EP0049874A2 - Method for the hydrothermal activation of bread cereals - Google Patents

Method for the hydrothermal activation of bread cereals Download PDF

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Publication number
EP0049874A2
EP0049874A2 EP81108093A EP81108093A EP0049874A2 EP 0049874 A2 EP0049874 A2 EP 0049874A2 EP 81108093 A EP81108093 A EP 81108093A EP 81108093 A EP81108093 A EP 81108093A EP 0049874 A2 EP0049874 A2 EP 0049874A2
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Prior art keywords
hours
conditioning
activation
cereal
water content
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Granted
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EP81108093A
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German (de)
French (fr)
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EP0049874A3 (en
EP0049874B1 (en
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Muhlen-Und Lieken-Batscheider
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Lieken-Batscheider Muehlen- und Backbetriebe GmbH
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Lieken-Batscheider Muehlen- und Backbetriebe GmbH
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Priority to AT81108093T priority Critical patent/ATE17660T1/en
Publication of EP0049874A2 publication Critical patent/EP0049874A2/en
Publication of EP0049874A3 publication Critical patent/EP0049874A3/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02BPREPARING GRAIN FOR MILLING; REFINING GRANULAR FRUIT TO COMMERCIAL PRODUCTS BY WORKING THE SURFACE
    • B02B1/00Preparing grain for milling or like processes
    • B02B1/08Conditioning grain with respect to temperature or water content

Definitions

  • the invention relates to a process for the hydrothermal activation of cereal used for bread production, in which the whole cereal grains are moistened to a water content of the seedling and the outer grain boundary layers of approx. 40% by weight, in the moist state then for conditioning for more than two hours at one Temperature between 10 ° C and below 20 ° C and finally dried back to a total water content of at most 20 wt .-%.
  • the cereal ingredients are there can be made accessible to nutrition in their full value and mass fraction in an improved manner that hydrothermal activation takes place before the processing of the cereal grains.
  • the procedure is such that the cereal grains are first carefully cleaned, moistened in the process and then subjected to thermal conditioning in the moist state.
  • This conditioning leads to an activation of the cereal metabolism, which should lead to natural vitaminization, in general to the biological quality increase of the cereal, a natural enrichment of important amino acids and overall to a positive change in the vitamin and mineral distribution of the cereal for human nutrition (DE -OS 24 20 910; DE-OS 16 92 752).
  • the hydrothermal conditioning must take place at temperatures which are clearly above room temperature, conditioning temperatures of 25 to 35 ° C. or 20 to 30 ° C. being regarded as particularly preferred.
  • DE-OS 29 21 682 proposes to carry out the conditioning in the manner mentioned at the outset for more than two hours at a temperature between 10 ° C. and below 20 ° C., DE-OS 29 21 682 teaching in particular a conditioning time of to use for two to nine hours.
  • the invention is therefore based on the object of developing the method according to DE-OS 29 21 682 in such a way that the baking properties of the activated grain and the taste acceptance of the bread to be produced therewith are further improved.
  • this object is achieved in the generic method in that the conditioning time is more than nine hours.
  • Particularly preferred embodiments of the invention result from the subclaims.
  • the invention is based on the surprising finding that it is possible to further improve the baking properties and the taste acceptance by using conditioning times of not more than two to nine hours, but instead of the teaching of DE-OS 29 21 682, of more than nine hours . It turned out that the feared effect an excessive enzyme activation with a very long conditioning time, as claimed according to the invention, does not occur under the conditions of cold storage, but on the other hand the activation achieved remains constant and, due to the time effect, causes further positive changes in the formation of so-called precursors for flavorings and, in general, the baking properties clearly be improved.
  • Example 2 The procedure was as in Example 1, but a conditioning time of 48 hours was selected at the same conditioning temperature. An amylogram maximum of 540 was shown (FIG. 3). The gelatinization temperature was 64 ° C., compared to 62.5 ° C. in the comparative test (FIG. 1) and 62.5 ° C. in example 1 (FIG. 2).
  • the enzymatic breakdown of higher polymer carbohydrates and proteins plays a special role here, since the breakdown products are the precursors of flavorings.
  • Baking tests carried out have proven the positive influence of the activation carried out according to the invention on the bread quality both in wheat and in rye.
  • the breads produced using cereal grains activated according to the invention were loosened better than the comparison bread and tasted more rounded. Both are due to the action of the enzymes during activation as well as when preparing and baking dough.
  • the taste of bread improves, a sign that the optimized enzyme activity is maintained over a long period of time, so that the enzymes formed can have an optimal effect on the flavor precursors.

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  • Bakery Products And Manufacturing Methods Therefor (AREA)

Abstract

1. A process for the hydrothermal activation of cereal for breadmaking, the entire grains of cereal being moistened so that the cereal germ and the outer edge layers of the grain have a water content of approximately 40 weight percent, then kept in a moist state for conditioning at a temperature of from 10 degrees C to below 20 degrees C for more than two hours, then dried back to a total water content of at most 20 weight percent, characterised in that the conditioning time is more than 9 hours.

Description

Die Erfindung betrifft ein Verfahren zum hydrothermischen Aktivieren von zur Brotherstellung dienendem Getreide, bei dem die ganzen Getreidekörner auf einen Wassergehalt des Keimlings und der äußeren Kornrandschichten von ca. 40 Gew.-% angefeuchtet, in feuchtem Zustand sodann zur Konditionierung mehr als zwei Stunden bei einer Temperatur zwischen 10° C und unter 20° C gehalten und schließlich auf einen Gesamtwassergehalt von höchstens 20 Gew.-% zurückgetrocknet werden.The invention relates to a process for the hydrothermal activation of cereal used for bread production, in which the whole cereal grains are moistened to a water content of the seedling and the outer grain boundary layers of approx. 40% by weight, in the moist state then for conditioning for more than two hours at one Temperature between 10 ° C and below 20 ° C and finally dried back to a total water content of at most 20 wt .-%.

Es ist bekannt, daß die Getreideinhaltsstoffe dadurch in ihrem vollen Wert und Massenanteil in verbesserter Weise der Ernährung zugänglich gemacht werden können, daß vor der Verarbeitung der Getreidekörner eine hydrothermische Aktivierung erfolgt. Dabei wird in der Weise vorgegangen, daß die Getreidekörner zunächst sorgfältig gereinigt, dabei angefeuchtet und anschließend im feuchten Zustand einer thermischen Konditionierung unterworfen werden. Diese Konditionierung führt zu einer Aktivierung des Getreidestoffwechsels, wobei es zur natürlichen Vitaminisierung, ganz allgemein zur biologischen Qualitätserhöhung des Getreides, einer natürlichen Anreicherung von wichtigen Aminosäuren sowie insgesamt zu einer für die menschliche Ernährung positiven Veränderung der Vitamin- und Mineralstoffverteilung des Getreides kommen soll (DE-OS 24 20 910; DE-OS 16 92 752). Allgemein wird bei den bekannten Verfahren zur Aktivierung der Korninhaltsstoffe davon ausgegangen, daß die hydrothermische Konditionierung bei Temperaturen erfolgen muß, die deutlich oberhalb der Raumtemperatur liegen, wobei als besonders bevorzugt Konditionierungstemperaturen von 25 bis 35°C bzw. 20 bis 30°C angesehen werden.It is known that the cereal ingredients are there can be made accessible to nutrition in their full value and mass fraction in an improved manner that hydrothermal activation takes place before the processing of the cereal grains. The procedure is such that the cereal grains are first carefully cleaned, moistened in the process and then subjected to thermal conditioning in the moist state. This conditioning leads to an activation of the cereal metabolism, which should lead to natural vitaminization, in general to the biological quality increase of the cereal, a natural enrichment of important amino acids and overall to a positive change in the vitamin and mineral distribution of the cereal for human nutrition (DE -OS 24 20 910; DE-OS 16 92 752). In general, in the known processes for activating the grain constituents, it is assumed that the hydrothermal conditioning must take place at temperatures which are clearly above room temperature, conditioning temperatures of 25 to 35 ° C. or 20 to 30 ° C. being regarded as particularly preferred.

Es hat sich gezeigt, daß der bei herkömmlichen Aktivierungsverfahren (Schäfer, W., Altrogge, L., "Wissenschaft und Praxis der Getreidekonditionierung", Detmold: Moritz Schäfer 1960) unter Verwendung der als optimal angesehenen erhöhten Konditionierungstemperaturen von oberhalb 25°C, erzielbare Aktivierungsgrad noch unbefriedigend ist.It has been shown that the conventional activation processes (Schäfer, W., Altrogge, L., "Science and Practice of Grain Conditioning", Detmold: Moritz Schäfer 1960) can be achieved using the conditioning temperatures of above 25 ° C. which are regarded as optimal Degree of activation is still unsatisfactory.

Zur verbesserten Aktivierung der Korninhaltsstoffe schlägt die DE-OS 29 21 682 daher vor, die Konditionierung in der eingangs genannten Art mehr als zwei Stunden bei einer Temperatur zwischen 10°C und unter 20°C durchzuführen, wobei die DE-OS 29 21 682 insbesondere lehrt, eine Konditionierungszeit von zwei bis neun Stunden zu verwenden.For improved activation of the grain ingredients DE-OS 29 21 682 therefore proposes to carry out the conditioning in the manner mentioned at the outset for more than two hours at a temperature between 10 ° C. and below 20 ° C., DE-OS 29 21 682 teaching in particular a conditioning time of to use for two to nine hours.

Das Verfahren nach der DE-OS 29 21 682 hat sich grundsätzlich bewährt, jedoch hat es sich gezeigt, daß ein Bedürfnis nach einer weiteren Verbesserung der Backeigenschaften sowie der geschmacklichen Akzeptanz des herzustellenden Brotes besteht.The method according to DE-OS 29 21 682 has proven itself in principle, but it has been shown that there is a need for a further improvement in the baking properties and the taste acceptance of the bread to be produced.

Der Erfindung liegt daher die Aufgabe zugrunde, das Verfahren nach der DE-OS 29 21 682 dahingehend weiterzubilden, daß die Backeigenschaften des aktivierten Getreides sowie die geschmackliche Akzeptanz des damit herzustellenden Brotes weiter verbessert werden.The invention is therefore based on the object of developing the method according to DE-OS 29 21 682 in such a way that the baking properties of the activated grain and the taste acceptance of the bread to be produced therewith are further improved.

Erfindungsgemäß wird diese Aufgabe bei dem gattungsgemäßen Verfahren dadurch gelöst, daß die Konditionierungszeit mehr als neun Stunden beträgt. Besonders bevorzugte Ausführungsformen der Erfindung ergeben sich aus den Unteransprüchen.According to the invention, this object is achieved in the generic method in that the conditioning time is more than nine hours. Particularly preferred embodiments of the invention result from the subclaims.

Der Erfindung liegt die überraschende Erkenntnis zugrunde, daß es gelingt, die Backeigenschaften sowie die geschmackliche Akzeptanz weiter zu verbessern, indem abweichend von der Lehre der DE-OS 29 21 682nicht Konditionierungszeiten von zwei bis neun Stunden, sondern solche von mehr als neun Stunden verwendet werden. Es hat sich nämlich herausgestellt, daß der an sich befürchtete Effekt einer übermäßigen Enzymaktivierung bei sehr langer Konditionierungszeit, wie sie erfindungsgemäß beansprucht wird, unter den Bedingungen der Kühllagerung nicht auftritt, jedoch andererseits die erreichte Aktivierung konstant bleibt und durch den Zeiteffekt weitere positive Veränderungen in der Bildung von sogenannten Vorläufern für Geschmacksstoffe hervorruft und allgemein die Backeigenschaften deutlich verbessert werden.The invention is based on the surprising finding that it is possible to further improve the baking properties and the taste acceptance by using conditioning times of not more than two to nine hours, but instead of the teaching of DE-OS 29 21 682, of more than nine hours . It turned out that the feared effect an excessive enzyme activation with a very long conditioning time, as claimed according to the invention, does not occur under the conditions of cold storage, but on the other hand the activation achieved remains constant and, due to the time effect, causes further positive changes in the formation of so-called precursors for flavorings and, in general, the baking properties clearly be improved.

Die Erfindung wird nachstehend unter Bezugnahme auf die Zeichnung anhand von Ausführungsbeispielen erläutert. Dabei zeigt:

  • Fig. 1 ein Amylogramm eines Vergleichsversuches;
  • Fig. 2 ein Amylogramm eines Versuches mit einer Konditionierungszeit von 24 Stunden;
  • Fig. 3 ein Amylogramm eines Versuches mit einer Konditionierungszeit von 48 Stunden; und
  • Fig. 4 ein Amylogramm eines Versuches mit einer Konditionierungszeit von 72 Stunden.
The invention is explained below with reference to the drawing using exemplary embodiments. It shows:
  • 1 shows an amylogram of a comparative experiment;
  • 2 shows an amylogram of a test with a conditioning time of 24 hours;
  • 3 shows an amylogram of a test with a conditioning time of 48 hours; and
  • Fig. 4 is an amylogram of an experiment with a conditioning time of 72 hours.

Beispiel 1example 1

5 kg Weizenkörner, gereinigt, wurden in 90 Minuten bei Raumtemperatur auf einen Feuchtigkeitsgehalt des Keimlings und der Kornrandschichten von ca.40 Gew.-% mit Wasser benetzt. Anschließend wurden die Weizenkörner gasdicht in Kunststoffolie eingeschweißt und daraufhin im Wasserbad 24 Stunden lang bei 14°C konditioniert. Anschließend wurden die Getreidekörner aus der Kunststoffolie herausgenommen und 90 Minuten lang bei einer Umgebungstemperatur von 38°C auf einen Gesamt-Restwassergehalt von ca. 16 Gew.-% getrocknet.5 kg of wheat kernels, cleaned, were wetted with water in 90 minutes at room temperature to a moisture content of the seedling and the grain edge layers of about 40% by weight. The wheat grains were then sealed gas-tight in plastic film and then conditioned in a water bath at 14 ° C for 24 hours. The cereal grains were then removed from the plastic film and dried for 90 minutes at an ambient temperature of 38 ° C. to a total residual water content of approx. 16% by weight.

Die auf diese Weise behandelten Getreidekörner zeigen im Amylogramm ein Maximum von 560, während ein Vergleichsversuch, bei dem bei ansonsten gleichen Bedingungen die Konditionierungstemperatur 40°C betrug, nur ein Amylogramm-Maximum von 460 ergab. (Fig. 2 bzw. Fig. 1).The cereal grains treated in this way show a maximum of 560 in the amylogram, while a comparative experiment, in which the conditioning temperature was 40 ° C. under otherwise identical conditions, only gave an amylogram maximum of 460. (Fig. 2 and Fig. 1).

Beispiel 2Example 2

Es wurde vorgegangen wie in Beispiel 1, wobei jedoch bei gleicher Konditionierungstemperatur eine Konditionierungszeit von 48 Stunden gewählt wurde. Dabei zeigte sich ein Amylogramm-Maximum von 540 (Fig. 3). Die Verkleisterungstemperatur betrug 64°C, im Vergleich zu 62,5°C beim Vergleichsversuch (Fig. 1) und 62,5°C bei Beispiel 1 (Fig. 2).The procedure was as in Example 1, but a conditioning time of 48 hours was selected at the same conditioning temperature. An amylogram maximum of 540 was shown (FIG. 3). The gelatinization temperature was 64 ° C., compared to 62.5 ° C. in the comparative test (FIG. 1) and 62.5 ° C. in example 1 (FIG. 2).

Beispiel 3Example 3

Es wurde wie in Beispiel 2 vorgegangen, wobei aber die Konditionierungszeit 72 Stunden betrug. Das Amylogramm-Maximum betrug 580, die Verkleisterungstemperatur 62,5°C (Fig. 4).The procedure was as in Example 2, but the conditioning time was 72 hours. The maximum amylogram was 580, the gelatinization temperature 62.5 ° C (Fig. 4).

Die Ergebnisse der vorstehenden Beispiele sowie des Vergleichsversuches zeigen, daß die erfindungsgemäß durchgeführte Konditionierung bei der Temperatur von 14°C im Vergleich zu den herkömmlichen Konditionierungstemperaturen von beispielsweise 40°C eine drastische Verbesserung des relativen Aktivierungsgrades mit sich bringt. Weiterhin zeigt sich, daß auch die langen Konditionierungszeiten von 24, 48 und 72 Stunden zu keiner bedeutenden Steigerung der Enzymaktivierung führen, woraus hervorgeht, daß sich auf diese Weise optimale Aktivierungsgrade unter entsprechender Verbesserung der Backeigenschaften sowie der geschmacklichen Akzeptanz erzielen lassen.The results of the above examples and of the comparative experiment show that the conditioning carried out according to the invention at a temperature of 14 ° C. brings about a drastic improvement in the relative degree of activation compared to the conventional conditioning temperatures of, for example, 40 ° C. Furthermore, it can be seen that the long conditioning times of 24, 48 and 72 hours do not result in any lead to significant increases in enzyme activation, from which it can be seen that in this way optimal degrees of activation can be achieved with a corresponding improvement in the baking properties and in taste acceptance.

Die Verbesserung der geschmacklichen Akzeptanz des aus erfindungsgemäß aktiviertem Getreide hergestellten Brotes beruht vermutlich darauf, daß aufgrund der starken Hydratisierung der Kornrandschichten (Wassergehalt = 40 %) die Enzyme auf die Inhaltsstoffe bei dem erfindungsgemäß vorgesehenen langen Aktivierungszeiten besonders günstig einwirken können. Dabei spielt der enzymatische Abbau von höherpolymeren Kohlehydraten sowie von Proteinen eine besondere Rolle, da die hierbei anfallenden Abbauprodukte die Vorläufer von Geschmacksstoffen sind. Durchgeführte Backversuche haben den positiven Einfluß der erfindungsgemäß vorgenommenen Aktivierung auf die Brotqualität sowohl bei Weizen als auch bei Roggen einwandfrei belegt. Die unter Verwendung erfindungsgemäß aktivierter Getreidekörner hergestellten Brote waren gegenüber dem Vergleichsbrot besser gelockert und schmeckten abgerundeter. Beides ist auf die Wirkung der Enzyme sowohl während der Aktivierung als auch beim Teigbereiten und Backen zurückzuführen. Mit wachsender Aktivierungszeit wird der Brotgeschmack immer besser, ein Zeichen dafür, daß die optimierte Enzymaktivität über einen langen Zeitraum aufrechterhalten bleibt, so daß die entstandenen Enzyme optimal auf die Geschmacksstoffvorläufer einwirken können.The improvement in the taste acceptance of the bread made from cereals activated according to the invention is presumably due to the fact that, due to the strong hydration of the grain edge layers (water content = 40%), the enzymes can have a particularly favorable effect on the ingredients in the long activation times provided according to the invention. The enzymatic breakdown of higher polymer carbohydrates and proteins plays a special role here, since the breakdown products are the precursors of flavorings. Baking tests carried out have proven the positive influence of the activation carried out according to the invention on the bread quality both in wheat and in rye. The breads produced using cereal grains activated according to the invention were loosened better than the comparison bread and tasted more rounded. Both are due to the action of the enzymes during activation as well as when preparing and baking dough. As the activation time increases, the taste of bread improves, a sign that the optimized enzyme activity is maintained over a long period of time, so that the enzymes formed can have an optimal effect on the flavor precursors.

Die in der vorstehenden Beschreibung, in der Zeichnung sowie in den Ansprüchen offenbarten Merkmale der Erfindung können sowohl einzeln als auch in beliebigen Kombinationen für die Verwirklichung der Erfindung in ihren verschiedenen Ausführungsformen wesentlich sein.The features of the invention disclosed in the above description, in the drawing and in the claims can be essential both individually and in any combination for realizing the invention in its various embodiments.

Claims (4)

1. Verfahren zum hydrothermischen Aktivieren von zur Brotherstellung dienendem Getreide, bei dem die ganzen Getreidekörner auf einen Wassergehalt des Keimlings und der äußeren Kornrandschichten von ca. 40 Gew.-% angefeuchtet, in feuchtem Zustand sodann zur Konditionierung mehr als zwei Stunden bei einer Temperatur zwischen 10°C und unter 20°C gehalten und schließlich auf einen Gesamtwassergehalt von höchstens 20 Gew.-% zurückgetrocknet werden, dadurch gekennzeichnet, daß die Konditionierungszeit mehr als 9 Stunden beträgt.1. A method for hydrothermally activating cereal used for bread production, in which the whole cereal grains are moistened to a water content of the seedling and the outer grain surface layers of approx. 40% by weight, then in a moist state for conditioning for more than two hours at a temperature between 10 ° C and below 20 ° C and finally dried back to a total water content of at most 20 wt .-%, characterized in that the conditioning time is more than 9 hours. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Konditionierungszeit mindestens 24 Stunden beträgt.2. The method according to claim 1, characterized in that the conditioning time is at least 24 hours. 3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß die Konditionierungszeit mindestens 48 Stunden beträgt.3. The method according to claim 2, characterized in that the conditioning time is at least 48 hours. 4. Verfahren nach einem der vorangehenden Ansprüche, dadurch gekennzeichnet, daß die Konditionierungszeit höchstens 72 Stunden beträgt.4. The method according to any one of the preceding claims, characterized in that the conditioning time is at most 72 hours.
EP81108093A 1980-10-11 1981-10-09 Method for the hydrothermal activation of bread cereals Expired EP0049874B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81108093T ATE17660T1 (en) 1980-10-11 1981-10-09 PROCESS FOR HYDROTHERMICALLY ACTIVATING CEREALS USED FOR BREADMAKING.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3038463A DE3038463C2 (en) 1980-10-11 1980-10-11 Process for the hydrothermal activation of bread-making cereals
DE3038463 1980-10-11

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EP0049874A2 true EP0049874A2 (en) 1982-04-21
EP0049874A3 EP0049874A3 (en) 1984-03-28
EP0049874B1 EP0049874B1 (en) 1986-01-29

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993006927A1 (en) * 1991-10-04 1993-04-15 The Pillsbury Company Rapidly producing stable flour from newly harvested wheat
RU2484901C1 (en) * 2011-10-06 2013-06-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Государственный университет - учебно-научно-производственный комплекс" (ФГБОУ ВПО "Госуниверситет - УНПК") Method of hydrothermal processing of buckwheat grain
RU2672331C1 (en) * 2017-12-18 2018-11-13 Федеральное государственное бюджетное образовательное учреждение высшего образования "Алтайский государственный технический университет им. И.И. Ползунова" (АлтГТУ), отдел интеллектуальной и промышленной собственности (ОИПС) Method of hydrothermal treatment of grain

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1692752A1 (en) * 1951-01-28 1972-03-16 Rheinische Reform Und Vollkorn Process and system for processing grain for bread or flake production
DE2420910A1 (en) * 1974-04-30 1975-11-06 Alfred Batscheider PROCEDURE FOR THE NATURAL VITAMINATION OF GRAIN
US3925564A (en) * 1974-07-22 1975-12-09 Ned W Finnell Method of curing and drying wild rice
EP0019868A1 (en) * 1979-05-29 1980-12-10 Lieken-Batscheider Mühlen- und Backbetriebe GmbH Process for activating bread grain

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1692752A1 (en) * 1951-01-28 1972-03-16 Rheinische Reform Und Vollkorn Process and system for processing grain for bread or flake production
DE2420910A1 (en) * 1974-04-30 1975-11-06 Alfred Batscheider PROCEDURE FOR THE NATURAL VITAMINATION OF GRAIN
US3925564A (en) * 1974-07-22 1975-12-09 Ned W Finnell Method of curing and drying wild rice
EP0019868A1 (en) * 1979-05-29 1980-12-10 Lieken-Batscheider Mühlen- und Backbetriebe GmbH Process for activating bread grain

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993006927A1 (en) * 1991-10-04 1993-04-15 The Pillsbury Company Rapidly producing stable flour from newly harvested wheat
RU2484901C1 (en) * 2011-10-06 2013-06-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Государственный университет - учебно-научно-производственный комплекс" (ФГБОУ ВПО "Госуниверситет - УНПК") Method of hydrothermal processing of buckwheat grain
RU2672331C1 (en) * 2017-12-18 2018-11-13 Федеральное государственное бюджетное образовательное учреждение высшего образования "Алтайский государственный технический университет им. И.И. Ползунова" (АлтГТУ), отдел интеллектуальной и промышленной собственности (ОИПС) Method of hydrothermal treatment of grain

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ATE17660T1 (en) 1986-02-15
DE3038463A1 (en) 1982-07-29
EP0049874A3 (en) 1984-03-28
DE3038463C2 (en) 1982-12-09
EP0049874B1 (en) 1986-01-29

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