DE69916857T2 - Durch kupfer katalysierte enantioselektive allylsubstituierungsreaktionen - Google Patents

Durch kupfer katalysierte enantioselektive allylsubstituierungsreaktionen Download PDF

Info

Publication number
DE69916857T2
DE69916857T2 DE69916857T DE69916857T DE69916857T2 DE 69916857 T2 DE69916857 T2 DE 69916857T2 DE 69916857 T DE69916857 T DE 69916857T DE 69916857 T DE69916857 T DE 69916857T DE 69916857 T2 DE69916857 T2 DE 69916857T2
Authority
DE
Germany
Prior art keywords
group
aryl
optionally substituted
process according
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69916857T
Other languages
German (de)
English (en)
Other versions
DE69916857D1 (de
Inventor
Paul Knochel
Frank Duebner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avecia Ltd
Original Assignee
Avecia Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avecia Ltd filed Critical Avecia Ltd
Publication of DE69916857D1 publication Critical patent/DE69916857D1/de
Application granted granted Critical
Publication of DE69916857T2 publication Critical patent/DE69916857T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69916857T 1998-08-28 1999-08-25 Durch kupfer katalysierte enantioselektive allylsubstituierungsreaktionen Expired - Fee Related DE69916857T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9818701.6A GB9818701D0 (en) 1998-08-28 1998-08-28 Stereospecific synthesis and catalysts therefor
GB9818701 1998-08-28
PCT/GB1999/002807 WO2000012449A1 (en) 1998-08-28 1999-08-25 Copper-catalyzed enantioselective allylic substitution reactions

Publications (2)

Publication Number Publication Date
DE69916857D1 DE69916857D1 (de) 2004-06-03
DE69916857T2 true DE69916857T2 (de) 2005-02-03

Family

ID=10837928

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69916857T Expired - Fee Related DE69916857T2 (de) 1998-08-28 1999-08-25 Durch kupfer katalysierte enantioselektive allylsubstituierungsreaktionen

Country Status (9)

Country Link
US (1) US6610871B1 (https=)
EP (1) EP1107936B1 (https=)
JP (1) JP2002523479A (https=)
AT (1) ATE265405T1 (https=)
AU (1) AU5438699A (https=)
CA (1) CA2341860C (https=)
DE (1) DE69916857T2 (https=)
GB (1) GB9818701D0 (https=)
WO (1) WO2000012449A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050032107A (ko) 2002-08-02 2005-04-06 메사추세츠 인스티튜트 오브 테크놀로지 구리를 촉매로 한 탄소-헤테로원자 결합 및 탄소-탄소결합 형성방법
US7419593B2 (en) * 2003-11-19 2008-09-02 Amcol International Corp. Bioremediation mat and method of manufacture and use
JP2007314433A (ja) * 2006-05-23 2007-12-06 Univ Of Tokyo 光学活性三級ホスフィン化合物、これを配位子とする金属錯体およびその用途
CN108409801A (zh) * 2018-02-05 2018-08-17 南京法恩化学有限公司 一种(s)-1-二茂铁基乙醇的制备方法

Also Published As

Publication number Publication date
JP2002523479A (ja) 2002-07-30
EP1107936B1 (en) 2004-04-28
CA2341860A1 (en) 2000-03-09
DE69916857D1 (de) 2004-06-03
US6610871B1 (en) 2003-08-26
GB9818701D0 (en) 1998-10-21
WO2000012449A1 (en) 2000-03-09
ATE265405T1 (de) 2004-05-15
AU5438699A (en) 2000-03-21
CA2341860C (en) 2008-12-23
EP1107936A1 (en) 2001-06-20

Similar Documents

Publication Publication Date Title
EP0104375B1 (de) Neue, phosphorhaltige Biphenylderivate und deren Verwendung für asymmetrische Hydrierungen und enantioselektive Wasserstoffverschiebungen
EP0794957B1 (de) Verfahren zur herstellung optisch aktiver metallocenylphosphine
Dolbier Jr et al. A new zinc difluorocarbenoid reagent
EP0638575B1 (de) Verfahren zur Herstellung von Diorganodialkoxysilanen
WO2002010178A1 (de) Adamantylgruppen enthaltende phosphanliganden, deren herstellung und ihre verwendung in katalytischen reaktionen
EP0643065A1 (de) Neue Bisphosphine für asymmetrische Hydrierkatalysatoren
EP0579797B1 (de) Diphosphinliganden
DE69716720T2 (de) Verfahren zur cyclotrimerisierung von alkinen in wässrigen lösungen
DE68916754T2 (de) Verfahren zur Herstellung von optisch aktiver 3-Hydroxybuttersäure.
DE3853043T2 (de) Isochinolinderivate, ihre Herstellung und Verwendung.
EP1414833B1 (de) Neue übergangsmetall-komplexe und deren einsatz in übergangsmetall-katalysierten reaktionen
DE69916857T2 (de) Durch kupfer katalysierte enantioselektive allylsubstituierungsreaktionen
EP0218970A2 (de) Chirale Rhodium-diphosphinkomplexe für asymmetrische Hydrierungen
CN113735867A (zh) 一种手性吲哚并氧杂七元环化合物及其合成方法
DE69902521T2 (de) Herstellung von phosphin-liganden
DE60021394T2 (de) Transferhydrierungsverfahren
HU196143B (en) Method for producing and applying novel catalyzers containing rhodium
DE69410856T2 (de) Verfahren zur Herstellung von optisch aktiven Beta-hydroxy-ketonen
WO2000014096A1 (de) Chirale diphosphonite auf ferrocenbasis für die asymmetrische katalyse
WO2006114438A2 (de) Mehrfach substituierte ferrocene
WO2004089920A2 (de) Amin-substituierte diphenyldiphosphine und deren verwendung in metallkomplexen für asymmetrische synthesen
DE19827163A1 (de) Verfahren zur katalytischen, unsymmetrischen Disubstitution von Carbonsäureamiden mit 2 unterschiedlichen Grignardreagenzien
EP1683791B1 (de) Verfahren zur Ruthenium-katalysierten Epoxidierung von Olefinen mit Wasserstoffperoxid
DE102010001364B4 (de) Neue P,O-Ferrocene, deren Herstellung und Verwendung in katalytischen Reaktionen
EP1636243B1 (de) Chirale liganden zur anwendung in asymmetrischen synthesen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee