DE69637377T2 - Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen - Google Patents
Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen Download PDFInfo
- Publication number
- DE69637377T2 DE69637377T2 DE69637377T DE69637377T DE69637377T2 DE 69637377 T2 DE69637377 T2 DE 69637377T2 DE 69637377 T DE69637377 T DE 69637377T DE 69637377 T DE69637377 T DE 69637377T DE 69637377 T2 DE69637377 T2 DE 69637377T2
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen peroxide
- complex
- container
- peroxide
- vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 593
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 135
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 131
- 238000000034 method Methods 0.000 claims abstract description 120
- 238000010438 heat treatment Methods 0.000 claims abstract description 38
- 230000008569 process Effects 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 60
- 239000000843 powder Substances 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 32
- 230000000694 effects Effects 0.000 claims description 29
- 239000007789 gas Substances 0.000 claims description 19
- 229910021432 inorganic complex Inorganic materials 0.000 claims description 14
- 230000004888 barrier function Effects 0.000 claims description 9
- 150000002484 inorganic compounds Chemical class 0.000 claims description 9
- 238000004891 communication Methods 0.000 claims description 8
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 8
- 229910010272 inorganic material Inorganic materials 0.000 claims description 8
- 150000004760 silicates Chemical class 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 7
- 150000005323 carbonate salts Chemical class 0.000 claims description 6
- 150000003891 oxalate salts Chemical class 0.000 claims description 6
- 230000007246 mechanism Effects 0.000 claims description 5
- 239000004155 Chlorine dioxide Substances 0.000 claims description 4
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 3
- 239000003206 sterilizing agent Substances 0.000 claims description 3
- 238000013022 venting Methods 0.000 claims description 2
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims 4
- 150000002978 peroxides Chemical class 0.000 abstract description 178
- 229910000402 monopotassium phosphate Inorganic materials 0.000 abstract description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract description 2
- 239000007836 KH2PO4 Substances 0.000 abstract 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 abstract 1
- 239000011734 sodium Substances 0.000 description 161
- 238000012360 testing method Methods 0.000 description 71
- 239000000243 solution Substances 0.000 description 54
- 239000000203 mixture Substances 0.000 description 53
- 229910052739 hydrogen Inorganic materials 0.000 description 51
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 47
- 229910052782 aluminium Inorganic materials 0.000 description 46
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 46
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 45
- 229940048086 sodium pyrophosphate Drugs 0.000 description 44
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 44
- 210000002381 plasma Anatomy 0.000 description 40
- 230000015572 biosynthetic process Effects 0.000 description 39
- 239000007787 solid Substances 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 35
- 238000003786 synthesis reaction Methods 0.000 description 34
- 239000007858 starting material Substances 0.000 description 27
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 27
- 229920002799 BoPET Polymers 0.000 description 25
- 239000005041 Mylar™ Substances 0.000 description 25
- 239000007921 spray Substances 0.000 description 22
- 239000000126 substance Substances 0.000 description 20
- 229910019142 PO4 Inorganic materials 0.000 description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 19
- 239000010452 phosphate Substances 0.000 description 19
- 235000021317 phosphate Nutrition 0.000 description 19
- 239000000523 sample Substances 0.000 description 19
- 229910001220 stainless steel Inorganic materials 0.000 description 19
- 239000010935 stainless steel Substances 0.000 description 19
- 239000012298 atmosphere Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 18
- 239000004775 Tyvek Substances 0.000 description 17
- 229920000690 Tyvek Polymers 0.000 description 17
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 16
- 239000000376 reactant Substances 0.000 description 16
- 210000004215 spore Anatomy 0.000 description 16
- -1 alkali metal oxalates Chemical class 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 238000005507 spraying Methods 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 230000036512 infertility Effects 0.000 description 14
- 238000001291 vacuum drying Methods 0.000 description 14
- 239000012808 vapor phase Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000011575 calcium Substances 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 12
- YMAWOPBAYDPSLA-UHFFFAOYSA-N glycine anhydride Natural products [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 12
- 239000011777 magnesium Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 11
- 235000014469 Bacillus subtilis Nutrition 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 10
- 230000008901 benefit Effects 0.000 description 10
- 235000013877 carbamide Nutrition 0.000 description 10
- 238000000354 decomposition reaction Methods 0.000 description 10
- BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 10
- 239000004202 carbamide Substances 0.000 description 9
- 235000011180 diphosphates Nutrition 0.000 description 9
- 238000004806 packaging method and process Methods 0.000 description 9
- 230000035484 reaction time Effects 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 230000009471 action Effects 0.000 description 8
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000000643 oven drying Methods 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
- 239000004809 Teflon Substances 0.000 description 6
- 229920006362 Teflon® Polymers 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 239000005297 pyrex Substances 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 6
- 229940057054 1,3-dimethylurea Drugs 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- VZWGHDYJGOMEKT-UHFFFAOYSA-J sodium pyrophosphate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O VZWGHDYJGOMEKT-UHFFFAOYSA-J 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000001308 synthesis method Methods 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- NTYJJOPFIAHURM-UHFFFAOYSA-N Histamine Chemical compound NCCC1=CN=CN1 NTYJJOPFIAHURM-UHFFFAOYSA-N 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- MFLMBWASGCAJGO-UHFFFAOYSA-L disodium;hydrogen peroxide;carbonate Chemical compound [Na+].[Na+].OO.[O-]C([O-])=O MFLMBWASGCAJGO-UHFFFAOYSA-L 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 229920006380 polyphenylene oxide Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GBFPIFMOELLUDL-UHFFFAOYSA-L OO.C(C(=O)[O-])(=O)[O-].[K+].[K+] Chemical compound OO.C(C(=O)[O-])(=O)[O-].[K+].[K+] GBFPIFMOELLUDL-UHFFFAOYSA-L 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- GEMCGUOJDLYZJY-UHFFFAOYSA-N carbonic acid;hydrogen peroxide;sodium Chemical compound [Na].OO.OC(O)=O GEMCGUOJDLYZJY-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 3
- 229910000160 potassium phosphate Inorganic materials 0.000 description 3
- 235000011009 potassium phosphates Nutrition 0.000 description 3
- 230000003330 sporicidal effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000010189 synthetic method Methods 0.000 description 3
- 239000001974 tryptic soy broth Substances 0.000 description 3
- 108010050327 trypticase-soy broth Proteins 0.000 description 3
- LKDXXGJHEOAEHV-UHFFFAOYSA-N 1,3-dimethylurea;hydrogen peroxide Chemical compound OO.CNC(=O)NC LKDXXGJHEOAEHV-UHFFFAOYSA-N 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229910017855 NH 4 F Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000010574 gas phase reaction Methods 0.000 description 2
- 229960001340 histamine Drugs 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002054 inoculum Substances 0.000 description 2
- 238000012806 monitoring device Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000006069 physical mixture Substances 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- HHLKGLWTIGUAPJ-UHFFFAOYSA-N (2-aminoacetyl) 2-aminoacetate;hydrogen peroxide Chemical compound OO.NCC(=O)OC(=O)CN HHLKGLWTIGUAPJ-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 241000193385 Geobacillus stearothermophilus Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910020335 Na3 PO4.12H2 O Inorganic materials 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- UISHMWJBGGDOII-UHFFFAOYSA-L S(=S)(=O)([O-])[O-].[Na+].[I+] Chemical compound S(=S)(=O)([O-])[O-].[Na+].[I+] UISHMWJBGGDOII-UHFFFAOYSA-L 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N ammonium carbonate Chemical class N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- 239000012472 biological sample Substances 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940043256 calcium pyrophosphate Drugs 0.000 description 1
- 229940078916 carbamide peroxide Drugs 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000000882 contact lens solution Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229940061607 dibasic sodium phosphate Drugs 0.000 description 1
- 235000019821 dicalcium diphosphate Nutrition 0.000 description 1
- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical compound [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- IKHMGDCRLIVYEL-UHFFFAOYSA-N dodecasodium;trisilicate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IKHMGDCRLIVYEL-UHFFFAOYSA-N 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000013305 flexible fiber Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- KNLIMQSABQICQW-UHFFFAOYSA-N hydrogen peroxide;propanamide Chemical class OO.CCC(N)=O KNLIMQSABQICQW-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009103 reabsorption Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- WPFGFHJALYCVMO-UHFFFAOYSA-L rubidium carbonate Chemical class [Rb+].[Rb+].[O-]C([O-])=O WPFGFHJALYCVMO-UHFFFAOYSA-L 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000012414 sterilization procedure Methods 0.000 description 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/14—Plasma, i.e. ionised gases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
- A61L2/208—Hydrogen peroxide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/26—Accessories or devices or components used for biocidal treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/03—Preparation from inorganic peroxy compounds, e.g. from peroxysulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/06—Peroxyhydrates; Peroxyacids or salts thereof containing sulfur
- C01B15/08—Peroxysulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/10—Peroxyhydrates; Peroxyacids or salts thereof containing carbon
- C01B15/103—Peroxyhydrates; Peroxyacids or salts thereof containing carbon containing only alkali metals as metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/14—Peroxyhydrates; Peroxyacids or salts thereof containing silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/16—Peroxyhydrates; Peroxyacids or salts thereof containing phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/12—Apparatus for isolating biocidal substances from the environment
- A61L2202/122—Chambers for sterilisation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/24—Medical instruments, e.g. endoscopes, catheters, sharps
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US549425 | 1995-10-27 | ||
| US08/549,425 US5667753A (en) | 1994-04-28 | 1995-10-27 | Vapor sterilization using inorganic hydrogen peroxide complexes |
| US08/716,094 US5785934A (en) | 1995-01-06 | 1996-09-19 | Vapor sterilization using inorganic hydrogen peroxide complexes |
| US716094 | 1996-09-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69637377D1 DE69637377D1 (de) | 2008-01-31 |
| DE69637377T2 true DE69637377T2 (de) | 2008-12-04 |
Family
ID=27069128
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69637377T Expired - Fee Related DE69637377T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen |
| DE69635826T Expired - Fee Related DE69635826T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter verwendung von anorganischen wasserstoffperoxidkomplexen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69635826T Expired - Fee Related DE69635826T2 (de) | 1995-10-27 | 1996-10-23 | Dampfsterilisation unter verwendung von anorganischen wasserstoffperoxidkomplexen |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5785934A (fr) |
| EP (2) | EP0862466B1 (fr) |
| JP (1) | JP2002515770A (fr) |
| KR (2) | KR100483219B1 (fr) |
| AT (2) | ATE317705T1 (fr) |
| AU (1) | AU704089B2 (fr) |
| BR (1) | BR9611152A (fr) |
| CA (1) | CA2235941C (fr) |
| DE (2) | DE69637377T2 (fr) |
| ES (2) | ES2257754T3 (fr) |
| IN (1) | IN182209B (fr) |
| MX (1) | MX209103B (fr) |
| NO (1) | NO981827D0 (fr) |
| TW (2) | TW343922B (fr) |
| WO (1) | WO1997015333A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015114555B4 (de) * | 2015-08-13 | 2021-03-18 | Uniwersytet Wrocławski | Verfahren zur Entfeuchtung von saugfähigen Objekten mit gleichzeitiger antimikrobiellen Wirkung sowie ein entsprechendes Gerät zur Umsetzung dieses Verfahrens |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6495100B1 (en) * | 1996-04-04 | 2002-12-17 | Ethicon, Inc. | Method for sterilizing devices in a container |
| US5820841A (en) * | 1996-09-19 | 1998-10-13 | Ethicon, Inc. | Hydrogen peroxide complexes of inorganic salts and synthesis thereof |
| US6355448B1 (en) | 1998-06-02 | 2002-03-12 | 3M Innovative Properties Company | Sterilization indicator with chemically stabilized enzyme |
| US7045343B2 (en) * | 1998-06-02 | 2006-05-16 | 3M Innovative Properties Company | Sterilization indicator test packs |
| AU1827600A (en) | 1998-11-23 | 2000-06-13 | Ecolab Inc. | Non-corrosive sterilant composition |
| GB2354443A (en) | 1999-09-21 | 2001-03-28 | Microflow Ltd | Vapour phase sterilisation |
| GB2360454A (en) * | 2000-03-21 | 2001-09-26 | Microflow Ltd | Control of gaseous sterilisation |
| GB2364914B (en) * | 2000-07-26 | 2002-07-24 | Jacques Protic | A sterilisation process and apparatus therefor |
| US20020098111A1 (en) * | 2000-12-04 | 2002-07-25 | Nguyen Nick N. | Vaporizer |
| GB0202064D0 (en) * | 2002-01-30 | 2002-03-13 | Reckitt Benckiser Uk Ltd | Device |
| US20030147773A1 (en) * | 2002-02-01 | 2003-08-07 | Bryner Roger S. | Apparatus and method for paper and dry goods bio-decontamination |
| US7300637B2 (en) * | 2002-09-30 | 2007-11-27 | Ethicon, Inc. | Sterilization container kit |
| US7369959B2 (en) * | 2002-11-26 | 2008-05-06 | Intercat Equipment, Inc. | Fluid catalytic cracking catalyst injection system and method for communicating with same |
| US7606678B2 (en) | 2002-11-26 | 2009-10-20 | Intercat Equipment, Inc. | Method for monitoring a FCC catalyst injection system |
| US8099259B2 (en) * | 2002-11-26 | 2012-01-17 | Intercat Equipment, Inc. | Method for monitoring catalyst requirements of a refinery |
| US7050944B2 (en) * | 2002-11-26 | 2006-05-23 | Intercat Equipment, Inc. | FCC catalyst injection system having local data access |
| DE10320196A1 (de) * | 2002-12-20 | 2004-07-08 | Henkel Kg Auf Aktien | Bleichmittelhaltige Wasch- oder Reinigungsmittel |
| ES2274296T3 (es) * | 2002-12-20 | 2007-05-16 | Degussa Gmbh | Composicion liquida de detergente y agente de limpieza. |
| WO2004056954A1 (fr) * | 2002-12-20 | 2004-07-08 | Degussa Ag | Composes peroxygenes enrobes, a liberation lente, leur procede de preparation et d'utilisation |
| SI1475350T1 (sl) * | 2003-05-07 | 2005-12-31 | Degussa | Prevlecene granule natrijevega perkarbonata z izboljsano stabilnostjo pri skladiscenju |
| JP2007504089A (ja) * | 2003-05-23 | 2007-03-01 | デグサ アクチエンゲゼルシャフト | 過酸化水素又は酸素の制御された放出のための、過酸化水素及び疎水化した二酸化ケイ素を含有する粉体状混合物の使用 |
| US20090252815A1 (en) * | 2003-05-23 | 2009-10-08 | Evonik Degussa Gmbh | Pulverulent mixtures containing hydrogen peroxide and hydrophobized silicon dioxide |
| US7556660B2 (en) * | 2003-06-11 | 2009-07-07 | James Kevin Shurtleff | Apparatus and system for promoting a substantially complete reaction of an anhydrous hydride reactant |
| US20050042130A1 (en) * | 2003-08-22 | 2005-02-24 | Szu-Min Lin | Mist sterilization system |
| JP2007521118A (ja) * | 2004-01-07 | 2007-08-02 | ノクシライザー，インコーポレイテッド | 殺菌システムおよび装置 |
| US8017074B2 (en) * | 2004-01-07 | 2011-09-13 | Noxilizer, Inc. | Sterilization system and device |
| US7329385B1 (en) | 2004-07-08 | 2008-02-12 | Radicone Michael C | Device and method for air stream, fluid and vessel decontamination |
| DE102004054495A1 (de) | 2004-11-11 | 2006-05-24 | Degussa Ag | Natriumpercarbonatpartikel mit einer Thiosulfat enthaltenden Hüllschicht |
| KR100588936B1 (ko) | 2005-03-29 | 2006-06-09 | 주식회사 대우일렉트로닉스 | 내부 청소가 용이한 증기소독실 구조 |
| US8137658B2 (en) | 2005-06-28 | 2012-03-20 | Isp Investments Inc. | Tooth whitening compositions |
| CN101237896B (zh) | 2005-08-04 | 2012-10-31 | 萨班有限公司 | 用于浓缩雾化剂的装置和方法以及物品消毒或灭菌的方法 |
| US8673297B2 (en) | 2006-02-28 | 2014-03-18 | Basf Corporation | Chlorine dioxide based cleaner/sanitizer |
| US8357214B2 (en) | 2007-04-26 | 2013-01-22 | Trulite, Inc. | Apparatus, system, and method for generating a gas from solid reactant pouches |
| DE102007025452A1 (de) | 2007-05-31 | 2008-12-04 | Ernst-Moritz-Arndt-Universität Greifswald | Verfahren zur Beschichtung von Oberflächen mit Mikro- und Nanopartikeln mit Hilfe von Plasmaverfahren |
| KR20100061453A (ko) | 2007-07-25 | 2010-06-07 | 트루라이트 인크. | 하이브리드 전력의 생성 및 사용을 관리하는 장치, 시스템 및 방법 |
| MX2010001444A (es) | 2007-08-07 | 2010-05-20 | Lee Antimicrobial Solutions Llc | Metodo y dispositivo de tratamiento con aire y radiacion ultravioleta. |
| WO2010096766A1 (fr) | 2009-02-23 | 2010-08-26 | Noxilizer, Inc. | Dispositif et procédé de stérilisation par gaz |
| US20100265816A1 (en) * | 2009-04-17 | 2010-10-21 | American Superconductor Corporation | Monitoring switching networks |
| JP5165647B2 (ja) * | 2009-07-16 | 2013-03-21 | パナソニックヘルスケア株式会社 | チャンバーユニット |
| US8889081B2 (en) | 2009-10-15 | 2014-11-18 | Medivators Inc. | Room fogging disinfection system |
| ES2534473T3 (es) | 2009-12-03 | 2015-04-23 | Minntech Corporation | Recipiente para la descontaminación de un dispositivo médico con niebla |
| WO2012148589A2 (fr) * | 2011-04-27 | 2012-11-01 | Sterilucent, Inc. | Système et procédé de stérilisation et procédé de compression et expansion |
| CN103702689B (zh) | 2011-05-27 | 2016-08-17 | 马尔科尔净化装置公司 | 包括使用净化物质的环境控制的净化系统 |
| JP6423004B2 (ja) | 2014-05-13 | 2018-11-14 | ラシリック, インコーポレイテッドRASIRC, Inc. | プロセスガスを重要工程処理に送達するための方法および系 |
| USD814006S1 (en) | 2014-07-18 | 2018-03-27 | Synexis Llc | Device for producing non-hydrated purified hydrogen peroxide gas |
| USD744627S1 (en) | 2014-07-23 | 2015-12-01 | Lee Antimicrobial Solutions, Llc | Air-permeable substrate structure |
| US10279060B2 (en) * | 2015-04-28 | 2019-05-07 | Medivators Inc. | System for decontamination of a lumen device |
| WO2018026026A1 (fr) * | 2016-08-02 | 2018-02-08 | 주식회사 피글 | Élément d'amélioration du plasma, dispositif d'alimentation en plasma et dispositif médical le comprenant |
| CN107648629A (zh) * | 2017-10-11 | 2018-02-02 | 冯利 | 一种带有净化功能的消毒柜 |
| JP7140324B2 (ja) * | 2018-04-19 | 2022-09-21 | 株式会社テクノ菱和 | 過酸化水素ガス発生装置および過酸化水素ガス発生方法 |
| RU2697714C1 (ru) * | 2018-09-17 | 2019-08-19 | Общество с ограниченной ответственностью "Мед ТеКо" | Плазменный пероксидный стерилизатор |
| RU2709217C1 (ru) | 2019-07-04 | 2019-12-18 | Алексей Васильевич Софронов | Способ получения дезинфицирующего раствора и устройство для его реализации |
| JP7360122B2 (ja) * | 2019-07-17 | 2023-10-12 | 株式会社テクノ菱和 | 過酸化水素ガス発生装置および過酸化水素ガス発生方法 |
| KR102264222B1 (ko) * | 2019-10-11 | 2021-06-10 | 오철 | 과산화수소 증기의 제조방법. |
| GB201918942D0 (en) * | 2019-12-20 | 2020-02-05 | Mas Innovation Private Ltd | Plasma deposition apparatus |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2105591B (en) * | 1981-09-08 | 1985-04-24 | American Sterilizer Co | Combined gaseous hydrogen peroxide sterilizing chamber and storage unit for sterilized goods |
| IN170602B (fr) * | 1987-07-30 | 1992-04-18 | Surgikos Inc | |
| WO1989006121A1 (fr) * | 1987-12-30 | 1989-07-13 | American Sterilizer Company | Procede de depyrogenation de vapeur de peroxyde d'hydrogene |
| US5288460A (en) * | 1989-03-08 | 1994-02-22 | Abtox, Inc. | Plasma cycling sterilizing process |
| EP0456135A2 (fr) * | 1990-05-11 | 1991-11-13 | Abtox, Inc. | Stérilisation avec du peroxyde d'hydrogène et un plasma |
| US5244629A (en) * | 1990-08-31 | 1993-09-14 | Caputo Ross A | Plasma sterilizing process with pulsed antimicrobial agent pretreatment |
| GB9022268D0 (en) * | 1990-10-13 | 1990-11-28 | Cmb Foodcan Plc | Sterilising apparatus |
| CN1097798A (zh) * | 1993-07-22 | 1995-01-25 | 上海市日用化学工业研究所 | 新型漂白剂和其制备方法及用途 |
| WO1995005341A2 (fr) * | 1993-08-16 | 1995-02-23 | Albright & Wilson Uk Limited | Agent de blanchiment oxydant |
| US5674450A (en) * | 1994-04-28 | 1997-10-07 | Johnson & Johnson Medical, Inc. | Vapor sterilization using a non-aqueous source of hydrogen peroxide |
-
1996
- 1996-09-19 US US08/716,094 patent/US5785934A/en not_active Expired - Fee Related
- 1996-10-23 DE DE69637377T patent/DE69637377T2/de not_active Expired - Fee Related
- 1996-10-23 EP EP96936565A patent/EP0862466B1/fr not_active Expired - Lifetime
- 1996-10-23 AT AT96936565T patent/ATE317705T1/de not_active IP Right Cessation
- 1996-10-23 AT AT04076536T patent/ATE381354T1/de not_active IP Right Cessation
- 1996-10-23 WO PCT/US1996/016570 patent/WO1997015333A1/fr active IP Right Grant
- 1996-10-23 DE DE69635826T patent/DE69635826T2/de not_active Expired - Fee Related
- 1996-10-23 JP JP51665597A patent/JP2002515770A/ja not_active Ceased
- 1996-10-23 AU AU74462/96A patent/AU704089B2/en not_active Ceased
- 1996-10-23 ES ES96936565T patent/ES2257754T3/es not_active Expired - Lifetime
- 1996-10-23 CA CA002235941A patent/CA2235941C/fr not_active Expired - Fee Related
- 1996-10-23 KR KR10-1998-0703075A patent/KR100483219B1/ko active
- 1996-10-23 EP EP04076536A patent/EP1473044B1/fr not_active Expired - Lifetime
- 1996-10-23 ES ES04076536T patent/ES2297336T3/es not_active Expired - Lifetime
- 1996-10-23 BR BR9611152-6A patent/BR9611152A/pt not_active Application Discontinuation
- 1996-10-26 KR KR1019960048719A patent/KR100457486B1/ko not_active IP Right Cessation
- 1996-10-28 IN IN1877CA1996 patent/IN182209B/en unknown
- 1996-12-30 TW TW85116248A patent/TW343922B/zh not_active IP Right Cessation
-
1997
- 1997-04-03 TW TW86104336A patent/TW368418B/zh not_active IP Right Cessation
-
1998
- 1998-04-23 NO NO981827A patent/NO981827D0/no unknown
- 1998-04-27 MX MX9803318A patent/MX209103B/es not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015114555B4 (de) * | 2015-08-13 | 2021-03-18 | Uniwersytet Wrocławski | Verfahren zur Entfeuchtung von saugfähigen Objekten mit gleichzeitiger antimikrobiellen Wirkung sowie ein entsprechendes Gerät zur Umsetzung dieses Verfahrens |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1997015333A1 (fr) | 1997-05-01 |
| EP0862466A1 (fr) | 1998-09-09 |
| AU704089B2 (en) | 1999-04-15 |
| TW368418B (en) | 1999-09-01 |
| KR970020122A (ko) | 1997-05-28 |
| DE69635826T2 (de) | 2006-09-28 |
| DE69637377D1 (de) | 2008-01-31 |
| KR100483219B1 (ko) | 2005-11-28 |
| CA2235941A1 (fr) | 1997-05-01 |
| CA2235941C (fr) | 2008-10-07 |
| DE69635826D1 (de) | 2006-04-20 |
| BR9611152A (pt) | 1999-12-28 |
| NO981827D0 (no) | 1998-04-23 |
| ATE317705T1 (de) | 2006-03-15 |
| ES2297336T3 (es) | 2008-05-01 |
| EP0862466B1 (fr) | 2006-02-15 |
| TW343922B (en) | 1998-11-01 |
| MX209103B (en) | 2002-07-22 |
| EP1473044B1 (fr) | 2007-12-19 |
| AU7446296A (en) | 1997-05-15 |
| KR100457486B1 (ko) | 2005-04-06 |
| ES2257754T3 (es) | 2006-08-01 |
| JP2002515770A (ja) | 2002-05-28 |
| IN182209B (fr) | 1999-01-30 |
| EP1473044A3 (fr) | 2004-11-17 |
| EP1473044A2 (fr) | 2004-11-03 |
| US5785934A (en) | 1998-07-28 |
| ATE381354T1 (de) | 2008-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69637377T2 (de) | Dampfsterilisation unter Verwendung von inorganischen Wasserstoffperoxidkomplexen | |
| US5667753A (en) | Vapor sterilization using inorganic hydrogen peroxide complexes | |
| AU704105B2 (en) | Vapor sterilization using a non-aqueous source of hydrogen peroxide | |
| WO1997015333A9 (fr) | Sterilisation par vapeur a l'aide de complexes de peroxyde d'hydrogene non organiques | |
| MXPA96005191A (en) | Sterilization with steam using inorganic compounds of hidrog peroxide | |
| US5820841A (en) | Hydrogen peroxide complexes of inorganic salts and synthesis thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |