DK2931763T3 - Ethylencopolymersammensætninger, film og polymeriseringsfremgangsmåder - Google Patents
Ethylencopolymersammensætninger, film og polymeriseringsfremgangsmåder Download PDFInfo
- Publication number
- DK2931763T3 DK2931763T3 DK13862866.4T DK13862866T DK2931763T3 DK 2931763 T3 DK2931763 T3 DK 2931763T3 DK 13862866 T DK13862866 T DK 13862866T DK 2931763 T3 DK2931763 T3 DK 2931763T3
- Authority
- DK
- Denmark
- Prior art keywords
- catalyst
- ethylene copolymer
- ethylene
- polymerization
- film
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Claims (5)
- deks CDBI50 på fra 50 vægt-% til 75 vægt-% som bestemt ved TREF, og som opfylder følgende forhold: (Mw/Mn) > 72 [(I21/I2)’1 + 10'6 (Mn)].
- 11. Filmlag ifølge krav 10, hvor filmlaget har et forhold mellem MD-slid og TD-slid på 0,45 eller mindre.
- 12. Filmlag ifølge krav 10, hvor filmlaget har en dart impact på mere end 500 g/mil.
- 13. Filmlag ifølge krav 10, hvor ethylencopolymeren yderligere opfylder forholdet: δχο < 80,7 - (CDBI50) / (Mw/Mn) ved en δχο på fra 55° til 70°.
- 14. Filmlag ifølge krav 10 eller krav 13, hvor ethylencopolymeren yderligere opfylder forholdet: δχο < 83,0 - 1,25 (CDBI50) / (Mw/Mn).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2798855A CA2798855C (en) | 2012-06-21 | 2012-12-14 | Ethylene copolymers having reverse comonomer incorporation |
PCT/CA2013/001002 WO2014089671A1 (en) | 2012-12-14 | 2013-12-04 | Ethylene copolymer compositions, film and polymerization processes |
Publications (1)
Publication Number | Publication Date |
---|---|
DK2931763T3 true DK2931763T3 (da) | 2018-04-16 |
Family
ID=50929151
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK13862866.4T DK2931763T3 (da) | 2012-12-14 | 2013-12-04 | Ethylencopolymersammensætninger, film og polymeriseringsfremgangsmåder |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2931763B1 (da) |
JP (1) | JP6231579B2 (da) |
KR (1) | KR102121298B1 (da) |
CN (1) | CN104918972B (da) |
BR (1) | BR112015014121B1 (da) |
CA (1) | CA2835740C (da) |
DK (1) | DK2931763T3 (da) |
ES (1) | ES2663020T3 (da) |
MX (1) | MX2015007292A (da) |
NO (1) | NO2931763T3 (da) |
WO (1) | WO2014089671A1 (da) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
EP3225639B1 (en) * | 2013-03-28 | 2019-12-18 | Dow Global Technologies LLC | An ethylene/alpha-olefin interpolymer |
RU2674254C1 (ru) * | 2014-02-11 | 2018-12-06 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Получение полиолефиновых продуктов |
US20170152377A1 (en) * | 2014-06-26 | 2017-06-01 | Dow Global Technologies Llc | Breathable films and articles incorporating same |
JP6824043B2 (ja) * | 2014-06-26 | 2021-02-03 | ダウ グローバル テクノロジーズ エルエルシー | 改善された靭性を有するキャストフィルム |
BR112016029163B8 (pt) * | 2014-06-26 | 2022-07-26 | Dow Global Technologies Llc | Película soprada, artigo e película espumada |
TWI557140B (zh) * | 2014-08-19 | 2016-11-11 | 努發化工(國際)公司 | 使用單活性中心催化劑產生之乙烯共聚物 |
KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
KR101889598B1 (ko) | 2015-12-08 | 2018-08-17 | 주식회사 엘지화학 | 올레핀계 중합체 |
KR20190021324A (ko) * | 2016-06-17 | 2019-03-05 | 보레알리스 아게 | 향상된 유동학적 특성을 갖는 바이모달 또는 멀티모달 폴리에틸렌 삼원공중합체 |
EP3475318A1 (en) | 2016-06-23 | 2019-05-01 | Borealis AG | Process for catalyst deactivation |
US10000594B2 (en) | 2016-11-08 | 2018-06-19 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability |
WO2019060387A1 (en) * | 2017-09-22 | 2019-03-28 | Dow Global Technologies Llc | THERMOFORMED FILM COMPOSITIONS HAVING ENHANCED TENACITY AFTER THERMOFORMING PROCESSES |
US10358506B2 (en) * | 2017-10-03 | 2019-07-23 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE copolymers with improved processability |
US10927202B2 (en) * | 2017-11-13 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and articles made therefrom |
EP3717527A1 (en) * | 2017-11-28 | 2020-10-07 | ExxonMobil Chemical Patents Inc. | Polyethylene compositions and films made therefrom |
CN111655744B (zh) | 2017-12-26 | 2023-04-28 | 陶氏环球技术有限责任公司 | 韧性改善的多峰型乙烯类聚合物组合物 |
SG11202005775UA (en) * | 2017-12-26 | 2020-07-29 | Dow Global Technologies Llc | Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures |
US11680119B2 (en) | 2017-12-26 | 2023-06-20 | Dow Global Technologies Llc | Process for the production of multimodal ethylene-based polymers |
EP3732215B8 (en) | 2017-12-26 | 2022-04-27 | Dow Global Technologies LLC | Dual reactor solution process for the production of multimodal ethylene-based polymer |
KR102013170B1 (ko) * | 2018-04-05 | 2019-08-22 | 대림산업 주식회사 | 폴리올레핀 수지 조성물 및 이의 제조방법 |
EP3867287A1 (en) * | 2018-10-15 | 2021-08-25 | Total Research & Technology Feluy | Polyethylene resins |
KR102116476B1 (ko) * | 2019-01-18 | 2020-05-28 | 대림산업 주식회사 | 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지 |
US20220298317A1 (en) * | 2019-09-03 | 2022-09-22 | Sabic Global Technologies B.V. | Package comprising a bi-directionally oriented polyethylene film |
KR102525719B1 (ko) * | 2019-11-28 | 2023-04-26 | 한화솔루션 주식회사 | 올레핀계 중합체 필름 및 그 제조방법 |
CA3172230A1 (en) * | 2020-04-01 | 2021-10-07 | Swapnil B. CHANDAK | Bimodal linear low density polyethylene copolymer |
CN118055965A (zh) | 2021-10-04 | 2024-05-17 | 埃克森美孚化学专利公司 | 聚乙烯共混物,其膜及其方法 |
WO2023120668A1 (ja) * | 2021-12-23 | 2023-06-29 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法及び触媒組成物 |
WO2023216022A1 (en) * | 2022-05-07 | 2023-11-16 | Dow Global Technologies Llc | A breathable, biaxially-oriented polyethylene film |
Family Cites Families (17)
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ATE212648T1 (de) | 1996-05-17 | 2002-02-15 | Bp Chem Int Ltd | Polyolefinzusammensetzung, deren molekulargewichtsmaximum sich in dem teil der zusammensetzung mit dem höheren comonomergehalt befindet |
JP4553924B2 (ja) | 1996-05-17 | 2010-09-29 | ザ ダウ ケミカル カンパニー | 共重合体の製造方法およびそれを含有するブレンド組成物 |
US6255426B1 (en) | 1997-04-01 | 2001-07-03 | Exxon Chemical Patents, Inc. | Easy processing linear low density polyethylene |
CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
CN101155841B (zh) | 2005-02-09 | 2011-06-08 | 英尼奥斯欧洲有限公司 | 共聚物及其薄膜 |
ES2484043T3 (es) * | 2006-06-27 | 2014-08-08 | Univation Technologies, Llc | Procesos de polimerización mejorados que utilizan catalizadores de metaloceno, sus productos polímeros y usos finales |
BRPI0712945B1 (pt) * | 2006-06-27 | 2018-05-08 | Univation Tech Llc | Processo para a produção de um Copolímero de Etileno Alfa- Olefina |
GB2458160A (en) * | 2008-03-07 | 2009-09-09 | Exxonmobil Chem Patents Inc | High MIR linear polyethylene, in co-extruded films |
EP2177548A1 (en) | 2008-10-14 | 2010-04-21 | Ineos Europe Limited | Copolymers and films thereof |
US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US8383754B2 (en) * | 2010-04-19 | 2013-02-26 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing high Mz/Mw polyolefins |
CA2734167C (en) * | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
CA2742454C (en) * | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
TWI460221B (zh) | 2011-07-08 | 2014-11-11 | Total Res & Technology Feluy | 經茂金屬催化之聚乙烯 |
CA2798855C (en) * | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
CA2780508A1 (en) * | 2012-06-21 | 2013-12-21 | Nova Chemicals Corporation | Polyethylene composition, film and polymerization process |
-
2013
- 2013-12-04 CA CA2835740A patent/CA2835740C/en active Active
- 2013-12-04 WO PCT/CA2013/001002 patent/WO2014089671A1/en active Application Filing
- 2013-12-04 DK DK13862866.4T patent/DK2931763T3/da active
- 2013-12-04 BR BR112015014121-8A patent/BR112015014121B1/pt active IP Right Grant
- 2013-12-04 ES ES13862866.4T patent/ES2663020T3/es active Active
- 2013-12-04 MX MX2015007292A patent/MX2015007292A/es active IP Right Grant
- 2013-12-04 EP EP13862866.4A patent/EP2931763B1/en active Active
- 2013-12-04 CN CN201380065313.9A patent/CN104918972B/zh active Active
- 2013-12-04 JP JP2015546784A patent/JP6231579B2/ja active Active
- 2013-12-04 KR KR1020157016006A patent/KR102121298B1/ko active IP Right Grant
- 2013-12-04 NO NO13862866A patent/NO2931763T3/no unknown
Also Published As
Publication number | Publication date |
---|---|
EP2931763B1 (en) | 2018-01-31 |
BR112015014121B1 (pt) | 2021-04-06 |
CA2835740A1 (en) | 2014-06-14 |
EP2931763A1 (en) | 2015-10-21 |
KR102121298B1 (ko) | 2020-06-11 |
WO2014089671A1 (en) | 2014-06-19 |
BR112015014121A2 (pt) | 2017-07-11 |
CN104918972A (zh) | 2015-09-16 |
CN104918972B (zh) | 2018-01-02 |
JP2016504442A (ja) | 2016-02-12 |
MX2015007292A (es) | 2015-09-10 |
JP6231579B2 (ja) | 2017-11-15 |
NO2931763T3 (da) | 2018-06-30 |
KR20150096665A (ko) | 2015-08-25 |
ES2663020T3 (es) | 2018-04-10 |
CA2835740C (en) | 2020-12-29 |
EP2931763A4 (en) | 2016-07-20 |
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