EA199901058A1 - Способ получения водорода и электрической энергии при риформинге биоэтанола с использованием топливных элементов и с нулевым выделением загрязнений - Google Patents

Способ получения водорода и электрической энергии при риформинге биоэтанола с использованием топливных элементов и с нулевым выделением загрязнений

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Publication number
EA199901058A1
EA199901058A1 EA199901058A EA199901058A EA199901058A1 EA 199901058 A1 EA199901058 A1 EA 199901058A1 EA 199901058 A EA199901058 A EA 199901058A EA 199901058 A EA199901058 A EA 199901058A EA 199901058 A1 EA199901058 A1 EA 199901058A1
Authority
EA
Eurasian Patent Office
Prior art keywords
ethanol
reforming
hydrogen
production
mixture
Prior art date
Application number
EA199901058A
Other languages
English (en)
Other versions
EA002382B1 (ru
Inventor
Ксенофон Верикиос
Original Assignee
Ксенофон Верикиос
Кадмос Аэ Эпендитикон Протовоулион
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ксенофон Верикиос, Кадмос Аэ Эпендитикон Протовоулион filed Critical Ксенофон Верикиос
Publication of EA199901058A1 publication Critical patent/EA199901058A1/ru
Publication of EA002382B1 publication Critical patent/EA002382B1/ru

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0643—Gasification of solid fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

Способ получения водорода и электрической энергии с нулевым выделением загрзянителей, из этанола, который получают из биомассы, отличающийся частичным окислением/риформингом этанола с водой для получения водорода, который затем подают в топливную ячейку для получения электрической энергии, в частности тем, что водный раствор этанола, образующегося при ферментации биомассы, разделяют перегонкой или любым другим методом, чтобы раствор содержал приблизительно 40-70 мас.% этанола, предпочтительно 50-60%, и эту смесь, смешанную с подходящим количеством воздуха так, чтобы отношение количества молей кислорода к количеству молей этанола находилось между нулем и 0,5, подают в реактор, где протекают реакции частичного окисления и риформинга этанола над подходящим катализатором, причем в том же самом или другом реакторе протекает реакция замещения и, если необходимо, реакция сгорания CO или его превращения в CH, а газообразную смесь, которая содержит водород в смеси с диоксидом углерода, азотом, метаном или другими газами в малых количествах, на выходе из реакторов разделяют до степени, которая желательна для любого вида применения.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199901058A 1998-05-22 1999-05-19 Способ получения водорода и электрической энергии при риформинге биоэтанола с использованием топливных элементов и с нулевым выделением загрязнителей EA002382B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GR98100180 1998-05-22
PCT/GR1999/000020 WO1999061369A1 (en) 1998-05-22 1999-05-19 Process for the production of hydrogen and electrical energy from reforming of bio-ethanol

Publications (2)

Publication Number Publication Date
EA199901058A1 true EA199901058A1 (ru) 2000-10-30
EA002382B1 EA002382B1 (ru) 2002-04-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EA199901058A EA002382B1 (ru) 1998-05-22 1999-05-19 Способ получения водорода и электрической энергии при риформинге биоэтанола с использованием топливных элементов и с нулевым выделением загрязнителей

Country Status (11)

Country Link
US (2) US6387554B1 (ru)
EP (1) EP1007472B1 (ru)
AT (1) ATE248766T1 (ru)
CA (2) CA2704690A1 (ru)
DE (1) DE69910957T2 (ru)
DK (1) DK1007472T3 (ru)
EA (1) EA002382B1 (ru)
ES (1) ES2209430T3 (ru)
GR (1) GR1003235B (ru)
PT (1) PT1007472E (ru)
WO (1) WO1999061369A1 (ru)

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Also Published As

Publication number Publication date
EA002382B1 (ru) 2002-04-25
DE69910957T2 (de) 2004-08-12
DE69910957D1 (de) 2003-10-09
US6605376B2 (en) 2003-08-12
US6387554B1 (en) 2002-05-14
WO1999061369A1 (en) 1999-12-02
CA2704690A1 (en) 1999-12-02
EP1007472B1 (en) 2003-09-03
ATE248766T1 (de) 2003-09-15
EP1007472A1 (en) 2000-06-14
PT1007472E (pt) 2004-01-30
GR1003235B (el) 1999-10-13
DK1007472T3 (da) 2003-12-22
CA2294361A1 (en) 1999-12-02
ES2209430T3 (es) 2004-06-16
US20010023034A1 (en) 2001-09-20

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