DE69427134T2 - Verfahren zur herstellung vinylaromatischer polymerzusammensetzungen und katalysator zur herstellung von vinylaromatischen polymeren - Google Patents

Verfahren zur herstellung vinylaromatischer polymerzusammensetzungen und katalysator zur herstellung von vinylaromatischen polymeren

Info

Publication number
DE69427134T2
DE69427134T2 DE69427134T DE69427134T DE69427134T2 DE 69427134 T2 DE69427134 T2 DE 69427134T2 DE 69427134 T DE69427134 T DE 69427134T DE 69427134 T DE69427134 T DE 69427134T DE 69427134 T2 DE69427134 T2 DE 69427134T2
Authority
DE
Germany
Prior art keywords
flavored
producing vinyl
catalyst
polymer compositions
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69427134T
Other languages
English (en)
Other versions
DE69427134D1 (de
Inventor
Mizutomo Takeuchi
Hajime Shouzaki
Norio Tomotsu
Masahiko Kuramoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Publication of DE69427134D1 publication Critical patent/DE69427134D1/de
Application granted granted Critical
Publication of DE69427134T2 publication Critical patent/DE69427134T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69427134T 1993-07-23 1994-07-20 Verfahren zur herstellung vinylaromatischer polymerzusammensetzungen und katalysator zur herstellung von vinylaromatischen polymeren Expired - Fee Related DE69427134T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP18238893A JP3216748B2 (ja) 1993-07-23 1993-07-23 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
PCT/JP1994/001192 WO1995003339A1 (fr) 1993-07-23 1994-07-20 Catalyseur utilise pour produire une composition polymere a base d'un compose vinylique aromatique, et procede permettant de produire un polymere a base d'un compose vinylique aromatique au moyen dudit catalyseur

Publications (2)

Publication Number Publication Date
DE69427134D1 DE69427134D1 (de) 2001-05-23
DE69427134T2 true DE69427134T2 (de) 2001-09-06

Family

ID=16117446

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69427134T Expired - Fee Related DE69427134T2 (de) 1993-07-23 1994-07-20 Verfahren zur herstellung vinylaromatischer polymerzusammensetzungen und katalysator zur herstellung von vinylaromatischen polymeren

Country Status (5)

Country Link
US (1) US5670587A (de)
EP (1) EP0739906B1 (de)
JP (1) JP3216748B2 (de)
DE (1) DE69427134T2 (de)
WO (1) WO1995003339A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6087447A (en) * 1989-08-31 2000-07-11 The Dow Chemical Company Blends of substantially random interpolymers with vinyl or vinylidene aromatic polymers
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
JP3369294B2 (ja) * 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
WO1996020226A1 (de) * 1994-12-23 1996-07-04 WÜNSCH, Josef Verfahren zur herstellung von polymerisaten von vinylaromatischen verbindungen unter verwendung von mischungen von metallocenkatalysatorsystemen
DE19542356A1 (de) * 1995-11-14 1997-05-15 Basf Ag Verfahren zur Herstellung von Copolymerisaten aus vinylaromatischen und olefinischen Verbindungen durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen
US6194341B1 (en) * 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
CA2264736A1 (en) * 1996-09-04 1998-03-12 The Dow Chemical Company Blends containing an interpolymer of alpha-olefin
DE19724743A1 (de) * 1997-06-12 1998-12-24 Danubia Petrochem Polymere Blends aus Polyolefinen und Polyvinylaromaten
ZA9811512B (en) * 1997-12-16 2000-06-15 Dow Chemical Co Seals produced from alpha-olefin/vinylidene aromatic and/or hindered aliphatic vinylidene/interpolymer based materials and sealing systems therefrom.
TR200002668T2 (tr) * 1998-03-16 2001-02-21 The Dow Chemical Company Açık hücreli köpük ve imalat yöntemi.
AR022608A1 (es) * 1999-02-17 2002-09-04 Dow Chemical Co Producto interpolimerico aromatico de alfa-olefina/vinilo o vinilideno y proceso para su elaboracion mediante sistemas catalizadores multiples
KR100674760B1 (ko) * 1999-03-04 2007-01-25 리가가쿠 겐큐쇼 촉매 조성물
WO2000067899A1 (fr) * 1999-05-06 2000-11-16 Idemitsu Petrochemical Co., Ltd. Adsorbants issus de polymeres de styrenes
US6291386B1 (en) * 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
JP2002179714A (ja) * 2000-12-12 2002-06-26 Idemitsu Petrochem Co Ltd 重合体混合物の製造方法
KR100455844B1 (ko) * 2001-11-30 2004-11-06 삼성토탈 주식회사 스티렌계 공중합체 및 그 제조방법
KR100455842B1 (ko) * 2001-11-30 2004-11-06 삼성토탈 주식회사 스티렌계 공중합체 및 그 제조방법
KR100455843B1 (ko) * 2001-11-30 2004-11-06 삼성토탈 주식회사 스티렌계 공중합체 및 그 제조방법
KR100501398B1 (ko) * 2003-01-15 2005-07-18 삼성토탈 주식회사 긴가지를 갖는 α-올레핀/환상올레핀/디엔 공중합체 및 그제조방법
JP5259089B2 (ja) * 2007-01-22 2013-08-07 出光興産株式会社 ポリスチレン系樹脂組成物
GB201608384D0 (en) * 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2062657A (en) * 1979-11-02 1981-05-28 Malley P Preparation of alternating copolymers
US4935474A (en) * 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
IT1221654B (it) * 1987-11-27 1990-07-12 Ausimont Spa Catalizzatori per la polimerizzazione delle olefine
WO1990011305A1 (en) * 1989-03-20 1990-10-04 Idemitsu Kosan Co., Ltd. Styrenic copolymer and production thereof
US5340892A (en) * 1989-09-29 1994-08-23 Idemitsu Kosan Co., Ltd. Process for producing styrene polymers
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2939354B2 (ja) * 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2977930B2 (ja) * 1991-03-27 1999-11-15 出光興産株式会社 スチレン系共重合体の製造方法
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
JP2988071B2 (ja) * 1991-10-14 1999-12-06 東ソー株式会社 芳香族ビニル化合物重合用触媒および芳香族ビニル化合物重合体の製造方法
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒

Also Published As

Publication number Publication date
US5670587A (en) 1997-09-23
DE69427134D1 (de) 2001-05-23
EP0739906A1 (de) 1996-10-30
EP0739906A4 (de) 1997-05-07
JPH0733813A (ja) 1995-02-03
WO1995003339A1 (fr) 1995-02-02
EP0739906B1 (de) 2001-04-18
JP3216748B2 (ja) 2001-10-09

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee