EP0041824A1 - Verfahren zur Herstellung elektrischer Isolierung - Google Patents

Verfahren zur Herstellung elektrischer Isolierung Download PDF

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Publication number
EP0041824A1
EP0041824A1 EP81302457A EP81302457A EP0041824A1 EP 0041824 A1 EP0041824 A1 EP 0041824A1 EP 81302457 A EP81302457 A EP 81302457A EP 81302457 A EP81302457 A EP 81302457A EP 0041824 A1 EP0041824 A1 EP 0041824A1
Authority
EP
European Patent Office
Prior art keywords
flakes
mica
coating
microns
bonding material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP81302457A
Other languages
English (en)
French (fr)
Inventor
Peter Henry Dawson
John Clifford Shaw
David Martin Summers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Associated Electrical Industries Ltd
Original Assignee
Associated Electrical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Associated Electrical Industries Ltd filed Critical Associated Electrical Industries Ltd
Publication of EP0041824A1 publication Critical patent/EP0041824A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06Applying particulate materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/34Applying different liquids or other fluent materials simultaneously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant
    • B05D2401/32Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant applied as powders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate

Definitions

  • This invention relates to a method of manufacturing electrical insulation and also to electrical insulation manufactured according to the method.
  • Mica is well known as an excellent electrical insulating material, having a very high dielectric strength, a great resistance to electric stress and discharge, excellent longevity, resistance to vibrations and is flexible.
  • One common way of using mica for electrical insulation is to lay cleaved flakes onto a backing in an overlapping pattern interspersed or subsequently infiltrated with a bonding agent.
  • the sizes of the flakes commonly used range from a few microns to 100 mm.
  • both the price and quality of the product increases sharply with the size of the flakes.
  • the backing is often in the form.of a sheet and such backing sheets carrying bonded mica flakes are generally cut into tapes which are wound around the components to be insulated. Both the labour and capital costs involved in such processes are high.
  • a method of forming electrical insulation comprises spraying both a bonding material and flakes of an insulating material onto a surface to form a mixture thereupon of the said materials, and treating the said materials to form a compact coherent layer on said surface.
  • This invention facilitates the use of very small flakes of insulating material. This is an advantage, because in the manufacture of electrically insulating coatings using flakes there is a tendency for air to be trapped in the coating to an extent dependent'on the size of the flakes. This is undesirable because the presence of air in a coating tends to promote electrical discharges at lower applied voltages than would otherwise be the case, and the trapping of air can be significant with solid bonding materials when the flake dimension approaches or exceeds 1 mm. Coatings incorporating flakes less than 200 microns in size and applied in accordance with the invention have been found to contain very little air and flakes 50 microns in size yield coatings containing virtually no air. Much larger flakes can be sprayed with liquid bonding materials.
  • a method according to the invention preferably includes electrostatic spraying, the voltage being such that the flakes of insulating material are caused to lie parallel to the said surface.
  • flakes of insulating material 50 to 100 microns in size may be sprayed at a voltage of about 35 kV and that for flakes of 200 to 400 microns in size the optimum voltage is about 15 kV.
  • a combination of electrostatic and non-electrostatic spraying may be used to great effect.
  • Electrostatic spraying tends to deposit an excessive coating on convex edges and corners whereas a non- electrostatically sprayed coating tends to deposit less at such positions relative to other surfaces.
  • Judicious use of a combination of electrostatic and non-electrostatic spraying gives a more uniform coating than may be obtained by the use of either technique alone.
  • electrostatic spraying enables coatings to be applied around and behind bodies of complex and re-entrant shape.
  • coatings in accordance with the invention are insulating there is a limit to the thickness that can be applied electrostatically. With a cold surface this is around 125 microns in one application or 200 microns with two applications. Greater thicknesses can be applied to heated surfaces. This self limiting effect provides a useful means of controlling the thickness of a coating.
  • a bonding material in accordance with the invention is conveniently a thermally curable or thermoplastic polymeric material or varnish.
  • Such materials include epoxy, acrylic and polyimide resins.
  • a mixture of a thermally curable polymer and flakes of insulating material may be treated in accordance with the invention to form a compact and flexible layer by baking it in an oven. The process may be repeated to form thick layers.
  • the insulating flakes and a suitable varnish may be simultaneously or alternately sprayed from separate spray guns to give a coating which may subsequently be hardened or cured in an oven.
  • an intimate mixture of insulating flakes and an appropriate polymeric material in powdered form may be sprayed as previously stated onto a pre-heated surface so that the coating flows out while being sprayed and may thereby be partially or wholly cured.
  • When necessary complete curing may be achieved by subsequent heating in an oven. Spraying onto a heated surface may provide coatings up to 1 mm thick or thicker with repeat coatings.
  • An insulating material which is available.as thin flakes and is particularly suitable for use in accordance with this invention is mica.
  • the optimum proportion by weight of polymer to mica has been found to lie in the range of 1 to 4 parts of polymer to each part of mica..
  • Electrical insulation in accordance with the invention may be formed as a coating directly onto a substrate which is desired to be insulated, or may be applied to a flexible backing such as woven glass . cloth or plastics sheet which can be subsequently applied to a surface requiring insulation.
  • the backing can be cut into strips or other shapes before application to said surface as may be appropriate.
  • the initial coating will, in general be relatively flexible, and in the case where the binder is thermally curable, it is conveniently left in an uncured or semi-cured state for applying to a component requiring insulation, curing or completion of curing, as the case may be, being effected after its application.
  • additives to the coating mixture may also be used to modify the mechanical or other properties of the formed coating.
  • glass fibre may be added to increase the mechanical strength of the coating.
  • finely divided silica may be used as an additive to increase the hardness and abrasion resistance of the coating.
  • An insulating coating may alternatively be . formed on a non-stick mould from which it is removed after being hardened so that the finished coating may subsequently be relocated as desired.
  • Alumina or other mineral fillers in the form of thin flakes may be used in place of or additionally to mica for forming electrical insulation in accordance with the invention.
  • a powder composite was prepared by ball milling for 16 hours a mixture of epoxy resin powder containing curing, heat stablising and flow agents appropriate to the resin and mica, the latter having a flake size of 100 microns across and 4 microns thick.
  • the particle size of the epoxy resin powder was in the range 50 to 150 ⁇ m and the mass ratio of mica flake to epoxy powder was 1 to 2.
  • the composite mixture as prepared above was sprayed onto an earthed, cold 3.5 x 15 mm copper armature conductor, using an air assisted electrostatic powder spray unit, to form a coating of insulation on the conductor.
  • a charging voltage of 35 kV was employed with 17 kPa pressure air assistance.
  • the thickness of the coating was self limiting.
  • the armature conductor was, within 5 minutes of spraying, passed through a convection oven at 200 C for 15 minutes to fuse and cure the coating.
  • the fully cured coating had a thickness of 100 microns and retained sufficient flexibility to withstand a 180° bend around a radius of 25 mm.
  • the coil was, within 5 minutes of spraying, passed .through a convection oven for 15 minutes at 80°C to fuse the coating.
  • the components were then clamped together to form the final winding and cured for 15 minutes at 200°C.
  • the final layer between turns had a thickness of 312 microns and was able to withstand applied voltages up to 7 kV without failure (221 ⁇ 2 MV/m).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Insulating Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Insulation, Fastening Of Motor, Generator Windings (AREA)
  • Inorganic Insulating Materials (AREA)
  • Organic Insulating Materials (AREA)
EP81302457A 1980-06-11 1981-06-03 Verfahren zur Herstellung elektrischer Isolierung Withdrawn EP0041824A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8019114 1980-06-11
GB8019114 1980-06-11

Publications (1)

Publication Number Publication Date
EP0041824A1 true EP0041824A1 (de) 1981-12-16

Family

ID=10513974

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81302457A Withdrawn EP0041824A1 (de) 1980-06-11 1981-06-03 Verfahren zur Herstellung elektrischer Isolierung

Country Status (3)

Country Link
EP (1) EP0041824A1 (de)
JP (1) JPS5734608A (de)
GB (1) GB2077625A (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2576545A1 (fr) * 1985-01-29 1986-08-01 Gle Produits Indls Exploit Procede de fabrication d'un materiau isolant electrique souple et materiau isolant electrique souple obtenu par ce procede
FR2690559A1 (fr) * 1992-04-27 1993-10-29 Udd Fim Sa Procédé d'isolation d'un conducteur électrique et conducteur électrique isolé tel qu'obtenu par la mise en Óoeuvre du procédé.
FR2715331A1 (fr) * 1994-01-24 1995-07-28 Packart Procédé de traitement de surface, ainsi que ses applications.
CN102514345A (zh) * 2011-12-12 2012-06-27 江苏冰城电材股份有限公司 一种云母带的制造方法
CN104354451A (zh) * 2011-12-12 2015-02-18 江苏冰城电材股份有限公司 一种高压发电机和高压电动机用的云母带的制造方法
CN104409187A (zh) * 2011-12-12 2015-03-11 江苏冰城电材股份有限公司 一种适于节能减排和减少环境污染的云母带的制造方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59139548A (ja) * 1982-11-17 1984-08-10 Toshiba Battery Co Ltd アルカリ電池の製造法
GB8406951D0 (en) * 1984-03-16 1984-04-18 Micanite & Insulators Co Ltd Electrical insulating material
JPS62154794A (ja) * 1985-12-27 1987-07-09 ノードソン株式会社 実装回路板への防湿絶縁剤の被覆方法
JP2008154280A (ja) * 2008-03-11 2008-07-03 Matsushita Electric Ind Co Ltd バイアス回路

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3546017A (en) * 1967-11-07 1970-12-08 Anaconda Wire & Cable Co Electrodeposition of particulate coating material
US3617379A (en) * 1968-08-05 1971-11-02 Annaconda Wire And Cable Co Electrical insulation coating containing particles of inorganic substance of dielectric constant no less than 1500
US4095557A (en) * 1974-11-26 1978-06-20 Westinghouse Electric Corp. Apparatus for making electrical coils using patterned dry resin coated sheet insulation
GB1558163A (en) * 1976-06-04 1979-12-19 Norsk Hydro As Insulating coatings

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3546017A (en) * 1967-11-07 1970-12-08 Anaconda Wire & Cable Co Electrodeposition of particulate coating material
US3617379A (en) * 1968-08-05 1971-11-02 Annaconda Wire And Cable Co Electrical insulation coating containing particles of inorganic substance of dielectric constant no less than 1500
US4095557A (en) * 1974-11-26 1978-06-20 Westinghouse Electric Corp. Apparatus for making electrical coils using patterned dry resin coated sheet insulation
GB1558163A (en) * 1976-06-04 1979-12-19 Norsk Hydro As Insulating coatings

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2576545A1 (fr) * 1985-01-29 1986-08-01 Gle Produits Indls Exploit Procede de fabrication d'un materiau isolant electrique souple et materiau isolant electrique souple obtenu par ce procede
EP0192523A1 (de) * 1985-01-29 1986-08-27 Societe D'exploitation Generale De Produits Industriels (S.E.G.) Biegsames elektrisches Isolierungsmaterial und Verfahren zu dessen Herstellung
FR2690559A1 (fr) * 1992-04-27 1993-10-29 Udd Fim Sa Procédé d'isolation d'un conducteur électrique et conducteur électrique isolé tel qu'obtenu par la mise en Óoeuvre du procédé.
EP0568415A1 (de) * 1992-04-27 1993-11-03 Udd-Fim S.A. Isolierungsverfahren eines elektrischen Leiters und isolierter elektrischer Daht hergestellt nach diesem Verfahren
FR2715331A1 (fr) * 1994-01-24 1995-07-28 Packart Procédé de traitement de surface, ainsi que ses applications.
CN102514345A (zh) * 2011-12-12 2012-06-27 江苏冰城电材股份有限公司 一种云母带的制造方法
CN102514345B (zh) * 2011-12-12 2014-12-24 江苏冰城电材股份有限公司 一种云母带的制造方法
CN104354451A (zh) * 2011-12-12 2015-02-18 江苏冰城电材股份有限公司 一种高压发电机和高压电动机用的云母带的制造方法
CN104409187A (zh) * 2011-12-12 2015-03-11 江苏冰城电材股份有限公司 一种适于节能减排和减少环境污染的云母带的制造方法

Also Published As

Publication number Publication date
JPS5734608A (en) 1982-02-25
GB2077625A (en) 1981-12-23

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PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

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AK Designated contracting states

Designated state(s): AT BE CH DE FR IT

STAA Information on the status of an ep patent application or granted ep patent

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18D Application deemed to be withdrawn

Effective date: 19821121

RIN1 Information on inventor provided before grant (corrected)

Inventor name: SHAW, JOHN CLIFFORD

Inventor name: SUMMERS, DAVID MARTIN

Inventor name: DAWSON, PETER HENRY