DE69811221D1 - Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen - Google Patents

Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen

Info

Publication number
DE69811221D1
DE69811221D1 DE69811221T DE69811221T DE69811221D1 DE 69811221 D1 DE69811221 D1 DE 69811221D1 DE 69811221 T DE69811221 T DE 69811221T DE 69811221 T DE69811221 T DE 69811221T DE 69811221 D1 DE69811221 D1 DE 69811221D1
Authority
DE
Germany
Prior art keywords
phosphol
cyclopentadienyl compounds
producing bridged
bridged
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69811221T
Other languages
English (en)
Other versions
DE69811221T2 (de
Inventor
Rupert Edward Von Haken Spence
Xiaoliang Gao
Linda Koch
Stephen John Brown
Daryll G Harrison
Qinyan Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Original Assignee
Nova Chemicals International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA filed Critical Nova Chemicals International SA
Publication of DE69811221D1 publication Critical patent/DE69811221D1/de
Application granted granted Critical
Publication of DE69811221T2 publication Critical patent/DE69811221T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69811221T 1997-05-08 1998-05-01 Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen Expired - Fee Related DE69811221T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002204803A CA2204803C (en) 1997-05-08 1997-05-08 Process to prepare bridged phosphole-cyclopentadienyl compounds
PCT/CA1998/000428 WO1998050392A1 (en) 1997-05-08 1998-05-01 Process to prepare bridged phosphole-cyclopentadienyl compounds

Publications (2)

Publication Number Publication Date
DE69811221D1 true DE69811221D1 (de) 2003-03-13
DE69811221T2 DE69811221T2 (de) 2003-10-30

Family

ID=4160606

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69811221T Expired - Fee Related DE69811221T2 (de) 1997-05-08 1998-05-01 Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen

Country Status (6)

Country Link
US (1) US6051667A (de)
EP (1) EP0983280B1 (de)
AU (1) AU7202498A (de)
CA (1) CA2204803C (de)
DE (1) DE69811221T2 (de)
WO (1) WO1998050392A1 (de)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
EP1098934A1 (de) 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastische mischung mit kristallpolymeren und kristallisierbaren polymeren des propens
FR2820137B1 (fr) * 2001-01-26 2005-12-23 Atofina Biphospholes pontes et metallocenes prepares a partir de ce ceux-ci
EP1390417B1 (de) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
US7220801B2 (en) 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
DE60304595T3 (de) 2002-10-02 2012-01-12 Dow Global Technologies Inc. Flüssige und gelartige niedermolekulare ethylenpolymere
DE60322410D1 (de) 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
EP1422249A1 (de) * 2002-11-20 2004-05-26 ATOFINA Research Neues Metallocenkatalysatorsystem
US7531601B2 (en) 2003-08-19 2009-05-12 Dow Global Technologies, Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
TW200604224A (en) 2004-03-17 2006-02-01 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene copolymer formation
BRPI0508161B1 (pt) 2004-03-17 2015-11-17 Dow Global Technologies Inc Composição, processo para preparar um homopolímero em multibloco de alto peso molecular e processo para preparar um copolímero em multibloco de alto peso molecular”
EP2357203B1 (de) 2004-03-17 2017-05-24 Dow Global Technologies LLC Katalysatorzusammensetzung mit Kettenübertragungsreagenz zur Bildung von Multiblock-Olefin-Copolymeren
US7553917B2 (en) 2004-06-16 2009-06-30 Dow Global Technologies, Inc. Technique for selecting polymerization modifiers cross reference statement
MX2007011340A (es) 2005-03-17 2007-10-03 Dow Global Technologies Inc Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples regio-irregular.
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
MX2007011337A (es) 2005-03-17 2007-10-02 Dow Global Technologies Inc Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples tactico/atactico.
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
EP1940897B1 (de) 2005-09-15 2014-05-07 Dow Global Technologies LLC Steuerung von polymerarchitektur und molekulargewichtsverteilung mit hilfe eines mehrzentrigen shuttling-mittels
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
EP2465876A1 (de) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Aktivierung von Trägern
US9012359B2 (en) 2011-01-20 2015-04-21 Ineos Sales (Uk) Limited Activating supports
ES2599176T3 (es) 2011-04-08 2017-01-31 Ineos Europe Ag Laminado que comprende una capa de poliolefina adherida a una capa de base
CN104105722B (zh) 2011-12-14 2016-11-09 英尼奥斯欧洲股份公司 聚合物
JP6832348B2 (ja) 2015-09-30 2021-02-24 ダウ グローバル テクノロジーズ エルエルシー 連鎖シャトリングに有用な多頭性または二頭性組成物、及びそれを調製するためのプロセス
WO2018064540A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Process for preparing multi- or dual-headed compositions useful for chain shuttling
WO2018064546A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Capped multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
TW201840572A (zh) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 適用於鏈梭移之多頭或雙頭組合物及其製備方法
CN110573533B (zh) 2017-03-09 2022-02-18 埃克森美孚化学专利公司 生产聚乙烯聚合物的方法
EP3596141B1 (de) 2017-03-15 2021-07-28 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
US20200247918A1 (en) 2017-03-15 2020-08-06 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
BR112019019076A2 (pt) 2017-03-15 2020-06-30 Dow Global Technologies Llc sistema catalisador de formação de copolímeros de múltiplos blocos
SG11201908306TA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
KR20190123340A (ko) 2017-03-15 2019-10-31 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
WO2019182988A1 (en) 2018-03-19 2019-09-26 Dow Global Technologies Llc Silicon-terminated organo-metal compounds and processes for preparing the same
JP2022516118A (ja) 2018-12-28 2022-02-24 ダウ グローバル テクノロジーズ エルエルシー 不飽和ポリオレフィンを含む硬化性組成物
EP3902852A1 (de) 2018-12-28 2021-11-03 Dow Global Technologies LLC Telechele polyolefine und verfahren zu ihrer herstellung
CN113498414A (zh) 2018-12-28 2021-10-12 陶氏环球技术有限责任公司 包括遥爪聚烯烃的可固化组合物
CN113498413A (zh) 2018-12-28 2021-10-12 陶氏环球技术有限责任公司 包括不饱和聚烯烃的可固化组合物
SG11202107067RA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Organometallic chain transfer agents

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
EP0617052B1 (de) * 1993-03-23 1998-06-03 Asahi Kasei Kogyo Kabushiki Kaisha Olefinpolymerisationkatalysator mit mehrzähnigem Ligand
EP0638593A1 (de) * 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzungen
US5563284A (en) * 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
KR960041204A (ko) * 1995-05-02 1996-12-19 고사이 아키오 올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법

Also Published As

Publication number Publication date
AU7202498A (en) 1998-11-27
EP0983280A1 (de) 2000-03-08
CA2204803A1 (en) 1998-11-08
CA2204803C (en) 2005-11-15
US6051667A (en) 2000-04-18
DE69811221T2 (de) 2003-10-30
WO1998050392A1 (en) 1998-11-12
EP0983280B1 (de) 2003-02-05

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