DE69512053D1 - Selektive herstellung von para-dialkylsubstituierten benzolderivaten - Google Patents

Selektive herstellung von para-dialkylsubstituierten benzolderivaten

Info

Publication number
DE69512053D1
DE69512053D1 DE69512053T DE69512053T DE69512053D1 DE 69512053 D1 DE69512053 D1 DE 69512053D1 DE 69512053 T DE69512053 T DE 69512053T DE 69512053 T DE69512053 T DE 69512053T DE 69512053 D1 DE69512053 D1 DE 69512053D1
Authority
DE
Germany
Prior art keywords
dialkyl
para
derivatives
selective production
benzole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69512053T
Other languages
English (en)
Other versions
DE69512053T2 (de
Inventor
Jeffrey Beck
Ralph Dessau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of DE69512053D1 publication Critical patent/DE69512053D1/de
Application granted granted Critical
Publication of DE69512053T2 publication Critical patent/DE69512053T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
DE69512053T 1994-05-16 1995-05-11 Selektive herstellung von para-dialkylsubstituierten benzolderivaten Expired - Fee Related DE69512053T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/242,828 US5488194A (en) 1994-05-16 1994-05-16 Selective production of para-dialkyl substituted benzenes and catalyst therefor
PCT/US1995/005920 WO1995031421A1 (en) 1994-05-16 1995-05-11 Selective production of para-dialkyl substituted benzenes

Publications (2)

Publication Number Publication Date
DE69512053D1 true DE69512053D1 (de) 1999-10-14
DE69512053T2 DE69512053T2 (de) 1999-12-30

Family

ID=22916337

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69512053T Expired - Fee Related DE69512053T2 (de) 1994-05-16 1995-05-11 Selektive herstellung von para-dialkylsubstituierten benzolderivaten

Country Status (9)

Country Link
US (1) US5488194A (de)
EP (1) EP0763001B1 (de)
JP (1) JPH10502908A (de)
AU (1) AU684368B2 (de)
CA (1) CA2187871A1 (de)
DE (1) DE69512053T2 (de)
ES (1) ES2135732T3 (de)
TW (1) TW368495B (de)
WO (1) WO1995031421A1 (de)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5698756A (en) * 1993-05-28 1997-12-16 Mobil Oil Corporation Toluene alkylation with ethylene to produce para-ethyloluene
US5476823A (en) * 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5659098A (en) * 1993-05-28 1997-08-19 Beck; Jeffrey S. High conversion touluene disproportionation with ex situ selectivated zeolite catalysts
JPH08119880A (ja) * 1994-09-27 1996-05-14 Mitsubishi Oil Co Ltd １，２，４，５，−ジメチルジイソプロピルベンゼンの製造方法
US5625104A (en) * 1995-06-06 1997-04-29 Mobil Oil Corporation Alkali metal ion exchanged selectivated zeolite catalyst
US5849968A (en) * 1995-06-06 1998-12-15 Mobil Oil Corporation Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst
US6037513A (en) * 1998-07-09 2000-03-14 Mobil Oil Corporation Hydroalkylation of aromatic hydrocarbons
US6133470A (en) * 1998-07-28 2000-10-17 Mobil Oil Corporation Integration of p-xylene production and subsequent conversion process
WO2001047840A1 (en) * 1999-11-09 2001-07-05 Mobil Oil Corporation Hydroalkylation of aromatic hydrocarbons
ATE429412T1 (de) 2000-09-25 2009-05-15 Exxonmobil Chem Patents Inc Hydrierung von spaltungsprodukten bei der phenolherstellung
US20040030211A1 (en) * 2000-09-25 2004-02-12 Chung-Ming Chi Maximizing meta-isomers in the production of dialkylbenzene compounds
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
US6518471B1 (en) 2001-06-25 2003-02-11 Exxonmobil Chemical Patents Inc. Selective production of meta-diisopropylbenzene
EP2176200B1 (de) 2007-08-25 2011-09-07 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von cyclohexylbenzen
EP2200955B1 (de) 2007-09-21 2011-04-20 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von cyclohexylbenzol
KR101405687B1 (ko) 2007-09-21 2014-06-10 엑손모빌 케미칼 패턴츠 인코포레이티드 사이클로헥실벤젠의 제조방법
KR101123499B1 (ko) 2008-02-12 2012-06-12 엑손모빌 케미칼 패턴츠 인코포레이티드 사이클로헥실벤젠의 제조방법
CN101998942B (zh) * 2008-04-14 2016-02-03 埃克森美孚化学专利公司 制备环己基苯的工艺
WO2009134516A1 (en) * 2008-05-01 2009-11-05 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
CN102216215B (zh) * 2008-07-28 2014-03-26 埃克森美孚化学专利公司 使用emm-12制备烷基芳族化合物的方法
US8212096B2 (en) * 2008-07-28 2012-07-03 Exxonmobil Chemical Patents Inc. Hydroalkylation of aromatic compounds using EMM-13
JP2012517469A (ja) 2009-02-26 2012-08-02 エクソンモービル・ケミカル・パテンツ・インク シクロヘキシルベンゼンの製造方法
WO2011061204A1 (en) * 2009-11-18 2011-05-26 Shell Internationale Research Maatschappij B.V. Catalyst and isomerisation process
US8575055B2 (en) 2010-03-30 2013-11-05 Uop Llc Surface-modified zeolites and methods for preparing the same
US9545622B2 (en) 2010-10-11 2017-01-17 Exxonmobil Chemical Patents Inc. Activation and use of hydroalkylation catalysts
CN103261125B (zh) 2010-12-21 2016-03-30 埃克森美孚化学专利公司 生产单环烷基取代的芳族化合物的方法
CN104066704B (zh) 2011-10-17 2016-05-25 埃克森美孚化学专利公司 生产环己基苯的方法
US9458067B2 (en) 2012-02-08 2016-10-04 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
CN102942441B (zh) * 2012-11-27 2014-06-04 南京理工大学常熟研究院有限公司 一种烷基化合成对二甲苯的制备方法
KR102235872B1 (ko) * 2016-10-06 2021-04-06 엑손모빌 케미칼 패턴츠 인코포레이티드 방향족 탄화수소의 메틸화 방법
BR112019006868A2 (pt) * 2016-10-06 2019-06-25 Exxonmobil Chemical Patents Inc processo para seletivar catalisador para produzir paraxileno por metilação de benzeno e/ou tolueno
JP6905055B2 (ja) * 2016-10-06 2021-07-21 エクソンモービル・ケミカル・パテンツ・インク ベンゼンおよび／またはトルエンのメチル化によるパラキシレン製造プロセス
US11208365B2 (en) 2016-12-20 2021-12-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
SG11201909968SA (en) * 2017-04-27 2019-11-28 Dalian Inst Chemical Physics Cas In-situ preparation method for catalyst for preparing at least one of toluene, para-xylene and light olefins, and reaction process
WO2019104655A1 (zh) * 2017-11-30 2019-06-06 中国科学院大连化学物理研究所 分子筛催化剂改性装置及方法
US11130719B2 (en) 2017-12-05 2021-09-28 Uop Llc Processes and apparatuses for methylation of aromatics in an aromatics complex
US11130720B2 (en) 2018-03-23 2021-09-28 Uop Llc Processes for methylation of aromatics in an aromatics complex
CN112320815B (zh) * 2019-08-05 2023-05-30 中国石油化工股份有限公司 巯基功能化mcm分子筛的制备方法和应用
WO2023064683A1 (en) * 2021-10-12 2023-04-20 Exxonmobil Chemical Patents Inc. Catalyst and methods for producing xylene products rich in o-xylene

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126422A (en) * 1964-03-24 Temperature
US2722504A (en) * 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
US2904607A (en) * 1957-01-29 1959-09-15 Exxon Research Engineering Co Alkylation of aromatics
US3251897A (en) * 1962-12-20 1966-05-17 Socony Mobil Oil Co Inc Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst
US3413374A (en) * 1966-05-04 1968-11-26 Toyo Rayon Co Ltd Disproportionation of toluene
US3598879A (en) * 1968-12-19 1971-08-10 Ashland Oil Inc Alkyl transfer of alkyl aromatics with group i-a,ii-a,iv,or rare earth metals on boria alumina
US3607961A (en) * 1968-12-19 1971-09-21 Ashland Oil Inc Alkyl transfer of alkyl aromatics with group viii metals on boria-alumina
US3598878A (en) * 1968-12-19 1971-08-10 Ashland Oil Inc Alkyl transfer of alkyl aromatics with vanadium on zeolites
US3682996A (en) * 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US3751506A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst
US4029716A (en) * 1975-12-08 1977-06-14 Mobil Oil Corporation Selective production of para-xylene
US4060568A (en) * 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4090981A (en) * 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4100219A (en) * 1976-03-31 1978-07-11 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4097543A (en) * 1976-05-12 1978-06-27 Mobil Oil Corporation Selective disproportionation of toluene
US4117026A (en) * 1976-05-12 1978-09-26 Mobil Oil Corporation Selective production of para dialkyl substituted benzenes
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4145315A (en) * 1976-12-23 1979-03-20 Mobil Oil Corporation Silica-modified zeolite catalyst
US4283306A (en) * 1979-04-20 1981-08-11 E. I. Du Pont De Nemours And Company Crystalline silica and use in alkylation of aromatics
US4379761A (en) * 1981-01-08 1983-04-12 Mobil Oil Corporation Catalyst and process for making said catalyst
DE3117135A1 (de) * 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4477583A (en) * 1983-06-09 1984-10-16 Mobil Oil Corporation Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
US4465886A (en) * 1983-06-09 1984-08-14 Mobil Oil Corporation Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
US4548914A (en) * 1983-08-26 1985-10-22 Mobil Oil Corporation Zeolite catalysts of improved activity and para-selectivity
US4954663A (en) * 1988-10-06 1990-09-04 Mobil Oil Corp. Process for preparing long chain alkyl phenols
US4954325A (en) * 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US4962256A (en) * 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing long chain alkyl aromatic compounds
US4847435A (en) * 1987-06-24 1989-07-11 Maruzen Petrochemical Co., Ltd. Process for the recovery of high-purity m-ethylphenol
JPH0660117B2 (ja) * 1987-12-18 1994-08-10 丸善石油化学株式会社 パラエチルフェノールの製造方法
US4962257A (en) * 1988-10-06 1990-10-09 Mobil Oil Corp. Process for the catalytic disproportionation of toluene
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5043512A (en) * 1988-10-06 1991-08-27 Mobil Oil Corp. Alkylaromatic isomerization process
US5001295A (en) * 1988-10-06 1991-03-19 Mobil Oil Corp. Process for preparing dialkylnaphthalene
US4950835A (en) * 1989-10-24 1990-08-21 Taiwan Styrene Monomer Corporation Novel silicon-modified catalyst Si/HZSM-5, it's preparation, and a process for synthesizing high purity p-dialkyl benzene from monoalkyl benzene by using said catalyst
EP0457853B1 (de) * 1989-12-13 1997-08-06 Mobil Oil Corporation Verfahren zur katalytischen konversion einer c9+ -aromatischen charge
US5173461A (en) * 1990-03-21 1992-12-22 Mobil Oil Corporation Toluene disproportionation catalyst
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5321183A (en) * 1992-03-12 1994-06-14 Mobil Oil Corp. Process for the regioselective conversion of aromatics to para-disubstituted benzenes
US5365003A (en) * 1993-02-25 1994-11-15 Mobil Oil Corp. Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve
US5349113A (en) * 1993-02-25 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversion over pre-selectivated, activated catalyst
US5371312A (en) * 1993-04-05 1994-12-06 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
US5349114A (en) * 1993-04-05 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversions over modified catalyst
US5329059A (en) * 1993-07-06 1994-07-12 Mobil Oil Corp. Alkylaromatic disproportionation

Also Published As

Publication number Publication date
US5488194A (en) 1996-01-30
JPH10502908A (ja) 1998-03-17
AU2512795A (en) 1995-12-05
WO1995031421A1 (en) 1995-11-23
ES2135732T3 (es) 1999-11-01
EP0763001A1 (de) 1997-03-19
EP0763001A4 (de) 1997-05-02
DE69512053T2 (de) 1999-12-30
CA2187871A1 (en) 1995-11-23
EP0763001B1 (de) 1999-09-08
TW368495B (en) 1999-09-01
AU684368B2 (en) 1997-12-11

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee