EP0035131B1 - Electrode métallique dégageant du gaz pour procédés électrochimiques - Google Patents
Electrode métallique dégageant du gaz pour procédés électrochimiques Download PDFInfo
- Publication number
- EP0035131B1 EP0035131B1 EP81100858A EP81100858A EP0035131B1 EP 0035131 B1 EP0035131 B1 EP 0035131B1 EP 81100858 A EP81100858 A EP 81100858A EP 81100858 A EP81100858 A EP 81100858A EP 0035131 B1 EP0035131 B1 EP 0035131B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- rods
- rectangle
- plane
- anode
- cross
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 9
- 239000002184 metal Substances 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims abstract description 6
- 229910000497 Amalgam Inorganic materials 0.000 claims abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000010936 titanium Substances 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
Definitions
- the invention relates to a gas-developing metal electrode for electrochemical processes, in particular coated titanium anode for amalgam cells, consisting of rods arranged in a horizontal plane at a distance from one another and parallel to one another, the surfaces of which form the working surface of the electrode and which have a cross section, the extent of which is vertical to the plane is larger than parallel to it.
- Gas-evolving, horizontally arranged metal electrodes usually the anode, to which a counter electrode, also horizontally arranged, and the cathode, is arranged, must meet several criteria.
- the first criterion is the requirement to remove the gas developed at the anode as quickly as possible.
- the anode must have a free area in the horizontal arrangement plane, ie interruptions or the like, through which the gas developing on the underside of the anode can escape upwards.
- This free area of the anode should be as large as possible. Based on experience, this free area should be 2: approx. 33% of the projected area of the anode, which is formed by the length times the width of the area occupied by the anode in the horizontal plane.
- edges such as. B. rectangular or triangular profiles
- the second criterion is therefore the measure to use a bar profile that has no sharp edges. Taking this condition into account, too, one has switched to bars with a circular cross section.
- the proportion of the area of the anode that runs parallel to the cathode should be as small as possible so that the free area for discharging the gas is as large as possible, a proportion of the working area must extend perpendicular to the plane of the anode. Based on experience, the difference between the closest and furthest point of the working surface with respect to the cathode should be a maximum of 2.0 mm. In this area, therefore, the coating on the carrier, i. H. the rods or the like may be applied.
- Another criterion is that the proportion of the working area of the anode, which from the point of view of the cathode lies in the current shadow, should be as small as possible.
- the radius of the round bars must be taken into account as a further limit value for the portion of the working surface which runs perpendicular to the anode plane.
- GB-A-1 068 992, Fig. 4b shows a relevant anode made of U-shaped profile plates.
- this anode is based on the task of improving the gas removal due to the largest possible free area, it is necessary to arrange the profile plates relatively close to one another in order to achieve a high current density, because the cross section of the individual profile plates is relatively small due to the desired small width , whereby the gas removal is deteriorated again.
- rods each have a full cross section with the shape of an oval, which is composed of a rectangle, the broad side of which runs parallel to the plane, and two segments, whose chord length corresponds to the broad side of the rectangle and which each connect with a chord to a broad side of the rectangle.
- the inventive design of the rods with a cross section in the manner of an oval ensures an increase in the distance between the individual rods and thus an increase in the free area of the anode with the result of an improved discharge of the gas generated at the anode during operation compared to anodes with round rods.
- the anode according to the invention is therefore particularly suitable for amalgam cells working with relatively high currents and thus high current densities, since the gas evolution which is likewise increased at increased current densities can be controlled.
- the proportion of the working surface running perpendicular to the arrangement plane of the rods is simultaneously increased in comparison with the round rods, and the proportion of the working surface lying in the current shadow from the point of view of the cathode is also reduced.
- the design of the rods according to the invention has the advantage that they have no edges of this type which cause increased wear on the coating.
- the cross section according to the invention can be easily, starting from a round material, for. B. by a drawing or rolling process.
- the segment of the cross section of the bars is a circular segment.
- the round material only has to be flattened on two opposite sides.
- the metal electrode according to the invention consists of rods 1 arranged in a horizontal plane at a distance from one another and parallel to one another. These rods 1 are connected both mechanically and electrically to current supply rails 2 which are spaced apart and parallel to one another and perpendicular to the bars are arranged on the top.
- the power supply rails 2 are either directly or via cross rails 3 with a power supply bolt 4 electrically conductive and optionally also mechanically connected.
- the cross-section of the rods 1 and their arrangement in the horizontal arrangement plane best result from FIG. 2.
- the cross-section of the rods 1 consists of a rectangle 1a, the height h R of which is perpendicular to the arrangement plane of the rods, and two segments 1b composed, whose chord corresponds to the width of the rectangle and which join with their chord on the respective broad side of the rectangle 1a.
- the segments 1b are preferably circular segments with a radius r.
- the rods 1 have a rod width s and are arranged at a distance of a gap width sp from one another.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inert Electrodes (AREA)
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81100858T ATE13912T1 (de) | 1980-03-03 | 1981-02-06 | Gasentwickelnde metallelektrode fuer elektrochemische prozesse. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803008116 DE3008116A1 (de) | 1980-03-03 | 1980-03-03 | Gasentwickelnde metallelektrode fuer elektrochemische prozesse |
DE3008116 | 1980-03-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0035131A1 EP0035131A1 (fr) | 1981-09-09 |
EP0035131B1 true EP0035131B1 (fr) | 1985-06-19 |
Family
ID=6096135
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81100858A Expired EP0035131B1 (fr) | 1980-03-03 | 1981-02-06 | Electrode métallique dégageant du gaz pour procédés électrochimiques |
Country Status (6)
Country | Link |
---|---|
US (1) | US4379742A (fr) |
EP (1) | EP0035131B1 (fr) |
JP (1) | JPS6045277B2 (fr) |
AT (1) | ATE13912T1 (fr) |
DE (2) | DE3008116A1 (fr) |
SG (1) | SG73685G (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3345530A1 (de) * | 1983-07-13 | 1985-06-27 | Basf Ag, 6700 Ludwigshafen | Gasentwickelnde metallelektrode fuer elektrolysezellen |
DE3406777C2 (de) * | 1984-02-24 | 1985-12-19 | Conradty GmbH & Co Metallelektroden KG, 8505 Röthenbach | Beschichtete Ventilmetallanode zur elektrolytischen Gewinnung von Metallen oder Metalloxiden |
DE3626206A1 (de) * | 1986-08-01 | 1988-02-04 | Conradty Metallelek | Stromzuleitung fuer elektroden |
US5087344A (en) * | 1990-09-26 | 1992-02-11 | Heraeus Elektroden Gmbh | Electrolysis cell for gas-evolving electrolytic processes |
DE4419277C2 (de) * | 1994-06-01 | 1998-07-02 | Heraeus Elektrochemie | Elektrolysezellen-Elektrode |
US5849164A (en) * | 1996-06-27 | 1998-12-15 | Eltech Systems Corporation | Cell with blade electrodes and recirculation chamber |
ATE382722T1 (de) * | 2001-07-13 | 2008-01-15 | Moltech Invent Sa | Anodenstrukturen auf der basis von legierungen für die herstellung von aluminium |
EP1880043A4 (fr) * | 2005-04-15 | 2009-06-03 | Innovative Hydrogen Solutions | Cellule electrolytique pour moteur a combustion interne |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3409533A (en) * | 1964-03-23 | 1968-11-05 | Asahi Chemical Ind | Mercury-method cell for alkali chloride electrolysis |
GB1068992A (en) * | 1964-03-31 | 1967-05-17 | Asahi Chemical Ind | Anode assembly |
US3507771A (en) * | 1966-09-30 | 1970-04-21 | Hoechst Ag | Metal anode for electrolytic cells |
DE2135873B2 (de) * | 1971-07-17 | 1980-05-14 | Conradty Gmbh & Co Metallelektroden Kg, 8505 Roethenbach | Zellenoberteil für Amalgamhochlastzellen |
US4022679A (en) * | 1973-05-10 | 1977-05-10 | C. Conradty | Coated titanium anode for amalgam heavy duty cells |
DE2323497B2 (de) * | 1973-05-10 | 1978-10-12 | C. Conradty Nuernberg Gmbh & Co Kg, 8505 Roethenbach | Beschichtete Titananode für Amalgamhochlastzellen |
US4033847A (en) * | 1973-11-05 | 1977-07-05 | Olin Corporation | Metal anode assembly |
US3953316A (en) * | 1973-11-05 | 1976-04-27 | Olin Corporation | Metal anode assembly |
DE2721958A1 (de) * | 1977-05-14 | 1978-11-16 | Hoechst Ag | Metallelektrode fuer elektrolyseapparate zum elektrolytischen herstellen von chlor |
-
1980
- 1980-03-03 DE DE19803008116 patent/DE3008116A1/de not_active Withdrawn
-
1981
- 1981-02-06 DE DE8181100858T patent/DE3170971D1/de not_active Expired
- 1981-02-06 EP EP81100858A patent/EP0035131B1/fr not_active Expired
- 1981-02-06 AT AT81100858T patent/ATE13912T1/de not_active IP Right Cessation
- 1981-02-23 US US06/237,279 patent/US4379742A/en not_active Expired - Lifetime
- 1981-03-03 JP JP56030427A patent/JPS6045277B2/ja not_active Expired
-
1985
- 1985-10-07 SG SG736/85A patent/SG73685G/en unknown
Also Published As
Publication number | Publication date |
---|---|
SG73685G (en) | 1986-11-21 |
DE3170971D1 (en) | 1985-07-25 |
US4379742A (en) | 1983-04-12 |
DE3008116A1 (de) | 1981-09-17 |
JPS6045277B2 (ja) | 1985-10-08 |
JPS56136986A (en) | 1981-10-26 |
EP0035131A1 (fr) | 1981-09-09 |
ATE13912T1 (de) | 1985-07-15 |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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