DE69839354D1 - Verwendung einer Mischung aus zwei Regioisomeren eines Metallocens als Katalysatorbestandteil für die Herstellung bimodaler isotaktischen Polyolefine - Google Patents

Verwendung einer Mischung aus zwei Regioisomeren eines Metallocens als Katalysatorbestandteil für die Herstellung bimodaler isotaktischen Polyolefine

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Publication number
DE69839354D1
DE69839354D1 DE69839354T DE69839354T DE69839354D1 DE 69839354 D1 DE69839354 D1 DE 69839354D1 DE 69839354 T DE69839354 T DE 69839354T DE 69839354 T DE69839354 T DE 69839354T DE 69839354 D1 DE69839354 D1 DE 69839354D1
Authority
DE
Germany
Prior art keywords
hydrocarbyl
chosen
carbon atoms
substituent
catalyst component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69839354T
Other languages
English (en)
Other versions
DE69839354T2 (de
Inventor
Abbas Razavi
Vincenzo Bellia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Application granted granted Critical
Publication of DE69839354D1 publication Critical patent/DE69839354D1/de
Publication of DE69839354T2 publication Critical patent/DE69839354T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69839354T 1997-05-26 1998-05-26 Verwendung einer Mischung aus zwei Regioisomeren eines Metallocens als Katalysatorbestandteil für die Herstellung bimodaler isotaktischen Polyolefine Expired - Lifetime DE69839354T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97108467 1997-05-26
EP97108467A EP0881236A1 (de) 1997-05-26 1997-05-26 Mettallocen-Katalysatorkomponente zur Herstellung von isotaktischen Polyolefinen

Publications (2)

Publication Number Publication Date
DE69839354D1 true DE69839354D1 (de) 2008-05-21
DE69839354T2 DE69839354T2 (de) 2009-05-28

Family

ID=8226830

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69839354T Expired - Lifetime DE69839354T2 (de) 1997-05-26 1998-05-26 Verwendung einer Mischung aus zwei Regioisomeren eines Metallocens als Katalysatorbestandteil für die Herstellung bimodaler isotaktischen Polyolefine
DE69815846T Expired - Lifetime DE69815846T2 (de) 1997-05-26 1998-05-26 Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69815846T Expired - Lifetime DE69815846T2 (de) 1997-05-26 1998-05-26 Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinen

Country Status (9)

Country Link
US (1) US6559089B1 (de)
EP (3) EP0881236A1 (de)
JP (1) JP4208097B2 (de)
AT (2) ATE391734T1 (de)
DE (2) DE69839354T2 (de)
DK (1) DK0984989T3 (de)
ES (2) ES2202875T3 (de)
PT (2) PT984989E (de)
WO (1) WO1998054230A1 (de)

Families Citing this family (32)

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Publication number Priority date Publication date Assignee Title
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
JP4864176B2 (ja) * 1999-02-19 2012-02-01 トータル・ペトロケミカルズ・リサーチ・フエリユイ ポリオレフィン製造
US6515086B1 (en) 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
EP1031582A1 (de) * 1999-02-26 2000-08-30 Fina Research S.A. Verwendung und Herstellung von Polypropylen
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
US7475098B2 (en) * 2002-03-19 2009-01-06 Network Appliance, Inc. System and method for managing a plurality of snapshots
WO2004020481A1 (en) 2002-08-29 2004-03-11 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
AU2003292690B2 (en) * 2003-03-28 2008-11-20 Mitsui Chemicals, Inc. Propylene copolymer, polypropylene composition, use thereof, transition metal compounds, and catalysts for olefin polymerization
US6855783B2 (en) 2003-04-11 2005-02-15 Fina Technology, Inc. Supported metallocene catalysts
US6878787B2 (en) 2003-08-26 2005-04-12 Fina Technology, Inc. Polyamide supported metallocene catalysts
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
CN101010350B (zh) * 2004-08-30 2013-01-02 三井化学株式会社 丙烯系聚合物的制造方法
CN100390256C (zh) 2004-11-26 2008-05-28 三井化学株式会社 合成润滑油和润滑油组合物
KR101169179B1 (ko) 2005-05-18 2012-07-30 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매, 올레핀 중합체의 제조방법, 프로필렌계 공중합체의 제조방법, 프로필렌 중합체, 프로필렌계 중합체 조성물 및 이들의 용도
US20090043057A1 (en) * 2005-05-25 2009-02-12 Mitsui Chemicals , Inc. Transition Metal Compound, Catalyst for Olefin Polymerization, and Process for Producing Olefin Polymer
US7834204B2 (en) * 2005-05-25 2010-11-16 Mitsui Chemicals, Inc. Fluorene derivative, transition metal compound, catalyst for olefin polymerization, and process for producing olefin polymer
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
EP1762577A1 (de) * 2005-09-02 2007-03-14 Total Petrochemicals Research Feluy Schlagfeste propylen-copolymere vorbereitet in einem reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
EP2204375A1 (de) 2008-12-12 2010-07-07 Total Petrochemicals Research Feluy Herstellung von monoarylsubstituierten, methylenverbrückten substituierten Cyclopentadienyl-Fluorenyl-Liganden und davon abgeleitete Zirkoniumkomplexe
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
US8716418B2 (en) 2009-12-21 2014-05-06 Mitsui Chemicals, Inc. Process for producing syndiotactic α-olefin polymer
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
SG10201508676PA (en) 2012-03-21 2015-11-27 Mitsui Chemicals Inc Method for producing olefin polymer
KR101838785B1 (ko) 2012-09-25 2018-03-14 미쓰이 가가쿠 가부시키가이샤 전이 금속 화합물, 올레핀 중합용 촉매 및 올레핀 중합체의 제조 방법
SG11201502288TA (en) 2012-09-25 2015-05-28 Mitsui Chemicals Inc Process for producing olefin polymer and olefin polymer
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US11028192B2 (en) 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
US6245870B1 (en) * 1992-03-20 2001-06-12 Fina Technology, Inc. Process for producing syndiotactic/isotactic block polyolefins
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4431643C2 (de) * 1994-07-22 2002-08-08 Borealis Polymere Holding Ag Verfahren zur Herstellung von Silizium-verbrückten unsymmetrischen Cyclopentadienyl-, Indenyl- und Fluorenyl-Ligandsystemen

Also Published As

Publication number Publication date
ATE391734T1 (de) 2008-04-15
EP1283223A3 (de) 2004-12-22
DE69839354T2 (de) 2009-05-28
EP1283223B1 (de) 2008-04-09
ES2202875T3 (es) 2004-04-01
PT984989E (pt) 2003-09-30
ES2302782T3 (es) 2008-08-01
US6559089B1 (en) 2003-05-06
EP0881236A1 (de) 1998-12-02
DK0984989T3 (da) 2003-10-06
DE69815846D1 (de) 2003-07-31
EP0984989B1 (de) 2003-06-25
EP1283223A2 (de) 2003-02-12
WO1998054230A1 (en) 1998-12-03
PT1283223E (pt) 2008-09-17
JP2001526730A (ja) 2001-12-18
ATE243717T1 (de) 2003-07-15
EP0984989A1 (de) 2000-03-15
JP4208097B2 (ja) 2009-01-14
DE69815846T2 (de) 2004-05-13

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