EP0106280B1 - Ventileinsatz für eine Zweikammer-Druckgaspackung - Google Patents

Ventileinsatz für eine Zweikammer-Druckgaspackung Download PDF

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Publication number
EP0106280B1
EP0106280B1 EP83110002A EP83110002A EP0106280B1 EP 0106280 B1 EP0106280 B1 EP 0106280B1 EP 83110002 A EP83110002 A EP 83110002A EP 83110002 A EP83110002 A EP 83110002A EP 0106280 B1 EP0106280 B1 EP 0106280B1
Authority
EP
European Patent Office
Prior art keywords
valve
discharge pipe
coupling
actuating
opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83110002A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0106280A1 (de
Inventor
Herbert Dr. Meuresch
Wolfgang Fuhrig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Prazisions-Ventil GmbH
Deutsche Prazisions Ventil GmbH
Original Assignee
Deutsche Prazisions-Ventil GmbH
Deutsche Prazisions Ventil GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Prazisions-Ventil GmbH, Deutsche Prazisions Ventil GmbH filed Critical Deutsche Prazisions-Ventil GmbH
Publication of EP0106280A1 publication Critical patent/EP0106280A1/de
Application granted granted Critical
Publication of EP0106280B1 publication Critical patent/EP0106280B1/de
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • B65D83/68Dispensing two or more contents
    • B65D83/682Dispensing two or more contents initially separated and subsequently mixed
    • B65D83/687Dispensing two or more contents initially separated and subsequently mixed with contents and the propellant being fully mixed on, or prior to, first use, e.g. by breaking an ampoule containing one of those components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • B65D83/42Filling or charging means
    • B65D83/425Delivery valves permitting filling or charging

Definitions

  • the invention relates to a valve insert for a two-chamber compressed gas pack for the separate storage of two product components in an inner and an outer container and for mixing the product components, with a cover having a removal tube in a central through opening for closing an opening of the outer container, which is smaller than the diameter of the outer container, with an elastic ring seal sealing the extraction tube against the through-opening, in which the extraction tube is axially displaceable from an outer to an inner end position for piercing a wall of the inner container, and manually to release the mixture removal Actuatable valve, wherein the extraction tube is closed at the end facing the inner container, so that the valve is closed in the intermediate position, and wherein the lid on the inside of a surrounding the extraction tube and passage openings for d he product component coupling for coupling the inner container to the lid.
  • the invention has for its object to provide a valve insert of the generic type, in which it is ensured that the removal is not possible before the product components are mixed.
  • this object is achieved in that the valve is moved into the inner end position by moving the extraction tube from the outer end position, in which the valve is closed, to an intermediate position, in which the wall of the inner container penetrates and the valve is still closed. in which the valve is open, can be actuated.
  • the ring seal can then be an annular disk held between the inside of the cover and the end of the coupling connected to the cover, and the removal tube can be guided axially displaceably in the coupling.
  • the extraction tube is closed at the end facing the inner container and has a radial valve opening which cooperates with the annular disc as a valve and which, in the intermediate position of the extraction tube, lies near the inside of the annular disc.
  • the ring seal also acts as a valve closure piece, so that a valve tappet is not required.
  • the removal tube can then have a cutting disc at the inner end with at least one cutting edge facing the inner container on the peripheral edge.
  • the cutting disc results in an immediate formation of a larger hole in the wall of the inner container facing it, through which the contents of the inner container, through which the contents of the inner container can escape quickly and can mix with the contents of the outer container as soon as the sampling tube has reached the intermediate position.
  • the extraction tube can be made correspondingly shorter than in the generic valve insert, in which the inner end section of the extraction tube is surrounded by an annular disc at a distance from the inner end of the extraction tube to widen the opening formed by this end in the inner container.
  • a further development can then consist in the coupling having a first coupling part which can be brought into engagement with the inner container and a second coupling part which is in engagement with the cover, which are axially fixedly connected, and in that the inside of the first coupling part has an undercut, on which a corresponding undercut on the circumference of the sampling tube is placed under the pressure of a return spring acting in the direction of the outer end position in the intermediate position.
  • This configuration ensures that the sampling tube cannot be returned to the outer end position after the inner container has been pierced.
  • the first coupling part has approximately the shape of a hood which positively engages over the inner container and has passage openings in the bottom which at the same time forms a bottom of the second coupling part on which the return spring is supported.
  • This type of connection e.g. B. a snap connection or screw connection between the first coupling part and the inner container allows easy assembly, for. B. automatically, and still causes a solid cohesion of both parts. Nevertheless, the contents of the inner container can pass freely through the passage opening after it has pierced its wall through the hood to mix it with the contents of the first container. At the same time, the bottom of the hood has a supporting function for the return spring.
  • the coupling parts can be manufactured separately and held together by a plug connection. This enables a simple production of the coupling from plastic plastic in a mold while avoiding demolding difficulties.
  • the second coupling part to the first coupling part can have axially continuous slots as through openings and engage under radial spring preload in an annular groove of the first coupling part.
  • the coupling parts can be easily connected to one another by plugging them together. Nevertheless, they are securely connected axially by a high frictional force.
  • the axially continuous slots lead on the one hand to a spring action of the finger-like webs remaining between them and on the other hand allow the product components to pass through.
  • the cutting disk can also have passage openings which radially overlap passage openings formed on both sides of the annular groove in the bottom of the first coupling part. This ensures a largely unhindered escape of the contents of the inner container after it has been opened.
  • an actuating cap can be attached to the outside of the lid with its opening edge so that the edge of a central outlet opening in a central actuating part of the actuating cap is seated on the outer open end of the extraction tube, and that the actuating part on the outer part of the Actuating cap is articulated.
  • This actuating cap allows the valve to be opened easily by pivoting the actuating part by means of the thumb or a finger of the same hand with which the compressed gas pack is held.
  • a protective hood covering the actuating cap firmly surrounds the peripheral wall of the actuating cap by means of a tear-off opening edge section, the axial length of which corresponds to the stroke of the extraction tube from the outside End position corresponds to the intermediate position, and when the protective hood is supported on the actuating part.
  • a pressure for. B. a blow to the protective cover this only by the mentioned stroke and thus the sampling tube from the end position inevitably initially only to the intermediate position in which the inner container is pushed open but the valve is not yet open.
  • the outlet opening can be formed in the bottom of a recess on the inside of the actuating part which swivels over the outer end of the removal tube.
  • the depression on the one hand ensures centering of the actuating part relative to the extraction tube, and vice versa, and on the other hand enables the actuating part to be pivoted while axially displacing the extraction tube without tilting the extraction tube itself.
  • the recess rotatably engages over the outer end of the sampling tube, that the actuating part has two sections which extend diametrically with respect to its axis of rotation, one section of which has an axial thickness greater than the mentioned stroke than the other Has section, the thickness of which is smaller than the axial stroke, and that the opening in the bottom of the actuating cap on the side of that section extends over a larger angle of rotation range of the actuating part than this section.
  • the actuating part after being brought into the intermediate position by sliding the hood to tear its connection with the outer part of the actuating cap, the actuating part can be rotated relative to the outer part of the actuating cap so that one section of the actuating cap is rotated, so that one section of the actuating part continues to protrude axially outward beyond the outer part of the actuating cap, whereas the other section of the actuating part rests articulated under this outer part of the actuating cap.
  • the actuating part is therefore no longer connected to the actuating cap, it is nevertheless pivotally mounted only against the pressure of the return spring in order to bring about the opening of the valve by axially displacing the extraction tube.
  • the circumference of the coupling end section facing the cover can then be provided with axial ribs, which are bordered by an edge section of the central through-opening of the cover, which takes up the play tube with play, leaving axial passage channels free, and the end face of the coupling end, which is designed as an annular disk, faces radially backward beveled outside.
  • This design allows easy filling of the outer container with compressed gas by attaching the filling head of a conventional filling device, the elastic ring disc being compressed at its outer peripheral edge and opening up an inlet channel for the compressed gas.
  • the two-chamber compressed gas pack consists of an outer container 1, an inner container 2 arranged in the outer container 1 and a valve insert 3.
  • the containers 1 and 2 each contain a gas product liquid component 4a and 4b, i.e. H. an active ingredient and an activator, in a predetermined amount, which are completely mixed before removal in the outer container 1, so that they are used in a precisely defined mixing ratio.
  • a wall 5, here a sealing film, of the inner container 2 is destroyed by means of the valve insert 3 and the product component 4b is released from the inner container 2 into the still closed outer container 1.
  • the valve insert 3 consists of a removal tube 6, a cover 7, a coupling 8 connecting the inner container 2 to the cover 7, a protective hood 9, a spring 10, an annular seal 11 and an actuating cap 12 (FIG. 3).
  • the extraction tube 6 is provided in its outer end section with an axial outlet channel 13, which is closed at the outer end by the protective hood 9 and in which a radial valve opening 14 opens at the other end.
  • the protective hood 9 covers the extraction tube 6 approximately up to the valve opening 14.
  • the extraction tube 6 has an undercut 15 in the form of an annular bead which is bevelled on the peripheral surface.
  • the removal tube 6 is provided with a cutting disk 16 which, if appropriate, faces the sealing film 5. Cutting edge interrupted in the circumferential direction and having a slightly smaller diameter than the opening of the container 2 covered by the sealing film 5.
  • the approximately plate-shaped cover 7 (also called valve plate) is inserted in the opening of the container 1 and its outer edge is connected tightly and pressure-securely to the flanged opening edge of the container 1. In the middle, the cover 7 is provided with a through opening 17 through which the removal tube 6 is guided with play.
  • the coupling 8 has a first coupling part 18 which can be brought into engagement with the inner container 2 and a coupling part 19 which engages with the cover 7.
  • the coupling part 18 has at the inner end a hood 20, which is interrupted several times in a segment-like manner by axial slots in the side wall and consists of a plurality of elastic holding claws 21 with an undercut, as a holder for receiving the container 2, the opening edge of which has a radially projecting annular flange 22 which engages behind the undercut.
  • the connection of container 2 and coupling part 18 can also be designed as a bayonet lock.
  • Passage openings 23 are formed in the bottom of the hood 20 which, when the sealing film 5 is pierced, allow the product component 4b to pass into the container 1.
  • the extraction tube 6 is then passed through a central bore in the bottom of the hood 20 with lateral guidance of the extraction tube 6.
  • the Kuppiungsteii 19 has at the free end facing the cover 2 (see in particular Fig. 1a) towards the inside a cylindrical depression 24 (shoulder) for receiving the washer 11 and on the outside of it several axial ribs 25 in the circumferential direction apart for pressurized gas filling.
  • the end section of the coupling part 19 which has the ribs 25 is framed by the edge section of the cover 7 adjoining the through opening 17, leaving the passage channels between the ribs 25 free, so that the coupling part 19) is fastened to the cover 7.
  • the coupling part 19 then has on its inside a ring bead forming an undercut 26, the inside diameter of which is slightly smaller than the outside diameter of the ring bead 15.
  • the annular beads 15, 26 can therefore be guided past one another with deformation when the extraction tube 6 is displaced.
  • the coupling part 19 is provided with through openings 27 in the form of axial slots.
  • the sealing film 5 is pierced by pushing the extraction tube 6 in that a pressure or impact is exerted on the protective hood 9 in the direction of arrow 28 until the protective hood 9 rests with its opening edge on the edge 29 of the through opening 17, so that the contents of the container 2 in the direction of the arrows 30 past the cutting disk 16 (or through passage openings which may be formed therein) and through the passage openings 23 into the container 1 and by shaking the container 1 in the head overlay shown in FIG the contents of the container 1 can be completely mixed.
  • the distances between the protective hood 9 and the valve opening 14 from the edge 29 of the cover 7 and the distance of the Undercuts 15 and 16 are chosen approximately the same and so large that, in the intermediate position shown in FIG. 2, on the one hand pierce the sealing film 5 and on the other hand the undercuts are locked together, the spring 10 surrounding the extraction tube 6, which is on the one hand on the ring bead 15 and on the other hand is supported on the bottom of the hood 20, the undercuts 15 and 26 press against one another and the valve opening 14 remains outside the inside of the annular disk 11. In this intermediate position of the removal tube 6, the valve formed from the annular disk 11 and the valve opening 14 is consequently still closed, so that the product mixture cannot yet exit the container 1.
  • the actuating cap 12 Only after removal of the protective hood 9 which is frictionally attached to the outer end of the removal tube 6, placement of the actuating cap 12 (FIG. 3) on the outer edge of the cover 7 in a snap fit and on the outer end of the removal tube 6 and pushing one in an opening 31 in Bottom of the actuating cap 12 articulated middle actuating part 32 of the cap 12 in the direction of arrow 33, the outlet of the mixture from the containers 1 and 2 in the direction of the flow arrows 34 is released as soon as the valve opening 14 comes to rest on the inside of the annular disk 11.
  • the actuating cap 12 has on its inside an insertion recess 35 with an outlet opening 36 which receives the outer end of the extraction tube 6 and which opens into an extraction tube 37 which extends the extraction tube 6.
  • the two-chamber compressed gas pack consists of an outer container, not shown, which corresponds to the outer container 1 according to FIG. 1, an inner container 52 arranged in the outer container and a valve insert 53.
  • the containers also each contain a liquid product component (not shown) under gas pressure, e.g. B. an active ingredient and an activator, in a predetermined amount, which are completely mixed before removal in the outer container, so that they are used in a precisely defined mixing ratio.
  • a liquid product component (not shown) under gas pressure, e.g. B. an active ingredient and an activator, in a predetermined amount, which are completely mixed before removal in the outer container, so that they are used in a precisely defined mixing ratio.
  • the wall 5, again a sealing film, of the inner container 52 is destroyed by means of the valve insert 53 and the product component is released from the inner container 52 into the still closed outer container.
  • the valve insert 53 consists of a removal tube 56, the cover 7, a coupling 58 connecting the inner container 52 to the cover 7, a protective hood 59, the spring 10, the ring seal 11 and an actuating cap 62.
  • the removal tube 56 is provided in its outer end section with the axial outlet channel 13, which is open at the outer end and into which the radial valve opening 14 opens.
  • the protective hood 59 covers the actuating cap 62, which in turn is seated on the outer edge of the cover 7 and is locked with it.
  • the removal tube 56 has the undercut 15 in the form of an annular bead which is bevelled on the circumferential surface.
  • the removal tube 56 is provided with a cutting disk 66, which has the cutting edge 16a facing the sealing film 5, possibly interrupted in the circumferential direction, at the peripheral edge, a slightly smaller diameter than the opening of the container 52 covered by the sealing film 5 and through openings 67.
  • the lid 7 is attached to the outer container and provided in the middle with the through opening 17 through which the removal tube 56 is guided with play.
  • the coupling 58 has a first coupling part 68 which can be brought into engagement with the inner container 52 and a coupling part 69 which engages with the cover 7.
  • the coupling part 68 has a hood 70 with an internal thread 71 at the inner end as a holder for receiving the inner container 52, the opening edge of which has an external thread 72 engaging in the internal thread.
  • the passage openings 23 are again formed in the bottom of the hood 70.
  • the extraction tube 56 is then passed through a central bore in the bottom of the hood 70 with lateral guidance of the extraction tube 56.
  • the bore is delimited by radial webs or ribs 65 which delimit further axial passage openings 63. Both the passage openings 23 and the passage openings 63 are radially overlapped by the passage openings 67.
  • the coupling part 69 has at the free end facing the cover 7 an inwardly tapered conical end face 74 for abutment of the annular disk 11 and on the outside thereof a plurality of axial ribs 75 which are spaced apart in the circumferential direction for pressurized gas filling.
  • the end section of the coupling part 69, which has the ribs 75, is bordered by the edge section of the cover 7 adjoining the passage opening 17, leaving the passage channels between the ribs 75 free, so that the coupling part 69 is fastened to the cover 7.
  • the coupling member 69 on its inside the undercut 2 6.
  • the coupling part 19 is provided with passage openings 77 in the form of axially continuous slots, which engage under radial spring preload in an annular groove 78 on the top of the coupling part 68 between the passage openings 23 and 63, so that the coupling parts 68 and 69 are connected to one another in a friction-locking manner.
  • a latching connector instead of this frictional connector.
  • the protective hood 59 has a tear-off opening edge section 79, which with the main part of the protective hood 59 has a predetermined breaking connection 80 in the form of predetermined breaking bars.
  • the axial length of the opening edge section 79 corresponds approximately to the distance of the valve opening 14 from the annular disk 11 in the outer end position of the removal tube 56.
  • the protective hood 59 has projections 59a, 59b on the inside in the form of ribs. These are supported on an actuating part 82 fastened in an opening 81 in the actuating cap 62 by means of a predetermined breaking connection 83 in the form of predetermined breaking webs.
  • the projections 59a and 59b radially outside of the actuating part 82 in the end position shown in FIG. 4 have an axial distance A from the actuating cap 62 which is at least equal to the axial length of the opening edge section 79.
  • the actuating part 82 has a recess 85 on the inside, in the bottom of which the outlet opening 36 for the product mixture is formed. This recess 85 rotatably engages over the outer end of the extraction tube 56 and with play and continues in an extraction tube 87 which extends the extraction tube 56.
  • the protective hood 59 is supported with its bottom also via this removal tube 87 on the actuating part 82, so that the projections 59a, 59b can be omitted.
  • the removal tube 87 could also be dispensed with and the protective hood supported directly or via correspondingly shorter projections on the actuating part 82.
  • annular bead 84 (FIG. 4) which engages in an annular groove 86 on the outside of the peripheral wall of the actuating cap 82.
  • the actuating part 82 has two sections 89 and 90 which extend diametrically with respect to its axis of rotation, of which one section 90 has a distance (A) or stroke of more than the mentioned distance Extraction tube 56 between the outer end position and the intermediate position has a greater axial thickness than the other section 89 (see FIG. 5).
  • the thickness of the section 89 is smaller than this axial stroke, and the opening 81 in the bottom of the actuating cap 62 extends on the side of the section 90 over a larger angle of rotation range of the actuating part 82 than this section 90.
  • the actuating cap 62 and the undamaged protective hood 59 are placed on the cover 7 in the position shown in FIG. 4, so that the removal tube 56 assumes the outer end position shown in FIG. 4.
  • the opening edge section 79 is first torn off from the protective hood 59 and the protective hood 59 is pressed in the direction of the cover 7, it finally being seated on the outer part of the actuating cap 62.
  • the actuating part 82 and the removal tube 56 are simultaneously pushed inwards, tearing off the predetermined breaking webs 83, the cutting disk 66 piercing the cover film 5 in the vicinity of the inner opening edge of the inner container 52.
  • the parts 59, 82 and 56 assume the intermediate position shown in FIG. 5, in which the valve 11, 14 is still closed, but the contents of the container 52 emerge into the outer container and are completely mixed with it by shaking can be.
  • section 90 of the actuating part 82 is now pressed, the actuating part is pivoted, the section 89 being supported on the underside of the bottom of the actuating cap 62.
  • the pivoting movement of the actuating part 82 causes an axial displacement of the extraction tube 56, which is guided on the one hand by the ring disk 11 and on the other hand by the coupling part 68 between the ribs 65, into an inner (not shown) end position in which the valve opening 14 lies on the inside of the ring disk 11 and the valve is open.
  • the contents of the outer container can then emerge unhindered via the slots 77, the valve opening 14, the channel 13 and the removal tube 37, as long as the section 90 of the actuating part 82 is pressed.
  • the extraction tube 56 with the ring disk 11 and the spring 10 is first preassembled and then (in head overhang) inserted into the through hole 17 in the cover 7.
  • the cover 7 is pressed together below the wider part of the ribs 75, so that the cover 7 engages around this part of the ribs.
  • the inner part of the removal tube 56 having the cutting disk 66 is preassembled with the hood 70 of the coupling part 68, this part being held in the hood 70 by friction.
  • This preassembled unit is then pressed with the pointed end of the lower part of the extraction tube first into an axial bore of the upper part of the extraction tube, the pointed end being fixed in the bore with a friction fit (in addition or instead, a latching connection can also be provided).
  • the end portion of the copper having the slots 77 engages plunging part 69 in the annular groove 68, where it is held in the frictional engagement. If desired, this frictional engagement by z. B. an ultrasonic welding of the plastic plastic coupling parts can be reinforced.
  • the pre-assembled valve insert is packaged and delivered to the filling station.
  • the inner container 52 is filled with a product component and then its threaded neck with a z. B. sealed aluminum foil 5 by gluing or welding.
  • the filling station now fills the outer container with the second product component and then inserts the valve insert into the opening of the outer container after the inner container 52 has been screwed tightly to the hood 70.
  • the unit which is then firmly closed by flanging the outer edge of the lid 7 around the opening edge of the outer container now reaches the usual propellant filler in the filling station.
  • a filling head 91 of the propellant gas filler is dimensioned in such a way that the extraction tube 56 is not pressed down by the attachment of the filling head.
  • the propellant gas is then pressed through the passage opening 17 and over the deforming annular disk 11 between the ribs 75 into the outer container, as is shown by the flow lines in FIG. 7.
  • the filling station places the combination of actuating cap 62 and protective hood 59 on the edge of the cover 7.
  • the package is then protected and secured for transport.
  • the customer additionally has an original closure guarantee. The removal can then be carried out in the manner already described.

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Closures For Containers (AREA)
  • Nozzles (AREA)
EP83110002A 1982-10-08 1983-10-06 Ventileinsatz für eine Zweikammer-Druckgaspackung Expired EP0106280B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823237263 DE3237263A1 (de) 1982-10-08 1982-10-08 Ventilsystem fuer druckgaspackung mit zweikomponentenprodukt
DE3237263 1982-10-08

Publications (2)

Publication Number Publication Date
EP0106280A1 EP0106280A1 (de) 1984-04-25
EP0106280B1 true EP0106280B1 (de) 1986-01-02

Family

ID=6175222

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83110002A Expired EP0106280B1 (de) 1982-10-08 1983-10-06 Ventileinsatz für eine Zweikammer-Druckgaspackung

Country Status (8)

Country Link
US (1) US4613061A (enrdf_load_stackoverflow)
EP (1) EP0106280B1 (enrdf_load_stackoverflow)
JP (1) JPS59501661A (enrdf_load_stackoverflow)
AU (1) AU546160B2 (enrdf_load_stackoverflow)
CA (1) CA1220767A (enrdf_load_stackoverflow)
DE (2) DE3237263A1 (enrdf_load_stackoverflow)
WO (1) WO1984001557A1 (enrdf_load_stackoverflow)
ZA (1) ZA837433B (enrdf_load_stackoverflow)

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CN109625625B (zh) * 2018-12-14 2023-09-26 重庆医科大学 用于调配酸奶制品的包装盒
US20240409301A1 (en) * 2021-09-30 2024-12-12 Samurai 2K Aerosol Sdn. Bhd. Multi-function aerosol valve assembly
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Also Published As

Publication number Publication date
EP0106280A1 (de) 1984-04-25
AU2075383A (en) 1984-05-04
AU546160B2 (en) 1985-08-15
JPS59501661A (ja) 1984-10-04
DE3237263A1 (de) 1984-04-12
US4613061A (en) 1986-09-23
WO1984001557A1 (en) 1984-04-26
CA1220767A (en) 1987-04-21
JPH0139825B2 (enrdf_load_stackoverflow) 1989-08-23
ZA837433B (en) 1984-06-27
DE3361726D1 (en) 1986-02-13

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