DE69722153T2 - Mehrkomponente-thermoplastische Elastomerzusammensetzung - Google Patents
Mehrkomponente-thermoplastische Elastomerzusammensetzung Download PDFInfo
- Publication number
- DE69722153T2 DE69722153T2 DE69722153T DE69722153T DE69722153T2 DE 69722153 T2 DE69722153 T2 DE 69722153T2 DE 69722153 T DE69722153 T DE 69722153T DE 69722153 T DE69722153 T DE 69722153T DE 69722153 T2 DE69722153 T2 DE 69722153T2
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- polar
- rubbers
- weight
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 125000000217 alkyl group Chemical group 0.000 description 3
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- 229910052717 sulfur Inorganic materials 0.000 description 3
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
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- 125000001931 aliphatic group Chemical group 0.000 description 2
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- 125000002619 bicyclic group Chemical group 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
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- 150000002148 esters Chemical class 0.000 description 2
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
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- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 description 1
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- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
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- 239000004698 Polyethylene Substances 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
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- 125000004429 atom Chemical group 0.000 description 1
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- TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 description 1
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
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- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
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- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000417 polynaphthalene Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
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- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L23/04—Homopolymers or copolymers of ethene
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- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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- C08L2312/04—Crosslinking with phenolic resin
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US768543 | 1985-08-23 | ||
| US08/768,543 US5910543A (en) | 1996-12-18 | 1996-12-18 | Thermoplastic elastomer with polar and non-polar rubber components |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69722153D1 DE69722153D1 (de) | 2003-06-26 |
| DE69722153T2 true DE69722153T2 (de) | 2004-02-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69722153T Expired - Lifetime DE69722153T2 (de) | 1996-12-18 | 1997-12-16 | Mehrkomponente-thermoplastische Elastomerzusammensetzung |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5910543A (enExample) |
| EP (1) | EP0849334B1 (enExample) |
| JP (1) | JP4615636B2 (enExample) |
| KR (1) | KR100486037B1 (enExample) |
| DE (1) | DE69722153T2 (enExample) |
| ES (1) | ES2194147T3 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6013727A (en) | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| US5777033A (en) * | 1996-07-26 | 1998-07-07 | Advanced Elastomer Systems, L.P. | Co-cured rubber-thermoplastic elastomer compositions |
| US5777029A (en) * | 1996-07-26 | 1998-07-07 | Advanced Elastomer Systems, L.P. | Co-cured rubber-thermoplastic elastomer compositions |
| US6020431A (en) * | 1996-07-26 | 2000-02-01 | Advanced Elastomer Systems, L.P. | Dynamic vulcanizates of engineering thermoplastic and acrylate rubber blends with dissimilar cure sites using a common curative |
| BR9713558A (pt) * | 1996-12-18 | 2000-03-14 | Exxon Chemical Patents Inc | Combinações de polìmeros compatibilizados formadas usando-se um agente multifuncional. |
| US6069202A (en) * | 1997-12-10 | 2000-05-30 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer triblend from an engineering thermoplastic, functionalized ethylene and or diene polymer, and brominated isobutylene p-methylstyrene copolymer |
| US6861139B2 (en) * | 1998-04-17 | 2005-03-01 | 3M Innovative Properties Company | Pressure sensitive adhesive composition and adhesive product using the same |
| DE19914161A1 (de) * | 1999-03-29 | 2000-10-05 | Degussa | Verbundgegenstand aus Polyestern und Elastomeren |
| DE10049804A1 (de) * | 2000-10-09 | 2002-04-18 | Bayer Ag | Wirkstoffkombinationen mit fungiziden und akariziden Eigenschaften |
| US7019058B2 (en) * | 2000-10-11 | 2006-03-28 | Exxonmobil Chemical Patents, Inc. | Halogenated elastomeric compositions having enhanced viscosity |
| US6552108B1 (en) | 2000-10-11 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Rubber blends having improved stability and green strength |
| BR0114445A (pt) * | 2000-10-11 | 2004-01-06 | Exxonmobil Chemical Patentes I | Composições termoplásticas de elastÈmeros halogenados |
| WO2002100940A1 (en) * | 2001-06-08 | 2002-12-19 | Thermoplastic Rubber Systems, Inc. | Thermoplastic vulcanizates |
| AU2002314821A1 (en) * | 2001-06-08 | 2002-12-23 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
| US20040245670A1 (en) * | 2003-06-03 | 2004-12-09 | Janssen Robert A. | Method of forming a low tack elastomeric article |
| US7585914B2 (en) * | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| US20090151846A1 (en) * | 2007-12-15 | 2009-06-18 | Junling Zhao | Tire with innerliner containing low melting polyamide |
| TWI400293B (zh) * | 2008-12-24 | 2013-07-01 | Ind Tech Res Inst | 熱塑性硫化體 |
| KR101696977B1 (ko) | 2014-10-08 | 2017-01-16 | 주식회사 엘지화학 | 절연 스위치 제어 장치 및 방법 |
| JP6456100B2 (ja) * | 2014-10-31 | 2019-01-23 | 住友ゴム工業株式会社 | ゴルフクラブ用グリップおよびゴルフクラブ |
| KR101916538B1 (ko) * | 2016-11-16 | 2019-01-07 | 현대자동차주식회사 | 내열성이 향상된 자동차 터보용 인테이크 호스용 수지 조성물 |
| WO2020068409A1 (en) | 2018-09-24 | 2020-04-02 | Exxonmobil Chemical Patents Inc. | Crosslinked elastomer-polymer blends |
| CN111748157B (zh) * | 2019-03-28 | 2022-05-06 | 合肥杰事杰新材料股份有限公司 | 一种高透明改性聚烯烃材料及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4311628A (en) * | 1977-11-09 | 1982-01-19 | Monsanto Company | Thermoplastic elastomeric blends of olefin rubber and polyolefin resin |
| US4338413A (en) * | 1980-10-16 | 1982-07-06 | Monsanto Company | Polymer blends |
| US4409365A (en) * | 1982-11-22 | 1983-10-11 | Monsanto Company | Thermoplastic rubber blends comprising crystalline polyolefin, vulcanized mono-olefin rubber and vulcanized nitrile rubber |
| JPS61291638A (ja) * | 1985-06-19 | 1986-12-22 | Tonen Sekiyukagaku Kk | 熱可塑性エラストマ−組成物 |
| US5177147A (en) * | 1986-03-03 | 1993-01-05 | Advanced Elastomer Systems, Lp | Elastomer-plastic blends |
| EP0262901B2 (en) * | 1986-09-30 | 1999-01-07 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition |
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US5013793A (en) * | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| US5073597A (en) * | 1989-05-26 | 1991-12-17 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
| US5143981A (en) * | 1989-12-08 | 1992-09-01 | Sumitomo Chemical Company, Limited | Resin composition |
| US5189103A (en) * | 1989-12-11 | 1993-02-23 | Sumitomo Chemical Company, Limited | Polyphenylene ether resin composition and process for producing the same |
| US5051477A (en) * | 1990-05-04 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| US5051478A (en) * | 1990-07-26 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Ethylene copolymer - modified dynamically vulcanized alloys |
| US5236929A (en) * | 1991-03-13 | 1993-08-17 | Kyowa Hakko Kogyo Co., Ltd. | Compound uca1064-b |
| IT1250738B (it) * | 1991-08-02 | 1995-04-21 | Donegani Guido Ist | Composizioni termoplastiche ad elevata tenacita' e resistenza all'urto |
| DE4210210A1 (de) * | 1992-03-28 | 1993-09-30 | Hoechst Ag | Kautschukmischungen |
| DE4331805A1 (de) * | 1993-09-18 | 1995-03-23 | Basf Ag | Matte, transparente Thermoplastharze |
| US5589544A (en) * | 1994-07-06 | 1996-12-31 | Advanced Elastomer Systems, L.P. | Soft thermoplastic elastomers having improved resistance to oil swell and compression set |
| US5726215A (en) * | 1994-11-08 | 1998-03-10 | Sumitomo Chemical Company, Limited | Styrene resin composition and shaped article thereof |
| JP3212470B2 (ja) * | 1995-02-16 | 2001-09-25 | 横浜ゴム株式会社 | タイヤ用ポリマー組成物 |
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1996
- 1996-12-18 US US08/768,543 patent/US5910543A/en not_active Expired - Lifetime
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1997
- 1997-12-09 JP JP35626197A patent/JP4615636B2/ja not_active Expired - Fee Related
- 1997-12-16 DE DE69722153T patent/DE69722153T2/de not_active Expired - Lifetime
- 1997-12-16 EP EP97122121A patent/EP0849334B1/en not_active Expired - Lifetime
- 1997-12-16 ES ES97122121T patent/ES2194147T3/es not_active Expired - Lifetime
- 1997-12-17 KR KR1019970070004A patent/KR100486037B1/ko not_active Expired - Fee Related
-
1999
- 1999-03-26 US US09/280,802 patent/US6140424A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5910543A (en) | 1999-06-08 |
| DE69722153D1 (de) | 2003-06-26 |
| JPH10176108A (ja) | 1998-06-30 |
| EP0849334B1 (en) | 2003-05-21 |
| JP4615636B2 (ja) | 2011-01-19 |
| EP0849334A1 (en) | 1998-06-24 |
| KR100486037B1 (ko) | 2005-09-02 |
| US6140424A (en) | 2000-10-31 |
| ES2194147T3 (es) | 2003-11-16 |
| KR19980064270A (ko) | 1998-10-07 |
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