DE651231C - Matting process for rayon - Google Patents
Matting process for rayonInfo
- Publication number
- DE651231C DE651231C DEC48953D DEC0048953D DE651231C DE 651231 C DE651231 C DE 651231C DE C48953 D DEC48953 D DE C48953D DE C0048953 D DEC0048953 D DE C0048953D DE 651231 C DE651231 C DE 651231C
- Authority
- DE
- Germany
- Prior art keywords
- matting
- parts
- water
- rayon
- pigments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 6
- 229920000297 Rayon Polymers 0.000 title description 5
- 239000002964 rayon Substances 0.000 title description 3
- 239000000049 pigment Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 5
- 229920002955 Art silk Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920000223 polyglycerol Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- -1 Monocarboxylic acid esters Chemical class 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- GLNADSQYFUSGOU-UHFFFAOYSA-J chembl1640 Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=CC4=CC(=CC(N)=C4C=3O)S([O-])(=O)=O)S([O-])(=O)=O)C)=C(O)C2=C1N GLNADSQYFUSGOU-UHFFFAOYSA-J 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
- D06M2101/08—Esters or ethers of cellulose
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Mattierungsverfahren für Kunstseide Die Mattierung von Kunstseide mit Hilfe von Pigmenten wurde bisher derart durchgeführt, daß die Ware mit den in Wasser suspendierten Pigmenten behandelt und nach dem Schleudern und Abquetschen getrocknet wurde. Derartige Mattierungseffekte sind verhältnismäßig gering und so unbeständig, daß bereits durch Spülen in warmem Wasser der erzielte Matteffekt wieder vollständig verlorengeht. Um diese Auflagemattierung gleichmäßiger und gegebenenfalls waschbeständiger zu machen, wird die Ware vielfach vor der Mattierung. mit einer Seifenlösung vorbehandelt und hierauf durch ;Eingehen in ein Tonerdebad Aluminiumseife auf der Faser, erzeugt.Matting process for artificial silk The matting of artificial silk with the help of pigments has been carried out so far that the goods with the in Treated water-suspended pigments and after centrifuging and squeezing was dried. Such matting effects are relatively minor and such inconsistent that the matt effect achieved can be restored by rinsing in warm water is completely lost. To make this overlay matting more even and where appropriate To make the goods more resistant to washing, the goods are often made before matting. with a Soap solution pretreated and then put through; aluminum soap immersed in an alumina bath on the fiber.
Es ist bereits vorgeschlagen worden, Celluloseester; oder -ätherfasern dadurch zu-mattieren, daß das Fasergut, beispielsweise Acetatseide, in alkalischen Dispersionen von farblosen Pigmenten' behandelt wird, wobei zur Erhöhung der Mattierungswirkung Zusätze von Quellungsmitteln vorgesehen sind.It has been proposed to use cellulose esters; or ether fibers to-matting that the fiber material, for example acetate silk, in alkaline Dispersions of colorless pigments' treated to increase the matting effect Additions of swelling agents are provided.
Es ist ferner bekannt, Kunstseide mittels Pigmentdispersionen unter Mitv erwendung von Paraffin oder ähnlichen Stoffen zu mattieren. Bei Verwendung von verhältnismäßig großen Mengen an Pigmenten erhält man hierbei zwar einen guten Matteffekt, der jedoch so unbeständig ist, daß bereits ein kurzes Spülen in Wasser genügt, um denselben weitgehend zum Verschwinden zu bringen.It is also known to use pigment dispersions under artificial silk With the use of paraffin or similar substances to mattify. Using A good one is obtained from relatively large amounts of pigments Matt effect, which is so unstable that even a short rinse in water is sufficient to make it largely disappear.
Es wurde nun gefunden', daß man auf ginfache Weise eine Mattierung von Kunstseide jeder Art erreichen kann, wenn man als Dispergator für die Pigmente Motiocärbonsäureester der Polyglycerine gemäß Patent 575 911 verwendet. Durch diese Monocarbonsäureester werden die Pigmente in äußerst feine Dispersionen übergeführt, so daß der auf der Ware erzielte Mattierungseffekt sehr gleichmäßig ausfällt. Das Aufziehen der Pigmente wird besonders begünstigt durch Verwendung von hartem Wasser; beim Arbeiten in weichem Wasser setzt maii zweckmäßig der Mattierungsflotte geringe .Mengen anorganische Salze, wie Kochsalz, Calciumchlorid, zu: Ein weiterer Vorteil des neuen Mattierungszerfahrens liegt darin, daß man für Gegensatz zu den bisherigen Arbeitsweisen in sehr verdünnten Flotten, beispielsweise solchen mit 1 bis 5 g/1 Mattierungsmittel, arbeiten kann, somit zu dem gleichen Mattierungseffekt mit wesentlich geringeren Pigmentnengen gelangt und eine Mattierung erhält, die selbst durch heißes Wasser nicht von der Ware -heruntergelöst wird.It has now been found that matting can be achieved in a simple manner Any kind of rayon can be achieved if one acts as a dispersant for the pigments Motiocarboxylic acid esters of polyglycerols according to patent 575 911 are used. Through this Monocarboxylic acid esters, the pigments are converted into extremely fine dispersions, so that the matting effect achieved on the goods is very uniform. That The pigments are absorbed by the use of hard water; when working in soft water, maii expediently uses a small amount of the matting liquor .Amounts of inorganic salts such as table salt, calcium chloride, too: Another advantage of the new matting process lies in the fact that one stands for contrast to the previous Working methods in very dilute liquors, for example those with 1 to 5 g / l Matting agents, can work, thus having the same matting effect with significantly low pigment amounts and a matt finish that even with hot Water is not detached from the goods.
Die erfindungsgemäß mattierten Gewebe und Gewirke zeichnen sich außerdem durch einen angenehmen weichen, glatten Griff aus. Beispiel 1 Ein ungefärbtes acetatseidenes Gewebe wird bei 20° C in einem Bade, das 3 g/1 einer Mischung von 2o Teilen Kokosfettsäurepolyglycerid; 6o Teilen Lithopone und -2o Teilen Wasser und außerdem 0,3 g/1 'Calciumchlorid enthält, 2o Minuten umgezogen. Anschließend wird das Gewebe in einer Flotte, die r g/1 30 °1oige Essigsäure enthält, lWi 6o bis 8o° C kurz gespült, darauf mit einem'substantiven Farbstoff gefärbt, wiederuni gdspilt und wie üblich fertiggestellt. s Beispiel 2 Gefärbter Vskoseseidentrikotwird in einer Flotte, die 5 g/1 einer Mischung von 18 Teilen Kokosfettsäurepolyglycerid, 65 Teilen Chiriaclay und 17 Teilen Wasser und außerdem o,5 g/1 Kochsalz enthält, bei 2o° C 1/2 Stunde umgezogen. Darauf wird der Trikot in 70° C warmem Wasser; das 1 g/1 30 °/oiger Essigsäure enthält, kurz gespült, geschleudert und auf dem Rahmen getrocknet.The fabrics and knitted fabrics matted according to the invention are also notable by a pleasant, soft, smooth handle. Example 1 An undyed silk acetate Tissue is at 20 ° C in a bath containing 3 g / 1 of a mixture of 20 parts of coconut fatty acid polyglyceride; 6o parts Lithopone and -2o parts Water and also 0.3 g / 1 'calcium chloride contains, moved 20 minutes. Then the fabric is in a liquor that r g / 1 contains 30 ° 10 acetic acid, rinsed briefly between 60 and 80 ° C, followed by a 'noun Dyed the dye, sprayed again and finished as usual. s example 2 Dyed silk viscose jersey is made in a liquor containing 5 g / 1 of a mixture of 18 Parts of coconut fatty acid polyglyceride, 65 parts of Chiriaclay and 17 parts of water and also contains 0.5 g / 1 table salt, moved at 20 ° C for 1/2 hour. Then the Jersey in 70 ° C warm water; which contains 1 g / 1 30% acetic acid, rinsed briefly, spun and dried on the frame.
Beispiel 3 Gefärbte Strümpfe aus Kupferkunstseide werden in einer Flotte, die- i g/1 einer Mischung von 2o Teilen Kokosfettsäurepolygjycerid, 6o Teilen Lithopone und 2o Teilen Wasser und außerdem 0,3 g/1 Calciumchlorid enthält, '/,!Stunde bei 2o° C umgezogen. Darauf werden die Strümpfe in Wasser von 7o bis 8o° C, dem o;5 9/130 o/oi@ger Ameisensäure zugefügt :wurde, gespült, geschleudert und wie üblich fertig gestellt. Beispiel ¢ Gereinigte Viskoseseidenstränge werden gleichzeitig gefärbt und mattiert in einem Bade, das mit o,o8 % Diaminreinblau FF (Farbstofftabellen G. Schultz, 7.Aufl. Bd.-1, Nr. 510, S. 2o9) und 8 % jeweils vom Gewicht der Ware einer Mischung von 2o Teilen Kokosfettsäurepolyglycerid, 6o Teilen Zinksulfid und 2o Teilen Wasser und außerdem mit 5 g/1 Glaubersalz beschickt ist. Das Flottenverhältnis beträgt i : 2o. Die Färbung wird bei einer Temperatur von 4o° C begönnen, und im Laufe i Stunde die Temperatur bis auf 8o°' C gesteigert. Anschließend werden die Stränge zweimal in warmem Wasser gespült; geschleudert und getrocknet. Bei dieser Arbeitsweise wird das Mattierungsmittel fast quäqtitatiu dem Farbbad entzogen, so daß die Farblösung am Schluß vollständig klar erscheint.EXAMPLE 3 Dyed stockings made of copper rayon are in a liquor containing 1/1 of a mixture of 20 parts of coconut fatty acid polyglyceride, 60 parts of lithopone and 20 parts of water and also 0.3 g / 1 of calcium chloride for 1/2 hour at 20 ° C moved. The stockings are then placed in water at 70 to 80 ° C., to which 5 9/130% formic acid has been added: was, rinsed, spun and finished as usual. EXAMPLE Purified viscose silk strands are dyed and matted at the same time in a bath containing 0.08% pure diamine blue FF (Dye Tables G. Schultz, 7th edition, vol. 1, no. 510, p. 209) and 8 % each by weight the product is charged with a mixture of 20 parts of coconut fatty acid polyglyceride, 60 parts of zinc sulfide and 20 parts of water and also with 5 g / 1 Glauber's salt. The liquor ratio is i: 2o. The coloration will begin at a temperature of 40 ° C, and in the course of an hour the temperature will be increased to 80 ° C. The strands are then rinsed twice in warm water; spun and dried. In this procedure, the matting agent is almost quäqtitatiu withdrawn from the dye bath, so that the dye solution appears completely clear at the end.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC48953D DE651231C (en) | 1934-03-08 | 1934-03-08 | Matting process for rayon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC48953D DE651231C (en) | 1934-03-08 | 1934-03-08 | Matting process for rayon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE651231C true DE651231C (en) | 1937-10-09 |
Family
ID=7026867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC48953D Expired DE651231C (en) | 1934-03-08 | 1934-03-08 | Matting process for rayon |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE651231C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE871435C (en) * | 1942-01-30 | 1953-03-23 | Christian Saar | Clamp label for woven goods, knitwear or the like. |
-
1934
- 1934-03-08 DE DEC48953D patent/DE651231C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE871435C (en) * | 1942-01-30 | 1953-03-23 | Christian Saar | Clamp label for woven goods, knitwear or the like. |
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