DK2643154T3 - Fleksibel undervandsslange omfattende et lag omfattende en polymerharpiks med aluminium- eller magnesiumsilicatnanorør. - Google Patents
Fleksibel undervandsslange omfattende et lag omfattende en polymerharpiks med aluminium- eller magnesiumsilicatnanorør. Download PDFInfo
- Publication number
- DK2643154T3 DK2643154T3 DK11790933.3T DK11790933T DK2643154T3 DK 2643154 T3 DK2643154 T3 DK 2643154T3 DK 11790933 T DK11790933 T DK 11790933T DK 2643154 T3 DK2643154 T3 DK 2643154T3
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- DK
- Denmark
- Prior art keywords
- group
- polymer
- nanotube
- groups
- bond
- Prior art date
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- 239000002071 nanotube Substances 0.000 title claims description 101
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 title claims description 34
- 229910052919 magnesium silicate Inorganic materials 0.000 title claims description 34
- 235000019792 magnesium silicate Nutrition 0.000 title claims description 34
- 239000000391 magnesium silicate Substances 0.000 title claims description 34
- 239000002952 polymeric resin Substances 0.000 title claims description 24
- 229920003002 synthetic resin Polymers 0.000 title claims description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 title 1
- 229920000642 polymer Polymers 0.000 claims description 126
- 239000004952 Polyamide Substances 0.000 claims description 44
- 229920002647 polyamide Polymers 0.000 claims description 44
- -1 polyethylene Polymers 0.000 claims description 37
- 239000004698 Polyethylene Substances 0.000 claims description 35
- 229920000573 polyethylene Polymers 0.000 claims description 35
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 30
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 30
- 125000003545 alkoxy group Chemical group 0.000 claims description 26
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- 238000004132 cross linking Methods 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 150000008064 anhydrides Chemical group 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 238000001125 extrusion Methods 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 150000002978 peroxides Chemical class 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229940124530 sulfonamide Drugs 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- 239000002033 PVDF binder Substances 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 3
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 229960002366 magnesium silicate Drugs 0.000 claims 6
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 63
- 239000012530 fluid Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 150000001412 amines Chemical group 0.000 description 11
- 230000007062 hydrolysis Effects 0.000 description 11
- 238000006460 hydrolysis reaction Methods 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 125000005372 silanol group Chemical group 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- 238000004299 exfoliation Methods 0.000 description 6
- 230000000930 thermomechanical effect Effects 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011295 pitch Substances 0.000 description 5
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- 241000009298 Trigla lyra Species 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000012412 chemical coupling Methods 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 229920000299 Nylon 12 Polymers 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229920000571 Nylon 11 Polymers 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004697 Polyetherimide Substances 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229910052621 halloysite Inorganic materials 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001601 polyetherimide Polymers 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- 229920006375 polyphtalamide Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical compound C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical class CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- WTMJHBZSSSDBFQ-UHFFFAOYSA-N 2,3,4-trimethyl-1h-pyrrole Chemical compound CC1=CNC(C)=C1C WTMJHBZSSSDBFQ-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- NEUMXSJTLLVTAD-UHFFFAOYSA-N CC(C)(C)C1=CC=CC(P(O)(O)O)=C1C(C)(C)C Chemical compound CC(C)(C)C1=CC=CC(P(O)(O)O)=C1C(C)(C)C NEUMXSJTLLVTAD-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 150000001263 acyl chlorides Chemical class 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 1
- 229910052898 antigorite Inorganic materials 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- VCIZMGNKKFEEHA-UHFFFAOYSA-N chembl1082237 Chemical compound C=1C=C2C(NC(=O)CCC)=NNC2=CC=1C1=CC=C(O)C=C1 VCIZMGNKKFEEHA-UHFFFAOYSA-N 0.000 description 1
- AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical group OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 description 1
- 229910052620 chrysotile Inorganic materials 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 229940026231 erythorbate Drugs 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 229920006017 homo-polyamide Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052899 lizardite Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical group ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
- B32B1/08—Tubular products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
- F16L11/08—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
- F16L11/081—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more layers of a helically wound cord or wire
- F16L11/083—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more layers of a helically wound cord or wire three or more layers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17D—PIPE-LINE SYSTEMS; PIPE-LINES
- F17D1/00—Pipe-line systems
- F17D1/08—Pipe-line systems for liquids or viscous products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/0318—Processes
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Water Supply & Treatment (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (14)
1. Fleksibelt undervandsrør beregnet til transport af væsker, især carbonhy-drider omfattende en række lag, hvor mindst et lag heraf omfatter en polymerharpiks omfattende mindst et aluminiumsilicat- eller magnesiumsilicatnanorør kemisk forbundet til polymeren via en covalent binding.
2. Fleksibelt undervandsrør ifølge krav 1, hvor polymeren og nævnte mindst ene aluminiumsilicat- eller magnesiumsilicat-nanorør er forbundet via en esterbinding, amidbinding, aminbinding, etherbinding, thioetherbinding, urinstofbinding, iminbinding, imidbinding, sulfonamidbinding, carbamatbinding, phosphat-binding, siloxanbinding, silanbinding eller carbon-carbontypen.
3. Fleksibelt undervandsrør ifølge et vilkårligt af kravene 1 til 2, hvor polymeren er et polyamid eventuelt indbefattet funktionelle laterale kæder, en polyethy-len indbefattet funktionelle laterale kæder eller en polyvinylidenfluorid indbefattet funktionelle laterale kæder.
4. Fleksibelt undervandsrør ifølge et vilkårligt af kravene 1 til 3, hvor nævnte mindst ene nanorør omfatter en kemisk forbindelse valgt fra: - et antikorrosionsmiddel og/eller - en C02-, H2S-, 02- og/eller CFU-sensor, og/eller - et antioxidantmiddel.
5. Fleksibelt undervandsrør ifølge et vilkårligt af kravene 1 til 4 omfattende, udover laget omfattende et polymerharpiks omfattende mindst et alumino-silicat- eller magnesiumsilicat-nanorør kemisk forbundet til polymeren via en covalent binding, et eller flere af de følgende lag: - en ekstern polymerskede, og/eller - mindst et trækstyrkearmeringsnet, og/eller - eventuelt en trykbeholder og/eller - eventuelt et metalskelet.
6. Fremgangsmåde til fremstilling af en fleksibelt undervandsrør ifølge et vilkårligt af kravene 1 til 5 omfattende følgende trin: a) blanding af polymer og mindst et aluminium-silicat- eller magnesium-silicatnanorør med mindst en gruppe A, som kan danne en covalent binding med nævnte polymer, b) ekstrusion til dannelse af et lag omfattende nævnte harpiks, c) samling af laget opnået i trin b) med mindst et andet lag.
7. Fremgangsmåde ifølge krav 6, hvor nævnte gruppe A er: - enten en gruppe G valgt fra: - en gruppe valgt fra halogen, -OFI, -COOFI, -NH2, -SH, -OSi(R7)(R8)(R9) og alkoxyl, og - en mættet, umættet eller aromatisk, lineær, forgrenet eller cyklisk car-bonhydridkæde, substitueret med en eller flere grupper valgt fra Hal, -CO-Hal, -OCO-Hal, -S02-Hal, -COOH, -OH, -SH, -CN, -NCO, -OSi(R7)-(R8)(R9), -CR-|R2-Hal, -NR-|H,
hvor, - R7, R8 og R9 er uafhængigt OH, en alkyl eller en alkoxyl, - R-ι, R2 og R3 er uafhængigt H eller en mættet, umættet eller aromatisk, lineær, forgrenet eller cyklisk carbonhydridkæde, eventuelt selv substitueret med en eller flere grupper valgt fra gruppen halogen eller a -CO-Hal, -OCO-Hal, -S02-Hal, -COOR4, -COR4, -CR4Rs-Hal, -OR4, -SR4, -NR4R5, NR4COR5, -COR4NR5, -NR4-CO-NR5R6, -O-CO-NR4, -NR4-CO-ORs, -CN, -NO2, -NCO,
hvor R4, R5 og R6 uafhængigt er H eller en mættet, umættet eller aromatisk, lineær, forgrenet eller cyklisk carbonhydridkæde, - Hal er et halogen valgt fra chlor, brom og iod, - eller en gruppe -O-POSS, hvor POSS er en polyhedral oligomer silses-quioxan: - med formlen (RSiO-i,5)x, hvor: - x er et helt tal større end eller lig med 6 og mindre end eller lig med 12, og - R repræsenterer: - en gruppe G som defineret ovenfor, eller - en mættet, umættet eller aromatisk, lineær, forgrenet eller cyklisk carbonhydridkæde, under forudsætning af at grupperne R for hver gruppe RSiOi,5 kan være identiske eller forskellige fra hinanden, og at mindst en gruppe R repræsenterer en gruppe G, eller - med formlen [(RSi015)x'(XRSiOl!o)x"], hvor: - x' og x" uafhængigt af hinanden er et helt tal således, at summen af x' og x" er større end eller lig med 6 og mindre end eller lig med 12, og - R er som defineret ovenfor, og - X repræsenterer en gruppe G som defineret ovenfor, idet grupperne X for hver gruppe XRSiOi,0, som kan være identiske eller forskellige med hinanden, og identisk med eller forskellig fra R, idet det forudsættes at nabostillede grupper A kan være bundet til hinanden via en POSS.
8. Fremgangsmåde ifølge krav 7, hvor nævnte gruppe A er valgt fra: - en gruppe G’ valgt fra gruppen alkoxyl, -OH og -OSi(R7)(R8)(R9), hvor R7, R8 og R9 uafhængigt er OH, en alkylgruppe eller en alkoxylgruppe, og - en gruppe O-POSS, hvor POSS har: - formlen (R'SiOi,5)x, hvor x er et helt tal større end eller lig med 6 og mindre end eller lig med 12, og hvor R’ repræsenterer: - en gruppe G’ som defineret ovenfor, eller - en mættet, umættet eller aromatisk, lineær, forgrenet eller cyklisk carbonhydridkæde, idet det skal bemærkes, at grupperne R’ fra hver gruppe R'SiOi,5 kan være identiske eller forskellige fra hinanden, og at mindst en gruppe R’ repræsenterer en gruppe G’, eller -formlen [(R'SiOi,5)x'(G'R'SiOi,o)x»], hvor: - x’ og x” uafhængigt af hinanden er et helt tal med x’ forskelligt fra 0, således at summen af x’ og x” er større end eller lig med 6 og mindre end eller lig med 12, og - R’ er som defineret ovenfor, og - grupperne G’ for hver gruppe G'R'SiO-ι,ο kan være identiske eller forskellige fra hinanden og identiske eller forskellige fra R’.
9. Fremgangsmåde ifølge krav 8, hvor nævnte gruppe A er en gruppe G’ valgt fra gruppen alkoxyl, -OH og -OSi(R7)(R8)(R9), hvor R7, R8 og R9 uafhængigt er OH, alkyl eller alkoxyl.
10. Fremgangsmåde ifølge et vilkårligt af kravene 6 til 9, hvor: - polymeren er en polyamid eventuelt omfattende funktionelle laterale kæder, og nævnte mindst ene nanorør er bærer af mindst en af grupperne -OH, NH2 eller COOH, - polymeren er en polyethylen indbefattet funktionelle laterale kæder som bærergrupper med formlen -Si-(ORio)(ORn)(ORi2), hvor R10, Ru og Ri2 er uafhængige alkylgrupper, og nævnte mindst ene nanorør er bærer af mindst en af grupperne -OH, -OSi(R7)(R8)(R9) eller alkoxyl, hvor R7, Rs og R9 uafhængigt repræsenterer OH, alkyl eller alkoxyl, eller - polymeren er en polyvinylidinfluorid indbefattet funktionelle laterale kæder med COOH-grupper eller anhydridgrupper, og nævnte mindst ene nanorør er en bærer af mindst en -OH-gruppe.
11. Fremgangsmåde ifølge et vilkårligt af kravene 6 til 10 omfattende et efterfølgende trin d) til tværbinding af samlingen opnået i løbet af trin c), hvor den covalente binding, som eventuelt kan dannes mellem gruppe A båret af alumi-no-silicat- eller magnesiumsilicat-nanorøret, og polymeren er en siloxanbinding.
12. Fremgangsmåde ifølge et vilkårligt af kravene 6 til 11 til fremstilling af et fleksibelt undervandsrør omfattende mindst et lag omfattende en polyethylen-polymerharpiks indbefattet lateral kæde med formlen -CH2-CH2-Si-(OR-i0)-(ORh)(ORi2), hvor R10, Ru og R-|2 uafhængigt er alkylgrupper, omfattende trinnene: a-ι) smeltning af en polyethylenpolymer, a2) tilsætning af et vinylsilanderivat med formlen CH2=CH-Si-(ORi0)(ORn)-(ORi2), en peroxidinitiator og mindst et alumino-silicat- eller magnesium-silicatnanorør med en bærer af hydroxyl, trialkoxysilan eller alkoxyl for at opnå en polyethylen indbefattet funktionelle laterale kæder, a3) blanding af polyethylenet, en katalysator for tværbindingsreaktionen, eventuelt en antioxidant og/eller en stabilisator, b) ekstrudering heraf til dannelse af et lag omfattende nævnte harpiks, c) samling af laget opnået i trin b) med mindst et andet lag, d) tværbinding af samlingen opnået i løbet af trin c), idet det underforstås at trinnene a2, a3 og b) kan udføres samtidigt.
13. Anvendelse af et fleksibelt undervandsrør ifølge et vilkårligt af kravene 1 til 5 til transport af væsker.
14. Anvendelse ifølge krav 13 til transport af carbonhydrider.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1059735A FR2968060B1 (fr) | 2010-11-25 | 2010-11-25 | Conduite flexible sous marine comprenant une couche comprenant une resine polymere comprenant des nanotubes alumino- ou magnesiosilicate |
| PCT/EP2011/070914 WO2012069577A1 (fr) | 2010-11-25 | 2011-11-24 | Conduite flexible sous marine comprenant une couche comprenant une résine polymère comprenant des nanotubes alumino- ou magnésiosilicate |
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| Publication Number | Publication Date |
|---|---|
| DK2643154T3 true DK2643154T3 (da) | 2015-02-16 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK11790933.3T DK2643154T3 (da) | 2010-11-25 | 2011-11-24 | Fleksibel undervandsslange omfattende et lag omfattende en polymerharpiks med aluminium- eller magnesiumsilicatnanorør. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9664311B2 (da) |
| EP (1) | EP2643154B1 (da) |
| AU (1) | AU2011333758B2 (da) |
| BR (1) | BR112013012942B1 (da) |
| DK (1) | DK2643154T3 (da) |
| FR (1) | FR2968060B1 (da) |
| MY (1) | MY156646A (da) |
| WO (1) | WO2012069577A1 (da) |
Families Citing this family (6)
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| FR2954451B1 (fr) * | 2009-12-21 | 2012-03-02 | Technip France | Conduite flexible sous-marine comprenant une couche comprenant une resine polyamide comprenant un silsesquioxane oligomerique polyedrique |
| JP2012131876A (ja) * | 2010-12-21 | 2012-07-12 | Bridgestone Corp | ゴム組成物及びそれを用いたタイヤ |
| EP3234217B1 (en) * | 2014-12-19 | 2020-07-01 | Solvay Specialty Polymers Italy S.p.A. | Methods for making multilayer tubular articles |
| FR3050005B1 (fr) * | 2016-04-06 | 2018-05-04 | Technip France | Conduite sous-marine comprenant une gaine comprenant un homopolymere de polypropylene |
| CN106838494A (zh) * | 2017-04-07 | 2017-06-13 | 康红艳 | 一种连续柔性增强粘合型复合管 |
| FR3109195B1 (fr) * | 2020-04-08 | 2022-11-04 | Technip N Power | Conduite sous-marine comprenant une gaine interne d’étanchéité |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4150099A (en) | 1974-11-19 | 1979-04-17 | Exxon Research & Engineering Co. | Synthetic halloysites |
| US5651976A (en) | 1993-06-17 | 1997-07-29 | The United States Of America As Represented By The Secretary Of The Navy | Controlled release of active agents using inorganic tubules |
| US5705191A (en) | 1995-08-18 | 1998-01-06 | The United States Of America As Represented By The Secretary Of The Navy | Sustained delivery of active compounds from tubules, with rational control |
| ATE335583T1 (de) * | 2002-03-20 | 2006-09-15 | Nkt Flexibles Is | Verfahren zur herstellung einer polymerschicht eines flexiblen offshore-rohrs |
| GB2410308B (en) * | 2004-01-20 | 2008-06-25 | Uponor Innovation Ab | Multilayer pipe |
| US8567450B2 (en) * | 2005-01-12 | 2013-10-29 | Smart Pipe Company Lp | Methods and systems for in situ manufacture and installation of non-metallic high pressure pipe and pipe liners |
| FR2885672B1 (fr) | 2005-05-11 | 2007-06-22 | Technip France Sa | Conduite tubulaire flexible a gaine anti-usure |
| US7888419B2 (en) * | 2005-09-02 | 2011-02-15 | Naturalnano, Inc. | Polymeric composite including nanoparticle filler |
| JP2008105395A (ja) * | 2006-09-27 | 2008-05-08 | Denso Corp | 冷媒輸送用ホースおよびその製造方法 |
| EP2126439B1 (en) | 2007-03-16 | 2014-06-11 | National Oilwell Varco Denmark I/S | A flexible pipe |
| FR2918067B1 (fr) * | 2007-06-27 | 2011-07-01 | Arkema France | Materiau composite comprenant des nanotubes disperses dans une matrice polymerique fluroree. |
| FR2918081B1 (fr) * | 2007-06-27 | 2009-09-18 | Cabinet Hecke Sa | Procede d'impregnation de fibres continues par une matrice polymerique composite renfermant un polymere thermoplastique |
| KR20110111421A (ko) * | 2009-01-20 | 2011-10-11 | 알케마 인코포레이티드 | 고성능 커넥터 |
| FR2956183B1 (fr) * | 2010-02-09 | 2012-03-16 | Technip France | Conduite flexible sous-marine comprenant une couche comprenant une resine polymere comprenant des nanoparticules de titane modifiees en surface |
-
2010
- 2010-11-25 FR FR1059735A patent/FR2968060B1/fr not_active Expired - Fee Related
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2011
- 2011-11-24 WO PCT/EP2011/070914 patent/WO2012069577A1/fr active Application Filing
- 2011-11-24 DK DK11790933.3T patent/DK2643154T3/da active
- 2011-11-24 MY MYPI2013001888A patent/MY156646A/en unknown
- 2011-11-24 EP EP11790933.3A patent/EP2643154B1/fr active Active
- 2011-11-24 BR BR112013012942-5A patent/BR112013012942B1/pt active IP Right Grant
- 2011-11-24 AU AU2011333758A patent/AU2011333758B2/en active Active
- 2011-11-24 US US13/988,951 patent/US9664311B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US9664311B2 (en) | 2017-05-30 |
| EP2643154A1 (fr) | 2013-10-02 |
| BR112013012942B1 (pt) | 2020-12-29 |
| AU2011333758A1 (en) | 2013-07-04 |
| FR2968060A1 (fr) | 2012-06-01 |
| MY156646A (en) | 2016-03-15 |
| FR2968060B1 (fr) | 2013-06-21 |
| EP2643154B1 (fr) | 2014-11-05 |
| BR112013012942A2 (pt) | 2016-08-23 |
| US20130247996A1 (en) | 2013-09-26 |
| AU2011333758B2 (en) | 2015-09-24 |
| WO2012069577A1 (fr) | 2012-05-31 |
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