 2023-02-09 | 2024-08-10 | Bae Systems Bofors Ab | Eldrör |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US930927A (en) * | 1906-03-19 | 1909-08-10 | Robert H Berkstresser | Gun-barrel and process of producing the same. |
US2372202A (en) * | 1940-05-08 | 1945-03-27 | Mallory & Co Inc P R | Bearing |
US2636849A (en) * | 1946-12-13 | 1953-04-28 | Us Sec War | Method of electroforming gun barrels and liners |
US2977666A (en) * | 1954-12-29 | 1961-04-04 | Porter H Brace | Method of making gun liner elements |
US3112553A (en) * | 1960-06-08 | 1963-12-03 | William H Safranek | Electroforming of gun liners |
US3261121A (en) * | 1961-10-13 | 1966-07-19 | Joseph R Eves | Gun barrel with explosively welded liner |
US3753704A (en) * | 1967-04-14 | 1973-08-21 | Int Nickel Co | Production of clad metal articles |
JPS50106844A (cs) * | 1974-01-31 | 1975-08-22 | ||
DE2514565C3 (de) * | 1975-04-03 | 1979-09-20 | Uralskij Nautschno-Issledovatelskij Institut Trubnoj Promyschlennosti, Tscheljabinsk (Sowjetunion) | Verfahren zur Herstellung eines Verbundrohres |
US4016008A (en) * | 1975-07-31 | 1977-04-05 | The International Nickel Company, Inc. | Clad metal tubes |
DE2737248C2 (de) * | 1977-08-18 | 1985-09-19 | MTU Motoren- und Turbinen-Union München GmbH, 8000 München | Bauteil hoher Festigkeit mit komplizierter geometrischer Form und Verfahren zu dessen Herstellung |
US4135286A (en) * | 1977-12-22 | 1979-01-23 | United Technologies Corporation | Sputtering target fabrication method |
GB2073783B (en) * | 1980-04-10 | 1984-10-10 | Cameron Iron Works Inc | Lining valves by hot isotatic pressing |
US4426248A (en) * | 1983-05-20 | 1984-01-17 | The United States Of America As Represented By The Secretary Of The Army | Process for coating rifle tubes |
-
1983
- 1983-12-08 GR GR73197A patent/GR79748B/el unknown
- 1983-12-14 US US06/561,279 patent/US4747225A/en not_active Expired - Fee Related
- 1983-12-21 GR GR73306A patent/GR81355B/el unknown
- 1983-12-22 ES ES528315A patent/ES8501657A1/es not_active Expired
- 1983-12-22 DE DE8383890232T patent/DE3376100D1/de not_active Expired
- 1983-12-22 AT AT83890232T patent/ATE33218T1/de not_active IP Right Cessation
- 1983-12-22 EP EP83890233A patent/EP0114592B1/de not_active Expired
- 1983-12-22 ES ES528317A patent/ES528317A0/es active Granted
- 1983-12-22 DE DE8383890233T patent/DE3376101D1/de not_active Expired
- 1983-12-22 AT AT83890233T patent/ATE33219T1/de not_active IP Right Cessation
- 1983-12-22 EP EP83890234A patent/EP0114593A1/de not_active Withdrawn
- 1983-12-22 EP EP83890232A patent/EP0114591B1/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
EP0114592A1 (de) | 1984-08-01 |
ES8501658A1 (es) | 1984-12-01 |
ES528315A0 (es) | 1984-12-01 |
GR79748B (cs) | 1984-10-31 |
GR81355B (cs) | 1984-12-11 |
ATE33218T1 (de) | 1988-04-15 |
ATE33219T1 (de) | 1988-04-15 |
EP0114591B1 (de) | 1988-03-30 |
DE3376101D1 (en) | 1988-05-05 |
US4747225A (en) | 1988-05-31 |
ES8501657A1 (es) | 1984-12-01 |
ES528317A0 (es) | 1984-12-01 |
DE3376100D1 (en) | 1988-05-05 |
EP0114591A1 (de) | 1984-08-01 |
EP0114593A1 (de) | 1984-08-01 |
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