DE654593C - Matting process for rayon - Google Patents
Matting process for rayonInfo
- Publication number
- DE654593C DE654593C DEC49856D DEC0049856D DE654593C DE 654593 C DE654593 C DE 654593C DE C49856 D DEC49856 D DE C49856D DE C0049856 D DEC0049856 D DE C0049856D DE 654593 C DE654593 C DE 654593C
- Authority
- DE
- Germany
- Prior art keywords
- rayon
- matting
- parts
- lecithin
- pigments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 7
- 229920000297 Rayon Polymers 0.000 title description 6
- 239000002964 rayon Substances 0.000 title description 5
- 239000000049 pigment Substances 0.000 claims description 10
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 229940067606 lecithin Drugs 0.000 claims description 6
- 235000010445 lecithin Nutrition 0.000 claims description 6
- 239000000787 lecithin Substances 0.000 claims description 6
- 229920002955 Art silk Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- -1 aliphatic alcohols Chemical class 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000835 fiber Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/53—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
- D06M2101/08—Esters or ethers of cellulose
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Mattierungsverfahren für Kunstseide Es ist an sich bekannt, Kunstseide mit wäßrigen Dispersionen von Pigmenten zu mattieren. Die bekannten Verfahren haben den Nachteil, daß der Mattierungseffekt nur gering ist, ungleichmäßig ausfällt und wenig beständig ist, d. h. die auf der Ware befindlichen Pigmente werden bereits durch Behandlung mit Wasser zum größten Teil wieder heruntergespült.Matting process for rayon rayon is known per se to matt with aqueous dispersions of pigments. The known procedures have the disadvantage that the matting effect is only slight, is uneven and is not very stable, d. H. the pigments on the goods are already for the most part washed down again by treatment with water.
Man hat ferner vorgeschlagen, Kunstseide durch Behandlung mit Latex enthaltenden Pigmentdispersionen zu mattieren. Nach diesem Verfahren erhält man lediglich auf Acetatseide einen brauchbaren Mattierungseffekt, wenn man bei hohen Temperaturen arbeitet, während beispielsweise Viscosefasern nur sehr wenig in ihrem Glanze verändert werden. Die Mattierung wird ebenfalls bereits beim Spülen größtenteils wieder rückgängig gemacht; ferner erhält die Ware einen harten, strohigen Griff.It has also been suggested that rayon can be treated with latex containing pigment dispersions to mattify. According to this procedure, one obtains only on acetate silk a usable matting effect, if you look at high Temperatures works, while for example viscose fibers very little in their Luster can be changed. Most of the matting is also removed during the rinsing process undone again; Furthermore, the goods are given a hard, straw-like feel.
Man hat auch schon Kunstseide mit Pigmente enthaltenden Paraffindispersionen mattiert; hierbei erhält man jedoch trotz Anwendung verhältnismäßig großer Mengen Pigmente nur sehr geringe Matteffekte, die bereits durch kurzes Spülen wieder vollständig verschwinden.Artificial silk with paraffin dispersions containing pigments has also been used matted; in this case, however, relatively large amounts are obtained despite the use of them Pigments only have very slight matt effects, which can be completely restored after a short rinse disappear.
Es wurde nun gefunden, daß man eine wesentlich bessere Mattierung von Kunstseide dadurch erhalten kann, daß man zum Dispergieren der üblichen Pigmente Lecithin verwendet. Die Pigmente werden unter Zusatz von geringen Mengen Wasser mit dem Lecithin innig vermischt, wobei, um die an und für sich geringe Wasserlöslichkeit von Lecithin zu erhöhen, ein- oder mehrwertige niedere aliphatische Alkohole oder Dispergatoren für sich allein oder in Mischung miteinander in geringen Mengen zuzusetzen sind. Der mit diesen Dispersionen erzielte Matteffekt ist gegenüber den bekannten Verfahren wesentlich stärker; außerdem wird erreicht, daß die Haftfähigkeit der Pigmente auf der Faser beträchtlich gesteigert wird. Die mattierteWare zeichnet sich zudem durch eine sehr gute gleichmäßige Mattierung und einen angenehmen, weichen, glatten Griff aus.It has now been found that a significantly better matting is obtained from rayon can be obtained by dispersing the usual pigments Lecithin used. The pigments are made with the addition of small amounts of water intimately mixed with the lecithin, with the in and of itself low water solubility of lecithin to increase, mono- or polyhydric lower aliphatic alcohols or To add dispersants alone or as a mixture with one another in small amounts are. The matt effect achieved with these dispersions is compared to the known ones Procedure much stronger; it is also achieved that the adhesiveness of the Pigments on the fiber is increased considerably. The matted goods are characterized is also characterized by a very good, even matt finish and a pleasant, soft, smooth handle.
Beispiel I Kunstseidenstränge werden bei einem Flottenverhältnis I :2o in 14° hartem Wasser bei 3o bis 4o° C 30 Minuten in einer Flotte behandelt, die 4 bis 6g/1 einer Mischung von 65 Teilen Lithopone, 2o Teilen Lecithin, 5 Teilen Äthylalkohol und i o Teilen Wasser enthält. Hierauf wird in Wasser von 6o° C gespült, geschleudert und getrocknet.Example I Artificial silk strands are made with a liquor ratio I. : Treated 2o in 14 ° hard water at 3o to 4o ° C for 30 minutes in a liquor, the 4 to 6g / 1 of a mixture of 65 parts of Lithopone, 20 parts of lecithin, 5 parts Contains ethyl alcohol and 10 parts water. Then it is rinsed in water at 60 ° C, spun and dried.
Beispiel 2 Kunstseidcnstränge werden gleichzeitig gefärbt und mattiert in einem Bade, das mit o, 5 a!o Siriwsgrün BL (Schultz, Farbstofftabellen Bd. 11, 1931, S. 198), und 3% Gla.ubersalz jeweils vom Gewicht der Ware beschickt ist und 5g/1 eines Mattierungsmitt s folgender Zusammensetzung : 60 Teile Li@on pone, I8 Teile Lecithin, z Teile Türkisch@t öl, z Teile Äthylalkohol, 15, Teile Wass@r enthält.Example 2 Artificial silk strands are dyed and matted at the same time in a bath marked with o, 5 a! o Siriwsgrün BL (Schultz, color tables, vol. 11, 1931, p. 198), and 3% Gla.ubersalz each on the weight of the goods is charged and 5g / 1 of a matting agent of the following composition: 60 parts Li @ on pone, I8 parts lecithin, z parts Turkish @ t oil, z parts ethyl alcohol, 15, Contains parts of Wass @ r.
Das Verhältnis von Ware zu Flotte betragt I :3o. Die Färbung wird bei einer Temperatur von 60°C begonnen; im Laufe I Stunde wird die Temperatur auf 9o° C gesteigert. Hierauf werden die Stränge kalt gespült, geschleudert und getrocknet.The ratio of goods to fleet is I: 3o. The coloring will started at a temperature of 60 ° C; in the course of 1 hour the temperature rises 90 ° C increased. The strands are then rinsed with cold water, spun and dried.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC49856D DE654593C (en) | 1934-11-14 | 1934-11-14 | Matting process for rayon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEC49856D DE654593C (en) | 1934-11-14 | 1934-11-14 | Matting process for rayon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE654593C true DE654593C (en) | 1937-12-23 |
Family
ID=7027054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEC49856D Expired DE654593C (en) | 1934-11-14 | 1934-11-14 | Matting process for rayon |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE654593C (en) |
-
1934
- 1934-11-14 DE DEC49856D patent/DE654593C/en not_active Expired
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