EP0035899A2 - Composition de conditionnement des cheveux et méthode de conditionnement des cheveux avec celle-ci - Google Patents

Composition de conditionnement des cheveux et méthode de conditionnement des cheveux avec celle-ci Download PDF

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Publication number
EP0035899A2
EP0035899A2 EP81300968A EP81300968A EP0035899A2 EP 0035899 A2 EP0035899 A2 EP 0035899A2 EP 81300968 A EP81300968 A EP 81300968A EP 81300968 A EP81300968 A EP 81300968A EP 0035899 A2 EP0035899 A2 EP 0035899A2
Authority
EP
European Patent Office
Prior art keywords
hair conditioning
hair
composition according
conditioning agent
volatile liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81300968A
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German (de)
English (en)
Other versions
EP0035899A3 (en
EP0035899B1 (fr
Inventor
Raymond Edward Bolich, Jr.
Lloyd Bruch Hartsough
Philip Earl Cothran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority claimed from US06/234,297 external-priority patent/US4374825A/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AT81300968T priority Critical patent/ATE7653T1/de
Publication of EP0035899A2 publication Critical patent/EP0035899A2/fr
Publication of EP0035899A3 publication Critical patent/EP0035899A3/en
Application granted granted Critical
Publication of EP0035899B1 publication Critical patent/EP0035899B1/fr
Expired legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic

Definitions

  • the present invention is related to hair conditioning compositions which can condition hair while not leaving an undesirable residue.
  • Some hair is naturally difficult to manage and to comb in the wet state, while other types of hair have become so as a result of the various treatments to which the hair has been subjected, such treatments including permanent waving, dyeing, tinting, frequent teasing, exposure to various atmospheric conditions, etc.
  • Hair that has been subjected to an oxidizing condition e.g. treatments with hydrogen peroxide or atmospheric oxygen photocatalyzed by sunlight, is especially difficult to comb in the wet state.
  • cream rinse products which provide good wet-combing of the hair contain quaternary ammonium compounds. Their use produces a dilemma, their effectiveness as a wet-combing aid is proportional to the amount of cream rinse retained on the hair but the rate at which the hair appears and feels dirty is also proportional to that amount.
  • U.S. Patent 3,577,528, May 4, 1971 to McDonough discloses two phase hair conditioners comprising an aqueous phase which contains a quaternary compound and a hydrocarbon or fluorinated hydrocarbon water immiscible phase.
  • Rudy et al in U.S. Patent 3,932,610, January 13, 1976 discloses a shampoo composition which may contain a volatile hydrocarbon solvent.
  • U.S. Patent 3,818,105, June 18, 1974 to Coopersmith et al discloses hair conditioners containing a C12 to C 14 isoparaffinic hydrocarbon fraction.
  • South African Patent Application 666421, April 12, 1967, Dasher and Fainer discloses hair conditoners containing volatile silicones.
  • compositions which contain components of the type present in the compositions of the present invention they are not entirely satisfactory, either lacking in stability or performance.
  • the present invention relates to hair conditioning compositions in the form of emulsions comprising from about 1% to about 13% of a volatile liquid hydrocarbon or silicone hair conditioning agent, from about 0.1% to about 8% of a substantially nonionic, water soluble thickening agent, from about 0.05% to about 4% of a cationic hair conditioning agent and water.
  • compositions of the present invention comprise the above described essential components and may additionally contain several optional components. Each of the components is discussed in detail below.
  • the hydrocarbon and silicone agents useful in the present compositions have a boiling point in the range of about 99°C. to about 260°C. and have a solubility in water of less than about 0.1%.
  • the hydrocarbons may be either straight or branched chain and may contain from about 10 to about 16, preferably from about 12 to about 16 carbon atoms. Examples of suitable hydrocarbons are decane, dodecane, tetradecane, tridecane and mixtures thereof.
  • the volatile silicones useful in the compositions of the present invention may be either a cyclic or a linear polydimethylsiloxane.
  • the number of silicon atoms in the cyclic silicones is preferably from about 3 to about 7, more preferably 4 or 5.
  • the general formula for such silicones is
  • the linear volatile silicones generally have viscosities of less than about 5 centistokes at 25°C. while the cyclic materials have viscosities less than about 10 centistokes.
  • Volatile means that the material has a measurable vapor pressure. A description of volatile silicones is found in Todd and Byers, "Volatile Silicone Fluids for Cosmetics", Cosmetics and Toiletries, Vol. 91, January, 1976, pp. 27 - 32, incorporated herein by reference.
  • the volatile agent is present in the compositions of this invention at a level of from about 1% to about 13%, preferably from about 2% to about 10%.
  • the volatile silicones are the preferred volatile agents.
  • the water soluble thickening agent useful in the present compositions is a substantially nonionic water soluble polymer.
  • the polymers are those which exhibit viscosities exceeding about 200 poises at low shear, about 10 -2 sec -1 , when their viscosities at 500 sec are less than about 9 poises.
  • Preferred are those polymers which show about a 100 fold increase in viscosity over the shear rate range of 500 to 10 -2 sec -1 .
  • polymers include polyoxyethylene, guar gum, methylcellulose, methyl hydroxypropyl cellulose, polypropyl hydroxyethyl cellulose, locust bean gum, hydroxypropyl guar gum, hydroxypropyl cellulose, starches and starch derivatives such as hydroxyethyl amylose and starch amylose and mixtures thereof.
  • Preferred polymers are guar gum and hydroxypropyl guar gum.
  • the water soluble thickening agent is present in the present compositions at a level of from about 0.1% to about 8%, preferably from about 0.5% to about 6.0%.
  • the cationic hair conditioning agent of the present compositions may be either a quaternary ammonium salt or the salt of a fatty amine.
  • Quaternary ammonium salts have the formula: Wherein R 1 is hydrogen, an aliphatic group of from 1 to 22 carbon atoms, or aromatic, aryl or alkaryl groups having from 12 to 22 carbon atoms; R 2 is an aliphatic group having 1 - 22 carbon atoms; R 3 and R 4 are each alkyl groups of from 1 to 3 carbon atoms, and X is an anion selected from halogen, acetate, phosphate, nitrate and methyl sulfate radicals.
  • the aliphatic groups may contain, in addition to carbon and hydrogen atoms, ether linkages as well as amido groups among other groups.
  • Preferred quaternary ammonium salts are the dialkyl dimethyl ammonium chlorides, wherein the alkyl groups have from 12 to 22 carbon atoms and are derived from long-chain fatty acids, such as hydrogenated tallow.
  • tallow refers to fatty alkyl groups derived from tallow fatty acids. Such fatty acids give rise to quaternary compounds wherein R 1 and R 2 have predominately from 16 to 18 carbon atoms.
  • the term "coconut” refers to fatty acid groups from coconut oil fatty acids. The coconut-alkyl R 1 and R 2 groups have from about 8 to about 18 carbon atoms and predominate in C 12 to C 14 alkyl groups.
  • quaternary ammonium salts of the invention include ditallow dimethyl ammonium chloride; ditallow dimethyl ammonium methyl sulfate; dihexadecyl dimethyl ammonium chloride; di(hydrogenated tallow) dimethyl ammonium chloride; dioctadecyl dimethyl ammonium chloride; dieicosyl dimethyl ammonium chloride; didocosyl dimethyl ammonium chloride; di(hydrogenated tallow) dimethyl ammonium acetate; dihexadecyl diethyl ammonium chloride; dihexadecyl dimethyl ammonium acetate; ditallow dipropyl ammonium phosphate; ditallow dimethyl ammonium nitrate; di(coconutalkyl)dimethyl ammonium chloride; and stearyl dimethyl benzyl ammonium chloride.
  • quaternary ammonium salts useful herein are the compounds of the formula wherein R 1 is an aliphatic group having 16 to 22 carbon atoms, R 2 , R 3 , R4, R 5 and R 6 are the same or different and are selected from H and alkyls having 1 - 4 carbon 'atoms and X is an anion as above defined.
  • R 1 is an aliphatic group having 16 to 22 carbon atoms
  • R 2 , R 3 , R4, R 5 and R 6 are the same or different and are selected from H and alkyls having 1 - 4 carbon 'atoms and X is an anion as above defined.
  • Tallow propanediammonium dichloride is an example of this quaternary ammonium salt.
  • Quaternary imidazolinium salts have the formula wherein R 6 is an alkyl group containing from 1 to 4, preferably from 1 to 2 carbon atoms, R 5 is an alkyl group containing from 1 to 4 carbon atoms or a hydrogen radical, R 8 is an alkyl group containing from 1 to 22, preferably at least 15 carbon atoms or a hydrogen radical, R 7 is an alkyl group containing from 8 to 22, preferably at least 15 carbon atoms, and X is an anion, preferably chloride.
  • Other suitable anions include those disclosed with reference to the quaternary ammonium salts described hereinbefore.
  • R 7 and R 8 are alkyls of from 12 to 22 carbon atoms, e.g., 1-methyl-l- [(stearoylamide)ethyl)] -2-heptadecyl-4, 5-dihydroimidazolinium chloride; 1-methyl-l-[(palmitoylqmide)ethyl] -2-octadecyl-4,5-dihydroimidazolinium chloride and 1-methyl-1-[(tallowamide)-ethyl] -2-tallow-imidazolinium methyl sulfate.
  • a suitable hair conditioner herein are salts of fatty amines.
  • the amines may be primary, secondary or tertiary but the alkyl, substituted and unsubstituted groups preferably have from 12 - 22 carbon atoms. Preferred are the primary and secondary amines with the primary being the most preferred. Diamines having a long chain alkyl group may also be used.
  • amines suitable for use include dimethyl stearamine, dimethyl soyamine, stearylamine, soyamine, myristylamine, tridecylamine, ethyl stearylamine, N-tallow propanediamine, ethoxylated (5 moles E.O.) stearylamine dihydroxyethyl stearylamine and arachidylbehenylamine.
  • the anions of the salts include those mentioned previously for the quaternary ammonium salts.
  • Specific amine salts include stearylamine hydrochloride, soyamine chloride, stearylamine formate and N-tallow propanediamine dichloride.
  • the cationic hair conditioning agent is present at a level of from about 0.05% to about 4%, preferably from about 0.1% to about 2%, in the compositions of the instant invention.
  • Water preferably, distilled water is the final essential component of the present compositions. Water makes up the remainder of the compositions and is generally present at a level of up to about 95%, preferably from about 75% to about 90%.
  • the present compositions may contain a wide variety of optional components.
  • the optional components can be materials which are soluble in the volatile agent phase, in the aqueous phase or not soluble in either phase.
  • hydrophobic polymers such as polyvinyl isobutyl ether, waxes such as cetyl alcohol and paraffin, and oils such as mineral oil, isopropyl myristate and non-volatile silicones.
  • Agents which are soluble in the aqueous phase include acrylamide and polyoxyethylene resins.
  • dyes include dyes, perfumes, opacifiers, pearlescent aids, buffers, preservatives, antioxidants, and antidandruff aids such as zinc pyrithione and sulfur.
  • the approach selected should provide particles of the volatile agent in the range of from about 1 to about 10 microns. This can be accomplished by adding the volatile agent phase to the aqueous phase or vice versa. Suitable processes are shown in the Examples.
  • the hair conditioning compositions of the present invention are preferably used as a rinse on freshly shampooed hair.
  • the compositions are used in an amount of from about lg. to about 60g., preferably from about 5g. to about 30g. and is then rinsed from the hair.
  • the above composition was prepared by dispersing 10 grams of Jaguar HP-60 in 926 grams of distilled water using a Lightnin® Mixer. The mixture was heated to about 65°C. to fully dissolve and hydrate the Jaguar gum. Four grams of Adogen 432 were then added and dispersed. The silicone fluid was added next and dispersed. A high shear mixer, an Ultra Turrax® Model 45S4 dispersator supplied by Tekmer Company, was finally used to further reduce the silicone particle size to about 1 to about 10 microns. The formaldehyde was added as the batch cooled to room temperature.
  • composition of the present invention is prepared in a manner similar to that described in Example I.
  • composition of the present invention is prepared in a manner similar to that described in Example I.
  • composition is prepared in a manner similar to that described in Example I except that the silicone and the Lutonal are preblended.
  • the above composition was prepared by placing 76.08 grams of the volatile silicone, 400 grams of distilled water and 4 grams of a stock solution consisting of 2% Lutonal 1C 115 in volatile silicone into a mix tank.
  • the stock solution had been prepared earlier by dissolving 2 grams of the ether in 98 grams of the volatile silicone and mixing with a magnetic stirrer for 24 hours.
  • a pre-mix was prepared by dispersing 2.4 grams of the quaternary and 11 grams of Jaguar HP-60 in 80 grams of ethanol. This was mixed with a magnetic stirrer for 10 minutes at ambient temperature. This pre-mix was then added to the main mix tank and sheared with a Ultra T urrax Model 45S4 for five minutes. To the batch were then added 421 grams of distilled water and 5 grams of perfume.
  • a Lightnin R mixer was used to complete mixing the batch for 15 minutes.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP19810300968 1980-03-10 1981-03-09 Composition de conditionnement des cheveux et méthode de conditionnement des cheveux avec celle-ci Expired EP0035899B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81300968T ATE7653T1 (de) 1980-03-10 1981-03-09 Mittel und verfahren zum konditionieren der haare.

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US12843680A 1980-03-10 1980-03-10
US128436 1980-03-10
US21837680A 1980-12-22 1980-12-22
US218376 1980-12-22
US234297 1981-02-17
US06/234,297 US4374825A (en) 1980-12-22 1981-02-17 Hair conditioning compositions

Publications (3)

Publication Number Publication Date
EP0035899A2 true EP0035899A2 (fr) 1981-09-16
EP0035899A3 EP0035899A3 (en) 1982-02-17
EP0035899B1 EP0035899B1 (fr) 1984-05-30

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EP19810300968 Expired EP0035899B1 (fr) 1980-03-10 1981-03-09 Composition de conditionnement des cheveux et méthode de conditionnement des cheveux avec celle-ci

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EP (1) EP0035899B1 (fr)
CA (1) CA1155397A (fr)
DE (1) DE3163816D1 (fr)
ES (1) ES8305580A1 (fr)
GR (1) GR74051B (fr)
IE (1) IE51031B1 (fr)
PH (1) PH16210A (fr)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2510403A1 (fr) * 1981-07-29 1983-02-04 Curtis Helene Ind Inc Compositions de mise en forme des cheveux contenant des silicones volatils
DE3247992A1 (de) * 1981-12-30 1983-07-07 Colgate-Palmolive Co., 10022 New York, N.Y. Fluessiges hautreinigungsmittel
EP0208533A2 (fr) * 1985-07-10 1987-01-14 The Procter & Gamble Company Compositions de shampooing et leur utilisation
DE3719293A1 (de) * 1986-06-17 1987-12-23 Colgate Palmolive Co Konditionierende haarspuelung
US4782095A (en) * 1984-02-22 1988-11-01 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates
FR2616658A1 (fr) * 1987-06-17 1988-12-23 Colgate Palmolive Co Composition de conditionnement capillaire pour emploi au rincage a base d'un compose ammonium quaternaire
US4801447A (en) * 1984-02-22 1989-01-31 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same
US4880563A (en) * 1985-08-01 1989-11-14 Deutsche Ici Gmbh Composition for personal care product comprising alkoxylated fatty alcohol and polysiloxane
US5085857A (en) * 1989-12-04 1992-02-04 Chesebrough-Pond's Usa Co. Conditioning shampoo comprising a surfactant, a non-volatile silicone oil and guar hydroxypropyltrimonium chloride as a cationic conditioning polymer
EP0642782A2 (fr) * 1993-08-30 1995-03-15 Helene Curtis, Inc. Composition de shampooing-conditionneur
US5439673A (en) * 1992-03-02 1995-08-08 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Hair care composition
FR2765479A1 (fr) * 1997-07-02 1999-01-08 Oreal Composition lavantes et conditionnantes a base de silicone et de gomme de galactomannane hydrophobe
US6586378B2 (en) 1999-12-20 2003-07-01 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Aqueous hair styling compositions
WO2008064976A1 (fr) * 2006-12-02 2008-06-05 Unilever Plc Compositions apres-shampooing
EP0859581B2 (fr) † 1995-09-29 2009-10-14 L'oreal Composition pour le traitement des matieres keratiniques comprenant au moins un polymere silicone greffe, a squelette polysiloxanique greffe par des monomeres organiques non-silicones et au moinsun hydrocarbure liquide en c 11-c 26
FR2954108A1 (fr) * 2009-12-23 2011-06-24 Oreal Utilisation d'une composition cosmetique contenant un alcane lineaire volatil et un polymere associatif non ionique pour le conditionnement des cheveux
FR2954109A1 (fr) * 2009-12-23 2011-06-24 Oreal Utilisation pour le traitement cosmetique des fibres keratiniques d'alcane(s) lineaire(s) volatil(s), d'alcool(s) gras solide(s) et d'epaississant(s) polymerique(s) a motif sucres
FR2954112A1 (fr) * 2009-12-23 2011-06-24 Oreal Composition cosmetique comprenant au moins un alcane lineaire volatil, au moins un tensioactif cationique dans un rapport alcane(s) lineaire(s) volatil(s)/tensioactif(s) cationique(s) particulier
CN111032013A (zh) * 2017-08-10 2020-04-17 花王株式会社 毛发化妆品

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6322778B1 (en) 1998-02-10 2001-11-27 Johnson & Johnson Consumer Companies, Inc. Hair conditioning compositions comprising a quaternary ammonium compound

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3577528A (en) 1966-05-27 1971-05-04 Zotos Int Inc Two phase hair conditioner compositions
US3818105A (en) 1971-08-23 1974-06-18 Exxon Research Engineering Co Composition and process for lubricating the skin
US3932610A (en) 1971-12-06 1976-01-13 Lever Brothers Company Shampoo composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3697644A (en) * 1966-10-18 1972-10-10 Gillette Co Cosmetic composition
US3964500A (en) * 1973-12-26 1976-06-22 Lever Brothers Company Lusterizing shampoo containing a polysiloxane and a hair-bodying agent
GB2025228A (en) * 1978-05-18 1980-01-23 Unilever Ltd Hair treatment compositions
JPH1195473A (ja) * 1997-09-17 1999-04-09 Canon Inc 電子写真感光体、プロセスカートリッジ及び電子写真装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3577528A (en) 1966-05-27 1971-05-04 Zotos Int Inc Two phase hair conditioner compositions
US3818105A (en) 1971-08-23 1974-06-18 Exxon Research Engineering Co Composition and process for lubricating the skin
US3932610A (en) 1971-12-06 1976-01-13 Lever Brothers Company Shampoo composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
TODD; BYERS: "Volatile Silicone Fluids for Cosmetics", COSMETICS AND TOILETRIES, vol. 91, January 1976 (1976-01-01), pages 27 - 32

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3228444A1 (de) * 1981-07-29 1983-02-17 Helene Curtis Industries Inc., 60659 Chicago, Ill. Haarpflegemittel
FR2510403A1 (fr) * 1981-07-29 1983-02-04 Curtis Helene Ind Inc Compositions de mise en forme des cheveux contenant des silicones volatils
DE3247992A1 (de) * 1981-12-30 1983-07-07 Colgate-Palmolive Co., 10022 New York, N.Y. Fluessiges hautreinigungsmittel
US4782095A (en) * 1984-02-22 1988-11-01 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates
US4801447A (en) * 1984-02-22 1989-01-31 Union Carbide Corporation Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same
EP0208533A3 (en) * 1985-07-10 1987-08-19 The Procter & Gamble Company Shampoo compositions and use thereof
EP0208533A2 (fr) * 1985-07-10 1987-01-14 The Procter & Gamble Company Compositions de shampooing et leur utilisation
US4880563A (en) * 1985-08-01 1989-11-14 Deutsche Ici Gmbh Composition for personal care product comprising alkoxylated fatty alcohol and polysiloxane
DE3719293A1 (de) * 1986-06-17 1987-12-23 Colgate Palmolive Co Konditionierende haarspuelung
FR2616658A1 (fr) * 1987-06-17 1988-12-23 Colgate Palmolive Co Composition de conditionnement capillaire pour emploi au rincage a base d'un compose ammonium quaternaire
BE1005555A5 (fr) * 1987-06-17 1993-10-26 Colgate Palmolive Co Composition de conditionnement capillaire pour emploi au rincage a base d'un compose ammonium quaternaire.
US5085857A (en) * 1989-12-04 1992-02-04 Chesebrough-Pond's Usa Co. Conditioning shampoo comprising a surfactant, a non-volatile silicone oil and guar hydroxypropyltrimonium chloride as a cationic conditioning polymer
US5439673A (en) * 1992-03-02 1995-08-08 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Hair care composition
EP0642782A2 (fr) * 1993-08-30 1995-03-15 Helene Curtis, Inc. Composition de shampooing-conditionneur
EP0642782A3 (fr) * 1993-08-30 1997-07-09 Curtis Helene Ind Inc Composition de shampooing-conditionneur.
EP0859581B2 (fr) † 1995-09-29 2009-10-14 L'oreal Composition pour le traitement des matieres keratiniques comprenant au moins un polymere silicone greffe, a squelette polysiloxanique greffe par des monomeres organiques non-silicones et au moinsun hydrocarbure liquide en c 11-c 26
WO1999001105A1 (fr) * 1997-07-02 1999-01-14 L'oreal Compositions lavantes et conditionnantes a base de silicone et de gomme de galactomannane hydrophobe
FR2765479A1 (fr) * 1997-07-02 1999-01-08 Oreal Composition lavantes et conditionnantes a base de silicone et de gomme de galactomannane hydrophobe
US6586378B2 (en) 1999-12-20 2003-07-01 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Aqueous hair styling compositions
WO2008064976A1 (fr) * 2006-12-02 2008-06-05 Unilever Plc Compositions apres-shampooing
EP2338468A1 (fr) * 2009-12-23 2011-06-29 L'Oréal Composition cosmétique comprenant au moins un alcane linéaire volatil, au moins un tensioactif cationique dans un rapport alcane(s) linéaire(s) volatil(s) tensioactif(s) cationique(s) particulier
FR2954109A1 (fr) * 2009-12-23 2011-06-24 Oreal Utilisation pour le traitement cosmetique des fibres keratiniques d'alcane(s) lineaire(s) volatil(s), d'alcool(s) gras solide(s) et d'epaississant(s) polymerique(s) a motif sucres
FR2954112A1 (fr) * 2009-12-23 2011-06-24 Oreal Composition cosmetique comprenant au moins un alcane lineaire volatil, au moins un tensioactif cationique dans un rapport alcane(s) lineaire(s) volatil(s)/tensioactif(s) cationique(s) particulier
FR2954108A1 (fr) * 2009-12-23 2011-06-24 Oreal Utilisation d'une composition cosmetique contenant un alcane lineaire volatil et un polymere associatif non ionique pour le conditionnement des cheveux
EP2338469A1 (fr) * 2009-12-23 2011-06-29 L'Oréal Utilisation d'une composition cosmétique contenant un alcane linéaire volatil et un polymère associatif non ionique pour le conditionnement des cheveux
EP2361605A1 (fr) * 2009-12-23 2011-08-31 L'Oréal Utilisation pour le traitement cosmétique des fibres keratiniques d'alcane(s) linéaire(s) volatil(s), d'alcool(s) gras solide(s) et d'épaississant(s) polymérique(s) a motifs sucres
US9566220B2 (en) 2009-12-23 2017-02-14 L'oreal Composition containing a volatile linear alkane and a nonionic associative polymer, useful for conditioning the hair
EP3207918A1 (fr) * 2009-12-23 2017-08-23 L'oreal Utilisation d'une composition cosmétique contenant un alcane linéaire volatil et un polymère associatif non ionique pour le conditionnement des cheveux
EP2361605B1 (fr) 2009-12-23 2018-01-24 L'Oréal Utilisation pour le traitement cosmétique des fibres keratiniques d'alcane(s) linéaire(s) volatil(s), d'alcool(s) gras solide(s) et d'épaississant(s) polymérique(s) a motifs sucres
CN111032013A (zh) * 2017-08-10 2020-04-17 花王株式会社 毛发化妆品
EP3666252A4 (fr) * 2017-08-10 2021-05-26 Kao Corporation Produit cosmétique pour les cheveux
TWI786154B (zh) * 2017-08-10 2022-12-11 日商花王股份有限公司 毛髮化妝料

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ES500227A0 (es) 1983-04-16
GR74051B (fr) 1984-06-06
CA1155397A (fr) 1983-10-18
ES8305580A1 (es) 1983-04-16
IE810500L (en) 1981-09-10
EP0035899A3 (en) 1982-02-17
DE3163816D1 (en) 1984-07-05
EP0035899B1 (fr) 1984-05-30
PH16210A (en) 1983-08-05
IE51031B1 (en) 1986-09-17

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