DE69904982D1 - Funktionalisierte Metallocene, deren Herstellung und deren Verwendung - Google Patents
Funktionalisierte Metallocene, deren Herstellung und deren VerwendungInfo
- Publication number
- DE69904982D1 DE69904982D1 DE69904982T DE69904982T DE69904982D1 DE 69904982 D1 DE69904982 D1 DE 69904982D1 DE 69904982 T DE69904982 T DE 69904982T DE 69904982 T DE69904982 T DE 69904982T DE 69904982 D1 DE69904982 D1 DE 69904982D1
- Authority
- DE
- Germany
- Prior art keywords
- group
- independently selected
- aryl
- alkyl
- lrk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 tetrahydroindenyl Chemical group 0.000 abstract 4
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 230000000737 periodic effect Effects 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98500105 | 1998-04-29 | ||
EP98500105 | 1998-04-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69904982D1 true DE69904982D1 (de) | 2003-02-27 |
DE69904982T2 DE69904982T2 (de) | 2004-01-08 |
Family
ID=8235814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69904982T Expired - Fee Related DE69904982T2 (de) | 1998-04-29 | 1999-04-26 | Funktionalisierte Metallocene, deren Herstellung und deren Verwendung |
Country Status (7)
Country | Link |
---|---|
US (1) | US6114555A (de) |
JP (1) | JP2000007692A (de) |
AT (1) | ATE231515T1 (de) |
DE (1) | DE69904982T2 (de) |
ES (1) | ES2190187T3 (de) |
NO (1) | NO992032L (de) |
PT (1) | PT955306E (de) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2154017T3 (es) * | 1996-10-31 | 2001-03-16 | Repsol Quimica Sa | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
ES2211013T3 (es) * | 1998-04-27 | 2004-07-01 | Repsol Quimica S.A. | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
ATE264344T1 (de) * | 1998-04-29 | 2004-04-15 | Repsol Quimica Sa | Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation |
DE50006923D1 (de) * | 1999-04-22 | 2004-08-05 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von silylverbrückten Fluorenyl-Cyclopentadienyl-Liganden und silylverbrückten Fluorenyl-Cyclopentadienyl-Metallocenen |
US6541410B1 (en) * | 2000-06-23 | 2003-04-01 | Exxonmobil Chemical Patents Inc. | Siloxy substituted cocatalyst activators for olefin polymerization |
KR100690345B1 (ko) * | 2004-09-03 | 2007-03-09 | 주식회사 엘지화학 | 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법 |
DE602004019667D1 (de) * | 2004-12-03 | 2009-04-09 | Repsol Quimica Sa | Katalysatorzusammensetzungen für die Polymerisation und Copolymerisation von alpha-Olefinen |
EP2774930A1 (de) * | 2013-03-07 | 2014-09-10 | Aptenia S.R.L. | Metallocenverbindungen und markierte Moleküle damit für In-vivo-Bildgebung |
KR101791231B1 (ko) | 2015-12-23 | 2017-10-27 | 주식회사 엘지화학 | 장섬유 강화용 올레핀 중합체의 제조 방법 및 장섬유 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
KR910008277B1 (ko) * | 1986-12-03 | 1991-10-12 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀 중합용 고체촉매 및 그 제조법 |
DE3718888A1 (de) * | 1987-06-05 | 1988-12-22 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
EP0816395B1 (de) * | 1994-04-11 | 2000-07-19 | Mitsui Chemicals, Inc. | Verfahren zur Herstellung von einer Propylen-Polymer-Zusammensetzung und Propylen-Polymer-Zusammensetzung |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
ES2120868B1 (es) * | 1995-08-03 | 2000-09-16 | Repsol Quimica Sa | Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. |
ES2129323B1 (es) * | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
ES2154017T3 (es) * | 1996-10-31 | 2001-03-16 | Repsol Quimica Sa | Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas. |
ES2192760T3 (es) * | 1997-02-01 | 2003-10-16 | Repsol Quimica Sa | Compuestos metalocenicos, su procedimiento de sistesis y uso de los mismos. |
-
1999
- 1999-04-26 DE DE69904982T patent/DE69904982T2/de not_active Expired - Fee Related
- 1999-04-26 PT PT99500064T patent/PT955306E/pt unknown
- 1999-04-26 AT AT99500064T patent/ATE231515T1/de not_active IP Right Cessation
- 1999-04-26 ES ES99500064T patent/ES2190187T3/es not_active Expired - Lifetime
- 1999-04-27 US US09/300,301 patent/US6114555A/en not_active Expired - Fee Related
- 1999-04-28 JP JP11121429A patent/JP2000007692A/ja not_active Ceased
- 1999-04-28 NO NO992032A patent/NO992032L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
US6114555A (en) | 2000-09-05 |
DE69904982T2 (de) | 2004-01-08 |
ATE231515T1 (de) | 2003-02-15 |
ES2190187T3 (es) | 2003-07-16 |
NO992032D0 (no) | 1999-04-28 |
JP2000007692A (ja) | 2000-01-11 |
NO992032L (no) | 1999-11-01 |
PT955306E (pt) | 2003-06-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |