DE69616377D1 - Thermoplastschaum und herstellungsverfahren dafür mittels kohlendioxid - Google Patents

Thermoplastschaum und herstellungsverfahren dafür mittels kohlendioxid

Info

Publication number
DE69616377D1
DE69616377D1 DE69616377T DE69616377T DE69616377D1 DE 69616377 D1 DE69616377 D1 DE 69616377D1 DE 69616377 T DE69616377 T DE 69616377T DE 69616377 T DE69616377 T DE 69616377T DE 69616377 D1 DE69616377 D1 DE 69616377D1
Authority
DE
Germany
Prior art keywords
carbon dioxide
polymer melt
blowing agent
additives
thermoplastic foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69616377T
Other languages
English (en)
Other versions
DE69616377T2 (de
Inventor
G Gusavage
G Schirmer
A Hessen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cryovac LLC
Original Assignee
Cryovac LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cryovac LLC filed Critical Cryovac LLC
Publication of DE69616377D1 publication Critical patent/DE69616377D1/de
Application granted granted Critical
Publication of DE69616377T2 publication Critical patent/DE69616377T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B32B2266/0228—Aromatic vinyl resin, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/025—Polyolefin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0264—Polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/04—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2377/00—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03—Extrusion of the foamable blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
DE69616377T 1995-12-18 1996-12-18 Thermoplastschaum und herstellungsverfahren dafür mittels kohlendioxid Expired - Lifetime DE69616377T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/573,812 US5670552A (en) 1995-12-18 1995-12-18 Foam and process for producing foam using a carbon dioxide blowing agent
PCT/IB1996/001478 WO1997022656A1 (en) 1995-12-18 1996-12-18 Thermoplastic foam and process for producing it using carbon dioxide

Publications (2)

Publication Number Publication Date
DE69616377D1 true DE69616377D1 (de) 2001-11-29
DE69616377T2 DE69616377T2 (de) 2002-07-11

Family

ID=24293488

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69616377T Expired - Lifetime DE69616377T2 (de) 1995-12-18 1996-12-18 Thermoplastschaum und herstellungsverfahren dafür mittels kohlendioxid

Country Status (11)

Country Link
US (2) US5670552A (de)
EP (1) EP0868472B1 (de)
CN (1) CN1080281C (de)
AT (1) ATE207507T1 (de)
AU (1) AU709247B2 (de)
BR (1) BR9612060A (de)
CA (1) CA2240774C (de)
DE (1) DE69616377T2 (de)
ES (1) ES2164267T3 (de)
NZ (1) NZ324417A (de)
WO (1) WO1997022656A1 (de)

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US5962545A (en) * 1997-06-23 1999-10-05 The Dow Chemical Company Method of enhancing open cell formation in alkenyl aromatic polymer foams
US6428297B1 (en) * 1998-10-28 2002-08-06 Dart Container Corporation Apparatus for making a corrugation-free foam
US6288144B1 (en) 1999-04-20 2001-09-11 Uniroyal Chemical Company, Inc. Processing of coupled, filled polyolefins
DE19921386A1 (de) 1999-05-10 2000-11-16 Basf Ag Offenzellig Partikelschaumstoffe
US6403663B1 (en) 1999-09-20 2002-06-11 North Carolina State University Method of making foamed materials using surfactants and carbon dioxide
US6773798B2 (en) * 1999-12-23 2004-08-10 Sealed Air Corporation (Us) Polyolefin foam composite structure and method for making the same
US6764756B1 (en) * 1999-12-23 2004-07-20 Sealed Air Corporation (Us) Polyolefin foam composite structure and method for making the same
CA2426013C (en) 2000-10-24 2009-09-15 Dow Global Technologies Inc. A water-free preparation process for multimodal thermoplastic polymer foam and foam therefrom
CA2432144C (en) * 2000-12-21 2009-09-29 Dow Global Technologies Inc. Blowing agent composition and polymeric foam containing a normally-liquid hydrofluorocarbon and carbon dioxide
US7658989B2 (en) * 2001-03-28 2010-02-09 North Carolina State University Nano-and micro-cellular foamed thin-walled material, and processes and apparatuses for making the same
CA2435144C (en) * 2003-07-15 2010-06-15 Beaver Plastics Ltd. Top dressing for seedling containers
US20060160928A1 (en) * 2005-01-18 2006-07-20 Cleveland Christopher S Thermoformed polystyrene products
US8314161B2 (en) 2005-08-22 2012-11-20 Owens Corning Intellectual Capital, Llc Deformable, rigid polystyrene foam board
DE102006014235A1 (de) * 2006-03-28 2007-10-04 Brugg Rohr Ag, Holding Mantel für wärmeisolierte Leitungsrohre
ITBO20070391A1 (it) * 2007-06-01 2008-12-02 Coopbox Europ Spa Foglia di materia plastica, vassoio per un prodotto alimentare ottenuto da detta foglia, confezione comprendente detto vassoio e relativo metodo di realizzazione.
US9676695B2 (en) * 2011-03-02 2017-06-13 Aither Chemical LLC Methods for integrated natural gas purification and products produced therefrom
CN102924742B (zh) * 2011-08-12 2015-09-30 黑龙江鑫达企业集团有限公司 超临界co2法制备聚丙烯树脂发泡颗粒的方法
CN102504498B (zh) * 2011-10-10 2013-06-26 北京工商大学 发泡pet片材及其制备方法
WO2014018768A1 (en) * 2012-07-27 2014-01-30 Reedy International Corporation Additives for low loss wire and cable dielectrics
WO2016023218A1 (en) 2014-08-15 2016-02-18 Dow Global Technologies Llc Polydimethylsiloxane grafted polyethylene foam
BR112018009883B1 (pt) * 2015-12-03 2022-01-04 Dow Global Technologies Llc. Processo para fazer uma composição de espuma e espuma
US11414529B2 (en) * 2018-06-21 2022-08-16 Fina Technology, Inc. Polystyrene compositions for foam extrusion

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US4344710A (en) * 1980-06-10 1982-08-17 Mobil Oil Corporation Polymer foam extrusion system
US4596832A (en) * 1980-07-28 1986-06-24 Dainippon Ink And Chemicals, Inc. Process for producing thermoplastic resin foam
US4452751A (en) * 1982-02-26 1984-06-05 The Dow Chemical Company Styrena polymer foam made with α-polyolefin additives
US4454086A (en) * 1982-06-18 1984-06-12 The Dow Chemical Company Making cross-linked styrene polymer foam
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US4728674A (en) * 1986-11-03 1988-03-01 General Electric Company Modified polyphenylene ether resins having improved foamability and methods of making the same
US4935089A (en) * 1987-10-30 1990-06-19 W. R. Grace & Co.-Conn. Method of making a thermoformable barrier sheet
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US5286429A (en) * 1988-06-27 1994-02-15 Mobil Oil Corporation High melt index polystyrene foam and method
JPH02240145A (ja) * 1989-03-14 1990-09-25 Sekisui Plastics Co Ltd ポリオレフィン樹脂発泡体の製造方法
US5250577A (en) * 1989-08-02 1993-10-05 The Dow Chemical Company Polystyrene foam made with only carbon dioxide as a blowing agent and a process for making the same
US5128196A (en) * 1990-03-16 1992-07-07 Amoco Corporation Foamed core-reclaim multi-layer sheet and process for production thereof
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US5269987A (en) * 1992-12-22 1993-12-14 Reedy Michael E Process for producing alkenyl aromatic foams using a combination of atmospheric and organic gases and foams produced thereby
US5422378A (en) * 1993-06-04 1995-06-06 The Dow Chemical Company Foamable styrenic polymer gel and resulting foam

Also Published As

Publication number Publication date
ATE207507T1 (de) 2001-11-15
CN1080281C (zh) 2002-03-06
AU709247B2 (en) 1999-08-26
AU1167997A (en) 1997-07-14
CA2240774A1 (en) 1997-06-26
NZ324417A (en) 1999-06-29
EP0868472A1 (de) 1998-10-07
CA2240774C (en) 2004-08-31
CN1209148A (zh) 1999-02-24
DE69616377T2 (de) 2002-07-11
US5670552A (en) 1997-09-23
WO1997022656A1 (en) 1997-06-26
EP0868472B1 (de) 2001-10-24
US5994420A (en) 1999-11-30
BR9612060A (pt) 1999-12-28
ES2164267T3 (es) 2002-02-16

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