DE69520662D1 - Verfahren zur copolymerisation von olefinen - Google Patents
Verfahren zur copolymerisation von olefinenInfo
- Publication number
- DE69520662D1 DE69520662D1 DE69520662T DE69520662T DE69520662D1 DE 69520662 D1 DE69520662 D1 DE 69520662D1 DE 69520662 T DE69520662 T DE 69520662T DE 69520662 T DE69520662 T DE 69520662T DE 69520662 D1 DE69520662 D1 DE 69520662D1
- Authority
- DE
- Germany
- Prior art keywords
- stage
- olefins
- polymerization
- compound
- polymerized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI942028A IT1270125B (it) | 1994-10-05 | 1994-10-05 | Processo per la ( co) polimerizzazione di olefine |
PCT/EP1995/003896 WO1996011218A1 (en) | 1994-10-05 | 1995-10-02 | Process for the (co)polymerization of olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69520662D1 true DE69520662D1 (de) | 2001-05-17 |
DE69520662T2 DE69520662T2 (de) | 2001-10-18 |
Family
ID=11369652
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69520662T Expired - Fee Related DE69520662T2 (de) | 1994-10-05 | 1995-10-02 | Verfahren zur copolymerisation von olefinen |
Country Status (29)
Country | Link |
---|---|
US (2) | US5648422A (de) |
EP (1) | EP0742801B1 (de) |
JP (1) | JP3897359B2 (de) |
KR (1) | KR100399625B1 (de) |
CN (1) | CN1070505C (de) |
AT (1) | ATE200499T1 (de) |
AU (1) | AU694276B2 (de) |
BG (1) | BG100674A (de) |
BR (1) | BR9506402A (de) |
CA (1) | CA2178077A1 (de) |
CZ (1) | CZ287739B6 (de) |
DE (1) | DE69520662T2 (de) |
DK (1) | DK0742801T3 (de) |
ES (1) | ES2156948T3 (de) |
FI (1) | FI962329A (de) |
GR (1) | GR3035745T3 (de) |
HU (1) | HU216285B (de) |
IL (1) | IL115515A (de) |
IT (1) | IT1270125B (de) |
MY (1) | MY112181A (de) |
NO (1) | NO311179B1 (de) |
PH (1) | PH31450A (de) |
PL (1) | PL314853A1 (de) |
PT (1) | PT742801E (de) |
RU (1) | RU2171265C2 (de) |
SK (1) | SK281619B6 (de) |
TR (1) | TR199501214A2 (de) |
WO (1) | WO1996011218A1 (de) |
ZA (1) | ZA958316B (de) |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1274469B (it) * | 1995-05-11 | 1997-07-17 | Spherilene Spa | Composizioni poliolefiniche vulcanizzabili dinamicamente |
WO1997049744A1 (en) * | 1996-06-24 | 1997-12-31 | Montell North America Inc. | High transparency and high flexibility elastoplastic polyolefin compositions |
DE69907785T2 (de) | 1998-03-09 | 2004-02-12 | Basell Poliolefine Italia S.P.A. | Mehrstufiges Verfahren zur Olefinpolymerisation |
EP0942011B1 (de) * | 1998-03-09 | 2003-05-14 | Basell Poliolefine Italia S.p.A. | Mehrstufiges Verfahren zur Olefinpolymerisation |
US6268062B1 (en) | 1998-04-06 | 2001-07-31 | Applied Extrusion Technologies, Inc. | Polypropylene blends and films prepared therewith |
US6037417A (en) * | 1998-08-18 | 2000-03-14 | Montell Technology Company Bv | Polypropylene composition useful for making solid state oriented film |
IT1302029B1 (it) | 1998-08-19 | 2000-07-20 | Montech Usa Inc | Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute |
US6992153B1 (en) * | 1999-03-09 | 2006-01-31 | Basell Polyolefine Gmbh | Multi-stage process for the (CO) polymerization of olefins |
FI991015A0 (fi) * | 1999-05-04 | 1999-05-04 | Borealis As | Menetelmä alfa-olefiinipolymeerien valmistamiseksi |
DE60024595T2 (de) | 1999-12-28 | 2006-07-27 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Ethylenpolymeren |
EP1187877B1 (de) * | 2000-03-22 | 2004-07-14 | Basell Polyolefine GmbH | Herstellung thermoplastischer Zusammensetzungen aus Hoch- und minderisotaktischem Polypropylen |
GB0008690D0 (en) * | 2000-04-07 | 2000-05-31 | Borealis Polymers Oy | Process |
US20020045190A1 (en) * | 2000-07-11 | 2002-04-18 | Wilson Robert B. | Encoding methods using up-converting phosphors for high-throughput screening of catalysts |
US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
US7183332B2 (en) * | 2000-12-22 | 2007-02-27 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous polymers and polymers obtainable thereof |
EP1368119A4 (de) * | 2001-01-16 | 2010-11-03 | Exxonmobil Chem Patents Inc | Polymerisationsverfahren mit mischkatalysatorzusammensetzungen |
WO2003008496A1 (en) * | 2001-07-17 | 2003-01-30 | Basell Polyolefine Gmbh | Multistep process for the (co)polymerization of olefins |
WO2003046023A1 (en) * | 2001-11-27 | 2003-06-05 | Basell Poliolefine Italia S.P.A. | Porous polymers of propylene |
WO2003046022A1 (en) * | 2001-11-27 | 2003-06-05 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
ATE405594T1 (de) * | 2002-01-15 | 2008-09-15 | Advanced Elastomer Systems | Thermoplastische elastomere |
WO2004011507A1 (en) * | 2002-07-24 | 2004-02-05 | Basell Polyolefine Gmbh | At least two-stage process for preparing propylene polymer compositions |
US6833416B2 (en) * | 2003-03-21 | 2004-12-21 | Univation Technologies, Llc | Methods of polymerizing olefin monomers with mixed catalyst systems |
TW200504093A (en) * | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
US7713520B2 (en) * | 2004-03-31 | 2010-05-11 | Shin-Etsu Chemical Co., Ltd. | Cosmetic comprising a silicone polymer |
US7947786B2 (en) * | 2004-10-13 | 2011-05-24 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
CN1328310C (zh) * | 2004-11-05 | 2007-07-25 | 中国科学院化学研究所 | 聚烯烃复合材料及其制备方法 |
US7629422B2 (en) * | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
AR058448A1 (es) * | 2005-09-15 | 2008-02-06 | Dow Global Technologies Inc | Control de arquitectura del polimero y distribucoin de peso molecular va el agente de transferencia multi- centrado |
US20080312390A1 (en) * | 2007-06-14 | 2008-12-18 | Petrochina Company Limited | Process for preparation of polyolefin alloy |
KR101141494B1 (ko) * | 2007-09-05 | 2012-05-03 | 에스케이이노베이션 주식회사 | 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법 |
MX2011001970A (es) * | 2008-08-21 | 2011-08-12 | Dow Global Technologies Llc | Composicion de catalizador con agente de control de selectividad mezclado y metodo de polimerizacion que la usa. |
SI2461767T1 (sl) | 2010-07-30 | 2013-08-30 | Novartis Ag | Silikonske hidrogelne leče s površinami, bogatimi z vodo |
ES2605429T3 (es) | 2011-06-15 | 2017-03-14 | Borealis Ag | Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno |
US8957168B1 (en) * | 2013-08-09 | 2015-02-17 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations with an alcohol compound |
WO2015095157A1 (en) | 2013-12-17 | 2015-06-25 | Novartis Ag | A silicone hydrogel lens with a crosslinked hydrophilic coating |
US11002884B2 (en) | 2014-08-26 | 2021-05-11 | Alcon Inc. | Method for applying stable coating on silicone hydrogel contact lenses |
CN105622808B (zh) * | 2014-10-31 | 2018-06-15 | 中国石油化工股份有限公司 | 一种抗冲聚丙烯的生产方法 |
US10077325B2 (en) | 2015-06-05 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
US9725569B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Porous propylene polymers |
US10570219B2 (en) | 2015-06-05 | 2020-02-25 | Exxonmobil Chemical Patents Inc. | Production of heterophasic polymers in gas or slurry phase |
WO2016195867A1 (en) * | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
US9920176B2 (en) | 2015-06-05 | 2018-03-20 | Exxonmobil Chemical Patents Inc. | Single site catalyst supportation |
EP3303417A4 (de) * | 2015-06-05 | 2018-08-22 | ExxonMobil Chemical Patents Inc. | Poröse propylenpolymere |
US9738779B2 (en) | 2015-06-05 | 2017-08-22 | Exxonmobil Chemical Patents Inc. | Heterophasic copolymers and sequential polymerization |
US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
EP3303419A4 (de) * | 2015-06-05 | 2018-06-20 | ExxonMobil Chemical Patents Inc. | Heterophasige copolymere und sequentielle polymerisierung |
EP3303423A1 (de) | 2015-06-05 | 2018-04-11 | ExxonMobil Chemical Patents Inc. | Einzelreaktor-herstellung von polymeren in der gas- oder suspensionsphase |
US9725537B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | High activity catalyst supportation |
US10723821B2 (en) | 2015-06-05 | 2020-07-28 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
CN105254808A (zh) * | 2015-09-30 | 2016-01-20 | 宁波职业技术学院 | 一种改性石油树脂的制备方法 |
SG11201803726VA (en) | 2015-12-15 | 2018-06-28 | Novartis Ag | Method for applying stable coating on silicone hydrogel contact lenses |
CN109312013A (zh) | 2016-05-27 | 2019-02-05 | 埃克森美孚化学专利公司 | 茂金属催化剂组合物和使用其的聚合方法 |
EP3724697B1 (de) | 2017-12-13 | 2022-01-12 | Alcon Inc. | Verfahren zur herstellung von mps-kompatiblen kontaktlinsen mit wassergradient |
CN110551242B (zh) * | 2018-05-31 | 2022-03-29 | 中国石油天然气股份有限公司 | 一种抗冲共聚聚丙烯及其制备方法 |
CN116547313A (zh) | 2020-11-23 | 2023-08-04 | 博里利斯股份公司 | 齐格勒-纳塔催化的成核聚丙烯和茂金属催化的聚丙烯的原位反应器共混物 |
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YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
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IT1227259B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Catalizzatori per la polimerizzazione di olefine. |
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IT1241093B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
ES2162953T3 (es) * | 1990-11-12 | 2002-01-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de un polimero de olefina. |
EP0485822B1 (de) * | 1990-11-12 | 1996-07-03 | Hoechst Aktiengesellschaft | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
FR2669915B1 (fr) * | 1990-11-29 | 1993-01-29 | Atochem | Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique. |
EP0527589B1 (de) * | 1991-08-08 | 1998-06-03 | Ube Rexene Corporation | Harzzusammensetzung aus amorphem Polyolefin und crystallinem Polypropylen |
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IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
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IT1264483B1 (it) * | 1993-06-30 | 1996-09-23 | Spherilene Srl | Copolimeri elastomerici dell'etilene con propilene |
IT1271407B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
US5397843A (en) * | 1993-11-22 | 1995-03-14 | Igi Baychem, Inc. | Polymer compositions comprising amorphous propylene polymer |
-
1994
- 1994-10-05 IT ITMI942028A patent/IT1270125B/it active IP Right Grant
-
1995
- 1995-06-05 US US08/461,691 patent/US5648422A/en not_active Expired - Lifetime
- 1995-10-02 AT AT95935892T patent/ATE200499T1/de not_active IP Right Cessation
- 1995-10-02 HU HU9601834A patent/HU216285B/hu not_active IP Right Cessation
- 1995-10-02 DK DK95935892T patent/DK0742801T3/da active
- 1995-10-02 KR KR1019960702939A patent/KR100399625B1/ko not_active IP Right Cessation
- 1995-10-02 ES ES95935892T patent/ES2156948T3/es not_active Expired - Lifetime
- 1995-10-02 RU RU96115290/04A patent/RU2171265C2/ru not_active IP Right Cessation
- 1995-10-02 SK SK872-96A patent/SK281619B6/sk unknown
- 1995-10-02 CN CN95191444A patent/CN1070505C/zh not_active Expired - Fee Related
- 1995-10-02 EP EP95935892A patent/EP0742801B1/de not_active Expired - Lifetime
- 1995-10-02 WO PCT/EP1995/003896 patent/WO1996011218A1/en active IP Right Grant
- 1995-10-02 PL PL95314853A patent/PL314853A1/xx unknown
- 1995-10-02 AU AU38033/95A patent/AU694276B2/en not_active Ceased
- 1995-10-02 CA CA002178077A patent/CA2178077A1/en not_active Abandoned
- 1995-10-02 BR BR9506402A patent/BR9506402A/pt not_active IP Right Cessation
- 1995-10-02 CZ CZ19961994A patent/CZ287739B6/cs not_active IP Right Cessation
- 1995-10-02 DE DE69520662T patent/DE69520662T2/de not_active Expired - Fee Related
- 1995-10-02 JP JP51231496A patent/JP3897359B2/ja not_active Expired - Fee Related
- 1995-10-02 PT PT95935892T patent/PT742801E/pt unknown
- 1995-10-03 ZA ZA958316A patent/ZA958316B/xx unknown
- 1995-10-04 MY MYPI95002960A patent/MY112181A/en unknown
- 1995-10-04 PH PH51428A patent/PH31450A/en unknown
- 1995-10-05 IL IL11551595A patent/IL115515A/xx not_active IP Right Cessation
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1996
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- 1996-06-04 FI FI962329A patent/FI962329A/fi not_active IP Right Cessation
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1997
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2001
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