DE69901159T2 - Zwei optisch variable pigmente enthaltende druckfarben-zusammensetzung - Google Patents
Zwei optisch variable pigmente enthaltende druckfarben-zusammensetzungInfo
- Publication number
- DE69901159T2 DE69901159T2 DE69901159T DE69901159T DE69901159T2 DE 69901159 T2 DE69901159 T2 DE 69901159T2 DE 69901159 T DE69901159 T DE 69901159T DE 69901159 T DE69901159 T DE 69901159T DE 69901159 T2 DE69901159 T2 DE 69901159T2
- Authority
- DE
- Germany
- Prior art keywords
- optically variable
- ink composition
- printing ink
- layer
- dichroic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 60
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 239000010410 layer Substances 0.000 claims description 84
- 239000010409 thin film Substances 0.000 claims description 26
- 238000007639 printing Methods 0.000 claims description 25
- 230000008859 change Effects 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 229910044991 metal oxide Inorganic materials 0.000 claims description 13
- 150000004706 metal oxides Chemical class 0.000 claims description 13
- 239000012792 core layer Substances 0.000 claims description 9
- 238000010586 diagram Methods 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 230000003042 antagnostic effect Effects 0.000 claims description 4
- 238000005229 chemical vapour deposition Methods 0.000 claims description 4
- 239000002952 polymeric resin Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 3
- 230000008485 antagonism Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 6
- 230000001419 dependent effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 28
- 239000000463 material Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 238000002156 mixing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003086 colorant Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 238000009501 film coating Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 235000019646 color tone Nutrition 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 206010067868 Skin mass Diseases 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229940087654 iron carbonyl Drugs 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/65—Chroma (C*)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
- C01P2006/66—Hue (H*)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1004—Interference pigments characterized by the core material the core comprising at least one inorganic oxide, e.g. Al2O3, TiO2 or SiO2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1004—Interference pigments characterized by the core material the core comprising at least one inorganic oxide, e.g. Al2O3, TiO2 or SiO2
- C09C2200/1008—Interference pigments characterized by the core material the core comprising at least one inorganic oxide, e.g. Al2O3, TiO2 or SiO2 comprising at least one metal layer adjacent to the core material, e.g. core-M or M-core-M
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/10—Wet methods, e.g. co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/20—PVD, CVD methods or coating in a gas-phase using a fluidized bed
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Liquid Crystal Substances (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Printing Methods (AREA)
- Credit Cards Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98118992 | 1998-10-08 | ||
| PCT/EP1999/007572 WO2000022049A1 (en) | 1998-10-08 | 1999-10-08 | Ink composition comprising first and second optically variable pigments |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69901159D1 DE69901159D1 (de) | 2002-05-08 |
| DE69901159T2 true DE69901159T2 (de) | 2003-01-09 |
Family
ID=8232763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69901159T Expired - Lifetime DE69901159T2 (de) | 1998-10-08 | 1999-10-08 | Zwei optisch variable pigmente enthaltende druckfarben-zusammensetzung |
Country Status (24)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004019084A1 (ja) * | 2001-03-28 | 2004-03-04 | Sumitomo Metal Mining Co.,Ltd. | 可視光吸収膜とこの可視光吸収膜を有する構造体および可視光吸収膜を形成する可視光吸収インク |
| EP1288269A1 (en) * | 2001-08-28 | 2003-03-05 | Sicpa Holding S.A. | Water-based screen printing ink |
| EP1288265A1 (en) * | 2001-08-28 | 2003-03-05 | Sicpa Holding S.A. | Ink composition comprising optically variable pigments, use of the composition, optically variable pigment and method of treating said pigment |
| US7029525B1 (en) | 2003-10-21 | 2006-04-18 | The Standard Register Company | Optically variable water-based inks |
| US7677714B2 (en) | 2004-10-01 | 2010-03-16 | Hewlett-Packard Development Company, L.P. | Inkjet inks providing improved wet smudge on porous print media |
| JP5086096B2 (ja) * | 2004-12-17 | 2012-11-28 | キャボット コーポレイション | 多層顔料を含むインクジェットインキ |
| CN100432164C (zh) * | 2005-06-09 | 2008-11-12 | 上海印钞厂 | 一种具有偏振效果的光学变色油墨 |
| EP1943188A2 (en) | 2005-10-03 | 2008-07-16 | Sun Chemical Corporation | Security pigments and the process of making thereof |
| US20080087189A1 (en) * | 2005-10-03 | 2008-04-17 | Sun Chemical Corporation | Security pigments and the process of making thereof |
| KR101385856B1 (ko) | 2006-05-24 | 2014-04-17 | 닛산 가가쿠 고교 가부시키 가이샤 | 게이트 절연막용 도포액, 게이트 절연막 및 유기 트랜지스터 |
| UA100152C2 (uk) | 2008-04-02 | 2012-11-26 | Сікпа Холдінг Са | Мітка для об'єкта чи виробу та її застосування, об'єкт чи виріб, що має мітку, спосіб його ідентифікації та спосіб його захисту і відстеження за допомогою мітки |
| ES2691381T3 (es) * | 2008-10-03 | 2018-11-27 | Sicpa Holding Sa | Elemento de seguridad doble ópticamente variable |
| PE20100769A1 (es) | 2009-04-02 | 2010-11-25 | Sicpa Holding Sa | Identificacion y autenticacion usando marcados de material de cristal liquido polimerico |
| FR2959843B1 (fr) | 2010-05-05 | 2013-01-25 | Honnorat Rech S & Services | Dispositif d'authentification discret. |
| FR2959842B1 (fr) | 2010-05-05 | 2012-05-04 | Honnorat Rech S & Services | Document securise, testeur et methode d'authentification. |
| EP2629980B1 (en) | 2010-10-22 | 2017-06-14 | Hewlett-Packard Development Company, L.P. | Printed articles with optically variable properties |
| ES2584727T3 (es) * | 2013-02-27 | 2016-09-28 | Philip Morris Products S.A. | Artículo para fumar con marca que cambia de color |
| FR3004471B1 (fr) | 2013-04-11 | 2015-10-23 | Arjowiggins Security | Element de securite comportant une structure de masquage contenant un melange de charges nanometriques. |
| FR3004470B1 (fr) * | 2013-04-11 | 2015-05-22 | Arjowiggins Security | Element de securite comportant un pigment interferentiel et une charge nanometrique. |
| IN2014MU03621A (cg-RX-API-DMAC7.html) | 2013-11-18 | 2015-10-09 | Jds Uniphase Corp | |
| WO2018024760A1 (de) * | 2016-08-04 | 2018-02-08 | Merck Patent Gmbh | Verfahren zum erzeugen eines optisch variablen druckbildes |
| EP3517579B1 (de) | 2018-01-23 | 2022-10-26 | Merck Patent GmbH | Pigmentgemisch enthaltend rote, blaue und grüne interferenzpigmente |
| US12692397B2 (en) * | 2019-10-08 | 2026-07-28 | Viavi Solutions Inc. | Composition including dual cavity color shifting pigments |
| CN114746513A (zh) | 2019-11-29 | 2022-07-12 | Viavi科技有限公司 | 一种包含具有不同粒径的变色颜料的组合物 |
| US20240208865A1 (en) * | 2022-12-21 | 2024-06-27 | Concrete Sealants, Inc. | Pigmented suspension for use in concrete densification agents |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5569535A (en) * | 1979-12-28 | 1996-10-29 | Flex Products, Inc. | High chroma multilayer interference platelets |
| US5766738A (en) * | 1979-12-28 | 1998-06-16 | Flex Products, Inc. | Paired optically variable article with paired optically variable structures and ink, paint and foil incorporating the same and method |
| DE3003352A1 (de) * | 1980-01-31 | 1981-08-06 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von eisenoxidbelegten metallpigmenten |
| US4879140A (en) * | 1988-11-21 | 1989-11-07 | Deposition Sciences, Inc. | Method for making pigment flakes |
| RU2035314C1 (ru) * | 1992-07-28 | 1995-05-20 | Предприятие "Спекл" | Способ изготовления голографических этикеток |
| EP0657297B2 (en) * | 1993-12-10 | 2003-04-23 | Agfa-Gevaert | Security document having a transparent or translucent support and containing interference pigments. |
| US5498781A (en) * | 1994-05-23 | 1996-03-12 | Basf Corporation | Passification of optically variable pigment and waterborne coating compositions containg the same |
| US5527848A (en) * | 1994-12-14 | 1996-06-18 | Basf Corporation | Pacification of optically variable pigments for use in waterborne coating compositions |
| US5871827A (en) * | 1996-06-21 | 1999-02-16 | Ciba Specialty Chemicals Corporation | Finishes containing light interference pigments |
| GB9619781D0 (en) * | 1996-09-23 | 1996-11-06 | Secr Defence | Multi layer interference coatings |
| EP1335005B1 (de) * | 1997-04-22 | 2006-06-21 | Ciba SC Holding AG | Farbige Effektpigmente und deren Verwendung |
| US6139613A (en) * | 1998-08-21 | 2000-10-31 | Aveka, Inc. | Multilayer pigments and their manufacture |
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1998
- 1998-10-08 ID IDW20001339A patent/ID26212A/id unknown
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1999
- 1999-08-10 UA UA2000074072A patent/UA52807C2/uk unknown
- 1999-10-08 TR TR2000/01659T patent/TR200001659T1/xx unknown
- 1999-10-08 BR BRPI9906859-1A patent/BR9906859B1/pt not_active IP Right Cessation
- 1999-10-08 HU HU0100370A patent/HU223659B1/hu active IP Right Grant
- 1999-10-08 KR KR1020007006188A patent/KR100620335B1/ko not_active Expired - Fee Related
- 1999-10-08 EP EP99952544A patent/EP1036116B1/en not_active Expired - Lifetime
- 1999-10-08 PT PT99952544T patent/PT1036116E/pt unknown
- 1999-10-08 JP JP2000575947A patent/JP2002527563A/ja active Pending
- 1999-10-08 PL PL341155A patent/PL199968B1/pl not_active IP Right Cessation
- 1999-10-08 NZ NZ505563A patent/NZ505563A/en not_active IP Right Cessation
- 1999-10-08 DK DK99952544T patent/DK1036116T3/da active
- 1999-10-08 US US09/555,879 patent/US6472455B1/en not_active Expired - Lifetime
- 1999-10-08 AU AU64699/99A patent/AU757967B2/en not_active Ceased
- 1999-10-08 ES ES99952544T patent/ES2176033T3/es not_active Expired - Lifetime
- 1999-10-08 CA CA002312155A patent/CA2312155C/en not_active Expired - Fee Related
- 1999-10-08 WO PCT/EP1999/007572 patent/WO2000022049A1/en not_active Ceased
- 1999-10-08 CZ CZ20002111A patent/CZ300777B6/cs not_active IP Right Cessation
- 1999-10-08 AT AT99952544T patent/ATE215589T1/de active
- 1999-10-08 RU RU2000118212/04A patent/RU2220174C2/ru not_active IP Right Cessation
- 1999-10-08 DE DE69901159T patent/DE69901159T2/de not_active Expired - Lifetime
- 1999-10-08 CN CNB998017892A patent/CN1168784C/zh not_active Expired - Lifetime
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2000
- 2000-06-07 ZA ZA200002863A patent/ZA200002863B/xx unknown
- 2000-06-07 NO NO20002897A patent/NO320205B1/no not_active IP Right Cessation
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2007
- 2007-09-28 JP JP2007252853A patent/JP2008050612A/ja active Pending
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Owner name: SICPA HOLDING SA, PRILLY, CH |