DE69811221D1 - Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen - Google Patents

Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen

Info

Publication number
DE69811221D1
DE69811221D1 DE69811221T DE69811221T DE69811221D1 DE 69811221 D1 DE69811221 D1 DE 69811221D1 DE 69811221 T DE69811221 T DE 69811221T DE 69811221 T DE69811221 T DE 69811221T DE 69811221 D1 DE69811221 D1 DE 69811221D1
Authority
DE
Germany
Prior art keywords
phosphol
cyclopentadienyl compounds
producing bridged
bridged
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69811221T
Other languages
English (en)
Other versions
DE69811221T2 (de
Inventor
Rupert Edward Von Haken Spence
Xiaoliang Gao
Linda Koch
Stephen John Brown
Daryll G Harrison
Qinyan Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals International SA
Original Assignee
Nova Chemicals International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals International SA filed Critical Nova Chemicals International SA
Publication of DE69811221D1 publication Critical patent/DE69811221D1/de
Application granted granted Critical
Publication of DE69811221T2 publication Critical patent/DE69811221T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69811221T 1997-05-08 1998-05-01 Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen Expired - Fee Related DE69811221T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002204803A CA2204803C (en) 1997-05-08 1997-05-08 Process to prepare bridged phosphole-cyclopentadienyl compounds
PCT/CA1998/000428 WO1998050392A1 (en) 1997-05-08 1998-05-01 Process to prepare bridged phosphole-cyclopentadienyl compounds

Publications (2)

Publication Number Publication Date
DE69811221D1 true DE69811221D1 (de) 2003-03-13
DE69811221T2 DE69811221T2 (de) 2003-10-30

Family

ID=4160606

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69811221T Expired - Fee Related DE69811221T2 (de) 1997-05-08 1998-05-01 Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen

Country Status (6)

Country Link
US (1) US6051667A (de)
EP (1) EP0983280B1 (de)
AU (1) AU7202498A (de)
CA (1) CA2204803C (de)
DE (1) DE69811221T2 (de)
WO (1) WO1998050392A1 (de)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
JP2002519497A (ja) 1998-07-01 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド
FR2820137B1 (fr) * 2001-01-26 2005-12-23 Atofina Biphospholes pontes et metallocenes prepares a partir de ce ceux-ci
EP1390417B1 (de) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Verfahren zur Polymerisation von Propylen und Ethylen in Lösung
EP1425345A1 (de) 2001-06-22 2004-06-09 Exxonmobil Chemical Patents Inc. Unter verwendung von metallocen hergestellte polyethylene sehr niedriger dichte oder lineare polyethylene niedriger dichte als schlagzähigkeitsmodifikatoren
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US7795365B2 (en) 2002-10-02 2010-09-14 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
DE60322410D1 (de) 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
EP1422249A1 (de) * 2002-11-20 2004-05-26 ATOFINA Research Neues Metallocenkatalysatorsystem
ATE455832T1 (de) 2003-08-19 2010-02-15 Dow Global Technologies Inc Interpolymere zur verwendung für schmelzklebstoffe und verfahren zu ihrer herstellung
RU2381240C2 (ru) 2004-03-17 2010-02-10 Дау Глобал Текнолоджиз Инк. Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена
AU2005224257B2 (en) 2004-03-17 2010-08-19 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
MXPA06010485A (es) 2004-03-17 2006-12-19 Dow Global Technologies Inc Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de etileno.
CN103102442B (zh) 2004-06-16 2016-01-20 陶氏环球技术有限责任公司 选择聚合改性剂的方法
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
EP1861438B1 (de) 2005-03-17 2015-03-04 Dow Global Technologies LLC Katalysatorzusammensetzung mit transportwirkstoff zur regio-irregulären multiblock-copolymer-formierung
ZA200708784B (en) 2005-03-17 2009-01-28 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for tactic/atactic multi-block copolymer formation
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
WO2007035493A2 (en) 2005-09-15 2007-03-29 Dow Global Technologies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
EP2465876A1 (de) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Aktivierung von Trägern
EP2665754A1 (de) 2011-01-20 2013-11-27 Ineos Commercial Services UK Limited Aktivierung von stützen
ES2599176T3 (es) 2011-04-08 2017-01-31 Ineos Europe Ag Laminado que comprende una capa de poliolefina adherida a una capa de base
EP2791189B1 (de) 2011-12-14 2018-05-02 Ineos Europe AG Neuartige polymere
KR102606500B1 (ko) 2015-09-30 2023-11-28 다우 글로벌 테크놀로지스 엘엘씨 사슬 왕복에 유용한 다중-헤드 또는 이중-헤드 조성물 및 이를 제조하는 방법
KR102490785B1 (ko) 2016-09-30 2023-01-20 다우 글로벌 테크놀로지스 엘엘씨 사슬 왕복에 유용한 캡핑된 다중- 또는 이중-헤드형 조성물 및 이의 제조 방법
EP3519455B1 (de) 2016-09-30 2024-04-10 Dow Global Technologies Llc Mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon
CN109963888A (zh) 2016-09-30 2019-07-02 陶氏环球技术有限责任公司 用于制备适用于链梭移的多头或双头组合物的方法
CA3055722C (en) 2017-03-09 2021-06-15 Exxonmobil Chemical Patents Inc. Process for producing polyethylene polymers
KR102631009B1 (ko) 2017-03-15 2024-01-30 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
EP3596141B1 (de) 2017-03-15 2021-07-28 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
CN110603271A (zh) 2017-03-15 2019-12-20 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
US11897992B2 (en) 2017-03-15 2024-02-13 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
BR112019019129A2 (pt) 2017-03-15 2020-04-14 Dow Global Technologies Llc sistema catalisador para formação de copolímero de múltiplos blocos
WO2019182988A1 (en) 2018-03-19 2019-09-26 Dow Global Technologies Llc Silicon-terminated organo-metal compounds and processes for preparing the same
WO2020140064A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Organometallic chain transfer agents
KR20210121027A (ko) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 불포화 폴리올레핀을 포함하는 경화성 조성물
KR20210121031A (ko) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 불포화 폴리올레핀을 포함하는 경화성 조성물
SG11202107051UA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Telechelic polyolefins and processes for preparing the same
JP2022516119A (ja) 2018-12-28 2022-02-24 ダウ グローバル テクノロジーズ エルエルシー テレケリックポリオレフィンを含む硬化性組成物

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
DE69415351D1 (de) * 1993-03-23 1999-01-28 Asahi Chemical Ind Olefinpolymerisationskatalysator mit mehrzähnigem Ligand
EP0638593A1 (de) * 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzungen
US5563284A (en) * 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
KR960041204A (ko) * 1995-05-02 1996-12-19 고사이 아키오 올레핀 중합 촉매 및 이를 사용하는 폴리올레핀의 제조방법

Also Published As

Publication number Publication date
CA2204803A1 (en) 1998-11-08
US6051667A (en) 2000-04-18
CA2204803C (en) 2005-11-15
WO1998050392A1 (en) 1998-11-12
EP0983280B1 (de) 2003-02-05
AU7202498A (en) 1998-11-27
DE69811221T2 (de) 2003-10-30
EP0983280A1 (de) 2000-03-08

Similar Documents

Publication Publication Date Title
DE69811221T2 (de) Verfahren zur herstellung von verbrükten phosphol-cyclopentadienyl verbindungen
DE69807859T2 (de) Verfahren zur herstellung von 4-bromomethyl diphenyl verbindungen
DE69805608D1 (de) Verfahren zur herstellung von epoxyverbindungen
DE59803946D1 (de) Verfahren zur herstellung von polyamiden
DE59807503D1 (de) Verfahren zur herstellung von erdalkalidiorganylverbindungen
DE69803652T2 (de) Verfahren zur herstellung von cyclopentadienylverbindungen
ATE274511T1 (de) Verfahren zur herstellung von eprosartan
DE69717484T2 (de) Verfahren zur herstellung von substituierten aromatischen verbindungen
DE69815082D1 (de) Verfahren zur herstellung aromatischer verbindungen
DE59900796D1 (de) Verfahren zur herstellung von polyamiden
DE69813596D1 (de) Verbindungen und verfahren zur herstellung substituierter 4-phenyl-4-cyanocyclohexansäuren
DE69819191D1 (de) Verfahren zur herstellung von pentafluorethan
DE59805920D1 (de) Verfahren zur herstellung von oxazaphosphorin-2-aminen
DE69805969D1 (de) Verfahren zur herstellung von epoxy-verbindungen
DE59802764D1 (de) Verfahren zur herstellung von phosphabenzolverbindungen
DE69733152D1 (de) Verfahren zur herstellung von tetrazolylbenzopyranen
DE69510227D1 (de) Verfahren zur herstellung von fluorierten heterozyklischen verbindungen
DE69806759T2 (de) Verfahren zur herstellung von pentafluorethan
DE59802548D1 (de) Verfahren zur herstellung von webware
DE59805432D1 (de) Verfahren zur herstellung von 2-cyclododecyl-1-propanol
ATE273291T1 (de) Verfahren zur herstellung von chlorbenzoxazolen
DE69813588D1 (de) Verfahren zur herstellung von 3-ispchromanon
DE69802546D1 (de) Verfahren zur herstellung von tuftingware
ATE236138T1 (de) Verfahren zur herstellung von n-alkylammonium- acetonitrlverbindungen
DE59804919D1 (de) Verfahren zur herstellung von caprolactam

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee