DE69936698D1 - Verfahren und eisenhaltiger Katalysator für die Herstellung von syndiotactischem 1,2-Polybutadien - Google Patents

Verfahren und eisenhaltiger Katalysator für die Herstellung von syndiotactischem 1,2-Polybutadien

Info

Publication number
DE69936698D1
DE69936698D1 DE69936698T DE69936698T DE69936698D1 DE 69936698 D1 DE69936698 D1 DE 69936698D1 DE 69936698 T DE69936698 T DE 69936698T DE 69936698 T DE69936698 T DE 69936698T DE 69936698 D1 DE69936698 D1 DE 69936698D1
Authority
DE
Germany
Prior art keywords
syndiotactic
polybutadiene
iron
preparation
containing catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69936698T
Other languages
English (en)
Other versions
DE69936698T2 (de
Inventor
Steven Luo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Application granted granted Critical
Publication of DE69936698D1 publication Critical patent/DE69936698D1/de
Publication of DE69936698T2 publication Critical patent/DE69936698T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
DE69936698T 1998-10-14 1999-10-13 Verfahren und eisenhaltiger Katalysator für die Herstellung von syndiotactischem 1,2-Polybutadien Expired - Lifetime DE69936698T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US172305 1998-10-14
US09/172,305 US6277779B1 (en) 1998-10-14 1998-10-14 Process and iron-based catalyst composition for the production of syndiotactic 1,2-polybutadiene

Publications (2)

Publication Number Publication Date
DE69936698D1 true DE69936698D1 (de) 2007-09-13
DE69936698T2 DE69936698T2 (de) 2008-04-30

Family

ID=22627140

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69936698T Expired - Lifetime DE69936698T2 (de) 1998-10-14 1999-10-13 Verfahren und eisenhaltiger Katalysator für die Herstellung von syndiotactischem 1,2-Polybutadien

Country Status (6)

Country Link
US (2) US6277779B1 (de)
EP (1) EP0994128B1 (de)
JP (3) JP2000119325A (de)
CA (1) CA2285860A1 (de)
DE (1) DE69936698T2 (de)
ES (1) ES2288311T3 (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
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US6399732B2 (en) * 1998-10-14 2002-06-04 Bridgestone Corporation Preparation of conjugated diene polymers by using an iron-based catalayst system
US6284702B1 (en) 1998-10-14 2001-09-04 Bridgestone Corporation Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene
US6211313B1 (en) * 1999-11-12 2001-04-03 Bridgestone Corporation Iron-based catalyst composition and process for producing conjugated diene polymers
WO2001032724A1 (en) * 1999-11-05 2001-05-10 Bridgestone Corporation Iron-based catalyst for producing oligomers of conjugated dienes
US6288183B1 (en) * 1999-12-30 2001-09-11 Bridgestone Corporation Catalyst composition and process for controlling the characteristics of conjugated diene polymers
US6197888B1 (en) * 1999-12-30 2001-03-06 Bridgestone Corporation Process for producing blends of syndiotactic 1, 2-polybutadiene and rubbery elastomers with an iron-based catalyst system
US6627712B2 (en) * 2001-02-19 2003-09-30 Bridgestone Corporation Manufacture of conjugated diene polymers by using an iron-based catalyst composition
US6433237B1 (en) * 2001-02-19 2002-08-13 Bridgestone Corporation Iron-based catalyst composition for producing oligomers of conjugated dienes
US6320004B1 (en) 2001-04-05 2001-11-20 Bridgestone Corporation Manufacture of conjugated diene polymers by using an iron-based catalyst composition
US6610804B2 (en) * 2001-08-24 2003-08-26 Bridgestone Corporation Iron-based catalyst composition for the manufacture of syndiotactic 1, 2-polybutadiene
ES2312621T3 (es) * 2001-08-24 2009-03-01 Bridgestone Corporation Composicion catalitica basada en hierro para la fabricacion de 1,2-polibutadieno sindiotactico.
US6576725B1 (en) 2002-01-18 2003-06-10 Bridgestone Corporation Iron-based catalyst for producing high-vinyl polybutadiene
US6720397B2 (en) 2002-02-20 2004-04-13 Bridgestone Corporation Polymerization process for preparing syndiotactic 1,2-polybutadiene
CA2739232A1 (en) * 2008-08-14 2010-02-18 Firestone Diversified Products, Llc Rubber articles subjected to repeated deformation and compositions for making the same
RU2445306C1 (ru) * 2010-11-17 2012-03-20 Государственное образовательное учреждение высшего профессионального образования "Башкирский государственный университет" Способ получения полимеров, содержащих циклопропановые группы
RU2447055C1 (ru) * 2010-11-17 2012-04-10 Государственное образовательное учреждение высшего профессионального образования "Башкирский государственный университет" Способ получения полимеров, содержащих циклопропановые группы
RU2443674C1 (ru) * 2010-11-17 2012-02-27 Государственное образовательное учреждение высшего профессионального образования "Башкирский государственный университет" ГОУ ВПО БашГУ Способ получения полимеров, содержащих циклопропановые группы
US20170320980A1 (en) * 2014-11-19 2017-11-09 Changghun Institute Of Applied Chemistry, Chinese Academy Of Sciences Random-syndiotactic block polybutadiene and preparation method thereof
ITUA20163932A1 (it) 2016-05-30 2017-11-30 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
IT201600105714A1 (it) * 2016-10-20 2018-04-20 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso piridilico di ferro(iii)
IT201600105530A1 (it) * 2016-10-20 2018-04-20 Versalis Spa Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro
IT201800001149A1 (it) 2018-01-17 2019-07-17 Versalis Spa Procedimento per la preparazione di poliisoprene a struttura prevalentemente alternata cis-1,4-alt-3,4 in presenza di un sistema catalitico comprendente un complesso piridilico di ferro
CN111727218B (zh) 2018-02-21 2023-05-16 株式会社普利司通 硫化橡胶组合物的制造方法
KR102060531B1 (ko) 2018-07-20 2020-02-11 금호석유화학 주식회사 고무 조성물의 제조방법
CN114341248A (zh) 2019-08-28 2022-04-12 株式会社普利司通 硫化橡胶组合物、硫化橡胶组合物的制造方法、和轮胎
WO2021039602A1 (ja) 2019-08-28 2021-03-04 株式会社ブリヂストン ゴム組成物及びタイヤ
JP7345434B2 (ja) 2020-06-08 2023-09-15 株式会社ブリヂストン 空気入りタイヤ

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Publication number Priority date Publication date Assignee Title
US3457186A (en) 1964-09-30 1969-07-22 Columbian Carbon Homogeneous iron coordination catalysts
US3498963A (en) 1966-09-26 1970-03-03 Japan Synthetic Rubber Co Ltd Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration
US3457250A (en) 1968-01-31 1969-07-22 Phillips Petroleum Co Process and catalyst for production of high-vinyl polybutadiene
BE759763A (fr) 1969-12-02 1971-05-17 Ube Industries Procede pour la preparption de 1,2-polybutadiene
US3725373A (en) 1970-01-12 1973-04-03 Atlantic Richfield Co Process for homopolymerizing acrylonitrile
JPS5023709B2 (de) 1971-12-09 1975-08-09
JPS5250779B2 (de) 1973-02-10 1977-12-27
US4048418A (en) 1974-11-22 1977-09-13 The Goodyear Tire & Rubber Company Method of polymerization of conjugated diolefins using iron catalysts and nitrogen ligands
JPS53143685A (en) 1977-05-23 1978-12-14 Japan Synthetic Rubber Co Ltd Preparation of 1,2-polybutadiene
US4168357A (en) 1978-04-05 1979-09-18 The Goodyear Tire & Rubber Company Preparation of high cis-1,4-polypentadiene
US4168374A (en) 1978-04-05 1979-09-18 The Goodyear Tire & Rubber Company Copolymerization of conjugated diolefins using a chromium-containing catalyst system
DE3538130A1 (de) 1985-10-26 1987-04-30 Bunawerke Huels Gmbh Verfahren und katalysator zur herstellung von syndiotaktischem 1,2-polybutadien
US5082906A (en) 1990-10-24 1992-01-21 The Goodyear Tire & Rubber Company Catalyst for the synthesis of crystalline 3,4-polyisoprene
US5239023A (en) 1990-10-24 1993-08-24 The Goodyear Tire & Rubber Company Process for the synthesis of crystallizable 3,4-polyisoprene and isoprene-butadiene copolymers having high vinyl contents
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US5677405A (en) 1995-05-24 1997-10-14 The B.F. Goodrich Company Homopolymers and copolymers of cationically polymerizable monomers and method of their preparation
US6201080B1 (en) 1997-12-23 2001-03-13 Bridgestone Corporation Preparation of syndiotactic 1, 2-polybutadiene using a chromium-containing catalyst system
US6117956A (en) 1998-06-01 2000-09-12 Bridgestone Corporation Catalyst composition and polymerization process for producing syndiotactic 1,2-polybutadiene
US5919875A (en) * 1998-10-14 1999-07-06 Bridgestone Corporation Method of preparing syndiotactic 1,2-polybutadiene with a chromium-based catalyst system
US6211313B1 (en) * 1999-11-12 2001-04-03 Bridgestone Corporation Iron-based catalyst composition and process for producing conjugated diene polymers
US6180734B1 (en) 1998-10-14 2001-01-30 Bridgestone Corporation Process for producing syndiotactic 1,2-polybutadiene and iron-based catalyst compositions for use therein
US6284702B1 (en) 1998-10-14 2001-09-04 Bridgestone Corporation Iron-based catalyst composition and process for producing syndiotactic 1,2-polybutadiene
WO2000075201A1 (en) 1999-06-09 2000-12-14 Bridgestone Corporation Molybdenum-based catalyst composition for polymerizing conjugated dienes
WO2001032724A1 (en) 1999-11-05 2001-05-10 Bridgestone Corporation Iron-based catalyst for producing oligomers of conjugated dienes
US6160063A (en) 1999-12-30 2000-12-12 Bridgestone Corporation Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene
US6288183B1 (en) * 1999-12-30 2001-09-11 Bridgestone Corporation Catalyst composition and process for controlling the characteristics of conjugated diene polymers
US6197888B1 (en) 1999-12-30 2001-03-06 Bridgestone Corporation Process for producing blends of syndiotactic 1, 2-polybutadiene and rubbery elastomers with an iron-based catalyst system

Also Published As

Publication number Publication date
DE69936698T2 (de) 2008-04-30
JP2012087321A (ja) 2012-05-10
US6277779B1 (en) 2001-08-21
US20010036899A1 (en) 2001-11-01
EP0994128B1 (de) 2007-08-01
EP0994128A1 (de) 2000-04-19
JP5584239B2 (ja) 2014-09-03
JP2009108330A (ja) 2009-05-21
ES2288311T3 (es) 2008-01-01
US6620760B2 (en) 2003-09-16
CA2285860A1 (en) 2000-04-14
JP2000119325A (ja) 2000-04-25

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