DE69610226D1 - Adsorptionsmedium und verfahren zur dessen herstellung - Google Patents

Adsorptionsmedium und verfahren zur dessen herstellung

Info

Publication number
DE69610226D1
DE69610226D1 DE69610226T DE69610226T DE69610226D1 DE 69610226 D1 DE69610226 D1 DE 69610226D1 DE 69610226 T DE69610226 T DE 69610226T DE 69610226 T DE69610226 T DE 69610226T DE 69610226 D1 DE69610226 D1 DE 69610226D1
Authority
DE
Germany
Prior art keywords
production
adsorption medium
adsorption
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69610226T
Other languages
English (en)
Other versions
DE69610226T2 (de
Inventor
A Hanggi
N Babu
L Davis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Application granted granted Critical
Publication of DE69610226D1 publication Critical patent/DE69610226D1/de
Publication of DE69610226T2 publication Critical patent/DE69610226T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282—Porous sorbents
    • B01J20/283—Porous sorbents based on silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3261—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/3276—Copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3291—Characterised by the shape of the carrier, the coating or the obtained coated product
    • B01J20/3293—Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/54—Sorbents specially adapted for analytical or investigative chromatography
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2995—Silane, siloxane or silicone coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2996—Glass particles or spheres
DE69610226T 1996-01-11 1996-05-23 Adsorptionsmedium und verfahren zur dessen herstellung Expired - Fee Related DE69610226T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/585,369 US5667674A (en) 1996-01-11 1996-01-11 Adsorption medium and method of preparing same
PCT/US1996/007516 WO1997025140A1 (en) 1996-01-11 1996-05-23 Adsorption medium and method of preparing same

Publications (2)

Publication Number Publication Date
DE69610226D1 true DE69610226D1 (de) 2000-10-12
DE69610226T2 DE69610226T2 (de) 2001-01-04

Family

ID=24341153

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69610226T Expired - Fee Related DE69610226T2 (de) 1996-01-11 1996-05-23 Adsorptionsmedium und verfahren zur dessen herstellung

Country Status (9)

Country Link
US (3) US5667674A (de)
EP (1) EP0873189B1 (de)
JP (1) JP2000502952A (de)
AU (1) AU5874196A (de)
CA (1) CA2240856A1 (de)
DE (1) DE69610226T2 (de)
DK (1) DK0873189T3 (de)
NO (1) NO983172L (de)
WO (1) WO1997025140A1 (de)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7226966B2 (en) 2001-08-03 2007-06-05 Nanogram Corporation Structures incorporating polymer-inorganic particle blends
US6599631B2 (en) 2001-01-26 2003-07-29 Nanogram Corporation Polymer-inorganic particle composites
US6136187A (en) * 1997-12-09 2000-10-24 The Board Of Trustees Of The Leland Stanford Junior University Separation column containing porous matrix and method of packing column
US20020104801A1 (en) * 1998-04-06 2002-08-08 Nicolas Voute Small dense microporous solid support materials, their preparation,and use for purification of large macromolecules and bioparticles
US6653519B2 (en) * 1998-09-15 2003-11-25 Nanoscale Materials, Inc. Reactive nanoparticles as destructive adsorbents for biological and chemical contamination
US7803267B2 (en) * 1998-12-28 2010-09-28 W. R. Grace & Co.-Conn. Gasoline sulfur reduction in fluid catalytic cracking
US6686035B2 (en) 1999-02-05 2004-02-03 Waters Investments Limited Porous inorganic/organic hybrid particles for chromatographic separations and process for their preparation
AU4905601A (en) * 2000-02-08 2001-08-20 3M Innovative Properties Company Improved media for cold image transfer
AU4905701A (en) 2000-02-08 2001-08-20 3M Innovative Properties Company Ink fixing materials and methods of fixing ink
US6866785B2 (en) * 2001-08-13 2005-03-15 The Board Of Trustees Of The Leland Stanford Junior University Photopolymerized sol-gel column and associated methods
US6875348B2 (en) * 2000-02-18 2005-04-05 The Board Of Trustees Of The Leland Stanford Junior University Separation column having a photopolymerized sol-gel component and associated methods
EP1126275A3 (de) * 2000-02-18 2002-12-18 The Board Of Trustees Of The Leland Stanford Junior University Kapillarsäule aus geschmolzenem Siliziumdioxid mit Photopolymerbestandteilen
US6528167B2 (en) * 2001-01-31 2003-03-04 Waters Investments Limited Porous hybrid particles with organic groups removed from the surface
US6794044B2 (en) 2001-03-02 2004-09-21 Selerity Technologies, Inc. Chromatographic packing materials and methods of making and using such packing materials
EP1417366A4 (de) * 2001-08-09 2010-10-27 Waters Technologies Corp Poröse anorganisch-organisch hybridartige monolithmaterialien für chromatographische trennungen sowie verfahren zu deren herstellung
US6987079B2 (en) * 2001-08-14 2006-01-17 W.R. Grace & Co.-Conn. Supported catalyst systems
US6802966B2 (en) * 2001-08-14 2004-10-12 W. R. Grace & Co. Conn. Solid compositions for selective adsorption from complex mixtures
US7081815B2 (en) * 2001-08-23 2006-07-25 Battelle Memorial Institute Radio frequency security system, method for a building facility or the like, and apparatus and methods for remotely monitoring the status of fire extinguishers
WO2003072640A2 (en) * 2002-02-25 2003-09-04 Cabot Coproration Compositions comprising continuous networks and monoliths
US20040071968A1 (en) * 2002-02-25 2004-04-15 Agathagelos Kyrlidis Porous compositions comprising surface modified monoliths
DE10219879A1 (de) * 2002-05-03 2003-11-20 Basf Ag Katalysatorträger und Verfahren zu seiner Herstellung
US6860924B2 (en) * 2002-06-07 2005-03-01 Nanoscale Materials, Inc. Air-stable metal oxide nanoparticles
AU2003285121A1 (en) 2002-10-30 2004-06-07 Waters Investments Limited Porous inorganic/organic hybrid materials and preparation thereof
AU2003300295A1 (en) * 2002-12-20 2004-07-22 Cardiac Inventions Unlimited, Inc. Left ventricular pacing lead and implantation method
US7112277B2 (en) * 2003-06-30 2006-09-26 Agilent Technologis, Inc. Methods and systems for separating constituents of a highly aqueous fluid
DK200301027A (da) * 2003-07-04 2005-01-05 Nkt Res & Innovation As A method of producing interpenetrating polymer networks (IPN) and applications of IPN'S
EP1641425A1 (de) * 2003-07-04 2006-04-05 Nanon A/S Verfahren zur herstellung eines silanisierten verbundfüllstoffs und verfahren zur herstellung eines verbundstoffs
US20050127002A1 (en) * 2003-12-12 2005-06-16 Zare Richard N. Immobilized-enzyme microreactor devices for characterization of biomolecular analytes and associated methods
WO2005079427A2 (en) * 2004-02-17 2005-09-01 Waters Investments Limited Porous hybrid monolith materials with organic groups removed from the surface
US10773186B2 (en) 2004-07-30 2020-09-15 Waters Technologies Corporation Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation
US8658277B2 (en) 2004-07-30 2014-02-25 Waters Technologies Corporation Porous inorganic/organic hybrid materials with ordered domains for chromatographic separations and processes for their preparation
WO2006045320A2 (en) 2004-10-25 2006-05-04 Nanon A/S A method of producing a silicone rubber item and the product obtainable by the method
JP5026420B2 (ja) * 2005-08-23 2012-09-12 ヨンセイ ユニバーシティ インダストリー‐アカデミック コーポレイション ファウンデーション 無機材料の表面改質方法
US20070256976A1 (en) * 2006-04-10 2007-11-08 Boyes Barry E Metal-coated sorbents as a separation medium for HPLC of phosphorus-containing materials
US20070284308A1 (en) * 2006-06-12 2007-12-13 Zare Richard N Immobilized-enzyme microreactor devices for characterization of biomolecular analytes and associated methods
US20080053336A1 (en) * 2006-09-06 2008-03-06 Tronox Llc Aqueous coating compositions with improved tint strength and gloss properties, comprising pigments surface-treated with certain organosilicon compounds
US7972691B2 (en) * 2006-12-22 2011-07-05 Nanogram Corporation Composites of polymers and metal/metalloid oxide nanoparticles and methods for forming these composites
WO2008085435A1 (en) 2007-01-12 2008-07-17 Waters Investments Limited Porous carbon-heteroatom-silicon hybrid inorganic/organic materials for chromatographic separations and process for the preparation thereof
WO2008100568A1 (en) * 2007-02-17 2008-08-21 Nanogram Corporation Functional composites, functional inks and applications thereof
US7628844B2 (en) * 2007-10-17 2009-12-08 J.M. Huber Corporation Filtration media for the removal of mercury from flue gas emissions
EP2385968B1 (de) 2009-01-08 2015-11-04 Nanogram Corporation Verbundwerkstoffe aus polysiloxanpolymeren und anorganischen nanopartikeln
JP6151021B2 (ja) 2009-06-01 2017-06-21 ウオーターズ・テクノロジーズ・コーポレイシヨン クロマトグラフ分離用ハイブリッド材料
US11439977B2 (en) 2009-06-01 2022-09-13 Waters Technologies Corporation Hybrid material for chromatographic separations comprising a superficially porous core and a surrounding material
US8470948B2 (en) * 2009-08-28 2013-06-25 Florida State University Research Foundation, Inc. High refractive index polymers
EP2598441B1 (de) 2010-07-26 2021-01-06 Waters Technologies Corporation Materialien mit poröser oberfläche und einem substantiell nicht-porösen kern mit enger partikelgrössenverteilung, herstellungsverfahren dafür und verwendung davon für chromatographische trennungen
KR20140044381A (ko) * 2011-06-29 2014-04-14 교에이샤 케미칼 주식회사 (메타)알릴실란 화합물, 그의 실란 커플링제, 및 그것을 이용한 기능 재료
US9409929B2 (en) 2011-06-29 2016-08-09 Kyoeisha Chemical Co., Ltd. (Meth)allylsilane compound, silane coupling agent therefor, and functional material using same
JP2013209462A (ja) * 2012-03-30 2013-10-10 Sumitomo Chemical Co Ltd 共役ジエン系重合体、重合体組成物、及び、共役ジエン系重合体の製造方法
CN104968403A (zh) 2012-09-17 2015-10-07 格雷斯公司 色谱介质和装置
EP2970662B1 (de) 2013-03-11 2020-02-12 Covestro LLC Zusammensetzungen mit polycarbonat und infrarotreflektierenden additiven
US9914807B2 (en) 2013-11-18 2018-03-13 Florida State University Research Foundation, Inc. Thiol-ene polymer metal oxide nanoparticle high refractive index composites
US11389783B2 (en) 2014-05-02 2022-07-19 W.R. Grace & Co.-Conn. Functionalized support material and methods of making and using functionalized support material
EP3302784B1 (de) 2015-06-05 2021-10-06 W.R. Grace & Co.-Conn. Adsorbierende klärmittel für bioprozesstechnik und verfahren zur herstellung und verwendung davon
US20190015815A1 (en) 2016-03-06 2019-01-17 Waters Technologies Corporation Superficially porous materials comprising a coated core having narrow particle size distribution; process for the preparation thereof; and use thereof for chromatographic separations

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2448391A (en) * 1946-10-15 1948-08-31 Gen Electric Alkenyl silane interpolymers
GB735405A (en) * 1952-08-27 1955-08-17 Us Rubber Co Improvements in composition of matter and use thereof
NL6702806A (de) * 1966-03-31 1967-10-02
US3722181A (en) * 1970-05-22 1973-03-27 Du Pont Chromatographic packing with chemically bonded organic stationary phases
GB1456865A (en) * 1973-12-14 1976-12-01 Pye Ltd Method of bonding copolymers
US4783516A (en) * 1983-03-31 1988-11-08 Union Carbide Corporation Polysilane precursors containing olefinic groups for silicon carbide
US4564576A (en) * 1983-05-27 1986-01-14 Nec Corporation Resist material comprising polymer of allylsilyl compound and pattern forming method using the resist material
JPS60115611A (ja) * 1983-11-25 1985-06-22 Shin Etsu Chem Co Ltd 紫外線硬化性オルガノポリシロキサン組成物
US4602050A (en) * 1985-04-08 1986-07-22 Wisconsin Alumni Research Foundation Method for cross-linking organopolysilane polymers
US4705725A (en) * 1986-11-28 1987-11-10 E. I. Du Pont De Nemours And Company Substrates with sterically-protected, stable, covalently-bonded organo-silane films
US4904632A (en) * 1987-06-19 1990-02-27 Pesek Joseph J Surface-modified chromatographic separation material
US5141634A (en) * 1988-02-03 1992-08-25 Regents Of The University Of Minnesota High stability porous zirconium oxide spherules
US5035803A (en) * 1989-02-14 1991-07-30 The Regents Of The University Of California High yield water-soluble polymer silica separation resins
US5015375A (en) * 1989-08-16 1991-05-14 Mcf Systems, Inc. Rechargeable filter assembly
US5017540A (en) * 1989-09-15 1991-05-21 Sandoval Junior E Silicon hydride surface intermediates for chemical separations apparatus
JP2874297B2 (ja) * 1989-12-18 1999-03-24 東ソー株式会社 逆相クロマトグラフィー用充填剤及びその製造方法
US5182016A (en) * 1990-03-22 1993-01-26 Regents Of The University Of Minnesota Polymer-coated carbon-clad inorganic oxide particles
US5108597A (en) * 1990-03-22 1992-04-28 Regents Of The University Of Minnesota Carbon-clad zirconium oxide particles
US5026893A (en) * 1990-06-11 1991-06-25 Lubricating Specialties Company Polysilahydrocarbon lubricants
US5100547A (en) * 1991-03-04 1992-03-31 Monsanto Company Chromatography supports consisting of an inorganic susbstrate coated with polybutadiene with alkyl side chains
JPH06294788A (ja) * 1993-04-09 1994-10-21 Nippon Carbon Co Ltd 液体クロマトグラフィー用充填剤及びその製造方法
DE69430479T2 (de) * 1993-07-28 2002-11-28 Monash University Clayton Zirkoniumoxid partikel

Also Published As

Publication number Publication date
AU5874196A (en) 1997-08-01
NO983172L (no) 1998-09-11
DE69610226T2 (de) 2001-01-04
EP0873189A1 (de) 1998-10-28
WO1997025140A1 (en) 1997-07-17
CA2240856A1 (en) 1997-07-17
US5667674A (en) 1997-09-16
JP2000502952A (ja) 2000-03-14
US5968652A (en) 1999-10-19
DK0873189T3 (da) 2001-01-02
EP0873189B1 (de) 2000-09-06
US5876595A (en) 1999-03-02

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