EP0083920A2 - Procédé pour la coulée d'aciers à teneurs en aluminium relativement élevées dans des installations de coulée continue de billettes - Google Patents
Procédé pour la coulée d'aciers à teneurs en aluminium relativement élevées dans des installations de coulée continue de billettes Download PDFInfo
- Publication number
- EP0083920A2 EP0083920A2 EP83100005A EP83100005A EP0083920A2 EP 0083920 A2 EP0083920 A2 EP 0083920A2 EP 83100005 A EP83100005 A EP 83100005A EP 83100005 A EP83100005 A EP 83100005A EP 0083920 A2 EP0083920 A2 EP 0083920A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- aluminum
- tundish
- casting
- pan
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 16
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 13
- 238000005266 casting Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000010959 steel Substances 0.000 title claims abstract description 13
- 239000004411 aluminium Substances 0.000 title abstract 4
- 239000011575 calcium Substances 0.000 claims abstract description 15
- 229910000882 Ca alloy Inorganic materials 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 11
- 238000009749 continuous casting Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002893 slag Substances 0.000 claims description 7
- 238000010405 reoxidation reaction Methods 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- YMUYTQCKKRCJMP-UHFFFAOYSA-N aluminum;calcium;oxygen(2-) Chemical class [O-2].[Al+3].[Ca+2] YMUYTQCKKRCJMP-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052791 calcium Inorganic materials 0.000 abstract description 4
- 230000001419 dependent effect Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000000155 melt Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 238000007664 blowing Methods 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- ULGYAEQHFNJYML-UHFFFAOYSA-N [AlH3].[Ca] Chemical class [AlH3].[Ca] ULGYAEQHFNJYML-UHFFFAOYSA-N 0.000 description 1
- VVTSZOCINPYFDP-UHFFFAOYSA-N [O].[Ar] Chemical compound [O].[Ar] VVTSZOCINPYFDP-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical class [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- -1 compounds calcium oxide - aluminum oxide Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012384 transportation and delivery Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0006—Adding metallic additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
- B22D11/11—Treating the molten metal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
Definitions
- the invention relates to a method for casting steel with over 0.02% metallic aluminum on billet continuous casting plants with free-running, calibrated tundish nozzles.
- aluminum oxide compounds can be modified in the treatment of the liquid melt with alloys and / or slags of the metals calcium and magnesium.
- the addition is expediently carried out by blowing into the casting ladle by means of an immersion lance.
- Argon is normally used as the carrier gas.
- ladle metallurgical treatment it is common to protect the melt in the ladle from further oxidation, e.g. thanks to protective gas, vacuum, special pan lid, keeping slag free, special slag compositions, pan deliveries made of refractories with low oxygen potential.
- a method known from DE-AS 25 27 156 for preventing the addition of immersion spouts, as are usually used in bloom and slab caster systems, consists in "overblowing" the melt with calcium treatment agents. When “overblown”, aluminum oxide compounds are largely reduced to calcium oxide, which is said to be completely separated.
- the invention is based on the object of metering the Ca amount in such a way that only liquid aluminum oxide compounds occur when casting steels with higher contents of metallic aluminum on billet continuous casting plants.
- the melt is not overblown, but that the amount of solids blown in is matched precisely to the steel composition before the blown-in treatment, in particular to the Oxygen content (carbon content). It is advisable to determine the free oxygen content of the melt in the pan after adding Al and before blowing in; if this is higher than 15 ppm, additional aluminum (per ppm O 2 3.0 ppm Al) must be added.
- the composition of the inclusion compounds calcium oxide - aluminum oxide is controlled so that - if there are no defined purity level requirements - a large part of the known fine grain steels can be cast between the ladle and the tundish without reoxidation protection.
- this limit is already 0.020% Al. It may then be advisable to additionally seal the tundish airtight using a lid and before pouring it on using inert gases such as e.g. Keep nitrogen or argon oxygen free.
- inert gases such as e.g. Keep nitrogen or argon oxygen free.
- the reoxidation protection can consist of a known shadow pipe.
- synthetic slags with a low oxidation potential for example Ca O with about 30% A1 2 ° 3 content, are additionally used to cover the steel surface in the tundish.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Continuous Casting (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT83100005T ATE23463T1 (de) | 1982-01-08 | 1983-01-03 | Verfahren zum giessen von staehlen mit hoeheren aluminiumgehalten auf knueppelstranggiessanlagen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH107/82 | 1982-01-08 | ||
CH10782 | 1982-01-08 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0083920A2 true EP0083920A2 (fr) | 1983-07-20 |
EP0083920A3 EP0083920A3 (en) | 1983-10-26 |
EP0083920B1 EP0083920B1 (fr) | 1986-11-12 |
Family
ID=4179430
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83100005A Expired EP0083920B1 (fr) | 1982-01-08 | 1983-01-03 | Procédé pour la coulée d'aciers à teneurs en aluminium relativement élevées dans des installations de coulée continue de billettes |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0083920B1 (fr) |
AT (1) | ATE23463T1 (fr) |
DE (1) | DE3367542D1 (fr) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2636400A1 (de) * | 1976-08-11 | 1978-02-16 | Mannesmann Ag | Verfahren zur verbesserung der kristallstruktur von im strang abgegossenem stahl |
DE2527156B2 (de) * | 1975-06-18 | 1980-09-04 | Thyssen Niederrhein Ag Huetten- Und Walzwerke, 4200 Oberhausen | Verfahren zur Vorbehandlung einer Stahlschmelze beim Stranggießen |
US4317678A (en) * | 1980-09-26 | 1982-03-02 | Union Carbide Corporation | Process for continuous casting of aluminum-deoxidized steel |
-
1983
- 1983-01-03 AT AT83100005T patent/ATE23463T1/de not_active IP Right Cessation
- 1983-01-03 EP EP83100005A patent/EP0083920B1/fr not_active Expired
- 1983-01-03 DE DE8383100005T patent/DE3367542D1/de not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2527156B2 (de) * | 1975-06-18 | 1980-09-04 | Thyssen Niederrhein Ag Huetten- Und Walzwerke, 4200 Oberhausen | Verfahren zur Vorbehandlung einer Stahlschmelze beim Stranggießen |
DE2636400A1 (de) * | 1976-08-11 | 1978-02-16 | Mannesmann Ag | Verfahren zur verbesserung der kristallstruktur von im strang abgegossenem stahl |
US4317678A (en) * | 1980-09-26 | 1982-03-02 | Union Carbide Corporation | Process for continuous casting of aluminum-deoxidized steel |
Also Published As
Publication number | Publication date |
---|---|
ATE23463T1 (de) | 1986-11-15 |
EP0083920A3 (en) | 1983-10-26 |
EP0083920B1 (fr) | 1986-11-12 |
DE3367542D1 (en) | 1987-01-02 |
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