ES2156359T3 - Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en suspension. - Google Patents

Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en suspension.

Info

Publication number
ES2156359T3
ES2156359T3 ES97903321T ES97903321T ES2156359T3 ES 2156359 T3 ES2156359 T3 ES 2156359T3 ES 97903321 T ES97903321 T ES 97903321T ES 97903321 T ES97903321 T ES 97903321T ES 2156359 T3 ES2156359 T3 ES 2156359T3
Authority
ES
Spain
Prior art keywords
carbon atoms
metal
aryl
alkyl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97903321T
Other languages
English (en)
Inventor
John Lynch
David Fischer
Hans-Helmut Gortz
Gunther Schweier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2156359T3 publication Critical patent/ES2156359T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA PRODUCCION DE POLIMEROS DE ALQUENOS MEDIANTE POLIMERIZACION POR SUSPENSION EN PRESENCIA DE UNOS SISTEMAS CATALIZADORES, UTILIZANDOSE UNOS SISTEMAS CATALIZADORES PORTADOS COMO SISTEMAS CATALIZADORES, QUE SON OBTENIDOS A) HACIENDO REACCIONAR UN MATERIAL PORTANTE INORGANICO CON UN COMPUESTO METALICO DE FORMULA GENERAL (I) M SUP,1 (R 1 ) R (R 2 ) S (R 3 ) T (R S UP,4 ) U , EN DONDE M 1 ES UN METAL ALCALINO O ALCALINOTERREO O UN METAL DEL III O IV GRUPO PRINCIPAL DEL SISTEMA PERIODICO; R 1 ES HIDROGENO, C 1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUILARILO O ARILALQUILO, EN CADA CASO, CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R 2 A R 4 SON HIDROGENO, HALOGENO, C 1 A C 10 ALQUILO, C 6 A C SU B,15 ARILO, ALQUILARILO, ARILALQUILO, ALCOXI O DIALQUILAMINO, EN CADA CASO CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R ES UN NUMERO ENTERO DEL 1 AL 4; S, T Y U SON NUMEROS ENTEROS DEL 0 AL 3, CORRESPONDIENDO LA SUMA R+S+T+U A LA VALENCIA DE M 1 ; B) HACIENDO REACCIONAR EL MATERIAL OBTENIDO SEGUN A) CON UN COMPLEJO METALOCENO EN SU FORMA METALICA DIHALOGENA Y UN COMPUESTO FORMADOR DE IONES METALOCENOS; C) REACCION POSTERIOR CON UN COMPUESTO METALICO DE FORMULA GENERAL (II) M 2 (R 5 ) O (R SU P,6 ) P (R 7 )(SUB,Q , EN DONDE M 2 ES UN METAL ALCALINO, ALCALINOTERREO O UN METAL DEL III GRUPO PRINCIPAL DEL SISTEMA PERIODICO; R 5 ES HIDROGENO, C 1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUILARILO O ARILALQUILO, EN CADA CASO, CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R 6 Y R 7 SON HIDROGENO, HALOGENO, C 1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUILARILO, ARILALQUILO O ALCOXI, EN CA DA CASO CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; O ES UN NUMERO ENTERO DEL 1 AL 3; P Y Q SON NUMEROS ENTEROS DEL 0 AL 2, CORRESPONDIENDO LA SUMA O+P+Q A LA VALENCIA DE M 2 .
ES97903321T 1996-02-20 1997-02-19 Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en suspension. Expired - Lifetime ES2156359T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19606166A DE19606166A1 (de) 1996-02-20 1996-02-20 Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation

Publications (1)

Publication Number Publication Date
ES2156359T3 true ES2156359T3 (es) 2001-06-16

Family

ID=7785835

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97903321T Expired - Lifetime ES2156359T3 (es) 1996-02-20 1997-02-19 Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en suspension.

Country Status (13)

Country Link
US (1) US6326444B2 (es)
EP (1) EP0882069B1 (es)
JP (1) JP2000504776A (es)
KR (1) KR100471333B1 (es)
CN (1) CN1128814C (es)
AT (1) ATE200784T1 (es)
AU (1) AU713739B2 (es)
BR (1) BR9707565A (es)
CA (1) CA2246389A1 (es)
DE (2) DE19606166A1 (es)
ES (1) ES2156359T3 (es)
NO (1) NO983787L (es)
WO (1) WO1997031029A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19703502A1 (de) * 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
DE19757262A1 (de) * 1997-12-23 1999-07-01 Targor Gmbh Verfahren zur Herstellung von Olefinpolymerisaten mit erhöhtem Schmelzpunkt
DE19806435A1 (de) 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
EP3889159B1 (en) 2014-10-23 2024-06-05 Inpria Corporation Organometallic solution based high resolution patterning compositions

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
ATE186918T1 (de) * 1990-01-02 1999-12-15 Exxon Chemical Patents Inc Ionische metallocenkatalysatoren auf träger für olefinpolymerisation
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
EP1110974B1 (en) 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Method for preparing a supported activator component
JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
BE1006880A3 (fr) 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
EP0619326B1 (en) * 1993-04-09 1997-06-25 Tosoh Corporation Olefin polymerization catalyst and olefin polymerisation process
JP2882241B2 (ja) * 1993-06-07 1999-04-12 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
EP0729477B1 (en) * 1993-11-19 1999-10-27 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
DE4344672C1 (de) * 1993-12-27 1995-06-14 Basf Ag Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
DE4431837A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
AU712417B2 (en) * 1995-03-10 1999-11-04 Dow Chemical Company, The Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation

Also Published As

Publication number Publication date
CN1211992A (zh) 1999-03-24
KR100471333B1 (ko) 2005-05-16
US20010001796A1 (en) 2001-05-24
NO983787D0 (no) 1998-08-19
AU1792197A (en) 1997-09-10
WO1997031029A1 (de) 1997-08-28
CA2246389A1 (en) 1997-08-28
US6326444B2 (en) 2001-12-04
EP0882069A1 (de) 1998-12-09
DE19606166A1 (de) 1997-08-21
KR19990087067A (ko) 1999-12-15
DE59703435D1 (de) 2001-05-31
AU713739B2 (en) 1999-12-09
ATE200784T1 (de) 2001-05-15
JP2000504776A (ja) 2000-04-18
CN1128814C (zh) 2003-11-26
BR9707565A (pt) 1999-07-27
NO983787L (no) 1998-10-19
EP0882069B1 (de) 2001-04-25

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