DE69404160T2 - Verfahren zur herstellung von syndiotaktischen vinylaromatischen polymeren unter verwendung von reduzierten metallkationischen katalysatoren - Google Patents
Verfahren zur herstellung von syndiotaktischen vinylaromatischen polymeren unter verwendung von reduzierten metallkationischen katalysatorenInfo
- Publication number
- DE69404160T2 DE69404160T2 DE69404160T DE69404160T DE69404160T2 DE 69404160 T2 DE69404160 T2 DE 69404160T2 DE 69404160 T DE69404160 T DE 69404160T DE 69404160 T DE69404160 T DE 69404160T DE 69404160 T2 DE69404160 T2 DE 69404160T2
- Authority
- DE
- Germany
- Prior art keywords
- reduced metal
- cationic catalysts
- vinylaromatic polymers
- metal cationic
- producing syndiotactic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011951 cationic catalyst Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13335693A | 1993-10-08 | 1993-10-08 | |
PCT/US1994/009732 WO1995010549A1 (en) | 1993-10-08 | 1994-08-30 | Process for preparation of syndiotactic vinyl aromatic polymers using reduced metal catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69404160D1 DE69404160D1 (de) | 1997-08-14 |
DE69404160T2 true DE69404160T2 (de) | 1998-01-08 |
Family
ID=22458212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69404160T Expired - Fee Related DE69404160T2 (de) | 1993-10-08 | 1994-08-30 | Verfahren zur herstellung von syndiotaktischen vinylaromatischen polymeren unter verwendung von reduzierten metallkationischen katalysatoren |
Country Status (6)
Country | Link |
---|---|
US (1) | US5512643A (de) |
EP (1) | EP0722466B1 (de) |
JP (1) | JPH09504816A (de) |
DE (1) | DE69404160T2 (de) |
MX (1) | MXPA94007798A (de) |
WO (1) | WO1995010549A1 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE37064E1 (en) * | 1994-03-31 | 2001-02-20 | Idemitsu Kosan Co., Ltd. | Process for producing styrenic polymer |
US5756612A (en) * | 1995-03-30 | 1998-05-26 | Idemitsu Kosan Co., Ltd. | Process for producing styrenic polymer |
BR9509457A (pt) * | 1994-10-31 | 1998-01-06 | Dsm Nv | Composição catalítica e processo para a polimerização de uma olefina |
WO1997042233A1 (en) * | 1996-05-03 | 1997-11-13 | Dsm N.V. | Process for the polymerization of vinyl aromatic monomers |
KR100474129B1 (ko) * | 1996-05-07 | 2005-08-17 | 다우 글로벌 테크놀로지스 인크. | 비닐리덴방향족단량체의신디오택틱중합체의제조방법 |
US6191197B1 (en) | 1996-09-23 | 2001-02-20 | Bridgestone Corporation | Extended polymer compostion derived from blends of elastomers and syndiotactic polystyrene |
US6329459B1 (en) | 1996-09-23 | 2001-12-11 | Bridgestone Corporation | Extended syndiotactic polystyrene-elastomeric block copolymers |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62187708A (ja) * | 1985-11-11 | 1987-08-17 | Idemitsu Kosan Co Ltd | スチレン系重合体の製造法 |
JP2911501B2 (ja) * | 1989-09-29 | 1999-06-23 | 出光興産株式会社 | スチレン系重合体の製造方法 |
US5340892A (en) * | 1989-09-29 | 1994-08-23 | Idemitsu Kosan Co., Ltd. | Process for producing styrene polymers |
US5066741A (en) * | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
EP0505997B1 (de) * | 1991-03-29 | 1997-05-28 | Idemitsu Kosan Company Limited | Verfahren zur Herstellung eines Homo- oder Copolymerisates des Styrols |
FR2679741B1 (fr) * | 1991-08-01 | 1993-11-19 | Charles Ballenegger | Fermoir pour chaine de perles. |
-
1994
- 1994-08-30 WO PCT/US1994/009732 patent/WO1995010549A1/en active IP Right Grant
- 1994-08-30 JP JP7511781A patent/JPH09504816A/ja not_active Ceased
- 1994-08-30 DE DE69404160T patent/DE69404160T2/de not_active Expired - Fee Related
- 1994-08-30 EP EP94927266A patent/EP0722466B1/de not_active Expired - Lifetime
- 1994-10-07 MX MXPA94007798A patent/MXPA94007798A/es unknown
-
1995
- 1995-08-11 US US08/514,060 patent/US5512643A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69404160D1 (de) | 1997-08-14 |
JPH09504816A (ja) | 1997-05-13 |
MXPA94007798A (es) | 2002-06-19 |
WO1995010549A1 (en) | 1995-04-20 |
US5512643A (en) | 1996-04-30 |
EP0722466A1 (de) | 1996-07-24 |
EP0722466B1 (de) | 1997-07-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: THE DOW CHEMICAL CO., MIDLAND, MICH., US IDEMITSU |
|
8339 | Ceased/non-payment of the annual fee |