CA2444905C - Polymer additives with improved permanence and surface affinity - Google Patents

Info

Publication number

CA2444905C

CA2444905C CA2444905A CA2444905A CA2444905C CA 2444905 C CA2444905 C CA 2444905C CA 2444905 A CA2444905 A CA 2444905A CA 2444905 A CA2444905 A CA 2444905A CA 2444905 C CA2444905 C CA 2444905C

Authority

CA

Canada

Prior art keywords

tert

additive

butyl

bis

formula

Prior art date

2001-05-17

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

Links

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• 239000000654 additive Substances 0.000 title claims abstract description 152
• 229920000642 polymer Polymers 0.000 title abstract description 84
• 230000000996 additive effect Effects 0.000 claims abstract description 101
• 229920001577 copolymer Polymers 0.000 claims abstract description 83
• 239000000412 dendrimer Substances 0.000 claims abstract description 54
• 229920000736 dendritic polymer Polymers 0.000 claims abstract description 53
• 239000003381 stabilizer Substances 0.000 claims abstract description 52
• 150000001875 compounds Chemical class 0.000 claims description 121
• 229920000587 hyperbranched polymer Polymers 0.000 claims description 43
• 150000001412 amines Chemical class 0.000 claims description 42
• 238000000034 method Methods 0.000 claims description 33
• 229920001223 polyethylene glycol Polymers 0.000 claims description 25
• 125000000524 functional group Chemical group 0.000 claims description 21
• 230000008569 process Effects 0.000 claims description 21
• PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 20
• 239000000126 substance Substances 0.000 claims description 17
• 229940124543 ultraviolet light absorber Drugs 0.000 claims description 17
• 125000005647 linker group Chemical group 0.000 claims description 16
• 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 16
• 238000002360 preparation method Methods 0.000 claims description 14
• 125000000743 hydrocarbylene group Chemical group 0.000 claims description 11
• 239000004611 light stabiliser Substances 0.000 claims description 11
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 10
• AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 9
• 239000003963 antioxidant agent Substances 0.000 claims description 9
• SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 claims description 9
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
• 230000003078 antioxidant effect Effects 0.000 claims description 5
• 229910052698 phosphorus Inorganic materials 0.000 claims description 5
• 239000011574 phosphorus Substances 0.000 claims description 5
• XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 4
• 239000013538 functional additive Substances 0.000 claims description 4
• 239000000758 substrate Substances 0.000 abstract description 19
• -1 fatty acid diester Chemical class 0.000 description 79
• 239000000203 mixture Substances 0.000 description 76
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 63
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 49
• 239000000306 component Substances 0.000 description 39
• 229920000728 polyester Polymers 0.000 description 32
• 229920002521 macromolecule Polymers 0.000 description 24
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 23
• 239000000975 dye Substances 0.000 description 22
• 239000000178 monomer Substances 0.000 description 22
• 239000000243 solution Substances 0.000 description 22
• 239000003999 initiator Substances 0.000 description 21
• 229920001684 low density polyethylene Polymers 0.000 description 21
• 239000004702 low-density polyethylene Substances 0.000 description 21
• 150000002148 esters Chemical class 0.000 description 20
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 20
• 239000000463 material Substances 0.000 description 20
• 239000004970 Chain extender Substances 0.000 description 19
• 239000004743 Polypropylene Substances 0.000 description 19
• 229920001155 polypropylene Polymers 0.000 description 19
• ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical class OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 description 18
• 229920005989 resin Polymers 0.000 description 17
• 239000011347 resin Substances 0.000 description 17
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
• 239000004952 Polyamide Substances 0.000 description 15
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 14
• 229920002647 polyamide Polymers 0.000 description 14
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
• 229920006150 hyperbranched polyester Polymers 0.000 description 13
• 239000000976 ink Substances 0.000 description 13
• ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 13
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 12
• 239000004698 Polyethylene Substances 0.000 description 11
• 238000006243 chemical reaction Methods 0.000 description 11
• 239000000835 fiber Substances 0.000 description 11
• 125000001183 hydrocarbyl group Chemical group 0.000 description 11
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
• 239000005977 Ethylene Substances 0.000 description 10
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 10
• 239000007787 solid Substances 0.000 description 10
• 150000002118 epoxides Chemical class 0.000 description 9
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 9
• 229920000573 polyethylene Polymers 0.000 description 9
• 229920000098 polyolefin Polymers 0.000 description 9
• VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical class OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 description 8
• 239000005062 Polybutadiene Substances 0.000 description 8
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 8
• 235000006708 antioxidants Nutrition 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 8
• 238000005227 gel permeation chromatography Methods 0.000 description 8
• 229910052751 metal Inorganic materials 0.000 description 8
• 239000002184 metal Substances 0.000 description 8
• 229910052757 nitrogen Inorganic materials 0.000 description 8
• 239000011368 organic material Substances 0.000 description 8
• 239000002904 solvent Substances 0.000 description 8
• 150000005846 sugar alcohols Polymers 0.000 description 8
• 238000012360 testing method Methods 0.000 description 8
• HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 7
• 239000002253 acid Substances 0.000 description 7
• 150000001993 dienes Chemical class 0.000 description 7
• 239000002245 particle Substances 0.000 description 7
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
• 229920002857 polybutadiene Polymers 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• 229920000877 Melamine resin Polymers 0.000 description 6
• 239000002202 Polyethylene glycol Substances 0.000 description 6
• 239000004721 Polyphenylene oxide Substances 0.000 description 6
• 125000000217 alkyl group Chemical group 0.000 description 6
• 239000003054 catalyst Substances 0.000 description 6
• 230000008859 change Effects 0.000 description 6
• JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 6
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 239000004700 high-density polyethylene Substances 0.000 description 6
• 238000010348 incorporation Methods 0.000 description 6
• 238000006116 polymerization reaction Methods 0.000 description 6
• 239000004800 polyvinyl chloride Substances 0.000 description 6
• 229920000915 polyvinyl chloride Polymers 0.000 description 6
• 229920002554 vinyl polymer Polymers 0.000 description 6
• KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
• 239000004593 Epoxy Substances 0.000 description 5
• 239000004793 Polystyrene Substances 0.000 description 5
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 5
• 150000001298 alcohols Chemical class 0.000 description 5
• 239000007795 chemical reaction product Substances 0.000 description 5
• 239000003795 chemical substances by application Substances 0.000 description 5
• 230000000052 comparative effect Effects 0.000 description 5
• 235000014113 dietary fatty acids Nutrition 0.000 description 5
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
• 238000005562 fading Methods 0.000 description 5
• 239000000194 fatty acid Substances 0.000 description 5
• 229930195729 fatty acid Natural products 0.000 description 5
• 229920001477 hydrophilic polymer Polymers 0.000 description 5
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 5
• 238000005580 one pot reaction Methods 0.000 description 5
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical group OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 5
• OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
• 229920006380 polyphenylene oxide Polymers 0.000 description 5
• 229920001451 polypropylene glycol Polymers 0.000 description 5
• 229920002223 polystyrene Polymers 0.000 description 5
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 4
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
• UYEMGAFJOZZIFP-UHFFFAOYSA-N 3,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC(O)=C1 UYEMGAFJOZZIFP-UHFFFAOYSA-N 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
• 150000007513 acids Chemical class 0.000 description 4
• 125000001931 aliphatic group Chemical group 0.000 description 4
• 125000003342 alkenyl group Chemical group 0.000 description 4
• 125000003118 aryl group Chemical group 0.000 description 4
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
• 239000012964 benzotriazole Substances 0.000 description 4
• CMXLJKWFEJEFJE-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound C1=CC(OC)=CC=C1C=C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(=O)OC1CC(C)(C)N(C)C(C)(C)C1 CMXLJKWFEJEFJE-UHFFFAOYSA-N 0.000 description 4
• FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
• MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
• 238000000576 coating method Methods 0.000 description 4
• 239000007859 condensation product Substances 0.000 description 4
• 150000001991 dicarboxylic acids Chemical class 0.000 description 4
• 229920001971 elastomer Polymers 0.000 description 4
• 229910052736 halogen Inorganic materials 0.000 description 4
• 150000002367 halogens Chemical class 0.000 description 4
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
• 229910052739 hydrogen Inorganic materials 0.000 description 4
• 239000001257 hydrogen Substances 0.000 description 4
• 238000007641 inkjet printing Methods 0.000 description 4
• 239000007788 liquid Substances 0.000 description 4
• 239000000314 lubricant Substances 0.000 description 4
• 229940063557 methacrylate Drugs 0.000 description 4
• 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 4
• 238000002156 mixing Methods 0.000 description 4
• 238000012986 modification Methods 0.000 description 4
• 230000004048 modification Effects 0.000 description 4
• DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
• 150000002815 nickel Chemical class 0.000 description 4
• 239000003921 oil Substances 0.000 description 4
• 230000002085 persistent effect Effects 0.000 description 4
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
• 239000004417 polycarbonate Substances 0.000 description 4
• 229920000647 polyepoxide Polymers 0.000 description 4
• 229920000570 polyether Polymers 0.000 description 4
• 229920002959 polymer blend Polymers 0.000 description 4
• 239000004814 polyurethane Substances 0.000 description 4
• 235000019260 propionic acid Nutrition 0.000 description 4
• 229940095574 propionic acid Drugs 0.000 description 4
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
• 235000013772 propylene glycol Nutrition 0.000 description 4
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
• IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 4
• 229920001897 terpolymer Polymers 0.000 description 4
• 239000004753 textile Substances 0.000 description 4
• 229920001169 thermoplastic Polymers 0.000 description 4
• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
• 239000011732 tocopherol Substances 0.000 description 4
• ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
• 239000001993 wax Substances 0.000 description 4
• VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 description 3
• RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 3
• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
• 229920000178 Acrylic resin Polymers 0.000 description 3
• 239000004925 Acrylic resin Substances 0.000 description 3
• 239000004215 Carbon black (E152) Substances 0.000 description 3
• LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
• 229920002943 EPDM rubber Polymers 0.000 description 3
• BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
• 239000004594 Masterbatch (MB) Substances 0.000 description 3
• JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
• 229920002396 Polyurea Polymers 0.000 description 3
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• 239000007983 Tris buffer Substances 0.000 description 3
• 150000001241 acetals Chemical class 0.000 description 3
• 150000007933 aliphatic carboxylic acids Chemical group 0.000 description 3
• 229920000180 alkyd Polymers 0.000 description 3
• 125000002877 alkyl aryl group Chemical group 0.000 description 3
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
• 150000001408 amides Chemical class 0.000 description 3
• 150000008064 anhydrides Chemical class 0.000 description 3
• 238000013459 approach Methods 0.000 description 3
• 150000001565 benzotriazoles Chemical class 0.000 description 3
• 238000007906 compression Methods 0.000 description 3
• 230000006835 compression Effects 0.000 description 3
• 238000001816 cooling Methods 0.000 description 3
• 125000004122 cyclic group Chemical group 0.000 description 3
• 230000002939 deleterious effect Effects 0.000 description 3
• JMFYZMAVUHNCPW-UHFFFAOYSA-N dimethyl 2-[(4-methoxyphenyl)methylidene]propanedioate Chemical compound COC(=O)C(C(=O)OC)=CC1=CC=C(OC)C=C1 JMFYZMAVUHNCPW-UHFFFAOYSA-N 0.000 description 3
• 150000002009 diols Chemical class 0.000 description 3
• 239000000986 disperse dye Substances 0.000 description 3
• 230000000694 effects Effects 0.000 description 3
• 239000000839 emulsion Substances 0.000 description 3
• 239000003822 epoxy resin Substances 0.000 description 3
• HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
• 150000002170 ethers Chemical class 0.000 description 3
• 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
• 239000005038 ethylene vinyl acetate Substances 0.000 description 3
• 150000004665 fatty acids Chemical class 0.000 description 3
• LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
• 229930195733 hydrocarbon Natural products 0.000 description 3
• 150000002430 hydrocarbons Chemical class 0.000 description 3
• 229920000554 ionomer Polymers 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• 239000000155 melt Substances 0.000 description 3
• 239000012528 membrane Substances 0.000 description 3
• 239000002480 mineral oil Substances 0.000 description 3
• 150000005673 monoalkenes Chemical class 0.000 description 3
• 229920005615 natural polymer Polymers 0.000 description 3
• 235000019198 oils Nutrition 0.000 description 3
• 230000003647 oxidation Effects 0.000 description 3
• 238000007254 oxidation reaction Methods 0.000 description 3
• 229920000233 poly(alkylene oxides) Polymers 0.000 description 3
• 229920000139 polyethylene terephthalate Polymers 0.000 description 3
• 239000005020 polyethylene terephthalate Substances 0.000 description 3
• 229920002451 polyvinyl alcohol Polymers 0.000 description 3
• 235000019422 polyvinyl alcohol Nutrition 0.000 description 3
• 150000003839 salts Chemical class 0.000 description 3
• 238000005507 spraying Methods 0.000 description 3
• 230000000087 stabilizing effect Effects 0.000 description 3
• 230000003068 static effect Effects 0.000 description 3
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