DEF0015507MA - - Google Patents

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Publication number

DEF0015507MA

DEF0015507MA DEF0015507MA DE F0015507M A DEF0015507M A DE F0015507MA DE F0015507M A DEF0015507M A DE F0015507MA

Authority

DE

Germany

Prior art keywords

decahydronaphthalene

oxygen

trans

vol

hydroperoxide

Prior art date

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 22
• 230000003647 oxidation Effects 0.000 claims description 13
• 238000007254 oxidation reaction Methods 0.000 claims description 13
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
• 229910001385 heavy metal Inorganic materials 0.000 claims description 7
• 239000001301 oxygen Substances 0.000 claims description 7
• 229910052760 oxygen Inorganic materials 0.000 claims description 7
• 239000003054 catalyst Substances 0.000 claims description 5
• 238000000034 method Methods 0.000 claims description 5
• 150000003839 salts Chemical class 0.000 claims description 4
• 239000007789 gas Substances 0.000 claims description 3
• 230000001590 oxidative effect Effects 0.000 claims description 3
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
• 150000002432 hydroperoxides Chemical class 0.000 description 4
• 239000002253 acid Substances 0.000 description 3
• 150000001298 alcohols Chemical class 0.000 description 3
• 238000006243 chemical reaction Methods 0.000 description 3
• 150000002576 ketones Chemical class 0.000 description 3
• 239000000203 mixture Substances 0.000 description 3
• CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical class C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
• 229910000831 Steel Inorganic materials 0.000 description 2
• 230000002378 acidificating effect Effects 0.000 description 2
• 239000003513 alkali Substances 0.000 description 2
• 239000010941 cobalt Substances 0.000 description 2
• 229910017052 cobalt Inorganic materials 0.000 description 2
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
• 239000012141 concentrate Substances 0.000 description 2
• 239000000470 constituent Substances 0.000 description 2
• 238000000354 decomposition reaction Methods 0.000 description 2
• 230000007935 neutral effect Effects 0.000 description 2
• ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
• 239000002904 solvent Substances 0.000 description 2
• 239000010959 steel Substances 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• YWBMNCRJFZGXJY-UHFFFAOYSA-N 1-hydroperoxy-1,2,3,4-tetrahydronaphthalene Chemical compound C1=CC=C2C(OO)CCCC2=C1 YWBMNCRJFZGXJY-UHFFFAOYSA-N 0.000 description 1
• 239000004342 Benzoyl peroxide Chemical class 0.000 description 1
• OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
• 229910052684 Cerium Inorganic materials 0.000 description 1
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
• 150000007513 acids Chemical class 0.000 description 1
• 235000019400 benzoyl peroxide Nutrition 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 238000007865 diluting Methods 0.000 description 1
• 229910001882 dioxygen Inorganic materials 0.000 description 1
• 150000002148 esters Chemical class 0.000 description 1
• 150000002170 ethers Chemical class 0.000 description 1
• 230000002349 favourable effect Effects 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 239000000543 intermediate Substances 0.000 description 1
• 238000009533 lab test Methods 0.000 description 1
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 238000002844 melting Methods 0.000 description 1
• 230000008018 melting Effects 0.000 description 1
• 150000002736 metal compounds Chemical class 0.000 description 1
• 230000003472 neutralizing effect Effects 0.000 description 1
• 229940049964 oleate Drugs 0.000 description 1
• 150000002978 peroxides Chemical class 0.000 description 1
• 239000003208 petroleum Substances 0.000 description 1
• 239000011541 reaction mixture Substances 0.000 description 1
• 239000007858 starting material Substances 0.000 description 1
• 238000003786 synthesis reaction Methods 0.000 description 1
• 238000005406 washing Methods 0.000 description 1
• 229910052725 zinc Inorganic materials 0.000 description 1
• 239000011701 zinc Substances 0.000 description 1