ES2190187T3 - Componentes de metaloceno funcionalizados, procedimiento de sintesis y uso. - Google Patents
Componentes de metaloceno funcionalizados, procedimiento de sintesis y uso.Info
- Publication number
- ES2190187T3 ES2190187T3 ES99500064T ES99500064T ES2190187T3 ES 2190187 T3 ES2190187 T3 ES 2190187T3 ES 99500064 T ES99500064 T ES 99500064T ES 99500064 T ES99500064 T ES 99500064T ES 2190187 T3 ES2190187 T3 ES 2190187T3
- Authority
- ES
- Spain
- Prior art keywords
- equal
- rent
- selected independently
- group
- different
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- -1 tetrahydroindenyl Chemical group 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 230000000737 periodic effect Effects 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- HPYIUKIBUJFXII-UHFFFAOYSA-N Cyclopentadienyl radical Chemical group [CH]1C=CC=C1 HPYIUKIBUJFXII-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A COMPUESTOS DE METALOCENO CARACTERIZADOS POR LAS SIGUIENTES FORMULAS: DONDE: L, IGUALES O DISTINTOS ENTRE SI, SE SELECCIONAN A PARTIR DEL GRUPO FORMADO POR: CICLOPENTADIENILO, INDENILO, TETRAHIDROINDENILO, FLUORENILO, OCTAHIDROFLUORENILO O BENZOINDENILO; CADA R SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE HIDROGENO, ALQUILO C 1 - C 20 , CICLOALQUILO C 3 - C 20 , ARILO C 6 - C 20 , ALQUENILO C 3 - C 20 , ARILALQUILO C SUB,7 - C 20 , ALQUILARILO C 7 - C 20 , ARILALQUEN ILO C 8 C 20 , LINEAL O RAMIFICADO, OPCIONALMENTE SUSTITUIDO POR 1 A 10 ATOMOS DE HALOGENO, O UN GRUPO SIR II SUB,3 ; CADA R I , IGUAL O DISTINTO DE LOS DEMAS, ES UN GRUPO SIR II 2 O UN GRUPO HIDROCARBONADO ALIFATICO O A ROMATICO DIVALENTE QUE CONTIENE DE 1 A 20 ATOMOS DE CARBONO, QUE CONTIENE OPCIONALMENTE DE 1 A 5 HETEROATOMOS DE LOS GRUPOS 14 A 16 DE LA TABLA PERIODICA DE LOS ELEMENTOS, Y BORO; CADA Q SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE B, C, SI, GE, SN; M ES UN METAL DE LOS GRUPOS3, 4 O 10 DE LA TABLA PERIODICA, LANTANIDO O ACTINIDO; CADA X SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE HIDROGENO, CLORO, BROMO, OR II , NR II 2 , ALQUILO C 1 - C 20 O ARILO C 5 - C 20 ; CADA R II SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE ALQUILO C 1 - C 20 , CICLOALQUILO C 3 C 20 ARI LO C 6 - C 20 , ALQUENILO C 3 C 20 , ARILALQUILO C 7 - C 20 , ARILALQUENILO C 7 - C 20 O ALQUILARILO, LINEAL O RAMIFICADO; R II ES PREFERIBLEMENTE METILO, ETILO O ISOPROPILO; L'' ES N O O; CUANDO L ES CICLOPENTADIENILO, K ES IGUAL A 5; CUANDO L ES INDENILO, K ES IGUAL A 7, CUANDO L ES FLUORENILO O BENZOINDENILO, K ES IGUAL A 9, CUANDO L ES TETRAHIDROINDENILO, K ES IGUAL A 11, Y CUANDO L ES OCTAHIDROFLUORENILO, K ES IGUAL A 17; Z ES IGUAL A 0, 1 O 2; X ES IGUAL A 1, 2 O 3; Y ES IGUAL A 1, 2 O 3; X + Y + Z ES IGUAL A LA VALENCIA DE M; M ES UN ENTERO QUE PUEDE TENER LOS VALORES 1, 2, 3 O 4; A Y B SON ENTEROS CUYO VALOR VARIA ENTRE 0 Y K-1; F ES UN ENTERO CUYO VALOR VARIA ENTRE 1 Y K; G ES 0 O 1; C Y E SON IGUALES A 0 O 1; A + B + C ES AL MENOS 1; A + G + C ES AL MENOS 1; D ES IGUAL A 0, 1 O 2; CUANDO Q ES B, C + D = 1; CUANDO Q ES C, SI, GE O SN, C + D = 2; CUANDO L'' ES N, G + E = 1; CUANDO L'' ES O, G = 0 Y E = 0.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98500105 | 1998-04-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2190187T3 true ES2190187T3 (es) | 2003-07-16 |
Family
ID=8235814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES99500064T Expired - Lifetime ES2190187T3 (es) | 1998-04-29 | 1999-04-26 | Componentes de metaloceno funcionalizados, procedimiento de sintesis y uso. |
Country Status (7)
Country | Link |
---|---|
US (1) | US6114555A (es) |
JP (1) | JP2000007692A (es) |
AT (1) | ATE231515T1 (es) |
DE (1) | DE69904982T2 (es) |
ES (1) | ES2190187T3 (es) |
NO (1) | NO992032L (es) |
PT (1) | PT955306E (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3955140B2 (ja) * | 1996-10-31 | 2007-08-08 | レプソル・ケミカ・ソシエダ・アノニマ | アルフアオレフインの重合及び共重合用触媒系 |
PT953581E (pt) * | 1998-04-27 | 2004-07-30 | Repsol Quimica Sa | Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas |
ATE264344T1 (de) * | 1998-04-29 | 2004-04-15 | Repsol Quimica Sa | Verfahren und verwendung von heterogenen katalysatorbestandteilen für die olefinpolymerisation |
EP1046642B1 (de) * | 1999-04-22 | 2004-06-30 | Basell Polyolefine GmbH | Verfahren zur Herstellung von silylverbrückten Fluorenyl-Cyclopentadienyl-Liganden und silylverbrückten Fluorenyl-Cyclopentadienyl-Metallocenen |
US6541410B1 (en) * | 2000-06-23 | 2003-04-01 | Exxonmobil Chemical Patents Inc. | Siloxy substituted cocatalyst activators for olefin polymerization |
KR100690345B1 (ko) * | 2004-09-03 | 2007-03-09 | 주식회사 엘지화학 | 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법 |
DE602004019667D1 (de) * | 2004-12-03 | 2009-04-09 | Repsol Quimica Sa | Katalysatorzusammensetzungen für die Polymerisation und Copolymerisation von alpha-Olefinen |
EP2774930A1 (en) * | 2013-03-07 | 2014-09-10 | Aptenia S.R.L. | Metallocene compounds and labeled molecules comprising the same for in vivo imaging. |
KR101791231B1 (ko) | 2015-12-23 | 2017-10-27 | 주식회사 엘지화학 | 장섬유 강화용 올레핀 중합체의 제조 방법 및 장섬유 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
US4921825A (en) * | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
DE3718888A1 (de) * | 1987-06-05 | 1988-12-22 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
US5753769A (en) * | 1994-04-11 | 1998-05-19 | Mitsui Petrochemical Industries, Ltd. | Process for preparing propylene polymer composition and propylene polymer composition |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
ES2120868B1 (es) * | 1995-08-03 | 2000-09-16 | Repsol Quimica Sa | Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. |
ES2129323B1 (es) * | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
JP3955140B2 (ja) * | 1996-10-31 | 2007-08-08 | レプソル・ケミカ・ソシエダ・アノニマ | アルフアオレフインの重合及び共重合用触媒系 |
ATE236914T1 (de) * | 1997-02-01 | 2003-04-15 | Repsol Quimica Sa | Metallocene, deren herstellung und verwendung |
-
1999
- 1999-04-26 DE DE69904982T patent/DE69904982T2/de not_active Expired - Fee Related
- 1999-04-26 AT AT99500064T patent/ATE231515T1/de not_active IP Right Cessation
- 1999-04-26 ES ES99500064T patent/ES2190187T3/es not_active Expired - Lifetime
- 1999-04-26 PT PT99500064T patent/PT955306E/pt unknown
- 1999-04-27 US US09/300,301 patent/US6114555A/en not_active Expired - Fee Related
- 1999-04-28 JP JP11121429A patent/JP2000007692A/ja not_active Ceased
- 1999-04-28 NO NO992032A patent/NO992032L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
DE69904982T2 (de) | 2004-01-08 |
US6114555A (en) | 2000-09-05 |
PT955306E (pt) | 2003-06-30 |
DE69904982D1 (de) | 2003-02-27 |
NO992032L (no) | 1999-11-01 |
JP2000007692A (ja) | 2000-01-11 |
NO992032D0 (no) | 1999-04-28 |
ATE231515T1 (de) | 2003-02-15 |
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