DE69840884D1 - Kupferkomplexe optisch aktiver Bisoxazoline als enantioselektive Katalysatoren bei Cyclopropanierungsreaktionen - Google Patents

Kupferkomplexe optisch aktiver Bisoxazoline als enantioselektive Katalysatoren bei Cyclopropanierungsreaktionen

Info

Publication number
DE69840884D1
DE69840884D1 DE69840884T DE69840884T DE69840884D1 DE 69840884 D1 DE69840884 D1 DE 69840884D1 DE 69840884 T DE69840884 T DE 69840884T DE 69840884 T DE69840884 T DE 69840884T DE 69840884 D1 DE69840884 D1 DE 69840884D1
Authority
DE
Germany
Prior art keywords
optically active
copper complexes
cyclopropanation reactions
enantioselective catalysts
bisoxazolines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69840884T
Other languages
English (en)
Inventor
Makoto Itagaki
Gohfu Suzukamo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of DE69840884D1 publication Critical patent/DE69840884D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D263/12—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with radicals containing only hydrogen and carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/743—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a three-membered ring and with unsaturation outside the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE69840884T 1997-08-05 1998-08-04 Kupferkomplexe optisch aktiver Bisoxazoline als enantioselektive Katalysatoren bei Cyclopropanierungsreaktionen Expired - Lifetime DE69840884D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21041797 1997-08-05

Publications (1)

Publication Number Publication Date
DE69840884D1 true DE69840884D1 (de) 2009-07-23

Family

ID=16588977

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69840884T Expired - Lifetime DE69840884D1 (de) 1997-08-05 1998-08-04 Kupferkomplexe optisch aktiver Bisoxazoline als enantioselektive Katalysatoren bei Cyclopropanierungsreaktionen

Country Status (6)

Country Link
US (2) US6072081A (de)
EP (1) EP0895992B8 (de)
KR (1) KR100537324B1 (de)
CN (2) CN1231456C (de)
CA (1) CA2244417C (de)
DE (1) DE69840884D1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE489356T1 (de) * 2001-04-27 2010-12-15 Sumitomo Chemical Co Asymmetrischer kupferkomplex und dessen verwendung in cyclopropanierungsreaktion
PL210934B1 (pl) 2003-02-07 2012-03-30 Sumitomo Chemical Co Optycznie czynne pochodne bisoksazoliny, sposób wytwarzania tych związków, substraty i sposób ich wytwarzania
EP1674445A4 (de) * 2003-09-19 2006-10-25 Sumitomo Chemical Co Verfahren zur herstellung einer optisch aktiven cyclopropanverbindung und dafür verwendeter asymmetrischer kupferkomplex
US7612236B2 (en) 2003-12-22 2009-11-03 Sumitomo Chemical Company, Limited Method for producing optically active bisamidoalcohol compound
KR101127255B1 (ko) * 2003-12-22 2012-04-12 스미또모 가가꾸 가부시키가이샤 광학 활성인 시클로알킬리덴비스옥사졸린 화합물의 제조방법 및 그의 중간체
ITMI20041211A1 (it) * 2004-06-16 2004-09-16 Endura Spa Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo
JP5002916B2 (ja) 2004-07-01 2012-08-15 住友化学株式会社 不斉銅錯体およびそれを用いた光学活性なシクロプロパンカルボン酸エステル化合物の製造方法
WO2006004180A1 (ja) 2004-07-01 2006-01-12 Sumitomo Chemical Company, Limited 光学活性なシクロプロパンカルボン酸エステル化合物の製造方法
CN1906293A (zh) * 2005-03-08 2007-01-31 科学技术研究院 固定化酶
WO2014193915A1 (en) * 2013-05-28 2014-12-04 Sigma-Aldrich Co. Llc Manganese complexes and use thereof for preparing thin films
CN104193645B (zh) * 2014-07-15 2017-02-01 上海应用技术学院 一种手性二甲基环丙甲酰胺的制备方法

Also Published As

Publication number Publication date
CN1134422C (zh) 2004-01-14
US6410741B1 (en) 2002-06-25
EP0895992A2 (de) 1999-02-10
EP0895992B1 (de) 2009-06-10
CN1231456C (zh) 2005-12-14
EP0895992B8 (de) 2009-09-02
CA2244417A1 (en) 1999-02-05
US6072081A (en) 2000-06-06
CN1480448A (zh) 2004-03-10
KR100537324B1 (ko) 2006-03-30
EP0895992A3 (de) 1999-02-17
KR19990023341A (ko) 1999-03-25
CA2244417C (en) 2006-07-18
CN1210858A (zh) 1999-03-17

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