DK2086929T3 - Allyliske polysulfaner - Google Patents

Allyliske polysulfaner Download PDF

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Publication number
DK2086929T3
DK2086929T3 DK07824539.6T DK07824539T DK2086929T3 DK 2086929 T3 DK2086929 T3 DK 2086929T3 DK 07824539 T DK07824539 T DK 07824539T DK 2086929 T3 DK2086929 T3 DK 2086929T3
Authority
DK
Denmark
Prior art keywords
sulfur
polysulfides
diallyl
disulfide
diallylic
Prior art date
Application number
DK07824539.6T
Other languages
English (en)
Inventor
Eric Block
Murree Groom
Original Assignee
Ecospray Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0622549A external-priority patent/GB0622549D0/en
Priority claimed from GB0711308A external-priority patent/GB0711308D0/en
Application filed by Ecospray Ltd filed Critical Ecospray Ltd
Application granted granted Critical
Publication of DK2086929T3 publication Critical patent/DK2086929T3/da

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/22Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides
    • C07C319/24Preparation of thiols, sulfides, hydropolysulfides or polysulfides of hydropolysulfides or polysulfides by reactions involving the formation of sulfur-to-sulfur bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/12Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
    • C07C321/18Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/22Thiols, sulfides, hydropolysulfides, or polysulfides having thio groups bound to carbon atoms of rings other than six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Fodder In General (AREA)

Claims (15)

  1. ALLYLISKE POLYSULFANER E Forbindelse med formlen:
    hvor n er fra 3 til 22; og R1 er udvalgt fra gruppen omfattende: hydrogen; phenyl; carboethoxy; carbomethoxy; carboxy; hydroxymethyl; trimethylsilylmethyl; kortkædet alkyl, med 2, 3 eller 4 carbonatomer; chlor og fluor; forudsat at R1, når n er fra 3 til 8, ikke er hydrogen.
  2. 2. Forbindelse med formlen:
    hvor n er fra 9 til 22.
  3. 3. Fremgangsmåde til forlængelse af svovlkædelængden af diallyliske polysulfider omfattende 2 eller flere svovlatomer udvalgt fra gruppen omfattende: bis(2-propenyl)-polysulfider og bis(2-sub stitueret-2-propenyl) -poly sulfider; omfattende trinnene med blanding af den diallyliske polysulfid med elementært svovl og opvarmning af blandingen til en temperatur overstigende 50 “Celsius.
  4. 4. Fremgangsmåde ifølge krav 3, hvori blandingen opvarmes til en temperatur på eller overstigende smeltepunktet for elementært svovl.
  5. 5. Fremgangsmåde ifølge enten krav 3 eller 4, hvori den diallyliske polysulfid omfatter diallylpolysulfider.
  6. 6. Fremgangsmåde til forlængelse af svovlkædelængden af diallyliske polysulfider omfattende 2 eller flere svovlatomer udvalgt fra gruppen omfattende: bis(2-propenyl)-polysulfider og bis(2-substitueret-2-propenyl)-polysulfider; hvilken fremgangsmåde omfatter trinnene med blanding af den diallyliske polysulfid med smeltet svovl.
  7. 7. Fremgangsmåde ifølge et hvilket som helst af kravene 3 til 4, hvori de diallyliske polysulfider omfatter polysulfider med færre end 22 svovlatomer.
  8. 8. Forbindelse ifølge krav 1 med formlen:
    hvor R1 er udvalgt fra gruppen omfattende: phenyl; carboethoxy; carbomethoxy; carboxy; hydroxymethyl; trimethylsilylmethyl; kortkædet alkyl, med 2, 3 eller 4 carbonatomer; chlor og fluor; og n er fra 3 til 18.
  9. 9. Forbindelse med formlen:
    hvor n er fra 3 til 18.
  10. 10. Fremgangsmåde til fremstilling af en forbindelse ifølge krav 9 omfattende trinnet med blanding af 2-cyclohexen-l-yl-disulfid med smeltet svovl.
  11. 11. Forbindelse med formlen:
    hvor n er fra 3 til 18.
  12. 12. Fremgangsmåde til fremstilling af en forbindelse ifølge krav 11 omfattende: trinnet med blanding af 2-cyclopenten-l-yl-disulfid med smeltet svovl.
  13. 13. Fremgangsmåde til forlængelse af svovlkædelængden af allylmethylpolysulfider (MeSnCH2CH=CH2), hvor n>2, omfattende trinnene med blanding af allylmethylpolysulfiderne med elementært svovl og opvarmning af blandingen til en temperatur overstigende 50 °Celsius.
  14. 14. Fremgangsmåde ifølge krav 13, hvori blandingen opvarmes til en temperatur på eller overstigende smeltepunktet for elementært svovl.
  15. 15. Fremgangsmåde til forlængelse af svovlkædelængden af allylmethylpolysulfider (MeSnCH2CH=CH2), hvor n>2, omfattende trinnet med blanding af allylmethylpolysulfiderne med smeltet svovl.
DK07824539.6T 2006-11-11 2007-11-12 Allyliske polysulfaner DK2086929T3 (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0622549A GB0622549D0 (en) 2006-11-11 2006-11-11 Industrial processing of plants
GB0711308A GB0711308D0 (en) 2007-06-12 2007-06-12 Garlic processing
PCT/GB2007/004310 WO2008059217A1 (en) 2006-11-11 2007-11-12 Allylic polysulfanes

Publications (1)

Publication Number Publication Date
DK2086929T3 true DK2086929T3 (da) 2016-07-04

Family

ID=38858572

Family Applications (1)

Application Number Title Priority Date Filing Date
DK07824539.6T DK2086929T3 (da) 2006-11-11 2007-11-12 Allyliske polysulfaner

Country Status (9)

Country Link
US (2) US8658833B2 (da)
EP (2) EP2079686B1 (da)
JP (3) JP5414529B2 (da)
AU (2) AU2007320987B2 (da)
DK (1) DK2086929T3 (da)
ES (2) ES2402375T3 (da)
GB (2) GB2456269B (da)
PL (1) PL2086929T3 (da)
WO (2) WO2008059213A1 (da)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009055677A1 (en) * 2007-10-24 2009-04-30 University Of South Florida Antibacterial s-heterosubstituted disulfides
US9119872B2 (en) 2012-11-26 2015-09-01 M. A. Deepa Garlic formulation and a process for preparing the same for treatment of diabetes
GB2599620B (en) * 2020-08-04 2023-11-22 Hayne Lane Ltd Ectoparasiticide veterinary composition

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE754968A (nl) * 1969-08-18 1971-02-18 Int Flavors & Fragrances Inc Werkwijze voor de bereiding van lookaroma's, alsmede voor het verlenen van een look-aroma aan een voedingsmiddel
IN144278B (da) 1975-11-27 1978-04-22 Bhabha Atomic Research Centre
US4551259A (en) * 1983-12-14 1985-11-05 Mobil Oil Corporation Phenolic antioxidants and lubricants containing same
JPS60258157A (ja) * 1984-06-02 1985-12-20 Riken Kagaku Kogyo Kk トリサルファイド化合物の製造法
BE903756A (fr) 1985-12-02 1986-06-02 Ferrando Jorge A S Un nouveau tiquicide injectable et le procede utilise pour le produire.
JP2963730B2 (ja) * 1990-06-22 1999-10-18 湧永製薬株式会社 ポリスルフィド化合物及びこれを有効成分とする脂質過酸化抑制剤
JP3079319B2 (ja) 1991-08-14 2000-08-21 理研ヘルス株式会社 植物休眠打破剤
US5530163A (en) * 1995-01-23 1996-06-25 Phillips Petroleum Company Process for producing organic polysulfide compounds
HUP9700287A1 (en) 1997-01-31 1998-11-30 Kompozicio Ipari Process for producing of synthetic alliaceous ethereal oil
JPH11222410A (ja) * 1998-02-03 1999-08-17 Riken Health Kk 植物の枯損防除及び活性化剤
US6511674B1 (en) 1998-06-17 2003-01-28 Anthony Arand Garlic composition for foliar applications
HUP9802619A1 (hu) 1998-11-11 2000-06-28 KOMPOZÍCIÓ Ipari, Mezőgazdasági és Kereskedelmi Kft. Eljárás szintetikus fokhagyma-illóolaj előállítására
DE19854427A1 (de) * 1998-11-25 2000-05-31 Basf Ag Verfahren zur Herstellung von organischen Disulfiden
US6051739A (en) * 1999-01-26 2000-04-18 Phillips Petroleum Company Process for producing organic polysulfides
US6555712B2 (en) 2001-03-28 2003-04-29 Indian Institute Of Technology Process for the preparation of diorganotrisulfide
JP3725079B2 (ja) * 2002-01-21 2005-12-07 株式会社 北海道バイオインダストリ− ネギ属植物処理物
CN1565430A (zh) 2003-06-22 2005-01-19 毛友昌 大蒜素环糊精包合物、制剂及制备方法
KR100508923B1 (ko) 2003-06-27 2005-08-17 삼성에스디아이 주식회사 비수성 전해질 및 이를 포함하는 리튬 이차 전지
US20050079095A1 (en) 2003-10-09 2005-04-14 Rosa Crovetto Inhibition of corrosion in aqueous systems
FR2863144B1 (fr) 2003-12-09 2006-08-04 Diana Vegetal Biopesticide comprenant une composition riche en polysulfures de diallyle
GB2414912A (en) 2004-06-11 2005-12-14 Garlic Farms Use of garlic extract for sytematic treatment of growing crops
GB0506759D0 (en) * 2005-04-02 2005-05-11 Medical Res Council Combination treatment methods
GB0507227D0 (en) * 2005-04-09 2005-05-18 Ecospray Ltd A pesticide and repellent
JP2007261983A (ja) 2006-03-28 2007-10-11 National Agriculture & Food Research Organization デオキシグルコソン生成抑制剤
CN100518507C (zh) 2006-12-08 2009-07-29 罗山峰 含有有机多硫醚类化合物的组合物及其应用

Also Published As

Publication number Publication date
GB2456269B (en) 2011-09-28
US8658833B2 (en) 2014-02-25
GB2456269A (en) 2009-07-15
JP5689509B2 (ja) 2015-03-25
JP2010509304A (ja) 2010-03-25
EP2079686B1 (en) 2013-01-02
PL2086929T3 (pl) 2016-10-31
EP2086929B1 (en) 2016-03-30
EP2086929A1 (en) 2009-08-12
US20100274037A1 (en) 2010-10-28
JP5414529B2 (ja) 2014-02-12
AU2007320987A1 (en) 2008-05-22
AU2007320991B2 (en) 2012-01-12
ES2578262T3 (es) 2016-07-22
JP2013256523A (ja) 2013-12-26
GB2443936A (en) 2008-05-21
WO2008059217A1 (en) 2008-05-22
US8101802B2 (en) 2012-01-24
US20100069674A1 (en) 2010-03-18
JP2010509302A (ja) 2010-03-25
GB0907967D0 (en) 2009-06-24
EP2079686A1 (en) 2009-07-22
JP5351036B2 (ja) 2013-11-27
AU2007320991A1 (en) 2008-05-22
GB2443936B (en) 2011-02-16
WO2008059217A8 (en) 2008-08-07
ES2402375T3 (es) 2013-05-03
WO2008059213A1 (en) 2008-05-22
GB0722185D0 (en) 2007-12-19
AU2007320987B2 (en) 2011-09-01

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