DK1799796T3 - Gylleafvanding og konvertering af slam til et vedvarende brændstof - Google Patents

Gylleafvanding og konvertering af slam til et vedvarende brændstof Download PDF

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Publication number
DK1799796T3
DK1799796T3 DK05818601.6T DK05818601T DK1799796T3 DK 1799796 T3 DK1799796 T3 DK 1799796T3 DK 05818601 T DK05818601 T DK 05818601T DK 1799796 T3 DK1799796 T3 DK 1799796T3
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Denmark
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sludge
slurry
biosolids
process according
water
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DK05818601.6T
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English (en)
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Kevin M Bolin
Edward Overstreet
Brian Dooley
Norman L Dickinson
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Sgc Advisors Llc
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/42Solid fuels essentially based on materials of non-mineral origin on animal substances or products obtained therefrom, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/46Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/086Hydrothermal carbonization
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/001Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/001Runoff or storm water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4043Limiting CO2 emissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081Recycling aspects
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80Additives
    • C10G2300/805Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80Additives
    • C10G2300/805Water
    • C10G2300/807Steam
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Claims (25)

1. En proces til konvertering af slam til et brændstof omfattende trinnene: tilvejebringelse af slam omfattende celler og celleforbundet vand; udøvelse af tilstrækkeligt tryk på slammen for at bevare likviditet; opvarmning af slammen under tryk til en første temperatur tilstrækkelig til at nedbryde cellerne til at danne en gylle af nedbrudte slamceller; opvarmning af slammen til en anden temperatur tilstrækkelig til at udvikle kuldioxid fra slammen og danne en forkulningsgylle omfattende forkullede, nedbrudte slamceller; afkøling af forkulningsgylle af forkullede, nedbrudte slamceller til en temperatur tæt på omgivelsestemperaturen, mens forkulningsgyllen bevares under et tilstrækkeligt tryk for at undgå fordampning; trykbegrænsning af den afkølede forkulningsgylle af forkullede, nedbrudte slamceller til et nominelt tryk over det atmosfæriske tryk for at danne en flydende forkulningsgylle; separering af kuldioxid fra den flydende forkulningsgylle, og fjernelse af mindst en del af vandet fra den flydende forkulningsgylle for at tilvejebringe et mindst delvist afvandet slamprodukt af nedbrudte celler.
2. En proces ifølge krav 1, omfattende modtagelse af slam fra flere kilder, hvor slammen omfatter en første slamtilførsel, som er mere fortyndet, og en anden slamtilførsel, som er mere tyktflydende, og blanding af den mere fortyndede første slamtilførsel med den mere tyktflydende anden slamtilførsel for at få en slamtilførsel, som bedre kan pumpes.
3. En proces ifølge krav 3, hvor fjernelse af mindst en del af vandet tilvejebringer et mindst delvist afvandet kulprodukt, og omfatter, at kulproduktet reagerer med en gas omfattende oxygen for at konvertere dets brændstofværdi til en termisk energi, og derudover omfattende mindst et af trinnene, at den termiske energi anvendes og brændstoffet forbrændes.
4. En proces ifølge krav 1, hvor trinnet med udøvelse af tilstrækkeligt tryk omfatter tilvejebringelse afen pumpe, og hvor forstærkerpumper tilvejebringes nedstrømsfor at reducere pumpens krævede stagnationstryk.
5. En proces ifølge krav 1, hvor trinnet med udøvelse af tilstrækkeligt tryk omfatter tilvejebringelse af en pumpe, og hvor frit vand fra trinnet med fjernelse recirkuleres til trinnet med tilvejebringelse for at reducere pumpens krævede stagnationstryk.
6. En proces ifølge krav 3, hvor trinnet med fjernelse af mindst en del af vandet omfatter fjernelse af vandopløselige bestanddele fra forkulningsgyllen.
7. En proces ifølge krav 1, hvor trinnet med fjernelse af mindst en del af vandet derudover omfatter trinnet med fjernelse af frit vand fra mindst en af slammen og det delvist afvandede produkt som damp, hvorved der fremstilles et tørret produkt.
8. En proces ifølge krav 7, hvor det tørrede produkt er et tørret kulprodukt, og omfattende blanding af det tørrede kulprodukt med en brændstofolie for at danne en kul-olie-blanding.
9. En proces ifølge krav 7, omfattende blanding af forkulningsgyllen med en brændstofolie for at danne en kul-olie-blanding.
10. En proces ifølge krav 1, hvor det mindst delvist afvandede slamprodukt af nedbrudte celler er et kulprodukt.
11. En proces ifølge krav 10, derudover omfattende transport af kulproduktet til et kemisk anlæg og konvertering af kulproduktet til mindst et af en syntesegas, olie, oxiderede forbindelser, kulfibre, gødningsadditiver og kombinationer deraf.
12. En proces ifølge krav 1, hvor trinnet med fjernelse derudover omfatter genanvendelse af mindst en del af vandet til trinnet med tilvejebringelse.
13. En proces ifølge krav 10, derudover omfattende forbehandling af vand fjernet fra forkulningsgyllen.
14. En proces ifølge krav 13, hvor forbehandling af mindst en del af vandet danner en metangas.
15. En proces ifølge krav 13, inklusive genanvendelse af mindst en del af det forbehandlede vand til trinnet med tilvejebringelse.
16. En proces ifølge krav 13, derudover omfattende tilføjelse af et chelatdannende middel til vandet fjernet fra forkulningsgyllen.
17. En proces ifølge krav 1, derudover omfattende tilføjelse af mindst en af vand, varme, damp og en kombination deraf til slammen før trinnet med tilføjelse af tilstrækkeligt tryk på slammen.
18. En proces ifølge krav 1, omfattende mindst en af formaling og klipning af slammen før trinnet med tilføjelse af tilstrækkeligt tryk på slammen.
19. En proces ifølge krav 1, omfattende at si slammen før trinnet med tilføjelse af tilstrækkeligt tryk på slammen.
20. En proces ifølge krav 1, derudover omfattende mindst en af køling af gyllen før trykbegrænsning og køling af gyllen efter trykbegrænsning.
21. En proces ifølge krav 20, hvor trinnet med afkøling sker før trinnet med trykbegrænsning.
22. En proces ifølge krav 1, hvor trinnet med separering af kuldioxid derudover omfatter mindst et af trinnene: isolering af kuldioxid i mindst en afjord og et stort vandlegeme; rensning og anvendelse af kuldioxid for mindst en af karbonisering af drikkevarer, tryktilførsel af brandslukkere, spraydåsedrivgas, kølemiddel og iner beskyttelsesgas; anvendelse af kuldioxid som et blandbart flydemiddel til en tertiær oliegenindvinding; og kombinationer deraf.
23. En proces ifølge krav 3, hvor produceret aske anvendes i mindst en af cementovne, byggematerialer, kompost eller gødningsprodukt.
24. En proces ifølge krav 1, hvor opvarmning omfatter damp som et varmemedium.
25. En proces ifølge krav 1, hvor svovl indeholdt i kuldioxidgassen genereres i trinnet med separering, og inklusive fjernelse af svovl med emissionsbeskyttelsesudstyr.
DK05818601.6T 2004-11-10 2005-11-08 Gylleafvanding og konvertering af slam til et vedvarende brændstof DK1799796T3 (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62668004P 2004-11-10 2004-11-10
US11/269,499 US7909895B2 (en) 2004-11-10 2005-11-07 Slurry dewatering and conversion of biosolids to a renewable fuel
PCT/US2005/040544 WO2006053020A2 (en) 2004-11-10 2005-11-08 Slurry dewatering and conversion of biosolids to a renewable fuel

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US (4) US7909895B2 (da)
EP (1) EP1799796B1 (da)
JP (1) JP2008519687A (da)
KR (1) KR20070084297A (da)
AU (1) AU2005304556B2 (da)
BR (1) BRPI0517570B1 (da)
CA (1) CA2587205A1 (da)
DK (1) DK1799796T3 (da)
ES (1) ES2706007T3 (da)
MX (1) MX2007005619A (da)
PL (1) PL1799796T3 (da)
PT (1) PT1799796T (da)
RU (1) RU2373263C2 (da)
WO (1) WO2006053020A2 (da)

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US9228132B2 (en) 2016-01-05
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US20060096163A1 (en) 2006-05-11
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