DK1387862T3

DK1387862T3 - Polymer WITH IMPROVED permanence AND OVERFLADEAFFINITET

Polymer WITH IMPROVED permanence AND OVERFLADEAFFINITET Download PDF

Info

Publication number: DK1387862T3
Authority: DK; Denmark
Prior art keywords: tert; formula; butyl; hyperbranched; bis
Prior art date: 2001-05-17

Application number

DK02735353.1T

Other languages

Danish (da)

English (en)

Inventor

John James Mcnamara

Ying Dong

Mervin Gale Wood

Original Assignee

Basf Se

Priority date

2001-05-17

Filing date

2002-05-10

Publication date

2015-01-19

2002-05-10 Application filed by Basf Se filed Critical Basf Se

2015-01-19 Application granted granted Critical

2015-01-19 Publication of DK1387862T3 publication Critical patent/DK1387862T3/en

Links

229920000642 polymer Polymers 0.000 title description 72
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150000001875 compounds Chemical class 0.000 claims description 103
239000000203 mixture Substances 0.000 claims description 77
230000000996 additive effect Effects 0.000 claims description 74
229920001577 copolymer Polymers 0.000 claims description 68
239000000412 dendrimer Substances 0.000 claims description 48
229920000736 dendritic polymer Polymers 0.000 claims description 47
239000003381 stabilizer Substances 0.000 claims description 45
229920000587 hyperbranched polymer Polymers 0.000 claims description 41
238000000034 method Methods 0.000 claims description 29
229920001223 polyethylene glycol Polymers 0.000 claims description 26
125000000524 functional group Chemical group 0.000 claims description 21
PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 19
230000008569 process Effects 0.000 claims description 16
239000000126 substance Substances 0.000 claims description 16
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 15
125000005647 linker group Chemical group 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 12
125000000743 hydrocarbylene group Chemical group 0.000 claims description 11
239000011368 organic material Substances 0.000 claims description 9
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229940124543 ultraviolet light absorber Drugs 0.000 claims description 8
239000006097 ultraviolet radiation absorber Substances 0.000 claims description 7
XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 5
230000003647 oxidation Effects 0.000 claims description 5
238000007254 oxidation reaction Methods 0.000 claims description 5
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OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
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239000013538 functional additive Substances 0.000 claims description 4
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238000004519 manufacturing process Methods 0.000 claims description 2
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ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 7
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229920000877 Melamine resin Polymers 0.000 description 6
239000004721 Polyphenylene oxide Substances 0.000 description 6
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
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125000000217 alkyl group Chemical group 0.000 description 6
239000003054 catalyst Substances 0.000 description 6
230000008859 change Effects 0.000 description 6
JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 6
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NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
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239000004700 high-density polyethylene Substances 0.000 description 6
238000010348 incorporation Methods 0.000 description 6
SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 6
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HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 5
239000004593 Epoxy Substances 0.000 description 5
239000004793 Polystyrene Substances 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
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CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
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239000003921 oil Substances 0.000 description 4
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AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical group [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
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RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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150000001241 acetals Chemical class 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
150000007933 aliphatic carboxylic acids Chemical group 0.000 description 3
229920000180 alkyd Polymers 0.000 description 3
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PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
150000001408 amides Chemical class 0.000 description 3
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125000004122 cyclic group Chemical group 0.000 description 3
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JMFYZMAVUHNCPW-UHFFFAOYSA-N dimethyl 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound COC(=O)C(C(=O)OC)=CC1=CC=C(OC)C=C1 JMFYZMAVUHNCPW-UHFFFAOYSA-N 0.000 description 3
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238000012546 transfer Methods 0.000 description 3
150000003918 triazines Chemical class 0.000 description 3
238000009736 wetting Methods 0.000 description 3
CHJJYTIOLUWORE-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methyl dihydrogen phosphate Chemical compound CC(C)(C)C1=CC(COP(O)(O)=O)=CC(C(C)(C)C)=C1O CHJJYTIOLUWORE-UHFFFAOYSA-N 0.000 description 2
ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 2
GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
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QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
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