EA200970093A1 - Ненасыщенные полиэфируретановые преполимеры и их применение - Google Patents
Ненасыщенные полиэфируретановые преполимеры и их применениеInfo
- Publication number
- EA200970093A1 EA200970093A1 EA200970093A EA200970093A EA200970093A1 EA 200970093 A1 EA200970093 A1 EA 200970093A1 EA 200970093 A EA200970093 A EA 200970093A EA 200970093 A EA200970093 A EA 200970093A EA 200970093 A1 EA200970093 A1 EA 200970093A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- resin
- optionally
- ethylenically unsaturated
- prepolymer
- application
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/68—Unsaturated polyesters
- C08G18/683—Unsaturated polyesters containing cyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/68—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Настоящее изобретение относится к преполимеру с этиленовой ненасыщенностью, содержащему по меньшей мере одну концевую группу X, активную к конденсации, выбранную из гидрокси и/или аминогрупп, или свободного изоцианата, и при необходимости концевую группу X' с этиленовой ненасыщенностью, причем преполимер является продуктом реакции следующих компонентов А и В: А) первый компонент А, содержащий следующую смесь: i) по меньшей мере одна первая смола с этиленовой ненасыщенностью, имеющая особые реакционноспособные концевые гидрокси и/или аминогруппы, и/или ii) при необходимости, в присутствии по меньшей мере одной второй смолы, отличной от смолы i), выбранной из гидроксилированных смол с этиленовой ненасыщенностью, и/или насыщенных гидроксилированных и/или аминированных смол, и/или iii) при необходимости, по меньшей мере одна третья насыщенная реакционноспособная смола, iv) факультативно, по меньшей мере один одноатомный спирт, с ненасыщенностью до 30 экв.% суммы ОН+NH, В) второй компонент В, содержащий по меньшей мере один полиизоцианат с функциональностью, равной 2 или выше 2, причем А и В находятся в пропорциях, позволяющих полностью избежать гелеобразования из-за сшивки. Изобретение относится также к сшиваемой смоляной композиции, содержащей по меньшей мере один преполимер согласно изобретению, и к ее использованию в различных областях применения.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0606276A FR2903412B1 (fr) | 2006-07-07 | 2006-07-07 | Pre-polymere urethane - polyester insature et ses applications |
PCT/EP2007/005900 WO2008003472A1 (fr) | 2006-07-07 | 2007-07-04 | Pre-polymere urethane-polyester insature et ses applications |
Publications (2)
Publication Number | Publication Date |
---|---|
EA200970093A1 true EA200970093A1 (ru) | 2009-06-30 |
EA019063B1 EA019063B1 (ru) | 2013-12-30 |
Family
ID=37836724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA200970093A EA019063B1 (ru) | 2006-07-07 | 2007-07-04 | Ненасыщенные полиэфируретановые преполимеры и их применение |
Country Status (9)
Country | Link |
---|---|
US (1) | US8609776B2 (ru) |
EP (1) | EP2038322B1 (ru) |
KR (1) | KR101441148B1 (ru) |
CN (1) | CN101484492B (ru) |
CA (1) | CA2656764C (ru) |
EA (1) | EA019063B1 (ru) |
FR (1) | FR2903412B1 (ru) |
MX (1) | MX336970B (ru) |
WO (1) | WO2008003472A1 (ru) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102174287B (zh) * | 2011-03-09 | 2013-06-26 | 株洲时代电气绝缘有限责任公司 | 一种互穿网络防水涂料及其制备方法 |
WO2013062486A1 (en) * | 2011-10-24 | 2013-05-02 | Tera-Barrier Films Pte Ltd | Encapsulation barrier stack |
CN103410290A (zh) * | 2013-08-28 | 2013-11-27 | 四川迪弗电工科技有限公司 | Smc材料的新用途 |
CN104629231B (zh) * | 2014-03-03 | 2017-12-08 | 青岛中科新材料有限公司 | 一种光固化3d打印用烯丙基酯树脂复合玻璃纤维光敏树脂的制备方法及应用 |
ES2595932B1 (es) | 2015-07-01 | 2017-10-24 | Construplas, S.L. | Procedimiento de moldeo de plancha sobre soporte |
CA3008414C (en) * | 2015-12-14 | 2021-05-18 | Ppg Industries Ohio, Inc. | Branched polyester-urethane resins and coatings comprising the same |
MX2019005366A (es) * | 2016-11-23 | 2019-08-12 | Spartech Llc | Materiales de lamina fundida de uretano urea acrilico. |
US20220274875A1 (en) * | 2019-07-19 | 2022-09-01 | Lx Hausys, Ltd. | Artificial stone |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3008917A (en) * | 1956-08-27 | 1961-11-14 | Pittsburgh Plate Glass Co | Coating mixture containing diisocyanate modified polyester and styrene |
DE2427089A1 (de) * | 1974-06-05 | 1975-12-18 | Bayer Ag | Verfahren zur herstellung von kunststoffen |
US4327145A (en) * | 1979-10-22 | 1982-04-27 | Dainippon Inc. & Chemicals, Inc. | Process for producing sheet molding compound |
US4289682A (en) * | 1979-12-26 | 1981-09-15 | Union Carbide Corporation | Curable resin compositions comprising hydroxyl-terminated unsaturated polyester oligomer, a polyisocyanate, an ethylenically unsaturated monomer and a catalyst |
JPS6056732B2 (ja) | 1980-04-30 | 1985-12-11 | 大日本インキ化学工業株式会社 | 熱硬化性成形用組成物 |
EP0203361A3 (en) * | 1985-04-29 | 1988-06-15 | THE GLIDDEN COMPANY (formerly known as ATKEMIX EIGHT INC.) | Improved polyester resin gelkote composition |
US4857434A (en) * | 1986-09-23 | 1989-08-15 | W. R. Grace & Co. | Radiation curable liquid (meth) acrylated polymeric hydrocarbon maleate prepolymers and formulations containing same |
US4822849A (en) * | 1987-08-03 | 1989-04-18 | Reichhold Chemicals, Inc. | Low shrink hybrid resins |
US5159044A (en) * | 1990-11-20 | 1992-10-27 | Amoco Corporation | Sheet molding compounds having improved viscosity |
FR2684680B1 (fr) * | 1991-12-05 | 1994-02-11 | Cray Valley Sa | Compositions ameliorees de resines polyesters insatures pour moulage. |
US5739240A (en) * | 1996-04-10 | 1998-04-14 | Hehr International Inc. | Modified acrylic urethane prepolymer concentrate and polyester resins containing same |
US20010031830A1 (en) * | 1999-04-26 | 2001-10-18 | Probir K. Guha | Composite molding compound additive |
US6774193B2 (en) * | 2000-06-14 | 2004-08-10 | Albemarle Corporation | Stabilized unsaturated polymer resin compositions and methods of using the same |
JP4484358B2 (ja) * | 2000-12-28 | 2010-06-16 | ジャパンコンポジット株式会社 | 防水被覆用樹脂組成物、防水被覆構造体および防水被覆工法 |
US20030220035A1 (en) * | 2002-05-17 | 2003-11-27 | Fjare Douglas E. | Reinforced unsaturated polyester resin compositions |
JP2004059647A (ja) | 2002-07-25 | 2004-02-26 | Hitachi Chem Co Ltd | 不飽和ポリエステル樹脂組成物及びこの製造法、並びにこれを用いた熱硬化性成形材料及びプラスチック成形品 |
US7326752B2 (en) * | 2003-02-28 | 2008-02-05 | Aoc, Llc | Styrene-free unsaturated polyester resin compositions for coating applications |
US8742054B2 (en) * | 2005-08-23 | 2014-06-03 | Ccp Composites Us | Polyester-polyurethane hybrid resin molding compositions comprising polyurethane with units derived from aliphatic isocyanates |
-
2006
- 2006-07-07 FR FR0606276A patent/FR2903412B1/fr active Active
-
2007
- 2007-07-04 CA CA2656764A patent/CA2656764C/fr active Active
- 2007-07-04 WO PCT/EP2007/005900 patent/WO2008003472A1/fr active Application Filing
- 2007-07-04 MX MX2008016298A patent/MX336970B/es active IP Right Grant
- 2007-07-04 CN CN2007800257466A patent/CN101484492B/zh active Active
- 2007-07-04 US US12/307,692 patent/US8609776B2/en active Active
- 2007-07-04 EP EP07765038.0A patent/EP2038322B1/fr active Active
- 2007-07-04 EA EA200970093A patent/EA019063B1/ru not_active IP Right Cessation
- 2007-07-04 KR KR1020097000259A patent/KR101441148B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
FR2903412B1 (fr) | 2012-10-05 |
BRPI0714916A2 (pt) | 2013-05-07 |
CA2656764C (fr) | 2015-05-26 |
EP2038322A1 (fr) | 2009-03-25 |
EA019063B1 (ru) | 2013-12-30 |
KR101441148B1 (ko) | 2014-09-18 |
KR20090035513A (ko) | 2009-04-09 |
MX2008016298A (es) | 2009-02-10 |
EP2038322B1 (fr) | 2021-03-03 |
US8609776B2 (en) | 2013-12-17 |
MX336970B (es) | 2016-02-08 |
CN101484492A (zh) | 2009-07-15 |
WO2008003472A1 (fr) | 2008-01-10 |
CA2656764A1 (fr) | 2008-01-10 |
FR2903412A1 (fr) | 2008-01-11 |
CN101484492B (zh) | 2012-05-30 |
US20090312451A1 (en) | 2009-12-17 |
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Legal Events
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MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ MD TM |
|
MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): BY KZ KG TJ RU |