ECSP13012469A - Absorbentes bromados mejorados para eliminar el mercurio de las emisiones producidas durante la combustión de combustible - Google Patents

Absorbentes bromados mejorados para eliminar el mercurio de las emisiones producidas durante la combustión de combustible

Info

Publication number
ECSP13012469A
ECSP13012469A ECSP13012469A ECSP13012469A EC SP13012469 A ECSP13012469 A EC SP13012469A EC SP13012469 A ECSP13012469 A EC SP13012469A EC SP13012469 A ECSP13012469 A EC SP13012469A
Authority
EC
Ecuador
Prior art keywords
absorbents
bored
improved
produced during
fuel combustion
Prior art date
Application number
Other languages
English (en)
Inventor
Christopher J Nalepa
Gregory H Lambeth
Qunhui Zhou
Jonathan P O'dwyer
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corp filed Critical Albemarle Corp
Publication of ECSP13012469A publication Critical patent/ECSP13012469A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C01B32/354—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

El carbón activado de base celulósica se hace más estable térmicamente por la exposición al agua o al ácido acuoso, y opcionalmente, a un halógeno y/o un compuesto que contiene halógeno. Tal carbón de base celulósica tratado mejora las propiedades térmicas y es adecuado para reducir el contenido de sustancias tóxicas en tiro de gases, especialmente el tiro de gases que tienen una temperatura dentro del intervalo de aproximadamente 100 ºC a aproximadamente 420 ºC.
ECSP13012469 2010-08-30 2013-02-28 Absorbentes bromados mejorados para eliminar el mercurio de las emisiones producidas durante la combustión de combustible ECSP13012469A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US37822110P 2010-08-30 2010-08-30

Publications (1)

Publication Number Publication Date
ECSP13012469A true ECSP13012469A (es) 2013-03-28

Family

ID=44534707

Family Applications (1)

Application Number Title Priority Date Filing Date
ECSP13012469 ECSP13012469A (es) 2010-08-30 2013-02-28 Absorbentes bromados mejorados para eliminar el mercurio de las emisiones producidas durante la combustión de combustible

Country Status (17)

Country Link
US (1) US9089834B2 (es)
EP (1) EP2611532A1 (es)
JP (1) JP2013536750A (es)
KR (1) KR20130111528A (es)
CN (1) CN103201029B (es)
AR (1) AR082783A1 (es)
AU (1) AU2011296402B2 (es)
BR (1) BR112013004470A2 (es)
CA (1) CA2805819A1 (es)
CL (1) CL2013000531A1 (es)
CO (1) CO6650384A2 (es)
EC (1) ECSP13012469A (es)
PE (1) PE20131030A1 (es)
RU (1) RU2013114265A (es)
TW (1) TW201208978A (es)
WO (1) WO2012030559A1 (es)
ZA (1) ZA201300580B (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130330257A1 (en) * 2012-06-11 2013-12-12 Calgon Carbon Corporation Sorbents for removal of mercury
TWI619550B (zh) 2013-03-15 2018-04-01 亞比馬利股份有限公司 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途
US10449492B2 (en) 2014-05-30 2019-10-22 Ada Carbon Solutions, Llc Catalytically enhanced compositions for efficient removal of contaminants in flue gas streams
US11285459B2 (en) 2015-08-14 2022-03-29 Ada Carbon Solutions, Llc Sorbent compositions having amorphous halogen species for the sequestration of contaminants
US11219878B2 (en) 2015-08-14 2022-01-11 Ada Carbon Solutions, Llc Sorbent compositions having amorphous halogen species for the sequestration of contaminants

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1788466A (en) 1923-05-09 1931-01-13 Gen Norit Company Ltd Process of treating active carbons for increasing their adsorbing efficiency
GB1038460A (en) 1963-12-23 1966-08-10 Du Pont Process for purification of nylon salt solutions
JPS5323777B2 (es) 1972-12-04 1978-07-17
GB1553364A (en) 1975-05-16 1979-09-26 Carborundum Co Granular activated carbon manufacture from sub-bituminous coal treated with dilute inorganic acid
NL7710632A (nl) * 1977-09-29 1979-04-02 Akzo Nv Werkwijze voor de verwijdering van kwik uit kwikdamp bevattende gassen.
JPS5799334A (en) 1980-12-05 1982-06-21 Takeda Chem Ind Ltd Activated carbon for deodorization and removal of offensive odor component
JPH0297414A (ja) 1988-10-01 1990-04-10 Kansai Coke & Chem Co Ltd 高品質活性炭の製造法
DE3842526A1 (de) 1988-12-17 1990-06-21 Bergwerksverband Gmbh Verfahren zur herstellung eines katalysators zur entfernung von stickstoffoxiden aus abgasen
US5883040A (en) 1995-05-31 1999-03-16 The Curators Of The University Of Missouri Activated carbon produced from agricultural residues
JP3537581B2 (ja) 1996-03-04 2004-06-14 クラレケミカル株式会社 水銀吸着剤
US6514907B2 (en) 1997-07-25 2003-02-04 Takeda Chemical Industries, Ltd. Bromine-impregnated activated carbon and process for preparing the same
JP3830234B2 (ja) * 1997-07-25 2006-10-04 日本エンバイロケミカルズ株式会社 臭素添着活性炭
CN1307931A (zh) 1999-10-06 2001-08-15 三菱化学株式会社 煤系成形活性炭及使用该活性炭处理含有二噁英类的废气的方法
AU2001255106A1 (en) 2000-05-08 2001-11-20 Norit Nederland B.V. Process for the purification of flue gas
JP4723240B2 (ja) 2002-05-06 2011-07-13 アルベマール コーポレイション 燃焼ガスからの水銀除去のための吸着材とその方法
US7435286B2 (en) * 2004-08-30 2008-10-14 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
JP3730987B2 (ja) * 2003-08-12 2006-01-05 日本エンバイロケミカルズ株式会社 臭素添着活性炭及びその製造方法
US20060051270A1 (en) 2004-09-03 2006-03-09 Robert Brunette Removal of volatile metals from gas by solid sorbent capture
DE102005038827B4 (de) * 2005-08-17 2010-02-11 Chi-Hsiang Wang Verfahren zur Herstellung eines künstlichen Kohleadsorptionsmittels aus Bambus
CN101024161B (zh) * 2006-02-20 2010-06-09 韩国电力公社 用于去除燃烧烟气中少量有害空气污染物的吸附剂及其制备方法
US20070234902A1 (en) 2006-03-29 2007-10-11 Fair David L Method for mercury removal from flue gas streams
WO2010036750A1 (en) * 2008-09-24 2010-04-01 Albemarle Corporation Bromine chloride compositions for removing mercury from emissions produced during fuel combustion
UA109399C2 (uk) * 2009-04-01 2015-08-25 Термічно активоване вугілля, стійке до самозапалювання

Also Published As

Publication number Publication date
AU2011296402A1 (en) 2013-02-07
AU2011296402B2 (en) 2015-01-22
BR112013004470A2 (pt) 2017-11-21
US20130165319A1 (en) 2013-06-27
ZA201300580B (en) 2013-09-25
TW201208978A (en) 2012-03-01
CN103201029B (zh) 2016-08-17
PE20131030A1 (es) 2013-09-28
US9089834B2 (en) 2015-07-28
CA2805819A1 (en) 2012-03-08
KR20130111528A (ko) 2013-10-10
CN103201029A (zh) 2013-07-10
CL2013000531A1 (es) 2013-09-23
RU2013114265A (ru) 2014-10-10
AR082783A1 (es) 2013-01-09
EP2611532A1 (en) 2013-07-10
CO6650384A2 (es) 2013-04-15
WO2012030559A1 (en) 2012-03-08
JP2013536750A (ja) 2013-09-26

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