DE69705218T2 - Verfahren zur herstellung von glinternden würfeleckigen retroflektierenden folien - Google Patents
Verfahren zur herstellung von glinternden würfeleckigen retroflektierenden folienInfo
- Publication number
- DE69705218T2 DE69705218T2 DE69705218T DE69705218T DE69705218T2 DE 69705218 T2 DE69705218 T2 DE 69705218T2 DE 69705218 T DE69705218 T DE 69705218T DE 69705218 T DE69705218 T DE 69705218T DE 69705218 T2 DE69705218 T2 DE 69705218T2
- Authority
- DE
- Germany
- Prior art keywords
- cube corner
- sheeting
- corner elements
- retroreflective
- cube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- WOWQDZZJHLLZGF-UHFFFAOYSA-N [(2,5-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,5-dimethoxyphenyl)methanone Chemical compound COC1=CC=C(OC)C(C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C=2C(=CC=C(OC)C=2)OC)=C1 WOWQDZZJHLLZGF-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
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- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
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- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
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- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
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- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
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- 238000009713 electroplating Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
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- 229910052739 hydrogen Inorganic materials 0.000 description 1
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- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 239000012948 isocyanate Chemical class 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
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- IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 description 1
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920005569 poly(vinylidene fluoride-co-hexafluoropropylene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
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- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920001291 polyvinyl halide Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 150000003254 radicals Chemical class 0.000 description 1
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- 239000007779 soft material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/32—Retroreflective
- A41D31/325—Retroreflective using layered materials
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Elements Other Than Lenses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/641,129 US5770124A (en) | 1996-04-30 | 1996-04-30 | Method of making glittering cube-corner retroreflective sheeting |
| PCT/US1997/006019 WO1997041466A1 (en) | 1996-04-30 | 1997-04-04 | Method of making glittering cube-corner retroreflective sheeting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69705218D1 DE69705218D1 (de) | 2001-07-19 |
| DE69705218T2 true DE69705218T2 (de) | 2002-02-28 |
Family
ID=24571055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69705218T Expired - Fee Related DE69705218T2 (de) | 1996-04-30 | 1997-04-04 | Verfahren zur herstellung von glinternden würfeleckigen retroflektierenden folien |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5770124A (enExample) |
| EP (1) | EP0896683B1 (enExample) |
| JP (1) | JP2000509168A (enExample) |
| KR (1) | KR100294100B1 (enExample) |
| CN (1) | CN1110712C (enExample) |
| AU (1) | AU706749B2 (enExample) |
| BR (1) | BR9708878A (enExample) |
| CA (1) | CA2252978C (enExample) |
| DE (1) | DE69705218T2 (enExample) |
| DK (1) | DK0896683T3 (enExample) |
| ES (1) | ES2157571T3 (enExample) |
| TW (1) | TW344804B (enExample) |
| WO (1) | WO1997041466A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10307808B4 (de) * | 2003-02-24 | 2009-04-09 | Fer Fahrzeugelektrik Gmbh | Verfahren zur Verminderung des Reflexwertes einer mikroprismatischen Reflexfolie |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USD444953S1 (en) | 1997-10-31 | 2001-07-17 | 3M Innovative Properties Company | Glittering cube-corner retroreflective sheeting |
| USD446946S1 (en) | 1997-10-31 | 2001-08-28 | 3M Innovative Properties Company | Glittering retroreflective sheeting |
| US6096247A (en) * | 1998-07-31 | 2000-08-01 | 3M Innovative Properties Company | Embossed optical polymer films |
| US6440334B2 (en) | 1999-06-11 | 2002-08-27 | 3M Innovative Properties Company | Method of making a retroreflective article |
| CA2384709A1 (en) * | 1999-10-04 | 2001-04-12 | 3M Innovative Properties Company | Improved continuous process for making glittering cube corner sheeting |
| CA2396163A1 (en) | 2000-01-21 | 2001-07-26 | 3M Innovative Properties Company | Retroreflective confetti |
| US7336422B2 (en) | 2000-02-22 | 2008-02-26 | 3M Innovative Properties Company | Sheeting with composite image that floats |
| ITVE20010026A1 (it) * | 2001-05-18 | 2002-11-18 | Giorgio Trani | Film flessibile strutturalmente modificabile, per realizzare oggetti dimensionalmente e strutturalmente stabili, in particolare contenitori |
| US20050042421A1 (en) * | 2002-03-04 | 2005-02-24 | Kurt Schwarzwalder | Multi-layer polymer component, apparatus and method |
| US20030165660A1 (en) * | 2002-03-04 | 2003-09-04 | Kurt Schwarzwalder | Polymer component, apparatus and method |
| MXPA05008114A (es) * | 2003-01-30 | 2005-12-12 | Tac Fast Systems Sa | Sistema y metodos para fabricar placas de ganchos. |
| US7152983B2 (en) | 2003-03-06 | 2006-12-26 | 3M Innovative Properties Company | Lamina comprising cube corner elements and retroreflective sheeting |
| BRPI0407946B1 (pt) * | 2003-03-06 | 2017-02-21 | 3M Innovative Properties Co | laminado retroreflexivo |
| JP2008525862A (ja) * | 2004-12-28 | 2008-07-17 | スリーエム イノベイティブ プロパティズ カンパニー | フッ素含有またはケイ素含有プリズムを有するプリズム再帰反射物品 |
| KR101425367B1 (ko) * | 2005-09-26 | 2014-08-13 | 애버리 데니슨 코포레이션 | 발산강화층을 포함하는 역반사 시트 |
| ATE550685T1 (de) * | 2005-11-18 | 2012-04-15 | Nanocomp Oy Ltd | Verfahren zum herstellen eines beugungsgitterelements |
| US7703698B2 (en) * | 2006-09-08 | 2010-04-27 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid treatment chamber and continuous flow mixing system |
| US7810743B2 (en) * | 2006-01-23 | 2010-10-12 | Kimberly-Clark Worldwide, Inc. | Ultrasonic liquid delivery device |
| US7611251B2 (en) * | 2006-04-18 | 2009-11-03 | 3M Innovative Properties Company | Retroreflective articles comprising olefinic seal films |
| US8215943B2 (en) * | 2006-06-01 | 2012-07-10 | Avery Dennison Corporation | Heat-transfer label assembly and apparatus for applying heat-transfer labels |
| BRPI0714441B1 (pt) * | 2006-07-17 | 2018-07-17 | Avery Dennison Corp | método para produção de um substrato para montagem em uma ferramenta de produção para fazer um conjunto de elementos ópticos aberrados, método para uma ferramenta, método para um conjunto, montagem de formação intermediária e revestimento retrorreflexivo |
| US9283188B2 (en) * | 2006-09-08 | 2016-03-15 | Kimberly-Clark Worldwide, Inc. | Delivery systems for delivering functional compounds to substrates and processes of using the same |
| US8034286B2 (en) | 2006-09-08 | 2011-10-11 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment system for separating compounds from aqueous effluent |
| PL2165224T3 (pl) | 2007-07-11 | 2024-03-18 | Thales Dis France Sas | Arkusz ze złożonym obrazem pływającym |
| US7998322B2 (en) | 2007-07-12 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber having electrode properties |
| US7947184B2 (en) | 2007-07-12 | 2011-05-24 | Kimberly-Clark Worldwide, Inc. | Treatment chamber for separating compounds from aqueous effluent |
| US7547105B2 (en) * | 2007-07-16 | 2009-06-16 | 3M Innovative Properties Company | Prismatic retroreflective article with cross-linked image layer and method of making same |
| EP2040244A1 (en) * | 2007-09-18 | 2009-03-25 | 3M Innovative Properties Company | Illumination device and actively illuminated article |
| CN101878438B (zh) * | 2007-11-27 | 2013-09-25 | 3M创新有限公司 | 形成具有悬浮合成图像的片材以及母模具的方法 |
| US8454889B2 (en) | 2007-12-21 | 2013-06-04 | Kimberly-Clark Worldwide, Inc. | Gas treatment system |
| US8858892B2 (en) | 2007-12-21 | 2014-10-14 | Kimberly-Clark Worldwide, Inc. | Liquid treatment system |
| US8632613B2 (en) | 2007-12-27 | 2014-01-21 | Kimberly-Clark Worldwide, Inc. | Process for applying one or more treatment agents to a textile web |
| US8206024B2 (en) | 2007-12-28 | 2012-06-26 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for particle dispersion into formulations |
| US8215822B2 (en) | 2007-12-28 | 2012-07-10 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for preparing antimicrobial formulations |
| US9421504B2 (en) * | 2007-12-28 | 2016-08-23 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for preparing emulsions |
| US20090166177A1 (en) | 2007-12-28 | 2009-07-02 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for preparing emulsions |
| US8057573B2 (en) | 2007-12-28 | 2011-11-15 | Kimberly-Clark Worldwide, Inc. | Ultrasonic treatment chamber for increasing the shelf life of formulations |
| EP2361396A4 (en) * | 2008-12-08 | 2018-01-24 | 3M Innovative Properties Company | Prismatic retroreflective article bearing a graphic and method of making same |
| KR20110098781A (ko) * | 2008-12-08 | 2011-09-01 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 그래픽을 갖는 보호 오버레이 및 오버레이를 포함하는 재귀반사성 물품 |
| US8685178B2 (en) * | 2008-12-15 | 2014-04-01 | Kimberly-Clark Worldwide, Inc. | Methods of preparing metal-modified silica nanoparticles |
| US8163388B2 (en) * | 2008-12-15 | 2012-04-24 | Kimberly-Clark Worldwide, Inc. | Compositions comprising metal-modified silica nanoparticles |
| US8727550B2 (en) * | 2009-03-12 | 2014-05-20 | Oryon Technologies, Llc | Hybrid electroluminescent assembly |
| US8288940B2 (en) * | 2009-03-12 | 2012-10-16 | 3M Innovative Properties Company | Laminate reflective and electroluminescent article |
| EP2405778B1 (en) | 2009-03-12 | 2013-07-17 | 3M Innovative Properties Company | Garment with a retroreflective and electroluminescent article |
| WO2011046957A2 (en) | 2009-10-16 | 2011-04-21 | 3M Innovative Properties Company | Prismatic retroreflective sheeting with reduced retroreflectivity of infra-red light |
| US8950877B2 (en) | 2009-11-12 | 2015-02-10 | 3M Innovative Properties Company | Security markings in retroreflective sheeting |
| DE102010047250A1 (de) | 2009-12-04 | 2011-06-09 | Giesecke & Devrient Gmbh | Sicherheitselement, Wertdokument mit einem solchen Sicherheitselement sowie Herstellungsverfahren eines Sicherheitselementes |
| CL2010000714A1 (es) * | 2010-07-02 | 2011-02-11 | Luis Harrison Eyquem Felipe | Procedimiento para aplicar material retrorreflectante sobre cuerpos elasticos que comprende aplicacion termica del material retrorreflectante, la cual se realiza mientras el cuerpo elastico es sometido a un estiramiento, alisamiento y fijacion del producto y luego un segundo estiramiento. |
| CN102182184B (zh) * | 2011-04-02 | 2012-08-15 | 汪明霞 | 一种桩型地锚 |
| EP2715414A4 (en) | 2011-05-31 | 2014-12-31 | 3M Innovative Properties Co | DICE LID COVER WITH OPTICAL VARIABLE LABEL |
| US9415539B2 (en) | 2011-05-31 | 2016-08-16 | 3M Innovative Properties Company | Method for making microstructured tools having discontinuous topographies, and articles produced therefrom |
| BR112013030706A2 (pt) | 2011-05-31 | 2016-12-06 | 3M Innovative Properties Co | métodos de fabricação de artigos microestruturados curados com padrão diferencialmente |
| TWI577523B (zh) * | 2011-06-17 | 2017-04-11 | 三菱麗陽股份有限公司 | 表面具有凹凸結構的模具、光學物品、其製造方法、面發光體用透明基材及面發光體 |
| BR112014014110A2 (pt) | 2011-12-15 | 2017-06-13 | 3M Innovative Properties Co | artigo de segurança personalizado e métodos de autenticação de um artigo de segurança e verificação de um portador de um artigo de segurança |
| CN104508172B (zh) * | 2012-11-13 | 2016-10-12 | 三菱重工业株式会社 | 真空蒸镀装置 |
| KR102205093B1 (ko) * | 2013-03-15 | 2021-01-20 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 미세타일화된 프리즘형 큐브 코너 물품 |
| KR101468683B1 (ko) * | 2013-03-20 | 2014-12-04 | 이병석 | 엘이디 스팽글 및 트랜스 제조 방법 |
| CN103192554A (zh) * | 2013-04-07 | 2013-07-10 | 福建省晋江市夜光达反光材料有限公司 | 一种微棱镜反光膜及其制造方法 |
| US20140352038A1 (en) * | 2013-05-31 | 2014-12-04 | Lenard Harris | Shell for a protective helmet |
| US9717297B2 (en) * | 2013-05-31 | 2017-08-01 | Lenard Harris | Shell for a protective helmet |
| KR101491804B1 (ko) * | 2013-06-19 | 2015-02-11 | 전상길 | 스파클 시트 및 이의 제조방법 |
| US9971074B2 (en) * | 2013-08-19 | 2018-05-15 | 3M Innovative Properties Company | Retroreflective sheeting including a substantially amorphous polymeric layer |
| KR102255973B1 (ko) * | 2013-08-19 | 2021-05-25 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 저탄성률 층을 포함하는 재귀반사성 시트류 |
| CN107219569B (zh) * | 2015-04-30 | 2020-04-03 | 夏普株式会社 | 光学膜的制造方法以及光学膜 |
| WO2017156448A1 (en) * | 2016-03-11 | 2017-09-14 | Mirraviz, Inc. | Customized reflection profiles for retro-reflective display system optimization |
| KR102105942B1 (ko) | 2017-02-14 | 2020-04-29 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 엔드 밀링에 의해 제조되는 미세구조체의 그룹을 포함하는 보안 물품 |
| CN110505814A (zh) | 2017-02-20 | 2019-11-26 | 3M创新有限公司 | 光学制品和与其进行交互的系统 |
| WO2019046403A1 (en) * | 2017-08-29 | 2019-03-07 | Avery Dennison Corporation | RETROREFLECTIVE SHEET FOR A PROJECTOR-BASED DISPLAY SYSTEM |
| EP3688662A1 (en) | 2017-09-27 | 2020-08-05 | 3M Innovative Properties Company | Personal protective equipment management system using optical patterns for equipment and safety monitoring |
Family Cites Families (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3010845A (en) * | 1957-05-15 | 1961-11-28 | Goodrich Co B F | Method and apparatus for decorating web or sheet material with glitter |
| US3450459A (en) * | 1965-10-24 | 1969-06-17 | Walter F Haggerty | Retroreflective device |
| US3924929A (en) * | 1966-11-14 | 1975-12-09 | Minnesota Mining & Mfg | Retro-reflective sheet material |
| US3541606A (en) * | 1967-10-16 | 1970-11-17 | Amerace Esna Corp | Reflectorized vehicles and reflectors therefor |
| US3469898A (en) * | 1967-11-20 | 1969-09-30 | Gerald Altman | Reflex reflective products and processes for their manufacture |
| US3632695A (en) * | 1970-03-05 | 1972-01-04 | Reflex Corp Canada Ltd | Making a combined lens and reflector |
| US3692731A (en) * | 1970-04-29 | 1972-09-19 | Mobil Oil Corp | Metallizing coating compositions containing coated metal flakes |
| US3697070A (en) * | 1970-06-19 | 1972-10-10 | Mobil Oil Corp | Metallizing coating compositions |
| US3810804A (en) * | 1970-09-29 | 1974-05-14 | Rowland Dev Corp | Method of making retroreflective material |
| US3689346A (en) * | 1970-09-29 | 1972-09-05 | Rowland Dev Corp | Method for producing retroreflective material |
| US3988494A (en) * | 1972-04-10 | 1976-10-26 | Mobil Oil Corporation | Metallizing coating compositions |
| US3935359A (en) * | 1972-06-23 | 1976-01-27 | Rowland Development Corporation | Retroreflective sheeting and method and apparatus for producing same |
| US3811983A (en) * | 1972-06-23 | 1974-05-21 | Rowland Dev Corp | Method for producing retroreflective sheeting |
| US3830682A (en) * | 1972-11-06 | 1974-08-20 | Rowland Dev Corp | Retroreflecting signs and the like with novel day-night coloration |
| US3873184A (en) * | 1973-02-16 | 1975-03-25 | Amerace Esna Corp | Reflector with interspersed angled reflex elements |
| US3923378A (en) * | 1973-04-24 | 1975-12-02 | Amerace Corp | Cube-corner reflector with non-aligned cube axes and element axes |
| US3926402A (en) * | 1973-04-24 | 1975-12-16 | Amerace Corp | Pin having nonaligned cube axis and pin axis and bundle of such pins |
| US3987229A (en) * | 1973-11-19 | 1976-10-19 | Reneer Films Corporation | Calendered film/plastisol film laminate structure |
| FR2288005A1 (fr) * | 1974-10-17 | 1976-05-14 | Greenwood William | Perfectionnements apportes aux procedes de decoration de produits et produits obtenus a l'aide de ces perfectionnements |
| USRE29396E (en) * | 1975-02-18 | 1977-09-13 | Amerace Corporation | Pin having nonaligned cube axis and pin axis and bundle of such pins |
| US3992080A (en) * | 1975-06-13 | 1976-11-16 | Reflexite Corporation | Retroreflective sheet material with controlled stretch and method of making same |
| US4025159A (en) * | 1976-02-17 | 1977-05-24 | Minnesota Mining And Manufacturing Company | Cellular retroreflective sheeting |
| US4066331A (en) * | 1976-06-25 | 1978-01-03 | Beatrice Foods Co. | Cube corner type retroreflectors with improved cube corner unit relationships |
| US4349598A (en) * | 1976-12-01 | 1982-09-14 | Minnesota Mining And Manufacturing Company | High incidence angle retroreflective material |
| US4202600A (en) * | 1978-04-24 | 1980-05-13 | Avery International Corporation | Diced retroreflective sheeting |
| US4668558A (en) * | 1978-07-20 | 1987-05-26 | Minnesota Mining And Manufacturing Company | Shaped plastic articles having replicated microstructure surfaces |
| US4243618A (en) * | 1978-10-23 | 1981-01-06 | Avery International Corporation | Method for forming retroreflective sheeting |
| EP0018798B1 (en) * | 1978-11-08 | 1983-06-08 | LUCAS INDUSTRIES public limited company | Reflex reflector device |
| US4332847A (en) * | 1979-09-20 | 1982-06-01 | Relfexite Corporation | Method for compression molding of retroreflective sheeting and sheeting produced thereby |
| US4601861A (en) * | 1982-09-30 | 1986-07-22 | Amerace Corporation | Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate |
| US4486363A (en) * | 1982-09-30 | 1984-12-04 | Amerace Corporation | Method and apparatus for embossing a precision optical pattern in a resinous sheet |
| US4588258A (en) * | 1983-09-12 | 1986-05-13 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles having wide angularity in multiple viewing planes |
| US4712868A (en) * | 1985-09-23 | 1987-12-15 | Minnesota Mining And Manufacturing Company | Expanded retroreflective sheet material |
| US4938563A (en) * | 1986-11-21 | 1990-07-03 | Minnesota Mining And Manufacturing Company | High efficiency cube corner retroflective material |
| US4775219A (en) * | 1986-11-21 | 1988-10-04 | Minnesota Mining & Manufacturing Company | Cube-corner retroreflective articles having tailored divergence profiles |
| US4801193A (en) * | 1988-03-04 | 1989-01-31 | Reflexite Corporation | Retroreflective sheet material and method of making same |
| US4895428A (en) * | 1988-07-26 | 1990-01-23 | Minnesota Mining And Manufacturing Company | High efficiency retroreflective material |
| JPH03124754A (ja) * | 1989-10-09 | 1991-05-28 | Mitsubishi Rayon Co Ltd | 耐衝撃性フイルム |
| US5202180A (en) * | 1990-02-06 | 1993-04-13 | Avery Dennison Corporation | Decorative web |
| US5138488A (en) * | 1990-09-10 | 1992-08-11 | Minnesota Mining And Manufacturing Company | Retroreflective material with improved angularity |
| ZA918849B (en) * | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
| US5084782A (en) * | 1990-12-20 | 1992-01-28 | Eastman Kodak Company | Decorative tape |
| US5152917B1 (en) * | 1991-02-06 | 1998-01-13 | Minnesota Mining & Mfg | Structured abrasive article |
| US5213872A (en) * | 1991-04-19 | 1993-05-25 | Stimsonite Corporation | Preprinted retroreflective highway sign and method for making the sign |
| US5276075A (en) * | 1991-10-30 | 1994-01-04 | Binney & Smith Inc. | Washable acrylic paint |
| JPH05209142A (ja) * | 1992-01-30 | 1993-08-20 | Mazda Motor Corp | 塗装用光輝材 |
| US5272562A (en) * | 1993-02-05 | 1993-12-21 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles |
| US5362374A (en) * | 1993-08-27 | 1994-11-08 | Chang Jung Ming | Method for making decorative stickers |
| CN1041962C (zh) * | 1993-10-20 | 1999-02-03 | 美国3M公司 | 超柔软的反光立方角复合片及其制造方法 |
| EP0724739B1 (en) * | 1993-10-20 | 1999-09-08 | Minnesota Mining And Manufacturing Company | Raised zone retroreflective cube corner article and method of manufacture |
| US5450235A (en) * | 1993-10-20 | 1995-09-12 | Minnesota Mining And Manufacturing Company | Flexible cube-corner retroreflective sheeting |
| US5454844A (en) * | 1993-10-29 | 1995-10-03 | Minnesota Mining And Manufacturing Company | Abrasive article, a process of making same, and a method of using same to finish a workpiece surface |
| USD366365S (en) | 1994-05-11 | 1996-01-23 | Minnesota Mining And Manufacturing Company | Coated abrasive sheet article |
| US5512219A (en) * | 1994-06-03 | 1996-04-30 | Reflexite Corporation | Method of casting a microstructure sheet having an array of prism elements using a reusable polycarbonate mold |
| JP3990446B2 (ja) * | 1994-09-28 | 2007-10-10 | リフレキサイト・コーポレーション | 再帰反射性傾斜プリズム構造体 |
| US5470058A (en) * | 1994-09-30 | 1995-11-28 | Lisco, Inc. | High visibility inflated game ball |
| US5485311A (en) * | 1995-01-06 | 1996-01-16 | Mcallister; Richard | Method of increasing retroreflective brightness in a retroreflective sheet material |
| US6143224A (en) * | 1995-05-18 | 2000-11-07 | Reflexite Corporation | Method for forming a retroreflective sheeting |
| US5592330A (en) * | 1995-05-19 | 1997-01-07 | Reflexite Corporation | Retroreflective prism arrays with formed air spheres therein |
-
1996
- 1996-04-30 US US08/641,129 patent/US5770124A/en not_active Expired - Fee Related
-
1997
- 1997-04-04 JP JP9538913A patent/JP2000509168A/ja not_active Withdrawn
- 1997-04-04 CN CN97194248A patent/CN1110712C/zh not_active Expired - Fee Related
- 1997-04-04 AU AU24551/97A patent/AU706749B2/en not_active Ceased
- 1997-04-04 DK DK97920330T patent/DK0896683T3/da active
- 1997-04-04 KR KR1019980708648A patent/KR100294100B1/ko not_active Expired - Fee Related
- 1997-04-04 EP EP97920330A patent/EP0896683B1/en not_active Expired - Lifetime
- 1997-04-04 ES ES97920330T patent/ES2157571T3/es not_active Expired - Lifetime
- 1997-04-04 WO PCT/US1997/006019 patent/WO1997041466A1/en not_active Ceased
- 1997-04-04 DE DE69705218T patent/DE69705218T2/de not_active Expired - Fee Related
- 1997-04-04 CA CA002252978A patent/CA2252978C/en not_active Expired - Fee Related
- 1997-04-04 BR BR9708878A patent/BR9708878A/pt not_active Application Discontinuation
- 1997-04-17 TW TW086104988A patent/TW344804B/zh active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10307808B4 (de) * | 2003-02-24 | 2009-04-09 | Fer Fahrzeugelektrik Gmbh | Verfahren zur Verminderung des Reflexwertes einer mikroprismatischen Reflexfolie |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2157571T3 (es) | 2001-08-16 |
| BR9708878A (pt) | 1999-08-03 |
| AU2455197A (en) | 1997-11-19 |
| TW344804B (en) | 1998-11-11 |
| WO1997041466A1 (en) | 1997-11-06 |
| CA2252978C (en) | 2006-01-24 |
| DK0896683T3 (da) | 2001-09-03 |
| HK1019932A1 (en) | 2000-03-03 |
| KR100294100B1 (ko) | 2001-09-07 |
| JP2000509168A (ja) | 2000-07-18 |
| EP0896683A1 (en) | 1999-02-17 |
| EP0896683B1 (en) | 2001-06-13 |
| CN1110712C (zh) | 2003-06-04 |
| CN1217067A (zh) | 1999-05-19 |
| AU706749B2 (en) | 1999-06-24 |
| DE69705218D1 (de) | 2001-07-19 |
| CA2252978A1 (en) | 1997-11-06 |
| US5770124A (en) | 1998-06-23 |
| KR20000058223A (ko) | 2000-10-05 |
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