DE69919730T2 - Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen - Google Patents

Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen Download PDF

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Publication number
DE69919730T2
DE69919730T2 DE69919730T DE69919730T DE69919730T2 DE 69919730 T2 DE69919730 T2 DE 69919730T2 DE 69919730 T DE69919730 T DE 69919730T DE 69919730 T DE69919730 T DE 69919730T DE 69919730 T2 DE69919730 T2 DE 69919730T2
Authority
DE
Germany
Prior art keywords
acid
hydroxyl
diol
powder coating
cycloaliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69919730T
Other languages
German (de)
English (en)
Other versions
DE69919730D1 (de
Inventor
P. Kamlesh PANANDIKER
Michael John BRONK
Paul Franklin SPITLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion Inc
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of DE69919730D1 publication Critical patent/DE69919730D1/de
Publication of DE69919730T2 publication Critical patent/DE69919730T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4263—Polycondensates having carboxylic or carbonic ester groups in the main chain containing carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/20—Compositions for powder coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyurethanes Or Polyureas (AREA)
DE69919730T 1998-09-18 1999-09-09 Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen Expired - Fee Related DE69919730T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/156,254 US6255523B1 (en) 1998-09-18 1998-09-18 Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates
US156254 1998-09-18
PCT/US1999/020654 WO2000017148A1 (en) 1998-09-18 1999-09-09 Powder coatings based on branched oligoesters and non-emissive uretdione polyisocyanates

Publications (2)

Publication Number Publication Date
DE69919730D1 DE69919730D1 (de) 2004-09-30
DE69919730T2 true DE69919730T2 (de) 2005-09-01

Family

ID=22558776

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69919730T Expired - Fee Related DE69919730T2 (de) 1998-09-18 1999-09-09 Verfahren zur Herstellung von auf verzweigten Oligoestern und emissionsfreien Uretdion- Polyisocyanaten basierenden Pulverbeschichtungen

Country Status (13)

Country Link
US (2) US6255523B1 (https=)
EP (2) EP1481963A1 (https=)
JP (1) JP2002526569A (https=)
KR (1) KR100650829B1 (https=)
CN (1) CN100357247C (https=)
AT (1) ATE274488T1 (https=)
AU (1) AU769617B2 (https=)
BR (1) BR9913799B1 (https=)
CA (1) CA2344540A1 (https=)
CZ (1) CZ2001980A3 (https=)
DE (1) DE69919730T2 (https=)
WO (1) WO2000017148A1 (https=)
ZA (1) ZA200102125B (https=)

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US6255523B1 (en) * 1998-09-18 2001-07-03 Mcwhorter Technologies, Inc. Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates
CN1239648C (zh) * 2001-04-25 2006-02-01 三菱瓦斯化学株式会社 制备聚酯粉末涂料的方法
US7192994B2 (en) * 2001-04-25 2007-03-20 Mitsubishi Gas Chemical Co., Inc. Method of producing polyester powdery coating material
DE10140156A1 (de) * 2001-08-16 2003-03-20 Basf Coatings Ag Thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe und ihre Verwendung
DE10233104A1 (de) * 2002-07-20 2004-01-29 Degussa Ag Verwendung von PUR-Pulverlacken für Coil Coating-Beschichtungen mit mattem Erscheinungsbild
DE102004020451A1 (de) * 2004-04-27 2005-12-01 Degussa Ag Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind und (teil-)kristalline Harze enthalten
US7510768B2 (en) 2005-06-17 2009-03-31 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
DE102005013401A1 (de) * 2005-03-23 2006-09-28 Degussa Ag Niedrigviskose uretdiongruppenhaltige Polyadditionsverbindungen, Verfahren zur Herstellung und Verwendung
US20060270773A1 (en) * 2005-05-26 2006-11-30 Hale Wesley R Polyester-polycarbonate blends for diffuser sheets with improved luminance
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US20130072628A1 (en) * 2005-06-17 2013-03-21 Eastman Chemical Company Coating compositions containing cyclobutanediol
US7956154B2 (en) * 2005-09-27 2011-06-07 Dow Global Technologies Llc Polymers incorporating 1,3 and 1,4 cyclohexanedimethanol
MY146045A (en) 2005-10-28 2012-06-15 Eastman Chem Co Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US8193302B2 (en) 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7737246B2 (en) 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
ZA200806228B (en) * 2006-02-03 2009-11-25 Dow Global Technologies Inc 1,3/1,4-cyclohexane dimethanol based monomers and polymers
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
CA2652297C (en) * 2006-05-18 2014-09-02 Dow Global Technologies Inc. Polyurethane elastomer with enhanced hydrolysis resistance
WO2008094898A1 (en) * 2007-01-31 2008-08-07 Dow Global Technologies Inc. Polyester coil coating formulation
JP5635411B2 (ja) 2007-11-21 2014-12-03 イーストマン ケミカル カンパニー プラスチック製哺乳瓶、他のブロー成形物品及びそれらの製造方法
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
US8895654B2 (en) 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
KR101492401B1 (ko) 2008-12-23 2015-02-13 에스케이케미칼주식회사 플라스틱 코팅용 에스테르계 폴리올
TWI448482B (zh) * 2009-02-02 2014-08-11 Ind Tech Res Inst 聚酯材料及其製造方法
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US20130217830A1 (en) 2012-02-16 2013-08-22 Eastman Chemical Company Clear Semi-Crystalline Articles with Improved Heat Resistance
CN103992468B (zh) * 2014-05-23 2016-01-20 三棵树涂料股份有限公司 超支化改性醇酸树脂及其制备方法
CN107868235A (zh) * 2017-10-30 2018-04-03 广州擎天材料科技有限公司 一种粉末涂料用双官能团聚酯树脂及其制备方法
EP4663682A1 (en) * 2024-06-10 2025-12-17 Arkema Quimica SAU Branched polyester for powder coatings

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Also Published As

Publication number Publication date
US20020091206A1 (en) 2002-07-11
US6255523B1 (en) 2001-07-03
US6541595B2 (en) 2003-04-01
AU769617B2 (en) 2004-01-29
JP2002526569A (ja) 2002-08-20
EP1114020B1 (en) 2004-08-25
KR100650829B1 (ko) 2006-11-27
DE69919730D1 (de) 2004-09-30
EP1114020A1 (en) 2001-07-11
CN1318045A (zh) 2001-10-17
CN100357247C (zh) 2007-12-26
EP1481963A1 (en) 2004-12-01
ATE274488T1 (de) 2004-09-15
CZ2001980A3 (cs) 2001-08-15
EP1114020A4 (en) 2001-12-12
CA2344540A1 (en) 2000-03-30
WO2000017148A1 (en) 2000-03-30
BR9913799B1 (pt) 2012-02-07
ZA200102125B (en) 2002-06-14
BR9913799A (pt) 2001-05-29
KR20010075172A (ko) 2001-08-09
AU5818599A (en) 2000-04-10

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Owner name: RESOLUTION SPECIALTY MATERIALS LLC, HOUSTON, TEX.,

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8339 Ceased/non-payment of the annual fee