DK3411332T3 - Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator - Google Patents

Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator Download PDF

Info

Publication number
DK3411332T3
DK3411332T3 DK17702840.4T DK17702840T DK3411332T3 DK 3411332 T3 DK3411332 T3 DK 3411332T3 DK 17702840 T DK17702840 T DK 17702840T DK 3411332 T3 DK3411332 T3 DK 3411332T3
Authority
DK
Denmark
Prior art keywords
procedure
zeolite catalyst
direct synthesis
iron aid
iron
Prior art date
Application number
DK17702840.4T
Other languages
English (en)
Inventor
García Nuria Martín
Canós Avelino Corma
Marín Manuel Moliner
Joakim Reimer Thøgersen
Peter Nicolai Ravnborg Vennestrøm
Original Assignee
Umicore Ag & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umicore Ag & Co Kg filed Critical Umicore Ag & Co Kg
Application granted granted Critical
Publication of DK3411332T3 publication Critical patent/DK3411332T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/202—Alkali metals
    • B01D2255/2027—Sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DK17702840.4T 2016-02-01 2017-01-30 Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator DK3411332T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201670053 2016-02-01
PCT/EP2017/051912 WO2017134006A1 (en) 2016-02-01 2017-01-30 Method for the direct synthesis of iron-containing aei-zeolite catalyst

Publications (1)

Publication Number Publication Date
DK3411332T3 true DK3411332T3 (da) 2021-05-17

Family

ID=57960435

Family Applications (1)

Application Number Title Priority Date Filing Date
DK17702840.4T DK3411332T3 (da) 2016-02-01 2017-01-30 Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator

Country Status (7)

Country Link
US (1) US20180346341A1 (da)
EP (1) EP3411332B1 (da)
JP (1) JP6951343B2 (da)
KR (1) KR20180111908A (da)
CN (1) CN109071245B (da)
DK (1) DK3411332T3 (da)
WO (1) WO2017134006A1 (da)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180111907A (ko) * 2016-02-01 2018-10-11 우미코레 아게 운트 코 카게 알칼리 금속을 본질적으로 함유하지 않는 Fe-AEI 제올라이트 재료를 포함하는 SCR 촉매의 존재하에 선택적 촉매 환원에 의해 배기 가스로부터 질소 산화물을 제거하는 방법
US10807080B2 (en) * 2016-09-30 2020-10-20 Johnson Matthey Public Limited Company Synthesis of metal promoted zeolite catalyst
EP3880610A4 (en) * 2018-11-16 2022-08-03 Basf Se METHOD FOR THE PRODUCTION OF A ZEOLITIC MATERIAL WITH AEI-TYPE CRYSTALLINE STRUCTURE BY INTERZEOLITIC CONVERSION WITHOUT SOLVENT
JP7417716B2 (ja) * 2019-10-02 2024-01-18 シェブロン ユー．エス．エー． インコーポレイテッド 小型結晶ｓｓｚ－２７、その合成及び使用
KR20210087743A (ko) * 2020-01-03 2021-07-13 현대자동차주식회사 촉매 및 촉매의 제조 방법
CN113371726A (zh) * 2021-06-25 2021-09-10 复旦大学 一种功能沸石分子筛材料及其制备方法
CN115924967B (zh) * 2023-03-08 2023-05-16 国能龙源环保有限公司 利用钛渣制备钛白粉的方法及其钛白粉

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2396233T3 (es) * 2003-12-23 2013-02-20 Exxonmobil Chemical Patents, Inc. Zeolita de tipo AEI y su uso en la conversión de compuestos oxigenados en olefinas
WO2006039213A1 (en) * 2004-09-30 2006-04-13 Chevron U.S.A. Inc. Molecular sieve ssz-65
DK3278863T3 (da) * 2007-04-26 2020-02-17 Johnson Matthey Plc Overgangsmetal/aei-zeolit-scr-katalysator
WO2009023202A2 (en) * 2007-08-13 2009-02-19 Pq Corporation Novel iron-containing aluminosilicate zeolites and methods of making and using same
CN106276952A (zh) * 2009-11-24 2017-01-04 巴斯夫欧洲公司 制备具有cha结构的沸石的方法
BR112014012818A2 (pt) * 2011-12-02 2017-06-13 Pq Corp material cristalino microporoso estabilizado, o processo de fabricaçãodo mesmo, e o uso para redução catalítica seletiva de nox
JP6567431B2 (ja) * 2013-03-15 2019-08-28 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ 排気ガスを処理するための触媒
BR112016012397B1 (pt) * 2013-12-02 2020-11-24 Johnson Matthey Public Limited Company método para sintetizar um zeólito, composição de zeólito, artigo de catalisador para tratar gás de escape e método para tratar gás de escape
US10850265B2 (en) * 2014-06-18 2020-12-01 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
CN110540215B (zh) * 2014-11-21 2024-02-06 三菱化学株式会社 Aei型铝硅酸盐沸石、催化剂和废气处理方法
ES2586770B1 (es) * 2015-04-16 2017-08-14 Consejo Superior De Investigaciones Científicas (Csic) Método de síntesis directa del material cu-silicoaluminato con la estructura zeolítica aei, y sus aplicaciones catalíticas

Also Published As

Publication number Publication date
CN109071245A (zh) 2018-12-21
JP2019503327A (ja) 2019-02-07
EP3411332A1 (en) 2018-12-12
JP6951343B2 (ja) 2021-10-20
KR20180111908A (ko) 2018-10-11
WO2017134006A1 (en) 2017-08-10
CN109071245B (zh) 2022-03-04
EP3411332B1 (en) 2021-03-10
US20180346341A1 (en) 2018-12-06

Similar Documents

Publication Publication Date Title
DK3411332T3 (da) Fremgangsmåde til direkte syntese af jernholdig aei-zeolitkatalysator
DK3294720T3 (da) Fremgangsmåde til fremstilling af terpinolenepoxid
DK3192902T3 (da) Fremgangsmåde til fremstilling af graphenholdige viscosefibre
DK3301115T3 (da) Kontinuerlig flertrinsfremgangsmåde til oprensning af antistoffer
DK3096741T3 (da) Fremgangsmåde til fremstillingen af hybridosomer
DK3066085T3 (da) Fremgangsmåde til syntesen af en indolamin-2,3-dioxygenaseinhibitor
DK3126499T3 (da) Sammensætninger til modulering af sod-1-ekspression
DK3250660T3 (da) Fremgangsmåde til hydrotermal oprensning
DK3317400T3 (da) Fremgangsmåde til kryokonservering af tumorinfiltrerende lymfocytter
DK3325443T3 (da) Fremgangsmåde til fremstilling af pridopidin
DK3448846T3 (da) Syntese af indazoler
DK3113858T3 (da) Fremgangsmåde til oprensning af il-15/il-15ralpha-baserede konjugater
DK3148529T3 (da) Forbindelser til behandling af hjernecancer
DK3261726T3 (da) Sammensætning til behandling af acne
DK2962754T3 (da) Fremgangsmåde til fremstilling af co-shiftkatalysator
DK3233813T3 (da) Fremgangsmåder til fremstilling af oxathiazin-lignende forbindelser
DK3390354T3 (da) Fremgangsmåde til tilvejebringelse af carbondioxid til syntese af urea
DK3448849T3 (da) Syntese af indazoler
DK3280408T3 (da) Fremgangsmåde til fremstilling af dicycloplatin
DK3529233T3 (da) Fremgangsmåde til fremstilling af 3-alkylsulfanyl-2-chlor-n-(1-alkyl-1h-tetrazol-5-yl)-4-trifluoromethyl-benzamider
DK3509745T3 (da) Katalysatorsammensætning omfattende modificeret krystallinsk aluminosilikat til dehydrering af alkoholer
DK3481811T3 (da) Industriel fremgangsmåde til forberedelse af cariprazin
DK3262023T3 (da) Fremgangsmåde til fremstillingen af diener
DK3548427T3 (da) Fremgangsmåde til fremstilling af hydrogen
DK3458467T3 (da) Fremgangsmåde til 6,7-alfa-epoxidering af steroid-4,6-diener