EA007525B1 - Керамический анод и способ его изготовления - Google Patents
Керамический анод и способ его изготовления Download PDFInfo
- Publication number
- EA007525B1 EA007525B1 EA200401591A EA200401591A EA007525B1 EA 007525 B1 EA007525 B1 EA 007525B1 EA 200401591 A EA200401591 A EA 200401591A EA 200401591 A EA200401591 A EA 200401591A EA 007525 B1 EA007525 B1 EA 007525B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- anode
- ceramic material
- doped
- ceramic
- fuel cell
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims description 66
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 69
- 239000000446 fuel Substances 0.000 claims abstract description 59
- 239000007787 solid Substances 0.000 claims abstract description 38
- 239000003792 electrolyte Substances 0.000 claims description 41
- 239000000463 material Substances 0.000 claims description 31
- 239000011148 porous material Substances 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 239000011159 matrix material Substances 0.000 claims description 23
- 229930195733 hydrocarbon Natural products 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- 238000001354 calcination Methods 0.000 claims description 20
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 20
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 13
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000010406 cathode material Substances 0.000 claims description 5
- 239000002001 electrolyte material Substances 0.000 claims description 5
- 238000005470 impregnation Methods 0.000 claims description 4
- 229910017563 LaCrO Inorganic materials 0.000 claims description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 3
- 150000001722 carbon compounds Chemical class 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 39
- 239000002131 composite material Substances 0.000 description 37
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 18
- 239000010405 anode material Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 12
- 239000004020 conductor Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 238000005325 percolation Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000013461 design Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000001273 butane Substances 0.000 description 5
- 239000011195 cermet Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- -1 cathodes Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000003837 high-temperature calcination Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 238000001453 impedance spectrum Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- BQENXCOZCUHKRE-UHFFFAOYSA-N [La+3].[La+3].[O-][Mn]([O-])=O.[O-][Mn]([O-])=O.[O-][Mn]([O-])=O Chemical compound [La+3].[La+3].[O-][Mn]([O-])=O.[O-][Mn]([O-])=O.[O-][Mn]([O-])=O BQENXCOZCUHKRE-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000012733 comparative method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 238000009766 low-temperature sintering Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 101000795655 Canis lupus familiaris Thymic stromal cotransporter homolog Proteins 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 150000001785 cerium compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical group [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- DTDCCPMQHXRFFI-UHFFFAOYSA-N dioxido(dioxo)chromium lanthanum(3+) Chemical compound [La+3].[La+3].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O DTDCCPMQHXRFFI-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910000473 manganese(VI) oxide Inorganic materials 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Composite Materials (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38700902P | 2002-06-06 | 2002-06-06 | |
| PCT/US2003/017735 WO2003105252A2 (en) | 2002-06-06 | 2003-06-05 | Ceramic anodes and method of producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200401591A1 EA200401591A1 (ru) | 2005-06-30 |
| EA007525B1 true EA007525B1 (ru) | 2006-10-27 |
Family
ID=29736251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200401591A EA007525B1 (ru) | 2002-06-06 | 2003-06-05 | Керамический анод и способ его изготовления |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7740772B2 (https=) |
| EP (1) | EP1530814A4 (https=) |
| JP (1) | JP2005529464A (https=) |
| KR (1) | KR20050036914A (https=) |
| CN (1) | CN1672283A (https=) |
| AU (1) | AU2003248623B2 (https=) |
| CA (1) | CA2488273A1 (https=) |
| EA (1) | EA007525B1 (https=) |
| IL (1) | IL165386A0 (https=) |
| MX (1) | MXPA04012068A (https=) |
| WO (1) | WO2003105252A2 (https=) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7090891B2 (en) * | 2003-04-28 | 2006-08-15 | Curators Of The University Of Missouri | Method for fabricating nanostructured solid oxide fuel cells and cell components |
| JP4405196B2 (ja) * | 2003-08-22 | 2010-01-27 | 新光電気工業株式会社 | 固体電解質燃料電池 |
| JP4695828B2 (ja) * | 2003-11-05 | 2011-06-08 | 本田技研工業株式会社 | 電解質・電極接合体及びその製造方法 |
| JP5260052B2 (ja) | 2004-06-10 | 2013-08-14 | テクニカル ユニバーシティ オブ デンマーク | 固体酸化物型燃料電池 |
| AU2005294472A1 (en) * | 2004-10-05 | 2006-04-20 | Ctp Hydrogen Corporation | Conducting ceramics for electrochemical systems |
| WO2006069753A1 (en) | 2004-12-28 | 2006-07-06 | Technical University Of Denmark | Method of producing metal to glass, metal to metal or metal to ceramic connections |
| JP5208518B2 (ja) | 2005-02-02 | 2013-06-12 | テクニカル ユニバーシティ オブ デンマーク | 可逆式固体酸化物型燃料電池を製造する方法 |
| US20080102337A1 (en) * | 2005-02-28 | 2008-05-01 | The Tokyo Electric Power Company, Incorporated | Solid Oxide Type Fuel Battery Cell and Process for Producing the Same |
| JP2008538543A (ja) * | 2005-04-21 | 2008-10-30 | ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア | 前駆体物質溶浸およびコーティング方法 |
| US20070037031A1 (en) * | 2005-07-13 | 2007-02-15 | Ion America Corporation | Cermet and ceramic interconnects for a solid oxide fuel cell |
| ES2434442T3 (es) * | 2005-08-31 | 2013-12-16 | Technical University Of Denmark | Apilamiento sólido reversible de pilas de combustible de óxido y método para preparar el mismo |
| US7864322B2 (en) | 2006-03-23 | 2011-01-04 | The Research Foundation Of State University Of New York | Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments |
| PL1999109T3 (pl) | 2006-03-30 | 2012-05-31 | Univ Pennsylvania | Pochodne styrylopirydyny i ich zastosowanie do wiązania i obrazowania blaszek amyloidowych |
| DE102006030393A1 (de) * | 2006-07-01 | 2008-01-03 | Forschungszentrum Jülich GmbH | Keramische Werkstoffkombination für eine Anode für eine Hochtemperatur-Brennstoffzelle |
| US8021799B2 (en) * | 2006-07-12 | 2011-09-20 | The Trustees Of The University Of Pennsylvania | High-performance ceramic anodes for use with strategic and other hydrocarbon fuels |
| US7748259B2 (en) * | 2006-12-15 | 2010-07-06 | General Electric Company | Systems and methods for solid oxide fuel cell surface analysis |
| US20080184892A1 (en) * | 2007-02-06 | 2008-08-07 | Ctp Hydrogen Corporation | Architectures for electrochemical systems |
| ES2367885T3 (es) * | 2007-08-31 | 2011-11-10 | Technical University Of Denmark | Electrodos que se basan en óxido de cerio y un acero inoxidable. |
| JP5383232B2 (ja) * | 2009-01-30 | 2014-01-08 | 三菱重工業株式会社 | 固体電解質型燃料電池の発電膜及びこれを備える固体電解質型燃料電池 |
| EP2244322A1 (en) * | 2009-04-24 | 2010-10-27 | Technical University of Denmark | Composite oxygen electrode and method for preparing same |
| WO2010135828A1 (en) * | 2009-05-26 | 2010-12-02 | Alex Mann | Low work function electrode |
| US9561476B2 (en) * | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
| US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
| CN103987681B (zh) | 2011-12-15 | 2016-08-24 | 普莱克斯技术有限公司 | 复合氧气传送膜 |
| EP2935155B1 (en) | 2012-12-19 | 2019-02-13 | Praxair Technology Inc. | Method for sealing an oxygen transport membrane assembly |
| US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
| US10446855B2 (en) * | 2013-03-15 | 2019-10-15 | Lg Fuel Cell Systems Inc. | Fuel cell system including multilayer interconnect |
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- 2003-06-05 CA CA002488273A patent/CA2488273A1/en not_active Abandoned
- 2003-06-05 EP EP03757352A patent/EP1530814A4/en not_active Withdrawn
- 2003-06-05 US US10/454,783 patent/US7740772B2/en not_active Expired - Fee Related
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- 2003-06-05 EA EA200401591A patent/EA007525B1/ru not_active IP Right Cessation
- 2003-06-05 CN CNA038173557A patent/CN1672283A/zh active Pending
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- 2003-06-05 WO PCT/US2003/017735 patent/WO2003105252A2/en not_active Ceased
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Also Published As
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| US20040043272A1 (en) | 2004-03-04 |
| US7740772B2 (en) | 2010-06-22 |
| EA200401591A1 (ru) | 2005-06-30 |
| WO2003105252A3 (en) | 2004-03-04 |
| AU2003248623A1 (en) | 2003-12-22 |
| CN1672283A (zh) | 2005-09-21 |
| AU2003248623B2 (en) | 2009-05-14 |
| IL165386A0 (en) | 2006-01-15 |
| EP1530814A2 (en) | 2005-05-18 |
| JP2005529464A (ja) | 2005-09-29 |
| MXPA04012068A (es) | 2005-03-07 |
| EP1530814A4 (en) | 2009-05-27 |
| CA2488273A1 (en) | 2003-12-18 |
| KR20050036914A (ko) | 2005-04-20 |
| WO2003105252A2 (en) | 2003-12-18 |
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