DE705909C - Water-soluble, durable mixtures containing per-compounds - Google Patents

Water-soluble, durable mixtures containing per-compounds

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Publication number
DE705909C
DE705909C DEH157991D DEH0157991D DE705909C DE 705909 C DE705909 C DE 705909C DE H157991 D DEH157991 D DE H157991D DE H0157991 D DEH0157991 D DE H0157991D DE 705909 C DE705909 C DE 705909C
Authority
DE
Germany
Prior art keywords
water
durable
soluble
compounds
mixtures containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEH157991D
Other languages
German (de)
Inventor
Dr Erhart Wolter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to DEH157991D priority Critical patent/DE705909C/en
Application granted granted Critical
Publication of DE705909C publication Critical patent/DE705909C/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0203—Preparation of oxygen from inorganic compounds
    • C01B13/0211—Peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Description

Wasserlösliche, haltbare, Perverbindungen enthaltende Gemische Es wurde gefunden, daß man wasserlösliche, haltbare, Perverbindungen @enthaltende Gemische aus Erdalkalisuperoxyden und Amänosulfonsäure herstellen kann. Bei der Einwirkung von Wasser auf diese Gemische bildet sich :ein in Wasser gelöstes Erdalkalisalz der Aminosulfonsäure, während Wasserstoffperoxyd in Freiheit gesetzt wird. Derartige Lösungen sind vorteilhaft als Bleichbäder, z. B. in der Textilindustrie, sowie, besonders bei Verwendung von Calcium-oder Magnesiumsuperoxyd, für pharmazeutische Zwecke und ferner zum Desinfizieren zu verwenden.Water-soluble, stable mixtures containing per-compounds Es it has been found that water-soluble, durable mixtures containing per compounds can be obtained can produce from alkaline earth metal superoxides and amanosulfonic acid. When acting from water to these mixtures forms: an alkaline earth salt dissolved in water the aminosulfonic acid, while hydrogen peroxide is set free. Such Solutions are beneficial as bleach baths, e.g. B. in the textile industry, as well as, especially when using calcium or magnesium peroxide, for pharmaceuticals Purposes and also to be used for disinfecting.

Weiter wurde die Feststellung gemacht, daß Gemische aus Erdalkalisuperoxyden und Aminosulfonsäure auch dann völlig beständig sind, wenn sie :eine geringe Menge eines Wasserstoffperoxyd zersetzenden Katalysators, z. B. Braunstein, enthalten. In Wasser eingetragen, :entwickelt :ein solches Gemisch stürmisch Sauerstoff und kann daher für eine bequeme und wohlfeile Herstellung von Sauerstoffbädern Verwendung finden. Z. B. können die Gemische in Verbindung mit Schaummitteln bekannter Art, beispielsweise Saponinen, Fettalkoholsulfonaten, Fettsäuretauriden u. dgl., zur Herstellung von Schaumbädern und in Verbindung mit Neutralsalzen, wie Kochsalz, zur Herstellung von Fußbädern dienen.It was also found that mixtures of alkaline earth metal superoxides and aminosulfonic acid are completely stable even if they: a small amount a hydrogen peroxide decomposing catalyst, e.g. B. Brownstone included. Entered into water,: develops: such a mixture stormy oxygen and can therefore be used for the convenient and inexpensive production of oxygen baths Find. For example, the mixtures can be used in conjunction with foaming agents of known type, for example saponins, fatty alcohol sulfonates, fatty acid taurides and the like Production of foam baths and in connection with neutral salts, such as table salt, used to make footbaths.

Bei der Aufbewahrung der Gemische ist es, wie sich von selbst versteht, notwendig, sie vor Feuchtigkeit zu schützen.When storing the mixtures, it goes without saying that necessary to protect them from moisture.

Es ist bereits bekannt, Desinfektions-, Wasch- und Bleichmittel aus hydratisierten Alkalisuperoxyden in fester Form in Verbindung mit seifenbildenden (Fett- und Harz-) Säuren zu verwenden. Diese Mischungen sind explosiv; sie geraten leicht, entweder bei der Herstellung oder bei der Lagerung, in Brand.It is already known to make disinfectants, detergents and bleaches hydrated alkali peroxides in solid form in combination with soap-forming Use (fatty and resin) acids. These mixtures are explosive; they guess easily caught on fire either during manufacture or in storage.

Man hat ferner bereits vorgeschlagen, Erdalkalisuperoxyd mit Säuren, wie Borsäure, in inniger Mischung mit einer indifferenten Substanz, wie kohlensaurem Kalk, Talkum, Paraftln, als haltbares Desinfektionsmittel zu verwenden. Dieser Zusatz wurde für notwendig= gehalten, weil das Superoxyd durch e rührung mit der Säure sofort zersetzt wü ' @ Diese bekannte Mischung weist den Nachte-'-N, auf, daß sie große Mengen eines Wasser= unlöslichen Stoffes enthält. Beispiele i. 85 Gewichtsteile Bariumsupero_xyd werden mit 97 Teilen trockener Aminosulfo!nsäure innig gemischt. Die Mischung ist bei Aus--, von Luftfeuchtigkeit lagerbeständig und enthält 4@`o aktiven Sauerstoff. Ihre wäßrige Lösung kann wie eine gewöhnliche Wasserstoffsuperoxydlösung verwendet werden.It has also already been proposed to use alkaline earth peroxide with acids such as boric acid in an intimate mixture with an inert substance such as carbonate of lime, talc, paraffin as a durable disinfectant. This addition was considered necessary because the superoxide would immediately decompose when it came into contact with the acid. Examples i. 85 parts by weight of barium superoxide are intimately mixed with 97 parts of dry aminosulfonic acid. The mixture can be stored in the absence of humidity and contains 4 @ `o active oxygen. Its aqueous solution can be used like an ordinary hydrogen peroxide solution.

2. Aus 17 Gewichtsteilen Bariumsuperoxyd, q. Gewichtsteilen Aminosulfonsäure und Gewichtsteilen Braunstein wird eine völlig lireständige Mischung hergestellt, die, in Wasser e 'Ingetragen, stürmisch Sauerstoff entwickelt.2. From 17 parts by weight of barium peroxide, q. Parts by weight of aminosulfonic acid and parts by weight of manganese dioxide, a mixture that is completely resistant to iron is produced, which, borne in water, violently evolves oxygen.

Claims (1)

PATENTANSPRUCH: Wasserlösliche, haltbare, Perver bindungen enthaltende Gemische, bestehend aus Erdalkalisuperoxyden und Aminosulf-ansäure, gegebenenfalls mit einem Zusatz von Wasserstoff superoxyd zersetzenden Katalysatoren.PATENT CLAIM: Water-soluble, durable, Perver compounds containing Mixtures consisting of alkaline earth metal superoxides and aminosulfuric acid, if appropriate with an addition of hydrogen superoxide decomposing catalysts.
DEH157991D 1938-12-13 1938-12-13 Water-soluble, durable mixtures containing per-compounds Expired DE705909C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEH157991D DE705909C (en) 1938-12-13 1938-12-13 Water-soluble, durable mixtures containing per-compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH157991D DE705909C (en) 1938-12-13 1938-12-13 Water-soluble, durable mixtures containing per-compounds

Publications (1)

Publication Number Publication Date
DE705909C true DE705909C (en) 1941-05-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DEH157991D Expired DE705909C (en) 1938-12-13 1938-12-13 Water-soluble, durable mixtures containing per-compounds

Country Status (1)

Country Link
DE (1) DE705909C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1016241B (en) * 1952-01-30 1957-09-26 Zampoli & Brogi Process for the solidification of hydrogen peroxide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1016241B (en) * 1952-01-30 1957-09-26 Zampoli & Brogi Process for the solidification of hydrogen peroxide

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