DK2755816T3 - Fremgangsmåde til fremstilling af et kompositmateriale under anvendelse af en nedbrydelig membran - Google Patents
Fremgangsmåde til fremstilling af et kompositmateriale under anvendelse af en nedbrydelig membran Download PDFInfo
- Publication number
- DK2755816T3 DK2755816T3 DK12801731.6T DK12801731T DK2755816T3 DK 2755816 T3 DK2755816 T3 DK 2755816T3 DK 12801731 T DK12801731 T DK 12801731T DK 2755816 T3 DK2755816 T3 DK 2755816T3
- Authority
- DK
- Denmark
- Prior art keywords
- degradable membrane
- membrane
- degradation
- resin
- degradable
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims description 144
- 239000002131 composite material Substances 0.000 title claims description 51
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 229920005989 resin Polymers 0.000 claims description 60
- 239000011347 resin Substances 0.000 claims description 60
- 239000000463 material Substances 0.000 claims description 52
- 230000002787 reinforcement Effects 0.000 claims description 43
- 230000015556 catabolic process Effects 0.000 claims description 36
- 238000006731 degradation reaction Methods 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 31
- 239000002904 solvent Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 230000008859 change Effects 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- 230000035699 permeability Effects 0.000 claims description 12
- 230000003014 reinforcing effect Effects 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 230000000977 initiatory effect Effects 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000000859 sublimation Methods 0.000 claims description 2
- 230000008022 sublimation Effects 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000010410 layer Substances 0.000 description 73
- 239000000835 fiber Substances 0.000 description 29
- 239000010408 film Substances 0.000 description 14
- 239000011162 core material Substances 0.000 description 10
- 239000011152 fibreglass Substances 0.000 description 9
- 239000000470 constituent Substances 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 238000013459 approach Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 240000007182 Ochroma pyramidale Species 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007596 consolidation process Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000009745 resin transfer moulding Methods 0.000 description 1
- 239000012056 semi-solid material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000013501 sustainable material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
- B29C70/443—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding and impregnating by vacuum or injection
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/54—Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
- B29C70/543—Fixing the position or configuration of fibrous reinforcements before or during moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
- B29K2025/04—Polymers of styrene
- B29K2025/06—PS, i.e. polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/06—Unsaturated polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0059—Degradable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
- B29L2031/082—Blades, e.g. for helicopters
- B29L2031/085—Wind turbine blades
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
Claims (13)
1. Fremgangsmåde til fremstilling af et kompositmateriale, som omfatter de følgende trin: - anbringe mindst ét forstærkningslag (2, 3, 4) på den indvendige flade af en form (6, 6a, 6b), - positionere en nedbrydelig membran (1) på det yderste forstærkningslag (2) af det mindst ét forstærkningslag (2, 3, 4), hvor den nedbrydelige membran (1) er fremstillet af et materiale, som har en mindre luftgennemtrængelighed end det mindst ét forstærkningslag, - anvende sugning mellem den indvendige flade af formen (6, 6a, 6b) og den nedbrydelige membran (1) til at presse det mindst ét forstærkningslag (2, 3, 4) mod den indvendige flade af formen (6, 6a, 6b), - dække den nedbrydelige membran (1) i det mindste delvist med mindst én vakuumfilm (9), - generere et vakuum i området mellem vakuumfilm (9) og formen (6, 6a, 6b), - indsprøjte harpiks i dette område ved hjælp af vakuum, og - lade harpiksen hærde, hvor fremgangsmåden omfatter initiering af en nedbrydning af den nedbrydelige membran (1) ved at forårsage en fysisk eller kemisk forandring af membranmaterialet efter at have genereret et vakuum i området mellem vakuumfilmen (9) og formen (6) og før harpiksen er fuldstændig hærdet.
2. Fremgangsmåde ifølge krav 1, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved hjælp af et nedbrydningsmiddel, der indføres som en gas i vakuummet eller som en del af harpiksen.
3. Fremgangsmåde ifølge krav 1 eller krav 2, - hvor harpiksen, f.eks. et materiale af umættet polyester, omfatter et opløsningsmiddel, og den nedbrydelige membran (1) er fremstillet af et materiale, f.eks. et syntetisk plastmateriale, som er opløseligt i opløsningsmidlet, som omfatter harpiks.
4. Fremgangsmåde ifølge et af kravene 1 til 3, - hvor harpiksen omfatter styren, og den nedbrydelige membran (1) er fremstillet af et materiale, som omfatter polystyren.
5. Fremgangsmåde ifølge et af kravene 1 til 3, - hvor harpiksen omfatter et akrylat, et methakrylat eller et fortyndingsmiddel, og den nedbrydelige membran (1) omfatter et materiale, som er opløseligt i den respektive harpiks.
6. Fremgangsmåde ifølge et af kravene 1 til 5, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved at hælde vand på den nedbrydelige membran, og hvor den nedbrydelige membran (1) omfatter et materiale, som kan opløses eller nedbrydes i vand.
7. Fremgangsmåde ifølge krav 1 til 6, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved at udsætte den nedbrydelige membran (1) til en kemisk substans, der er forskellig fra et opløsningsmiddel.
8. Fremgangsmåde ifølge et af kravene 1 til 7, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved at opvarme den nedbrydelige membran (1) til en temperatur, der er højere end en forudbestemt temperatur.
9. Fremgangsmåde ifølge et af kravene 1 til 8, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved at forårsage en sublimation af den nedbrydelige membran (1).
10. Fremgangsmåde ifølge et af kravene 1 til 9, - hvor nedbrydningen af den nedbrydelige membran (1) initieres med en ændring af vakuumbetingelserne i området mellem vakuumfilmen (9) og formen (6, 6a, 6b).
11. Fremgangsmåde ifølge et af kravene 1 til 10, - hvor nedbrydningen af den nedbrydelige membran (1) initieres ved at udsætte den nedbrydelige membran (1) for lys eller ved hjælp af molekylær nedbrydning.
12. Fremgangsmåde ifølge et af kravene 1 til 11, - hvor den nedbrydelige membran (1) er enten fuldstændig uigennemtrængelig eller delvis gennemtrængelig, f.eks. perforeret, på det tidspunkt, hvor den nedbrydelige membran (1) er anbragt på det yderste forstærkningslag (2) af det mindst ét forstærkningslag (2, 3, 4).
13. Fremgangsmåde ifølge et af kravene 1 til 12, - hvor den nedbrydelige membran (1) er stiv, strækbar, fastgjort til et bærermedium og/eller fremstillet direkte øverst på det yderste forstærkningslag (2) eller øverst på et bærermedium.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11195628.0A EP2607059A1 (en) | 2011-12-23 | 2011-12-23 | Method for manufacturing a composite using a degradable membrane |
| PCT/EP2012/075321 WO2013092359A2 (en) | 2011-12-23 | 2012-12-13 | Method for manufacturing a composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2755816T3 true DK2755816T3 (da) | 2016-01-25 |
Family
ID=47358462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12801731.6T DK2755816T3 (da) | 2011-12-23 | 2012-12-13 | Fremgangsmåde til fremstilling af et kompositmateriale under anvendelse af en nedbrydelig membran |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9610736B2 (da) |
| EP (2) | EP2607059A1 (da) |
| JP (1) | JP5980348B2 (da) |
| KR (1) | KR20140107607A (da) |
| CN (1) | CN103998212B (da) |
| BR (1) | BR112014015353A2 (da) |
| CA (1) | CA2862025C (da) |
| DK (1) | DK2755816T3 (da) |
| IN (1) | IN2014DN03071A (da) |
| MX (1) | MX354554B (da) |
| WO (1) | WO2013092359A2 (da) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2799215B1 (en) * | 2013-05-02 | 2018-09-19 | Siemens Aktiengesellschaft | Perforated vacuum membrane for fibre reinforced laminates |
| EP2952315A1 (en) | 2014-06-02 | 2015-12-09 | Siemens Aktiengesellschaft | A method for manufacturing a single- or multi-cell composite material structure |
| DK3708825T3 (da) * | 2019-03-12 | 2023-11-13 | Lm Wind Power As | Vindmøllevinge og fremgangsmåde til fremstilling af en vindmøllevinge |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58136412A (ja) * | 1982-02-09 | 1983-08-13 | Showa Highpolymer Co Ltd | 絵付け成形品の製造法 |
| US6630095B2 (en) | 2001-08-01 | 2003-10-07 | Lockheed Martin Corporation | Method for making composite structures |
| DK176335B1 (da) | 2001-11-13 | 2007-08-20 | Siemens Wind Power As | Fremgangsmåde til fremstilling af vindmöllevinger |
| JP4160771B2 (ja) * | 2002-04-18 | 2008-10-08 | 三菱レイヨン株式会社 | 繊維強化プラスチック成形体の成形装置とその成形方法 |
| EP1740368B1 (en) * | 2004-04-29 | 2010-04-14 | Cook Composites & Polymers Company | In-mold coating by a multiple step infusion process |
| GB0702781D0 (en) | 2007-02-13 | 2007-03-21 | Airbus Uk Ltd | Method of processing a composite material |
| EP2123431B1 (en) * | 2008-05-21 | 2011-03-02 | Siemens Aktiengesellschaft | Method for manufacturing a composite |
-
2011
- 2011-12-23 EP EP11195628.0A patent/EP2607059A1/en not_active Withdrawn
-
2012
- 2012-12-13 MX MX2014007702A patent/MX354554B/es active IP Right Grant
- 2012-12-13 BR BR112014015353A patent/BR112014015353A2/pt not_active Application Discontinuation
- 2012-12-13 US US14/367,905 patent/US9610736B2/en active Active
- 2012-12-13 DK DK12801731.6T patent/DK2755816T3/da active
- 2012-12-13 IN IN3071DEN2014 patent/IN2014DN03071A/en unknown
- 2012-12-13 EP EP12801731.6A patent/EP2755816B1/en active Active
- 2012-12-13 KR KR1020147020763A patent/KR20140107607A/ko active IP Right Grant
- 2012-12-13 CN CN201280063812.XA patent/CN103998212B/zh active Active
- 2012-12-13 JP JP2014547857A patent/JP5980348B2/ja not_active Expired - Fee Related
- 2012-12-13 WO PCT/EP2012/075321 patent/WO2013092359A2/en active Application Filing
- 2012-12-13 CA CA2862025A patent/CA2862025C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014015353A8 (pt) | 2017-06-13 |
| JP5980348B2 (ja) | 2016-08-31 |
| CN103998212A (zh) | 2014-08-20 |
| CA2862025A1 (en) | 2013-06-27 |
| BR112014015353A2 (pt) | 2017-06-13 |
| MX2014007702A (es) | 2014-08-21 |
| WO2013092359A3 (en) | 2013-08-15 |
| KR20140107607A (ko) | 2014-09-04 |
| US9610736B2 (en) | 2017-04-04 |
| WO2013092359A2 (en) | 2013-06-27 |
| JP2015506282A (ja) | 2015-03-02 |
| US20140361468A1 (en) | 2014-12-11 |
| EP2755816A2 (en) | 2014-07-23 |
| EP2607059A1 (en) | 2013-06-26 |
| CA2862025C (en) | 2019-05-14 |
| CN103998212B (zh) | 2017-07-04 |
| IN2014DN03071A (da) | 2015-05-15 |
| MX354554B (es) | 2018-03-09 |
| EP2755816B1 (en) | 2015-10-28 |
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