DE69514414T2 - Katalysator für die Herstellung des ungesättigtes Aldehyd und einer ungesättigten Carbonsäure und Verfahren zur Herstellung des ungesättigten Aldehyds und einer ungesättigten Carbonsäure unter Verwendung der Katalysators - Google Patents

Katalysator für die Herstellung des ungesättigtes Aldehyd und einer ungesättigten Carbonsäure und Verfahren zur Herstellung des ungesättigten Aldehyds und einer ungesättigten Carbonsäure unter Verwendung der Katalysators

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Publication number
DE69514414T2
DE69514414T2 DE69514414T DE69514414T DE69514414T2 DE 69514414 T2 DE69514414 T2 DE 69514414T2 DE 69514414 T DE69514414 T DE 69514414T DE 69514414 T DE69514414 T DE 69514414T DE 69514414 T2 DE69514414 T2 DE 69514414T2
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Germany
Prior art keywords
catalyst
oxide
powder
oxidation
component
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69514414T
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German (de)
English (en)
Other versions
DE69514414D1 (de
Inventor
Yukio Aoki
Tatsuya Kawajiri
Ikuo Kurimoto
Hideo Onodera
Michio Tanimoto
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Nippon Shokubai Co Ltd
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Nippon Shokubai Co Ltd
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Publication of DE69514414D1 publication Critical patent/DE69514414D1/de
Application granted granted Critical
Publication of DE69514414T2 publication Critical patent/DE69514414T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69514414T 1994-05-31 1995-05-31 Katalysator für die Herstellung des ungesättigtes Aldehyd und einer ungesättigten Carbonsäure und Verfahren zur Herstellung des ungesättigten Aldehyds und einer ungesättigten Carbonsäure unter Verwendung der Katalysators Expired - Lifetime DE69514414T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11822994 1994-05-31

Publications (2)

Publication Number Publication Date
DE69514414D1 DE69514414D1 (de) 2000-02-17
DE69514414T2 true DE69514414T2 (de) 2000-06-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE69514414T Expired - Lifetime DE69514414T2 (de) 1994-05-31 1995-05-31 Katalysator für die Herstellung des ungesättigtes Aldehyd und einer ungesättigten Carbonsäure und Verfahren zur Herstellung des ungesättigten Aldehyds und einer ungesättigten Carbonsäure unter Verwendung der Katalysators

Country Status (6)

Country Link
US (2) US5700752A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0685260B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR100247525B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1060154C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69514414T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW309513B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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TW309513B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1994-05-31 1997-07-01 Nippon Catalytic Chem Ind
FR2760008A1 (fr) * 1997-02-27 1998-08-28 Atochem Elf Sa Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
US7232515B1 (en) 1997-07-15 2007-06-19 Exxonmobil Research And Engineering Company Hydrofining process using bulk group VIII/Group VIB catalysts
US6278030B1 (en) 1997-07-15 2001-08-21 Exxon Chemical Patents, Inc. Process for preparing alcohols by the Oxo process
US6162350A (en) * 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US7288182B1 (en) 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US6156695A (en) * 1997-07-15 2000-12-05 Exxon Research And Engineering Company Nickel molybdotungstate hydrotreating catalysts
US7229548B2 (en) 1997-07-15 2007-06-12 Exxonmobil Research And Engineering Company Process for upgrading naphtha
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
TWI268806B (en) * 1999-09-15 2006-12-21 Rohm & Haas A catalyst useful for oxidation of alkanes
KR100336969B1 (ko) * 1999-09-30 2002-05-17 김충섭 코아-쉘 구조를 갖는 고체촉매를 이용한 아크롤레인의 제조방법
JP3744750B2 (ja) * 1999-12-08 2006-02-15 株式会社日本触媒 複合酸化物触媒およびアクリル酸の製造方法
DE10063162A1 (de) * 2000-12-18 2002-06-20 Basf Ag Verfahren zur Herstellung einer Mo, Bi, Fe sowie Ni und/oder Co enthaltenden Multimetalloxidativmasse
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
JP4242597B2 (ja) 2002-02-28 2009-03-25 株式会社日本触媒 不飽和アルデヒド合成用触媒とその製造方法、およびその触媒を用いた不飽和アルデヒドの製造方法
AU2003247951A1 (en) 2002-07-10 2004-01-23 Kansas State University Research Foundation Compositions and methods for controlling parasitic nematodes
US7361791B2 (en) * 2003-03-31 2008-04-22 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
CN101385978B (zh) * 2007-09-12 2011-04-20 上海华谊丙烯酸有限公司 一种合成甲基丙烯醛的催化剂及其制备方法
CN102211027B (zh) * 2010-04-07 2013-06-12 烟台万华聚氨酯股份有限公司 一种催化剂及其制备方法,以及采用该催化剂制备甲基丙烯醛的方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN108355721B (zh) * 2018-02-02 2020-11-13 上海东化环境工程有限公司 改性载体、担载型催化剂及其应用
CN109851476B (zh) * 2019-01-03 2021-08-17 河北工业大学 一种甲基叔丁基醚液相羰基化制备烷基衍生物的方法
KR102325331B1 (ko) * 2019-12-20 2021-11-10 한화토탈 주식회사 터트-부탄올로부터 이소부틸렌의 제조방법
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Also Published As

Publication number Publication date
EP0685260B1 (en) 2000-01-12
DE69514414D1 (de) 2000-02-17
US5700752A (en) 1997-12-23
EP0685260A2 (en) 1995-12-06
EP0685260A3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1996-01-03
KR950031215A (ko) 1995-12-18
KR100247525B1 (ko) 2000-03-15
CN1060154C (zh) 2001-01-03
CN1119638A (zh) 1996-04-03
TW309513B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1997-07-01
US5981804A (en) 1999-11-09

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