DE69637377T2 - Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen - Google Patents
Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen Download PDFInfo
- Publication number
- DE69637377T2 DE69637377T2 DE69637377T DE69637377T DE69637377T2 DE 69637377 T2 DE69637377 T2 DE 69637377T2 DE 69637377 T DE69637377 T DE 69637377T DE 69637377 T DE69637377 T DE 69637377T DE 69637377 T2 DE69637377 T2 DE 69637377T2
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen peroxide
- complex
- container
- peroxide
- vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 593
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 135
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 131
- 238000000034 method Methods 0.000 claims abstract description 120
- 238000010438 heat treatment Methods 0.000 claims abstract description 38
- 230000008569 process Effects 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 60
- 239000000843 powder Substances 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 32
- 230000000694 effects Effects 0.000 claims description 29
- 239000007789 gas Substances 0.000 claims description 19
- 229910021432 inorganic complex Inorganic materials 0.000 claims description 14
- 230000004888 barrier function Effects 0.000 claims description 9
- 150000002484 inorganic compounds Chemical class 0.000 claims description 9
- 238000004891 communication Methods 0.000 claims description 8
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 8
- 229910010272 inorganic material Inorganic materials 0.000 claims description 8
- 150000004760 silicates Chemical class 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 7
- 150000005323 carbonate salts Chemical class 0.000 claims description 6
- 150000003891 oxalate salts Chemical class 0.000 claims description 6
- 230000007246 mechanism Effects 0.000 claims description 5
- 239000004155 Chlorine dioxide Substances 0.000 claims description 4
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 3
- 239000003206 sterilizing agent Substances 0.000 claims description 3
- 238000013022 venting Methods 0.000 claims description 2
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims 4
- 150000002978 peroxides Chemical class 0.000 abstract description 178
- 229910000402 monopotassium phosphate Inorganic materials 0.000 abstract description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract description 2
- 239000007836 KH2PO4 Substances 0.000 abstract 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 161
- 238000012360 testing method Methods 0.000 description 71
- 239000000243 solution Substances 0.000 description 54
- 239000000203 mixture Substances 0.000 description 53
- 229910052739 hydrogen Inorganic materials 0.000 description 51
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 47
- 229910052782 aluminium Inorganic materials 0.000 description 46
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 46
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 45
- 229940048086 sodium pyrophosphate Drugs 0.000 description 44
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 44
- 210000002381 plasma Anatomy 0.000 description 40
- 230000015572 biosynthetic process Effects 0.000 description 39
- 239000007787 solid Substances 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 35
- 238000003786 synthesis reaction Methods 0.000 description 34
- 239000007858 starting material Substances 0.000 description 27
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 27
- 229920002799 BoPET Polymers 0.000 description 25
- 239000005041 Mylar™ Substances 0.000 description 25
- 239000007921 spray Substances 0.000 description 22
- 239000000126 substance Substances 0.000 description 20
- 229910019142 PO4 Inorganic materials 0.000 description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 19
- 239000010452 phosphate Substances 0.000 description 19
- 235000021317 phosphate Nutrition 0.000 description 19
- 239000000523 sample Substances 0.000 description 19
- 229910001220 stainless steel Inorganic materials 0.000 description 19
- 239000010935 stainless steel Substances 0.000 description 19
- 239000012298 atmosphere Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 18
- 239000004775 Tyvek Substances 0.000 description 17
- 229920000690 Tyvek Polymers 0.000 description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 16
- 239000000376 reactant Substances 0.000 description 16
- 210000004215 spore Anatomy 0.000 description 16
- -1 alkali metal oxalates Chemical class 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 238000005507 spraying Methods 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 230000036512 infertility Effects 0.000 description 14
- 238000001291 vacuum drying Methods 0.000 description 14
- 239000012808 vapor phase Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000011575 calcium Substances 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 12
- YMAWOPBAYDPSLA-UHFFFAOYSA-N glycine anhydride Natural products [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 12
- 239000011777 magnesium Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 11
- 235000014469 Bacillus subtilis Nutrition 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 235000013877 carbamide Nutrition 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 10
- 239000004202 carbamide Substances 0.000 description 9
- 235000011180 diphosphates Nutrition 0.000 description 9
- 238000004806 packaging method and process Methods 0.000 description 9
- 230000035484 reaction time Effects 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 230000009471 action Effects 0.000 description 8
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000000643 oven drying Methods 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
- 239000004809 Teflon Substances 0.000 description 6
- 229920006362 Teflon® Polymers 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 239000005297 pyrex Substances 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 6
- 229940057054 1,3-dimethylurea Drugs 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- VZWGHDYJGOMEKT-UHFFFAOYSA-J sodium pyrophosphate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O VZWGHDYJGOMEKT-UHFFFAOYSA-J 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000001308 synthesis method Methods 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- NTYJJOPFIAHURM-UHFFFAOYSA-N Histamine Chemical compound NCCC1=CN=CN1 NTYJJOPFIAHURM-UHFFFAOYSA-N 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- MFLMBWASGCAJGO-UHFFFAOYSA-L disodium;hydrogen peroxide;carbonate Chemical compound [Na+].[Na+].OO.[O-]C([O-])=O MFLMBWASGCAJGO-UHFFFAOYSA-L 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 229920006380 polyphenylene oxide Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GBFPIFMOELLUDL-UHFFFAOYSA-L OO.C(C(=O)[O-])(=O)[O-].[K+].[K+] Chemical compound OO.C(C(=O)[O-])(=O)[O-].[K+].[K+] GBFPIFMOELLUDL-UHFFFAOYSA-L 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- GEMCGUOJDLYZJY-UHFFFAOYSA-N carbonic acid;hydrogen peroxide;sodium Chemical compound [Na].OO.OC(O)=O GEMCGUOJDLYZJY-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 3
- 229910000160 potassium phosphate Inorganic materials 0.000 description 3
- 235000011009 potassium phosphates Nutrition 0.000 description 3
- 230000003330 sporicidal effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000010189 synthetic method Methods 0.000 description 3
- 239000001974 tryptic soy broth Substances 0.000 description 3
- 108010050327 trypticase-soy broth Proteins 0.000 description 3
- LKDXXGJHEOAEHV-UHFFFAOYSA-N 1,3-dimethylurea;hydrogen peroxide Chemical compound OO.CNC(=O)NC LKDXXGJHEOAEHV-UHFFFAOYSA-N 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229910017855 NH 4 F Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 229960001340 histamine Drugs 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002054 inoculum Substances 0.000 description 2
- 238000012806 monitoring device Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000006069 physical mixture Substances 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- HHLKGLWTIGUAPJ-UHFFFAOYSA-N (2-aminoacetyl) 2-aminoacetate;hydrogen peroxide Chemical compound OO.NCC(=O)OC(=O)CN HHLKGLWTIGUAPJ-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910020335 Na3 PO4.12H2 O Inorganic materials 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- UISHMWJBGGDOII-UHFFFAOYSA-L S(=S)(=O)([O-])[O-].[Na+].[I+] Chemical compound S(=S)(=O)([O-])[O-].[Na+].[I+] UISHMWJBGGDOII-UHFFFAOYSA-L 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- 239000012472 biological sample Substances 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940043256 calcium pyrophosphate Drugs 0.000 description 1
- 229940078916 carbamide peroxide Drugs 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000000882 contact lens solution Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229940061607 dibasic sodium phosphate Drugs 0.000 description 1
- 235000019821 dicalcium diphosphate Nutrition 0.000 description 1
- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical compound [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- IKHMGDCRLIVYEL-UHFFFAOYSA-N dodecasodium;trisilicate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IKHMGDCRLIVYEL-UHFFFAOYSA-N 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- KNLIMQSABQICQW-UHFFFAOYSA-N hydrogen peroxide;propanamide Chemical class OO.CCC(N)=O KNLIMQSABQICQW-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009103 reabsorption Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- WPFGFHJALYCVMO-UHFFFAOYSA-L rubidium carbonate Chemical class [Rb+].[Rb+].[O-]C([O-])=O WPFGFHJALYCVMO-UHFFFAOYSA-L 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000012414 sterilization procedure Methods 0.000 description 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/14—Plasma, i.e. ionised gases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
- A61L2/208—Hydrogen peroxide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/26—Accessories or devices or components used for biocidal treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/03—Preparation from inorganic peroxy compounds, e.g. from peroxysulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
- C01B15/08—Peroxysulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/10—Peroxyhydrates; Peroxyacids or salts thereof containing carbon
- C01B15/103—Peroxyhydrates; Peroxyacids or salts thereof containing carbon containing only alkali metals as metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/14—Peroxyhydrates; Peroxyacids or salts thereof containing silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/16—Peroxyhydrates; Peroxyacids or salts thereof containing phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/12—Apparatus for isolating biocidal substances from the environment
- A61L2202/122—Chambers for sterilisation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/24—Medical instruments, e.g. endoscopes, catheters, sharps
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/549,425 US5667753A (en) | 1994-04-28 | 1995-10-27 | Vapor sterilization using inorganic hydrogen peroxide complexes |
US549425 | 1995-10-27 | ||
US08/716,094 US5785934A (en) | 1995-01-06 | 1996-09-19 | Vapor sterilization using inorganic hydrogen peroxide complexes |
US716094 | 1996-09-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69637377D1 DE69637377D1 (de) | 2008-01-31 |
DE69637377T2 true DE69637377T2 (de) | 2008-12-04 |
Family
ID=27069128
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69637377T Expired - Fee Related DE69637377T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen |
DE69635826T Expired - Fee Related DE69635826T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter verwendung von anorganischen wasserstoffperoxidkomplexen |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69635826T Expired - Fee Related DE69635826T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter verwendung von anorganischen wasserstoffperoxidkomplexen |
Country Status (15)
Country | Link |
---|---|
US (1) | US5785934A (fr) |
EP (2) | EP0862466B1 (fr) |
JP (1) | JP2002515770A (fr) |
KR (2) | KR100483219B1 (fr) |
AT (2) | ATE381354T1 (fr) |
AU (1) | AU704089B2 (fr) |
BR (1) | BR9611152A (fr) |
CA (1) | CA2235941C (fr) |
DE (2) | DE69637377T2 (fr) |
ES (2) | ES2257754T3 (fr) |
IN (1) | IN182209B (fr) |
MX (1) | MX209103B (fr) |
NO (1) | NO981827D0 (fr) |
TW (2) | TW343922B (fr) |
WO (1) | WO1997015333A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015114555B4 (de) * | 2015-08-13 | 2021-03-18 | Uniwersytet Wrocławski | Verfahren zur Entfeuchtung von saugfähigen Objekten mit gleichzeitiger antimikrobiellen Wirkung sowie ein entsprechendes Gerät zur Umsetzung dieses Verfahrens |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6495100B1 (en) * | 1996-04-04 | 2002-12-17 | Ethicon, Inc. | Method for sterilizing devices in a container |
US5820841A (en) * | 1996-09-19 | 1998-10-13 | Ethicon, Inc. | Hydrogen peroxide complexes of inorganic salts and synthesis thereof |
US7045343B2 (en) * | 1998-06-02 | 2006-05-16 | 3M Innovative Properties Company | Sterilization indicator test packs |
US6355448B1 (en) | 1998-06-02 | 2002-03-12 | 3M Innovative Properties Company | Sterilization indicator with chemically stabilized enzyme |
CA2349318C (fr) | 1998-11-23 | 2010-08-24 | Ecolab Inc. | Composition de sterilisation non-corrosive |
GB2354443A (en) | 1999-09-21 | 2001-03-28 | Microflow Ltd | Vapour phase sterilisation |
GB2360454A (en) * | 2000-03-21 | 2001-09-26 | Microflow Ltd | Control of gaseous sterilisation |
GB2364914B (en) * | 2000-07-26 | 2002-07-24 | Jacques Protic | A sterilisation process and apparatus therefor |
US20020098111A1 (en) * | 2000-12-04 | 2002-07-25 | Nguyen Nick N. | Vaporizer |
GB0202064D0 (en) * | 2002-01-30 | 2002-03-13 | Reckitt Benckiser Uk Ltd | Device |
US20030147773A1 (en) * | 2002-02-01 | 2003-08-07 | Bryner Roger S. | Apparatus and method for paper and dry goods bio-decontamination |
US7300637B2 (en) * | 2002-09-30 | 2007-11-27 | Ethicon, Inc. | Sterilization container kit |
US7369959B2 (en) * | 2002-11-26 | 2008-05-06 | Intercat Equipment, Inc. | Fluid catalytic cracking catalyst injection system and method for communicating with same |
US7050944B2 (en) * | 2002-11-26 | 2006-05-23 | Intercat Equipment, Inc. | FCC catalyst injection system having local data access |
US8099259B2 (en) * | 2002-11-26 | 2012-01-17 | Intercat Equipment, Inc. | Method for monitoring catalyst requirements of a refinery |
US7606678B2 (en) | 2002-11-26 | 2009-10-20 | Intercat Equipment, Inc. | Method for monitoring a FCC catalyst injection system |
JP2006511677A (ja) * | 2002-12-20 | 2006-04-06 | デグサ アクチエンゲゼルシャフト | 液体洗剤及び洗滌剤組成物 |
EP1572852B1 (fr) * | 2002-12-20 | 2006-10-11 | Degussa AG | Composes peroxygenes enrobes, a liberation lente, leur procede de preparation et d'utilisation |
DE10320196A1 (de) * | 2002-12-20 | 2004-07-08 | Henkel Kg Auf Aktien | Bleichmittelhaltige Wasch- oder Reinigungsmittel |
PT1475350E (pt) * | 2003-05-07 | 2005-09-30 | Degussa | Granulado de percarbonato de sodio revestido com estabilidade no armazenamento melhorada |
US20090252815A1 (en) * | 2003-05-23 | 2009-10-08 | Evonik Degussa Gmbh | Pulverulent mixtures containing hydrogen peroxide and hydrophobized silicon dioxide |
WO2004103508A2 (fr) * | 2003-05-23 | 2004-12-02 | Degussa Ag | Utilisation de melanges pulverulents contenant du peroxyde d'hydrogene et du dioxyde de silicium rendu hydrophobe pour la liberation controlee de peroxyde d'hydrogene ou d'oxygene |
US7556660B2 (en) * | 2003-06-11 | 2009-07-07 | James Kevin Shurtleff | Apparatus and system for promoting a substantially complete reaction of an anhydrous hydride reactant |
US20050042130A1 (en) * | 2003-08-22 | 2005-02-24 | Szu-Min Lin | Mist sterilization system |
US8017074B2 (en) * | 2004-01-07 | 2011-09-13 | Noxilizer, Inc. | Sterilization system and device |
JP2007521118A (ja) * | 2004-01-07 | 2007-08-02 | ノクシライザー,インコーポレイテッド | 殺菌システムおよび装置 |
US7329385B1 (en) | 2004-07-08 | 2008-02-12 | Radicone Michael C | Device and method for air stream, fluid and vessel decontamination |
DE102004054495A1 (de) | 2004-11-11 | 2006-05-24 | Degussa Ag | Natriumpercarbonatpartikel mit einer Thiosulfat enthaltenden Hüllschicht |
KR100588936B1 (ko) | 2005-03-29 | 2006-06-09 | 주식회사 대우일렉트로닉스 | 내부 청소가 용이한 증기소독실 구조 |
US8137658B2 (en) | 2005-06-28 | 2012-03-20 | Isp Investments Inc. | Tooth whitening compositions |
WO2007014436A1 (fr) | 2005-08-04 | 2007-02-08 | Saban Ventures Pty Limited | Stérilisation de membrane |
US8673297B2 (en) | 2006-02-28 | 2014-03-18 | Basf Corporation | Chlorine dioxide based cleaner/sanitizer |
US8357214B2 (en) | 2007-04-26 | 2013-01-22 | Trulite, Inc. | Apparatus, system, and method for generating a gas from solid reactant pouches |
DE102007025452A1 (de) | 2007-05-31 | 2008-12-04 | Ernst-Moritz-Arndt-Universität Greifswald | Verfahren zur Beschichtung von Oberflächen mit Mikro- und Nanopartikeln mit Hilfe von Plasmaverfahren |
AU2008279082A1 (en) | 2007-07-25 | 2009-01-29 | Trulite, Inc. | Apparatus, system, and method to manage the generation and use of hybrid electric power |
EP2175894B1 (fr) | 2007-08-07 | 2013-04-10 | Lee Antimicrobial Solutions LLC | Procede et dispositif de traitement de l'air par ultraviolets |
AU2010215774B2 (en) | 2009-02-23 | 2015-05-21 | Noxilizer, Inc. | Device and method for gas sterilization |
US20100265816A1 (en) * | 2009-04-17 | 2010-10-21 | American Superconductor Corporation | Monitoring switching networks |
JP5165647B2 (ja) * | 2009-07-16 | 2013-03-21 | パナソニックヘルスケア株式会社 | チャンバーユニット |
WO2011047127A1 (fr) | 2009-10-15 | 2011-04-21 | Minntech Corporation | Système de désinfection de pièce par brumisation |
AU2010325926B2 (en) | 2009-12-03 | 2014-01-09 | Minntech Corporation | Container and system for decontaminating a medical device with a fog |
US8840836B2 (en) | 2011-04-27 | 2014-09-23 | Sterilucent, Inc. | Sterilization method with compression and expansion |
US9017607B2 (en) | 2011-05-27 | 2015-04-28 | Medivators Inc. | Decontamination system including environmental control using a decontaminating substance |
US9410191B2 (en) | 2014-05-13 | 2016-08-09 | Rasirc, Inc. | Method and system for decontaminating materials |
USD814006S1 (en) | 2014-07-18 | 2018-03-27 | Synexis Llc | Device for producing non-hydrated purified hydrogen peroxide gas |
USD744627S1 (en) | 2014-07-23 | 2015-12-01 | Lee Antimicrobial Solutions, Llc | Air-permeable substrate structure |
US10279060B2 (en) * | 2015-04-28 | 2019-05-07 | Medivators Inc. | System for decontamination of a lumen device |
WO2018026026A1 (fr) * | 2016-08-02 | 2018-02-08 | 주식회사 피글 | Élément d'amélioration du plasma, dispositif d'alimentation en plasma et dispositif médical le comprenant |
CN107648629A (zh) * | 2017-10-11 | 2018-02-02 | 冯利 | 一种带有净化功能的消毒柜 |
JP7140324B2 (ja) * | 2018-04-19 | 2022-09-21 | 株式会社テクノ菱和 | 過酸化水素ガス発生装置および過酸化水素ガス発生方法 |
RU2697714C1 (ru) * | 2018-09-17 | 2019-08-19 | Общество с ограниченной ответственностью "Мед ТеКо" | Плазменный пероксидный стерилизатор |
RU2709217C1 (ru) | 2019-07-04 | 2019-12-18 | Алексей Васильевич Софронов | Способ получения дезинфицирующего раствора и устройство для его реализации |
JP7360122B2 (ja) * | 2019-07-17 | 2023-10-12 | 株式会社テクノ菱和 | 過酸化水素ガス発生装置および過酸化水素ガス発生方法 |
KR102264222B1 (ko) * | 2019-10-11 | 2021-06-10 | 오철 | 과산화수소 증기의 제조방법. |
GB201918942D0 (en) * | 2019-12-20 | 2020-02-05 | Mas Innovation Private Ltd | Plasma deposition apparatus |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2105591B (en) * | 1981-09-08 | 1985-04-24 | American Sterilizer Co | Combined gaseous hydrogen peroxide sterilizing chamber and storage unit for sterilized goods |
IN170602B (fr) * | 1987-07-30 | 1992-04-18 | Surgikos Inc | |
WO1989006121A1 (fr) * | 1987-12-30 | 1989-07-13 | American Sterilizer Company | Procede de depyrogenation de vapeur de peroxyde d'hydrogene |
US5288460A (en) * | 1989-03-08 | 1994-02-22 | Abtox, Inc. | Plasma cycling sterilizing process |
EP0456135A2 (fr) * | 1990-05-11 | 1991-11-13 | Abtox, Inc. | Stérilisation avec du peroxyde d'hydrogène et un plasma |
US5244629A (en) * | 1990-08-31 | 1993-09-14 | Caputo Ross A | Plasma sterilizing process with pulsed antimicrobial agent pretreatment |
GB9022268D0 (en) * | 1990-10-13 | 1990-11-28 | Cmb Foodcan Plc | Sterilising apparatus |
CN1097798A (zh) * | 1993-07-22 | 1995-01-25 | 上海市日用化学工业研究所 | 新型漂白剂和其制备方法及用途 |
AU7984094A (en) * | 1993-08-16 | 1995-03-14 | Albright & Wilson Limited | Oxidising bleach |
US5674450A (en) * | 1994-04-28 | 1997-10-07 | Johnson & Johnson Medical, Inc. | Vapor sterilization using a non-aqueous source of hydrogen peroxide |
-
1996
- 1996-09-19 US US08/716,094 patent/US5785934A/en not_active Expired - Fee Related
- 1996-10-23 AT AT04076536T patent/ATE381354T1/de not_active IP Right Cessation
- 1996-10-23 EP EP96936565A patent/EP0862466B1/fr not_active Expired - Lifetime
- 1996-10-23 AT AT96936565T patent/ATE317705T1/de not_active IP Right Cessation
- 1996-10-23 EP EP04076536A patent/EP1473044B1/fr not_active Expired - Lifetime
- 1996-10-23 WO PCT/US1996/016570 patent/WO1997015333A1/fr active IP Right Grant
- 1996-10-23 DE DE69637377T patent/DE69637377T2/de not_active Expired - Fee Related
- 1996-10-23 ES ES96936565T patent/ES2257754T3/es not_active Expired - Lifetime
- 1996-10-23 KR KR10-1998-0703075A patent/KR100483219B1/ko active
- 1996-10-23 DE DE69635826T patent/DE69635826T2/de not_active Expired - Fee Related
- 1996-10-23 BR BR9611152-6A patent/BR9611152A/pt not_active Application Discontinuation
- 1996-10-23 ES ES04076536T patent/ES2297336T3/es not_active Expired - Lifetime
- 1996-10-23 JP JP51665597A patent/JP2002515770A/ja not_active Ceased
- 1996-10-23 AU AU74462/96A patent/AU704089B2/en not_active Ceased
- 1996-10-23 CA CA002235941A patent/CA2235941C/fr not_active Expired - Fee Related
- 1996-10-26 KR KR1019960048719A patent/KR100457486B1/ko not_active IP Right Cessation
- 1996-10-28 IN IN1877CA1996 patent/IN182209B/en unknown
- 1996-12-30 TW TW85116248A patent/TW343922B/zh not_active IP Right Cessation
-
1997
- 1997-04-03 TW TW86104336A patent/TW368418B/zh not_active IP Right Cessation
-
1998
- 1998-04-23 NO NO981827A patent/NO981827D0/no unknown
- 1998-04-27 MX MX9803318A patent/MX209103B/es not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015114555B4 (de) * | 2015-08-13 | 2021-03-18 | Uniwersytet Wrocławski | Verfahren zur Entfeuchtung von saugfähigen Objekten mit gleichzeitiger antimikrobiellen Wirkung sowie ein entsprechendes Gerät zur Umsetzung dieses Verfahrens |
Also Published As
Publication number | Publication date |
---|---|
KR100457486B1 (ko) | 2005-04-06 |
EP0862466B1 (fr) | 2006-02-15 |
TW343922B (en) | 1998-11-01 |
ATE381354T1 (de) | 2008-01-15 |
CA2235941C (fr) | 2008-10-07 |
JP2002515770A (ja) | 2002-05-28 |
EP1473044A2 (fr) | 2004-11-03 |
EP1473044A3 (fr) | 2004-11-17 |
EP1473044B1 (fr) | 2007-12-19 |
KR970020122A (ko) | 1997-05-28 |
DE69635826T2 (de) | 2006-09-28 |
US5785934A (en) | 1998-07-28 |
AU7446296A (en) | 1997-05-15 |
NO981827D0 (no) | 1998-04-23 |
ATE317705T1 (de) | 2006-03-15 |
EP0862466A1 (fr) | 1998-09-09 |
DE69637377D1 (de) | 2008-01-31 |
ES2297336T3 (es) | 2008-05-01 |
DE69635826D1 (de) | 2006-04-20 |
IN182209B (fr) | 1999-01-30 |
AU704089B2 (en) | 1999-04-15 |
KR100483219B1 (ko) | 2005-11-28 |
CA2235941A1 (fr) | 1997-05-01 |
MX209103B (en) | 2002-07-22 |
TW368418B (en) | 1999-09-01 |
WO1997015333A1 (fr) | 1997-05-01 |
ES2257754T3 (es) | 2006-08-01 |
BR9611152A (pt) | 1999-12-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69637377T2 (de) | Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen | |
US5667753A (en) | Vapor sterilization using inorganic hydrogen peroxide complexes | |
AU704105B2 (en) | Vapor sterilization using a non-aqueous source of hydrogen peroxide | |
WO1997015333A9 (fr) | Sterilisation par vapeur a l'aide de complexes de peroxyde d'hydrogene non organiques | |
MXPA96005191A (en) | Sterilization with steam using inorganic compounds of hidrog peroxide | |
US5820841A (en) | Hydrogen peroxide complexes of inorganic salts and synthesis thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |