DE651231C - Matting process for rayon - Google Patents

Matting process for rayon

Info

Publication number
DE651231C
DE651231C DEC48953D DEC0048953D DE651231C DE 651231 C DE651231 C DE 651231C DE C48953 D DEC48953 D DE C48953D DE C0048953 D DEC0048953 D DE C0048953D DE 651231 C DE651231 C DE 651231C
Authority
DE
Germany
Prior art keywords
matting
parts
water
rayon
pigments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEC48953D
Other languages
German (de)
Inventor
Dr Konrad Cremer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stockhausen GmbH and Co KG
Original Assignee
Chemische Fabrik Stockhausen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik Stockhausen GmbH filed Critical Chemische Fabrik Stockhausen GmbH
Priority to DEC48953D priority Critical patent/DE651231C/en
Application granted granted Critical
Publication of DE651231C publication Critical patent/DE651231C/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • D06M2101/08Esters or ethers of cellulose

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

Mattierungsverfahren für Kunstseide Die Mattierung von Kunstseide mit Hilfe von Pigmenten wurde bisher derart durchgeführt, daß die Ware mit den in Wasser suspendierten Pigmenten behandelt und nach dem Schleudern und Abquetschen getrocknet wurde. Derartige Mattierungseffekte sind verhältnismäßig gering und so unbeständig, daß bereits durch Spülen in warmem Wasser der erzielte Matteffekt wieder vollständig verlorengeht. Um diese Auflagemattierung gleichmäßiger und gegebenenfalls waschbeständiger zu machen, wird die Ware vielfach vor der Mattierung. mit einer Seifenlösung vorbehandelt und hierauf durch ;Eingehen in ein Tonerdebad Aluminiumseife auf der Faser, erzeugt.Matting process for artificial silk The matting of artificial silk with the help of pigments has been carried out so far that the goods with the in Treated water-suspended pigments and after centrifuging and squeezing was dried. Such matting effects are relatively minor and such inconsistent that the matt effect achieved can be restored by rinsing in warm water is completely lost. To make this overlay matting more even and where appropriate To make the goods more resistant to washing, the goods are often made before matting. with a Soap solution pretreated and then put through; aluminum soap immersed in an alumina bath on the fiber.

Es ist bereits vorgeschlagen worden, Celluloseester; oder -ätherfasern dadurch zu-mattieren, daß das Fasergut, beispielsweise Acetatseide, in alkalischen Dispersionen von farblosen Pigmenten' behandelt wird, wobei zur Erhöhung der Mattierungswirkung Zusätze von Quellungsmitteln vorgesehen sind.It has been proposed to use cellulose esters; or ether fibers to-matting that the fiber material, for example acetate silk, in alkaline Dispersions of colorless pigments' treated to increase the matting effect Additions of swelling agents are provided.

Es ist ferner bekannt, Kunstseide mittels Pigmentdispersionen unter Mitv erwendung von Paraffin oder ähnlichen Stoffen zu mattieren. Bei Verwendung von verhältnismäßig großen Mengen an Pigmenten erhält man hierbei zwar einen guten Matteffekt, der jedoch so unbeständig ist, daß bereits ein kurzes Spülen in Wasser genügt, um denselben weitgehend zum Verschwinden zu bringen.It is also known to use pigment dispersions under artificial silk With the use of paraffin or similar substances to mattify. Using A good one is obtained from relatively large amounts of pigments Matt effect, which is so unstable that even a short rinse in water is sufficient to make it largely disappear.

Es wurde nun gefunden', daß man auf ginfache Weise eine Mattierung von Kunstseide jeder Art erreichen kann, wenn man als Dispergator für die Pigmente Motiocärbonsäureester der Polyglycerine gemäß Patent 575 911 verwendet. Durch diese Monocarbonsäureester werden die Pigmente in äußerst feine Dispersionen übergeführt, so daß der auf der Ware erzielte Mattierungseffekt sehr gleichmäßig ausfällt. Das Aufziehen der Pigmente wird besonders begünstigt durch Verwendung von hartem Wasser; beim Arbeiten in weichem Wasser setzt maii zweckmäßig der Mattierungsflotte geringe .Mengen anorganische Salze, wie Kochsalz, Calciumchlorid, zu: Ein weiterer Vorteil des neuen Mattierungszerfahrens liegt darin, daß man für Gegensatz zu den bisherigen Arbeitsweisen in sehr verdünnten Flotten, beispielsweise solchen mit 1 bis 5 g/1 Mattierungsmittel, arbeiten kann, somit zu dem gleichen Mattierungseffekt mit wesentlich geringeren Pigmentnengen gelangt und eine Mattierung erhält, die selbst durch heißes Wasser nicht von der Ware -heruntergelöst wird.It has now been found that matting can be achieved in a simple manner Any kind of rayon can be achieved if one acts as a dispersant for the pigments Motiocarboxylic acid esters of polyglycerols according to patent 575 911 are used. Through this Monocarboxylic acid esters, the pigments are converted into extremely fine dispersions, so that the matting effect achieved on the goods is very uniform. That The pigments are absorbed by the use of hard water; when working in soft water, maii expediently uses a small amount of the matting liquor .Amounts of inorganic salts such as table salt, calcium chloride, too: Another advantage of the new matting process lies in the fact that one stands for contrast to the previous Working methods in very dilute liquors, for example those with 1 to 5 g / l Matting agents, can work, thus having the same matting effect with significantly low pigment amounts and a matt finish that even with hot Water is not detached from the goods.

Die erfindungsgemäß mattierten Gewebe und Gewirke zeichnen sich außerdem durch einen angenehmen weichen, glatten Griff aus. Beispiel 1 Ein ungefärbtes acetatseidenes Gewebe wird bei 20° C in einem Bade, das 3 g/1 einer Mischung von 2o Teilen Kokosfettsäurepolyglycerid; 6o Teilen Lithopone und -2o Teilen Wasser und außerdem 0,3 g/1 'Calciumchlorid enthält, 2o Minuten umgezogen. Anschließend wird das Gewebe in einer Flotte, die r g/1 30 °1oige Essigsäure enthält, lWi 6o bis 8o° C kurz gespült, darauf mit einem'substantiven Farbstoff gefärbt, wiederuni gdspilt und wie üblich fertiggestellt. s Beispiel 2 Gefärbter Vskoseseidentrikotwird in einer Flotte, die 5 g/1 einer Mischung von 18 Teilen Kokosfettsäurepolyglycerid, 65 Teilen Chiriaclay und 17 Teilen Wasser und außerdem o,5 g/1 Kochsalz enthält, bei 2o° C 1/2 Stunde umgezogen. Darauf wird der Trikot in 70° C warmem Wasser; das 1 g/1 30 °/oiger Essigsäure enthält, kurz gespült, geschleudert und auf dem Rahmen getrocknet.The fabrics and knitted fabrics matted according to the invention are also notable by a pleasant, soft, smooth handle. Example 1 An undyed silk acetate Tissue is at 20 ° C in a bath containing 3 g / 1 of a mixture of 20 parts of coconut fatty acid polyglyceride; 6o parts Lithopone and -2o parts Water and also 0.3 g / 1 'calcium chloride contains, moved 20 minutes. Then the fabric is in a liquor that r g / 1 contains 30 ° 10 acetic acid, rinsed briefly between 60 and 80 ° C, followed by a 'noun Dyed the dye, sprayed again and finished as usual. s example 2 Dyed silk viscose jersey is made in a liquor containing 5 g / 1 of a mixture of 18 Parts of coconut fatty acid polyglyceride, 65 parts of Chiriaclay and 17 parts of water and also contains 0.5 g / 1 table salt, moved at 20 ° C for 1/2 hour. Then the Jersey in 70 ° C warm water; which contains 1 g / 1 30% acetic acid, rinsed briefly, spun and dried on the frame.

Beispiel 3 Gefärbte Strümpfe aus Kupferkunstseide werden in einer Flotte, die- i g/1 einer Mischung von 2o Teilen Kokosfettsäurepolygjycerid, 6o Teilen Lithopone und 2o Teilen Wasser und außerdem 0,3 g/1 Calciumchlorid enthält, '/,!Stunde bei 2o° C umgezogen. Darauf werden die Strümpfe in Wasser von 7o bis 8o° C, dem o;5 9/130 o/oi@ger Ameisensäure zugefügt :wurde, gespült, geschleudert und wie üblich fertig gestellt. Beispiel ¢ Gereinigte Viskoseseidenstränge werden gleichzeitig gefärbt und mattiert in einem Bade, das mit o,o8 % Diaminreinblau FF (Farbstofftabellen G. Schultz, 7.Aufl. Bd.-1, Nr. 510, S. 2o9) und 8 % jeweils vom Gewicht der Ware einer Mischung von 2o Teilen Kokosfettsäurepolyglycerid, 6o Teilen Zinksulfid und 2o Teilen Wasser und außerdem mit 5 g/1 Glaubersalz beschickt ist. Das Flottenverhältnis beträgt i : 2o. Die Färbung wird bei einer Temperatur von 4o° C begönnen, und im Laufe i Stunde die Temperatur bis auf 8o°' C gesteigert. Anschließend werden die Stränge zweimal in warmem Wasser gespült; geschleudert und getrocknet. Bei dieser Arbeitsweise wird das Mattierungsmittel fast quäqtitatiu dem Farbbad entzogen, so daß die Farblösung am Schluß vollständig klar erscheint.EXAMPLE 3 Dyed stockings made of copper rayon are in a liquor containing 1/1 of a mixture of 20 parts of coconut fatty acid polyglyceride, 60 parts of lithopone and 20 parts of water and also 0.3 g / 1 of calcium chloride for 1/2 hour at 20 ° C moved. The stockings are then placed in water at 70 to 80 ° C., to which 5 9/130% formic acid has been added: was, rinsed, spun and finished as usual. EXAMPLE Purified viscose silk strands are dyed and matted at the same time in a bath containing 0.08% pure diamine blue FF (Dye Tables G. Schultz, 7th edition, vol. 1, no. 510, p. 209) and 8 % each by weight the product is charged with a mixture of 20 parts of coconut fatty acid polyglyceride, 60 parts of zinc sulfide and 20 parts of water and also with 5 g / 1 Glauber's salt. The liquor ratio is i: 2o. The coloration will begin at a temperature of 40 ° C, and in the course of an hour the temperature will be increased to 80 ° C. The strands are then rinsed twice in warm water; spun and dried. In this procedure, the matting agent is almost quäqtitatiu withdrawn from the dye bath, so that the dye solution appears completely clear at the end.

Claims (1)

PATENTANSPRUCII: Verfahren zum Mattieren von Kunstseide mit Pigmentdispersionen, dadurch gekennzeichnet, daß man solche Dispersionen verwendet, die als Dispergatoren höhere Monofettsäureester der Polyglycerine gemäß Patent 575 911 und gegebenenfalls als Zusatz geringe Mengen anorganischer Salze enthalten.PATENT CLAIM: Process for matting artificial silk with pigment dispersions, characterized in that such dispersions are used as dispersants higher monofatty acid esters of polyglycerols according to patent 575 911 and optionally contain small amounts of inorganic salts as additives.
DEC48953D 1934-03-08 1934-03-08 Matting process for rayon Expired DE651231C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEC48953D DE651231C (en) 1934-03-08 1934-03-08 Matting process for rayon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEC48953D DE651231C (en) 1934-03-08 1934-03-08 Matting process for rayon

Publications (1)

Publication Number Publication Date
DE651231C true DE651231C (en) 1937-10-09

Family

ID=7026867

Family Applications (1)

Application Number Title Priority Date Filing Date
DEC48953D Expired DE651231C (en) 1934-03-08 1934-03-08 Matting process for rayon

Country Status (1)

Country Link
DE (1) DE651231C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE871435C (en) * 1942-01-30 1953-03-23 Christian Saar Clamp label for woven goods, knitwear or the like.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE871435C (en) * 1942-01-30 1953-03-23 Christian Saar Clamp label for woven goods, knitwear or the like.

Similar Documents

Publication Publication Date Title
DE3247095C2 (en)
DE529859C (en) Process for the treatment of vegetable, animal or other substances
DE651231C (en) Matting process for rayon
DE1005923B (en) Process for cleaning, in particular for boiling and boiling, cellulose fiber fibers
DE752227C (en) Finishing and sizing agents
DE2324687B2 (en) Process for dyeing cellulose products
DE673158C (en) Process for dyeing with Kuepen dyes
DE912926C (en) Process for refining fibrous materials
DE933022C (en) Process for the production of fiber reinforcements containing effect threads
DE599477C (en) Process for the finishing of animal fibers
DE661136C (en) Process for dyeing fibrous materials with Kuepen dyes
DE719056C (en) Process for rendering fibrous materials water repellent
DE849834C (en) Process for matting and, if necessary, simultaneous dyeing of acetate rayon
DE749708C (en) Process for printing fibrous materials with Kuepen and sulfur dyes
DE730173C (en) Process for dyeing cellulose fibers
DE188595C (en)
CH385392A (en) Coloring detergent
DE615962C (en) Process for the finishing and softening of textiles, especially rayon
DE919286C (en) Process for simultaneous bleaching and dyeing
AT211781B (en) Process for dyeing with highly disperse vat dye pigments
DE738194C (en) Process for dyeing rayon from cellulose with substantive dyes
DE653305C (en) Process for dyeing wound material made of cellulose synthetic silk, linen or hemp in the form of packages with Kuepen dyes in apparatus
DE1071653B (en) Process for dyeing textile yarns with vat and / or sulfur dyes on yarn or spray dyeing machines
DE518197C (en) Process for achieving good color penetration on piece goods and yarns with box dyes
AT58300B (en) Process for the production of plain and contrasting colors on semi-woolen webs and fabrics.