DE69811942D1 - Aromatische sulfone, ihre verwendung in substanzen, welche lichtinduziert säure freisetzen, photopolymerisierbare gemische diese enthaltend, stereolithographische harze und stereolithographischer prozess - Google Patents

Aromatische sulfone, ihre verwendung in substanzen, welche lichtinduziert säure freisetzen, photopolymerisierbare gemische diese enthaltend, stereolithographische harze und stereolithographischer prozess

Info

Publication number
DE69811942D1
DE69811942D1 DE69811942T DE69811942T DE69811942D1 DE 69811942 D1 DE69811942 D1 DE 69811942D1 DE 69811942 T DE69811942 T DE 69811942T DE 69811942 T DE69811942 T DE 69811942T DE 69811942 D1 DE69811942 D1 DE 69811942D1
Authority
DE
Germany
Prior art keywords
stereolithographic
substances
light
mixtures containing
resins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69811942T
Other languages
English (en)
Other versions
DE69811942T2 (de
Inventor
Kazuo Ohkawa
Hiroyuki Tachikawa
Satoyuki Chikaoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adeka Corp
Original Assignee
Asahi Denka Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Denka Kogyo KK filed Critical Asahi Denka Kogyo KK
Publication of DE69811942D1 publication Critical patent/DE69811942D1/de
Application granted granted Critical
Publication of DE69811942T2 publication Critical patent/DE69811942T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/0045Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/12Sulfonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0037Production of three-dimensional images
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/038Macromolecular compounds which are rendered insoluble or differentially wettable

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Epoxy Resins (AREA)
  • Materials For Photolithography (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
DE69811942T 1997-12-04 1998-12-04 Aromatische sulfone, ihre verwendung in substanzen, welche lichtinduziert säure freisetzen, photopolymerisierbare gemische diese enthaltend, stereolithographische harze und stereolithographischer prozess Expired - Fee Related DE69811942T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP33452997 1997-12-04
JP29189898A JP4204113B2 (ja) 1997-12-04 1998-10-14 新規な芳香族スルホニウム化合物、これからなる光酸発生剤およびこれを含む光重合性組成物、光造形用樹脂組成物ならびに光学的立体造形法
PCT/JP1998/005472 WO1999028295A1 (fr) 1997-12-04 1998-12-04 Composes sulfonium, generateurs photoacides les renfermant, compositions photopolymerisables les renfermant, compositions de resines stereolithographiques, et procede de stereolithographie

Publications (2)

Publication Number Publication Date
DE69811942D1 true DE69811942D1 (de) 2003-04-10
DE69811942T2 DE69811942T2 (de) 2003-09-04

Family

ID=26558750

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69811942T Expired - Fee Related DE69811942T2 (de) 1997-12-04 1998-12-04 Aromatische sulfone, ihre verwendung in substanzen, welche lichtinduziert säure freisetzen, photopolymerisierbare gemische diese enthaltend, stereolithographische harze und stereolithographischer prozess

Country Status (5)

Country Link
US (1) US6368769B1 (de)
EP (1) EP1036789B1 (de)
JP (1) JP4204113B2 (de)
DE (1) DE69811942T2 (de)
WO (1) WO1999028295A1 (de)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136497A (en) * 1998-03-30 2000-10-24 Vantico, Inc. Liquid, radiation-curable composition, especially for producing flexible cured articles by stereolithography
US6100007A (en) * 1998-04-06 2000-08-08 Ciba Specialty Chemicals Corp. Liquid radiation-curable composition especially for producing cured articles by stereolithography having high heat deflection temperatures
US6762002B2 (en) 1998-07-10 2004-07-13 Dsm Desotech, Inc. Solid imaging compositions for preparing polypropylene-like articles
US6287748B1 (en) 1998-07-10 2001-09-11 Dsm N.V. Solid imaging compositions for preparing polyethylene-like articles
US6379866B2 (en) 2000-03-31 2002-04-30 Dsm Desotech Inc Solid imaging compositions for preparing polypropylene-like articles
US6660446B2 (en) * 2000-05-30 2003-12-09 Fuji Photo Film Co., Ltd. Heat-sensitive composition and planographic printing plate
CA2443317C (en) * 2001-03-30 2013-06-18 The Arizona Board Of Regents On Behalf Of The University Of Arizona Materials, methods, and uses for photochemical generation of acids and/or radical species
TWI246525B (en) 2001-11-06 2006-01-01 Wako Pure Chem Ind Ltd Hybrid onium salt
JP2004091698A (ja) * 2002-09-02 2004-03-25 Konica Minolta Holdings Inc 活性光線硬化型組成物、活性光線硬化型インクとそれを用いた画像形成方法及びインクジェット記録装置
WO2004029037A1 (ja) 2002-09-25 2004-04-08 Asahi Denka Co.Ltd. 新規な芳香族スルホニウム塩化合物、これからなる光酸発生剤およびこれを含む光重合性組成物、光学的立体造形用樹脂組成物並びに光学的立体造形法
US20040077745A1 (en) * 2002-10-18 2004-04-22 Jigeng Xu Curable compositions and rapid prototyping process using the same
US20040137368A1 (en) * 2003-01-13 2004-07-15 3D Systems, Inc. Stereolithographic resins containing selected oxetane compounds
JP2005060518A (ja) * 2003-08-12 2005-03-10 Konica Minolta Medical & Graphic Inc 光重合性組成物およびインクジェットインク
JP4595311B2 (ja) * 2003-11-06 2010-12-08 コニカミノルタエムジー株式会社 活性光線硬化型インクジェットインク組成物、それを用いた画像形成方法及びインクジェット記録装置
US7282324B2 (en) 2004-01-05 2007-10-16 Microchem Corp. Photoresist compositions, hardened forms thereof, hardened patterns thereof and metal patterns formed using them
US20050260522A1 (en) * 2004-02-13 2005-11-24 William Weber Permanent resist composition, cured product thereof, and use thereof
JP4716749B2 (ja) * 2004-02-20 2011-07-06 株式会社Adeka 新規な芳香族スルホニウム塩化合物、これからなる光酸発生剤およびこれを含む光重合性組成物、光学的立体造形用樹脂組成物ならびに光学的立体造形法
WO2005093514A1 (ja) * 2004-03-26 2005-10-06 Tokyo Ohka Kogyo Co., Ltd. 感光性樹脂組成物および該組成物を用いたパターン形成方法
JP4492209B2 (ja) * 2004-05-14 2010-06-30 東亞合成株式会社 光学物品の製造方法
US7449280B2 (en) * 2004-05-26 2008-11-11 Microchem Corp. Photoimageable coating composition and composite article thereof
KR100698917B1 (ko) * 2004-06-22 2007-03-22 미쓰이 가가쿠 가부시키가이샤 이온성 화합물 및 그것을 함유하는 수지 조성물과 그 용도
US20060172230A1 (en) 2005-02-02 2006-08-03 Dsm Ip Assets B.V. Method and composition for reducing waste in photo-imaging applications
US7799885B2 (en) * 2005-11-30 2010-09-21 Corning Incorporated Photo or electron beam curable compositions
JP4695996B2 (ja) * 2006-02-27 2011-06-08 富士フイルム株式会社 感光性組成物及び該感光性組成物を用いたパターン形成方法
CN101466804B (zh) * 2006-04-13 2012-02-22 西巴控股有限公司 硫鎓盐引发剂
JP5168860B2 (ja) * 2006-09-14 2013-03-27 株式会社スリーボンド 光重合性組成物
US20080103226A1 (en) * 2006-10-31 2008-05-01 Dsm Ip Assets B.V. Photo-curable resin composition
EP2197840B1 (de) * 2007-10-10 2013-11-06 Basf Se Sulfoniumsalzinitiatoren
US20100297541A1 (en) * 2007-10-10 2010-11-25 Basf Se Sulphonium salt initiators
US8383862B2 (en) 2007-11-01 2013-02-26 Adeka Corporation Salt compound, cationic polymerization initiator and cationically polymerizable composition
US8293809B2 (en) 2008-03-11 2012-10-23 Kyoto University Cationic photopolymerization initiator
JP5721630B2 (ja) 2008-10-20 2015-05-20 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se スルホニウム誘導体および潜在酸としてのその使用
KR101700980B1 (ko) 2009-02-20 2017-01-31 산아프로 가부시키가이샤 술포늄염, 광산 발생제 및 감광성 수지 조성물
US8853290B2 (en) * 2009-06-08 2014-10-07 Sanyo Chemical Industries, Ltd. Photosensitive composition
TWI498350B (zh) 2009-10-01 2015-09-01 Hitachi Chemical Co Ltd 有機電子用材料、有機電子元件、有機電激發光元件、及使用其之顯示元件、照明裝置、顯示裝置
EP2495234B1 (de) * 2009-10-26 2018-06-06 Adeka Corporation Aromatische sulfoniumsalzverbindung
JP5717959B2 (ja) 2009-11-17 2015-05-13 株式会社Adeka 芳香族スルホニウム塩化合物
KR101833078B1 (ko) 2009-12-17 2018-02-27 디에스엠 아이피 어셋츠 비.브이. 적층식 제작을 위한 발광 다이오드 경화성 액체 수지 조성물
EP2526463B1 (de) 2010-01-22 2016-07-13 DSM IP Assets B.V. Verfahren zur herstellung eines dreidimensionalen artikels mit selektiven visuellen effekten
WO2011104127A1 (en) 2010-02-24 2011-09-01 Basf Se Latent acids and their use
KR20140108701A (ko) 2010-04-22 2014-09-12 히타치가세이가부시끼가이샤 유기 일렉트로닉스 재료, 중합 개시제 및 열중합 개시제, 잉크 조성물, 유기 박막 및 그 제조 방법, 유기 일렉트로닉스 소자, 유기 일렉트로 루미네센스 소자, 조명 장치, 표시 소자, 및 표시 장치
EP2502728B1 (de) 2011-03-23 2017-01-04 DSM IP Assets B.V. Leichte und hochfeste, mittels Additivherstellungsverfahren erzeugbare dreidimensionale Artikel
KR101263673B1 (ko) * 2011-08-03 2013-05-22 금호석유화학 주식회사 술포늄 화합물, 광산발생제 및 레지스트 조성물
JP5828715B2 (ja) * 2011-08-25 2015-12-09 サンアプロ株式会社 スルホニウム塩、光酸発生剤、硬化性組成物およびレジスト組成物
US9416220B2 (en) 2012-05-18 2016-08-16 Cmet Inc. Resin composition for optical stereolithography
CN103012227A (zh) * 2013-01-04 2013-04-03 同济大学 一种高光生酸量子产率硫鎓盐类光生酸剂、制备方法及其应用
CN105027677B (zh) 2013-03-08 2018-05-25 日立化成株式会社 含有离子性化合物的处理液、有机电子元件和有机电子元件的制造方法
KR20140131609A (ko) 2013-05-02 2014-11-14 삼성디스플레이 주식회사 감광성 수지 조성물, 패턴 형성 방법 및 이를 이용한 액정 표시 장치
JP6240409B2 (ja) * 2013-05-31 2017-11-29 サンアプロ株式会社 スルホニウム塩および光酸発生剤
EP2842980B1 (de) 2013-08-09 2021-05-05 DSM IP Assets B.V. Niedrigviskose flüssige strahlungshärtbare harzzusammensetzungen für zahnregulierungsform zur herstellung von zusatzstoffen
EP3971235A1 (de) 2013-11-05 2022-03-23 Covestro (Netherlands) B.V. Stabilisierte matrixgefüllte flüssige strahlungshärtbare harzzusammensetzungen zur generativen fertigung
JP6169545B2 (ja) * 2014-09-09 2017-07-26 富士フイルム株式会社 重合性組成物、インクジェット記録用インク組成物、インクジェット記録方法、及び記録物
US20180046076A1 (en) * 2015-03-23 2018-02-15 Dow Global Technologies Llc Photocurable Compositions for Three-Dimensional Printing
US10604659B2 (en) 2015-06-08 2020-03-31 Dsm Ip Assets B.V. Liquid, hybrid UV/VIS radiation curable resin compositions for additive fabrication
WO2016200972A1 (en) 2015-06-08 2016-12-15 Dsm Ip Assets B.V. Liquid, hybrid uv/vis radiation curable resin compositions for additive fabrication
EP3567428B1 (de) 2015-10-01 2021-06-23 DSM IP Assets B.V. Flüssige hybride uv/vis-strahlungshärtbare harzzusammensetzungen zur generativen fertigung
CN108472834B (zh) 2015-11-17 2021-05-25 帝斯曼知识产权资产管理有限公司 用于加成法制造的经改进的不含锑的可辐射固化组合物及其在熔模铸造工艺中的应用
JP2017115072A (ja) * 2015-12-25 2017-06-29 株式会社ダイセル 立体造形用硬化性組成物
EP3429833B1 (de) 2016-03-14 2022-04-13 Covestro (Netherlands) B.V. Strahlungshärtbare zusammensetzungen zur generativen fertigung mit verbesserter zähigkeit und hitzebeständigkeit
JP6807530B2 (ja) * 2016-11-10 2021-01-06 岡本化学工業株式会社 光学的立体造形用組成物
JP7223693B2 (ja) 2016-12-23 2023-02-16 スリーエム イノベイティブ プロパティズ カンパニー ポリマー及び重合性成分を含むプリント可能な組成物、物品、並びにそれから物品を製造する方法
CN109456242B (zh) * 2017-09-06 2021-02-12 常州强力电子新材料股份有限公司 硫鎓盐光引发剂、其制备方法、包含其的光固化组合物及其应用
JP7215654B2 (ja) 2017-12-15 2023-01-31 コベストロ (ネザーランズ) ビー.ブイ. 粘性熱硬化性樹脂を高温噴射して、積層造形を介して固体物品を作製するための組成物及び方法
WO2019133349A1 (en) 2017-12-29 2019-07-04 Dsm Ip Assets, B.V. Compositions and articles for additive fabrication and methods of using the same
JP2020015713A (ja) * 2018-07-11 2020-01-30 住友化学株式会社 塩、酸発生剤、レジスト組成物及びレジストパターンの製造方法
US11866526B2 (en) 2019-08-30 2024-01-09 Stratasys, Inc. Liquid, hybrid UV/vis radiation curable resin compositions for additive fabrication
JPWO2022018968A1 (de) * 2020-07-23 2022-01-27
US20240027901A1 (en) 2020-12-14 2024-01-25 San-Apro Ltd. Photoacid generator, and photosensitive composition using same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3625219B2 (ja) * 1993-06-18 2005-03-02 日本化薬株式会社 新規オニウム塩、光重合開始剤、これを含有するエネルギー線硬化性組成物及びその硬化物
CA2187046A1 (fr) 1996-10-03 1998-04-03 Alain Vallee Sulfonylimidures et sulfonylmethylures, leur utilisation comme photoinitiateur
JP3844824B2 (ja) * 1996-11-26 2006-11-15 株式会社Adeka エネルギー線硬化性エポキシ樹脂組成物、光学的立体造形用樹脂組成物及び光学的立体造形方法

Also Published As

Publication number Publication date
US6368769B1 (en) 2002-04-09
EP1036789A1 (de) 2000-09-20
EP1036789A4 (de) 2001-04-04
JP4204113B2 (ja) 2009-01-07
WO1999028295A1 (fr) 1999-06-10
JP2000186071A (ja) 2000-07-04
EP1036789B1 (de) 2003-03-05
DE69811942T2 (de) 2003-09-04

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