DE725105T1 - Ungesättigte Polyesterabmischung für Sanitärprodukte - Google Patents
Ungesättigte Polyesterabmischung für SanitärprodukteInfo
- Publication number
- DE725105T1 DE725105T1 DE0725105T DE95490004T DE725105T1 DE 725105 T1 DE725105 T1 DE 725105T1 DE 0725105 T DE0725105 T DE 0725105T DE 95490004 T DE95490004 T DE 95490004T DE 725105 T1 DE725105 T1 DE 725105T1
- Authority
- DE
- Germany
- Prior art keywords
- composition
- sanitary products
- pigment
- calcium carbonate
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims 9
- 229920006305 unsaturated polyester Polymers 0.000 title 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract 9
- 238000000465 moulding Methods 0.000 claims abstract 7
- 239000000049 pigment Substances 0.000 claims abstract 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract 5
- 239000011248 coating agent Substances 0.000 claims abstract 5
- 238000000576 coating method Methods 0.000 claims abstract 5
- 239000003365 glass fiber Substances 0.000 claims abstract 5
- 239000004005 microsphere Substances 0.000 claims abstract 4
- 239000004698 Polyethylene Substances 0.000 claims abstract 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract 3
- 239000011575 calcium Substances 0.000 claims abstract 3
- 239000013078 crystal Substances 0.000 claims abstract 3
- 239000011521 glass Substances 0.000 claims abstract 3
- 239000004579 marble Substances 0.000 claims abstract 3
- 229920001225 polyester resin Polymers 0.000 claims abstract 3
- 239000004645 polyester resin Substances 0.000 claims abstract 3
- -1 polyethylene Polymers 0.000 claims abstract 3
- 229920000573 polyethylene Polymers 0.000 claims abstract 3
- 239000011347 resin Substances 0.000 claims abstract 3
- 229920005989 resin Polymers 0.000 claims abstract 3
- 229920001169 thermoplastic Polymers 0.000 claims abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract 3
- 238000005299 abrasion Methods 0.000 claims abstract 2
- 230000015556 catabolic process Effects 0.000 claims abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract 2
- 238000004132 cross linking Methods 0.000 claims abstract 2
- 239000011243 crosslinked material Substances 0.000 claims abstract 2
- 238000006731 degradation reaction Methods 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims abstract 2
- 150000001451 organic peroxides Chemical class 0.000 claims abstract 2
- 230000003014 reinforcing effect Effects 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims abstract 2
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 3
- 229920000728 polyester Polymers 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- 150000004684 trihydrates Chemical class 0.000 claims 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 235000013539 calcium stearate Nutrition 0.000 claims 1
- 239000008116 calcium stearate Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920000193 polymethacrylate Polymers 0.000 claims 1
- 239000004926 polymethyl methacrylate Substances 0.000 claims 1
- 239000005361 soda-lime glass Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 229960001763 zinc sulfate Drugs 0.000 claims 1
- 229910000368 zinc sulfate Inorganic materials 0.000 claims 1
- 230000006378 damage Effects 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (5)
- PATENTANSPRÜCHE&Iacgr;. Zusammenstellung einer Formmasse, insbesondere für Sanitärprodukte, wie Spülbecken, Badewannen oder Waschbecken aus Kunststoff, die geeignet sind, unter Druck und bei hoher Temperatur geformt zu werden, umfassende:- ein in einem flüssigen Monomer mit einer polymerisierbaren Vinylgruppe vernetzbares Polyesterharz,- ein in der Harzmischung lösbares, Schrumpfungsverhütendes, thermoplastisches Polymer der Art Polyäthylen,- einen organischen Peroxydkatalysator zum Einleiten der Vernetzung durch Einbringung von freien Radikalen während deren Zersetzung bei hoher Temperatur,- Verstärkungsfasern, wie Glasfasern, um die Steifheit des vernetzten Materials zu sichern,- einen Entformungsagent, wie Kalzium- oder Zinkstearat,dadurch gekennzeichnet, daß sie Füllstoffe enthält, die gewählt werden aus:1) Kalknatronglas-Mikrokugeln mit chemischer Beschichtung,
- 2) Kalziumkarbonat in Marmorkristalform, mit oder ohne Pigmentbeschichtung,um den Zerfall der Glasfasern zu vermindern und ein abrasions-, wärme- und wasserbeständiges Sanitärprodukt zu erhalten.2. Zusammenstellung einer Formmasse, insbesondere für Sanitärprodukte, nach Anspruch 1, dadurch gekennzeichnet, daß das schrumpfungsverhütende, thermoplastische Polymer aus gesättigtem Polyester, Vinylpolyazetat, EVA (Ethylen- und Vinylazetat-Mischpolymerisaten), ABS (Akrylnitril-, Butadien- und Styrol-Mischpolymerisaten), PMMA (Methylpolymethakrylat) gewählt wird.
- 3. Zusammenstellung einer Formmasse, insbesondere für Sanitärprodukte, nach Anspruch 1, dadurch gekennzeichnet, daß die Füllstoffmischung außerdem Kalziumkarbonat in Marmorkristalform, Glas-Mikrokugeln, mikronisiertes Tonerdetrihydrat enthält.
- 4. Zusammenstellung einer Formmasse, insbesondere für Sanitärprodukte, nach Anspruch 1, dadurch gekennzeichnet, daß das Kalziumkarbonat mit Pigmentbeschichtung der Art Epoxydharz-Polyurethan-gesättigter Polyester ist, um eine bessere Haftung des Pigmentes an den Substraten zu sichern.
- 5. Zusammenstellung einer Formmasse, insbesondere für Sanitärprodukte, nach Anspruch 1, dadurch gekennzeichnet, daß sie folgende Produkte enthält:- im Styrol gelöstes, ungesättigtesPolyesterharz (der Art NPG-Orthophtalat) 10 bis 20 %- schrumpfungsverhütendes Polymer (der ArtPolyäthylen und/oder gesättigter Polyester) 4 bis 7 %- Zinksulfat (Pigment) 0 bis 2 %- sonstiges Pigment 0 bis 0,5 %- Äthyl-2 tertiäres Butylperhexanoat 0,03 bis 0,5 %- tertiäres Butylperbenzoate 0,10 bis 0,4 %- Trimethyl-3,3,5 tertiäres Butylperhexanoat 0 bis 0,1 %- Zinkstearat 0,75 bis 1,7 %- Kalziumstearat 0 bis 0,80 %- Parabenzochinon 0 bis 0,05 %- Glasfasern 6 mm 5 bis 10 %- Tonerdetrihydrat 30 bis 40 %- Kalziumkarbonat 15 bis 25 %- Glas-Mikrokugeln 12 bis 25 %
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP95490004A EP0725105B1 (de) | 1995-02-06 | 1995-02-06 | Ungesättigte Polyesterabmischung für Sanitärprodukte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE725105T1 true DE725105T1 (de) | 1997-03-13 |
Family
ID=8221636
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE0725105T Pending DE725105T1 (de) | 1995-02-06 | 1995-02-06 | Ungesättigte Polyesterabmischung für Sanitärprodukte |
| DE69513629T Expired - Fee Related DE69513629T2 (de) | 1995-02-06 | 1995-02-06 | Ungesättigte Polyesterabmischung für Sanitärprodukte |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69513629T Expired - Fee Related DE69513629T2 (de) | 1995-02-06 | 1995-02-06 | Ungesättigte Polyesterabmischung für Sanitärprodukte |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0725105B1 (de) |
| AT (1) | ATE187188T1 (de) |
| DE (2) | DE725105T1 (de) |
| ES (1) | ES2092457T3 (de) |
| PT (1) | PT725105E (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2734271B1 (fr) * | 1995-05-19 | 1997-07-18 | Nayad Diffusion | Composition destinee a la fabrication de materiaux solides, notamment utilises dans la fabrication d'objets sanitaires |
| EP1172410A3 (de) * | 2000-07-11 | 2002-04-10 | Kao Corporation | Ungesättigte Polyester Formmasse |
| ITMI20030406A1 (it) * | 2003-03-05 | 2004-09-06 | Elleci Spa | Materiale composito termoindurente, particolarmente per la realizzazione di articoli sanitari e lavelli da cucina. |
| RU2534692C1 (ru) * | 2013-09-25 | 2014-12-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Мордовский государственный университет им. Н.П. Огарёва" | Полимерное вяжущее для полимербетона |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1413988A (fr) * | 1964-09-01 | 1965-10-15 | Remoda Anstalt | Nouveau matériau pour revêtements de sols et de murs en dalles minces préfabriquées |
| US4016131A (en) * | 1975-04-04 | 1977-04-05 | Vitrofil Corporation | Preparation of unsaturated polyester compositions |
| JPS53140397A (en) * | 1977-05-14 | 1978-12-07 | Matsushita Electric Works Ltd | Sheet molding compound |
| JPH03234761A (ja) * | 1990-02-09 | 1991-10-18 | Matsushita Electric Works Ltd | 不飽和ポリエステル樹脂成形材料 |
| JPH0496975A (ja) * | 1990-08-14 | 1992-03-30 | Matsushita Electric Works Ltd | 精密成形用成形材料 |
| JP3281094B2 (ja) * | 1992-02-28 | 2002-05-13 | 三井武田ケミカル株式会社 | 人造大理石用不飽和ポリエステルモールディングコンパウンド及び人造大理石 |
-
1995
- 1995-02-06 EP EP95490004A patent/EP0725105B1/de not_active Expired - Lifetime
- 1995-02-06 PT PT95490004T patent/PT725105E/pt unknown
- 1995-02-06 DE DE0725105T patent/DE725105T1/de active Pending
- 1995-02-06 AT AT95490004T patent/ATE187188T1/de not_active IP Right Cessation
- 1995-02-06 ES ES95490004T patent/ES2092457T3/es not_active Expired - Lifetime
- 1995-02-06 DE DE69513629T patent/DE69513629T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2092457T1 (es) | 1996-12-01 |
| DE69513629D1 (de) | 2000-01-05 |
| DE69513629T2 (de) | 2000-06-15 |
| ATE187188T1 (de) | 1999-12-15 |
| PT725105E (pt) | 2000-04-28 |
| EP0725105B1 (de) | 1999-12-01 |
| EP0725105A1 (de) | 1996-08-07 |
| ES2092457T3 (es) | 2000-02-16 |
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