DE905967C - Process for matting textiles - Google Patents

Process for matting textiles

Info

Publication number
DE905967C
DE905967C DEC1376D DEC0001376D DE905967C DE 905967 C DE905967 C DE 905967C DE C1376 D DEC1376 D DE C1376D DE C0001376 D DEC0001376 D DE C0001376D DE 905967 C DE905967 C DE 905967C
Authority
DE
Germany
Prior art keywords
matting
aluminum
textiles
pigments
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEC1376D
Other languages
German (de)
Inventor
Dr Albert Landolt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG, Ciba AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of DE905967C publication Critical patent/DE905967C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/57Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic System, e.g. alums

Description

Es wurde gefunden, daß wäßrige Suspensionen feinverteilter anorganischer Pigmente, deren wäßrige Phase aus einer Lösung von Aluminiumsalzen, die das Aluminium als Kation enthalten, besteht, zum Mattieren der Textilien mit Erfolg verwendet werden können. Solche Suspensionen können als Bäder dienen, aus welchen die Pigmente eine unerwartete Affinität zur Faser haben. Die Mattierung kann in der Weise vorgenommen werden, daß die PigmenteIt has been found that aqueous suspensions of finely divided inorganic pigments, their aqueous Phase consists of a solution of aluminum salts, which contain the aluminum as a cation, for Matting the textiles can be used with success. Such suspensions can be used as baths serve, from which the pigments have an unexpected affinity for the fiber. The matting can be done in the way that the pigments are made

ίο zum Aufziehen auf das Textilmaterial (z. B. Kunstseiden aus regenerierter Cellulose oder Celluloseäthern und -estern, mercerisierter Baumwolle, Naturseide usw.) gebracht werden, was zweckmäßig durch einfaches Umziehen des Mattierungsgutes in verdünnten Mattierungsbädern geschieht. Man kann auch derart arbeiten, daß die Textilien mit konzentrierten Suspensionen kurze Zeit behandelt und hierauf getrocknet werden. Die so erhältlichen Mattierungseffekte stäuben überraschenderweise nicht und können der Wäsche recht gut widerstehen. Die auf diese Art auf der Faser fixierten Pigmente verbessern ganz wesentlich die Schiebefestigkeit von ansonst schiebenden Geweben.ίο to pull onto the textile material (e.g. artificial silk made from regenerated cellulose or cellulose ethers and esters, mercerized cotton, natural silk etc.), which is expedient by simply moving the matting material in diluted Matting baths happen. You can also work in such a way that the textiles are concentrated Suspensions are treated for a short time and then dried. The matting effects thus obtainable surprisingly do not dust and can withstand laundry quite well. The on This type of pigment fixed on the fiber significantly improves the slip resistance of otherwise pushing tissues.

Als Pigmente kommen in Betracht Titandioxyd, Bariumsulfat, Kaolin, Antimonoxyd, Lithopon, usw., ferner auch gefärbte Pigmente, wie z. B. Eisenoxyd, Cadmiumsulfid usw.The pigments are titanium dioxide, barium sulfate, kaolin, antimony oxide, lithopon, etc., also colored pigments, such as. B. iron oxide, cadmium sulfide, etc.

Die Verwendung von wäßrigen Suspensionen von Pigmenten, deren wäßrige Phase aus Lösungen von Zirkonsalzen besteht, ist bereits zum Mattieren von Textilien empfohlen worden. Zirkonsalze unterscheiden sich bekanntlich aber von anderen Salzen durch eigenartige Affinitätsiverhältnisse zur Cellulosefaser. Aus dem Verhalten des Zirkons war deshalb nicht vorauszusehen, daß die wohlfeilen Aluminiumsalze die Eigenschaft haben würden, in gleicher Weise dasThe use of aqueous suspensions of pigments, the aqueous phase of which consists of solutions of Zirconium salts has already been recommended for matting textiles. Differentiate between zirconium salts It is well known, however, that it differs from other salts through peculiar affinity relationships with cellulose fibers. From the behavior of the zircon, therefore, it could not be foreseen that the cheap aluminum salts would have the property in the same way that

Ziehen der Pigmente; auf der Faser zu fördern. Dies ist um SO' überraschender, als ansonst vergleichbare Salze anderer Metalle, z. B. Magnesium oder Calcium, diese Eigenschaft nicht oder nur in untergeordnetem Maße zeigen.Pulling the pigments; to promote on the fiber. This is SO 'more surprising than otherwise comparable Salts of other metals, e.g. B. Magnesium or calcium, this property not or only to a minor extent Dimensions show.

Es ist ferner bekannt, die Pigmentteilchen durch auf der Faser erzeugte wasserunlösliche Aluminiumseife aufzukleben.It is also known to remove the pigment particles from water-insoluble aluminum soap produced on the fiber stick on.

Die Erfindung beruht im Gegensatz hierzu darauf, ίο daß durch die Aluminiumionen die Pigmentteilchen derart beeinflußt werden, daß sie Substantiven Charakter und somit eine Affinität der Cellulosefaser erhalten. Diese Beeinflussung wird wahrscheinlich durch die elektrische Ladung der Aluminiumionen bewirkt. Die Erfindung beruht also auf einer eigenartigen Erzeugung und Erhöhung des Ziehvermögens der Pigmentteilchen.In contrast to this, the invention is based on the fact that the pigment particles are formed by the aluminum ions are influenced in such a way that they have noun character and thus an affinity of the cellulose fiber obtain. This influence is likely due to the electrical charge of the aluminum ions causes. The invention is therefore based on a peculiar production and increase of the drawability the pigment particles.

Beispiel 1example 1

10 Teile Titandioxyd (Titanweiß des Handels) und ι Teil Aluminiumformiat werden mit wenig Wasser angepastet; die so erhaltene Paste gießt man unter Umrühren in 15000 Teile Wasser von 20°. In das so bereitete Mattiierungsbad geht man mit 50O' Teilen Viskosekunstseide ein und hantiert bei gewöhnlicher Temperatur während Va Stunde. Hierauf wird gespült und getrocknet. Man erhält eine starke, nicht stäubende Mattierung, die der Wäsche recht gut widersteht. Ähnliche Effekte erzielt man, wenn das Aluminiumtrifocmiat durch Aluminiumsulfat ersetzt wird.10 parts titanium dioxide (commercial titanium white) and ι part of aluminum formate are made into a paste with a little water; the paste thus obtained is poured with stirring in 15,000 parts of water at 20 °. You go into the matting bath prepared in this way 50O 'Divide viscose rayon and handle with ordinary Temperature for Va hour. This is followed by rinsing and drying. You get a strong, non-dusting matt finish that withstands laundry quite well. Similar effects can be achieved if the aluminum trifocmate is replaced by aluminum sulfate will.

Liegt ein Titandioxyd von gröberer Beschaffenheit vor, so· kann es sich empfehlen, dem Mattierungsbad geringe Mengen, z. B. iofl/o des verwendeten Aluminiumformiates, eines geeigneten Schutzkolloides, wie Leim oder Johannisbrotkernmehl, zuzugeben. If the titanium dioxide is coarser, it may be advisable to add small amounts to the matting bath, e.g. B. io fl / o of the aluminum formate used, a suitable protective colloid such as glue or locust bean gum to add.

Beispiel 2Example 2

Viskosekunstseidengewebe wird auf dem Foulard in einer Mattierungsflotte bei gewöhnlicher Temperatur foulardiert, welche pro Liter 20 g einer Suspension enthält, die hergestellt worden ist durch Verreiben von 10 Teilen Titandioxyd (in Form von Titanweiß), ι Teil Aluminiumtriformiat mit 10 Teilen Wasser. Man erhält nach dem Abquetschen und Trocknen einen starken gleichmäßigen Matteffekt.Viscose rayon fabric is placed on the padder in a matting liquor at normal temperature padded, which contains per liter 20 g of a suspension which has been prepared by trituration of 10 parts of titanium dioxide (in the form of titanium white), ι part of aluminum triformate with 10 parts Water. After squeezing and drying, a strong, even matt effect is obtained.

Claims (1)

Patentanspruch:Claim: Verfahren zum Mattieren von Textilien, gekennzeichnet durch die Verwendung von wäßrigen Suspensionen anorganischer Pigmente, deren wäßrige Phase im wesentlichen aus Lösungen von Aluminiumsalzen, die das Aluminium als Kation enthalten, gegebenenfalls mit geringen Mengen eines geeigneten Schutzkolloides, besteht. Process for matting textiles, characterized by the use of aqueous Suspensions of inorganic pigments, the aqueous phase of which consists essentially of solutions of aluminum salts, which contain the aluminum as a cation, possibly with a small amount Amounts of a suitable protective colloid. Angezogene Druckschriften:
FranzösischePatentschriftenNr. 841 316, 739214; •deutsche Patentschrift Nr. 679 465;
Chemisches Zentralblatt, 1939, II, S. 3764.
Referred publications:
French Patent No. 841 316, 739214; • German patent specification No. 679 465;
Chemisches Zentralblatt, 1939, II, p. 3764.
1 5812 2.541 5812 2.54
DEC1376D 1939-08-19 1940-08-02 Process for matting textiles Expired DE905967C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH549138X 1939-08-19

Publications (1)

Publication Number Publication Date
DE905967C true DE905967C (en) 1954-03-08

Family

ID=4519518

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC1376D Expired DE905967C (en) 1939-08-19 1940-08-02 Process for matting textiles

Country Status (4)

Country Link
US (1) US2309964A (en)
DE (1) DE905967C (en)
FR (1) FR872222A (en)
GB (1) GB549138A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4283452A (en) * 1979-09-06 1981-08-11 Milliken Research Corporation Polyester textile material having improved opacity
US4420507A (en) * 1980-03-10 1983-12-13 Milliken Research Corporation Process for improving opacity of polyester textile materials

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR739214A (en) * 1931-12-17 1933-01-06 Erba A G Fabrik Chemischer Pro Process for treating textiles and the like
DE679465C (en) * 1933-10-10 1939-08-05 Stockhausen & Cie Chem Fab Process for matting rayon

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR739214A (en) * 1931-12-17 1933-01-06 Erba A G Fabrik Chemischer Pro Process for treating textiles and the like
DE679465C (en) * 1933-10-10 1939-08-05 Stockhausen & Cie Chem Fab Process for matting rayon

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers
US4773912A (en) * 1984-11-28 1988-09-27 Heidelinde Nordmann Process for increasing the performance of pleated silk or wool by treatment with keratolytic liquor and impregnating with glazing powder and heating

Also Published As

Publication number Publication date
GB549138A (en) 1942-11-09
FR872222A (en) 1942-06-02
US2309964A (en) 1943-02-02

Similar Documents

Publication Publication Date Title
DE905967C (en) Process for matting textiles
DE626519C (en) Process for refining regenerated cellulose
AT166460B (en) Process for matting textiles
DE1719352B2 (en)
DE715255C (en) Process for refining fibrous material, feathers or tobacco products
DE1000334B (en) Process for the finishing of textile fibers
DE752227C (en) Finishing and sizing agents
DE975801C (en) Process for impregnating textiles with aqueous dispersions of paraffin or waxes containing metal salts in a single bath process
DE1619088C3 (en) Prevention of graying and graying of woven and knitted fabrics made from man-made fibers
DE592817C (en) Matting agent for textiles
DE753016C (en) Method for rendering cellulose hydrate fabrics water repellent
DE615307C (en) Process for matting textiles, especially rayon
DE902003C (en) Process for refining folded cellulose
DE679465C (en) Process for matting rayon
DE748154C (en) Process for the production of linen-like effects on threads or fabrics made of hydrate cellulose wool
DE3007796A1 (en) Whitening synthetic or mixed fibre fabric - esp. polyester or polyacrylonitrile curtain by coating with binder and pigment from aq. liquor contg. electrolyte
DE748755C (en) Fulling process
DE727319C (en) Process for finishing, in particular making textiles water-repellent
DE651231C (en) Matting process for rayon
DE737414C (en) Process for matting textiles made from cellulose hydrate or cellulose acetate
DE757261C (en) Process for making textiles made of cotton crease-proof
DE731971C (en) Method for weighing textile goods
DE741319C (en) Process for the production of a textile material with a felt-like surface similar to wool fur
DE734208C (en) Process for making textiles made of cellulose or cellulose hydrate fibers water-repellent and crease-proof
AT142556B (en) Process for the production of patterns on crepe fabrics.