DE69403090T2 - Entfernung von argon in einem verfahren zur herstellung von ethylenoxid - Google Patents
Entfernung von argon in einem verfahren zur herstellung von ethylenoxidInfo
- Publication number
- DE69403090T2 DE69403090T2 DE69403090T DE69403090T DE69403090T2 DE 69403090 T2 DE69403090 T2 DE 69403090T2 DE 69403090 T DE69403090 T DE 69403090T DE 69403090 T DE69403090 T DE 69403090T DE 69403090 T2 DE69403090 T2 DE 69403090T2
- Authority
- DE
- Germany
- Prior art keywords
- stream
- argon
- reactor
- membrane
- methane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 20
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000012528 membrane Substances 0.000 claims description 44
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 41
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 38
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 35
- 229910052786 argon Inorganic materials 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 18
- 239000012466 permeate Substances 0.000 claims description 18
- 239000001569 carbon dioxide Substances 0.000 claims description 17
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 17
- 239000012465 retentate Substances 0.000 claims description 12
- 238000011010 flushing procedure Methods 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 238000010926 purge Methods 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 6
- 238000000926 separation method Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000012510 hollow fiber Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229920002492 poly(sulfone) Polymers 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- -1 polydimethylsiloxane Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/32—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93202726 | 1993-09-20 | ||
| PCT/EP1994/003144 WO1995008545A1 (en) | 1993-09-20 | 1994-09-19 | Argon removal in a process for ethylene oxide production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69403090D1 DE69403090D1 (de) | 1997-06-12 |
| DE69403090T2 true DE69403090T2 (de) | 1997-10-02 |
Family
ID=8214110
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69403090T Expired - Fee Related DE69403090T2 (de) | 1993-09-20 | 1994-09-19 | Entfernung von argon in einem verfahren zur herstellung von ethylenoxid |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5519152A (enExample) |
| EP (1) | EP0720606B1 (enExample) |
| JP (1) | JPH09503758A (enExample) |
| KR (1) | KR100354431B1 (enExample) |
| CN (1) | CN1131419A (enExample) |
| AU (1) | AU678062B2 (enExample) |
| CA (1) | CA2172064C (enExample) |
| DE (1) | DE69403090T2 (enExample) |
| ES (1) | ES2102886T3 (enExample) |
| SG (1) | SG59960A1 (enExample) |
| TW (1) | TW314512B (enExample) |
| WO (1) | WO1995008545A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6040467A (en) * | 1997-07-24 | 2000-03-21 | Praxair Technology, Inc. | High purity oxygen for ethylene oxide production |
| US6667409B2 (en) | 2001-09-27 | 2003-12-23 | Praxair Technology, Inc. | Process and apparatus for integrating an alkene derivative process with an ethylene process |
| MY136774A (en) * | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
| MY146505A (en) * | 2003-02-28 | 2012-08-15 | Shell Int Research | A method of manufacturing ethylene oxide |
| EP1841718B1 (en) * | 2004-12-30 | 2014-06-25 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of lower olefins from heavy wax |
| KR20070093139A (ko) * | 2004-12-31 | 2007-09-17 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 통합적 제조 및 분리 방법 |
| CA2758818C (en) * | 2009-04-21 | 2018-05-29 | Dow Technology Investments Llc | Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages |
| CA2759496C (en) * | 2009-04-21 | 2018-05-01 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
| US8362284B2 (en) * | 2009-04-21 | 2013-01-29 | Dow Technology Investments Llc | Method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
| JP2012522061A (ja) * | 2009-12-28 | 2012-09-20 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法 |
| WO2020012268A1 (en) | 2018-07-13 | 2020-01-16 | Sabic Global Technologies B.V. | Process for separating carbon dioxide and argon from hydrocarbons |
| CN110201487B (zh) * | 2019-06-24 | 2021-06-25 | 浙江天采云集科技股份有限公司 | 一种乙烯法制环氧乙烷中高纯度高收率甲烷致稳气净化与再利用方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3337572A1 (de) * | 1983-10-15 | 1985-04-25 | Linde Ag, 6200 Wiesbaden | Verfahren und vorrichtung zum abtrennen einer komponente aus einem gasgemisch |
| IN165859B (enExample) * | 1985-05-01 | 1990-01-27 | Halcon Sd Group Inc | |
| US4879396A (en) * | 1985-05-01 | 1989-11-07 | Scientific Design Company, Inc. | Selective extraction of CO2 and argon from ethylene oxide recycle system |
| US4834779A (en) * | 1986-10-27 | 1989-05-30 | Liquid Air Corporation | Process for membrane seperation of gas mixtures |
| US5084073A (en) * | 1990-10-11 | 1992-01-28 | Union Carbide Industrial Gases Technology Corporation | Membrane drying process and system |
| US5233060A (en) * | 1992-08-13 | 1993-08-03 | The Dow Chemical Company | Ethylene recovery in direct-oxidation ethylene oxide processes |
-
1994
- 1994-09-01 TW TW083108055A patent/TW314512B/zh not_active IP Right Cessation
- 1994-09-19 EP EP94928382A patent/EP0720606B1/en not_active Expired - Lifetime
- 1994-09-19 WO PCT/EP1994/003144 patent/WO1995008545A1/en not_active Ceased
- 1994-09-19 KR KR1019960701419A patent/KR100354431B1/ko not_active Expired - Lifetime
- 1994-09-19 ES ES94928382T patent/ES2102886T3/es not_active Expired - Lifetime
- 1994-09-19 SG SG1996005641A patent/SG59960A1/en unknown
- 1994-09-19 CN CN94193443A patent/CN1131419A/zh active Pending
- 1994-09-19 CA CA002172064A patent/CA2172064C/en not_active Expired - Fee Related
- 1994-09-19 AU AU77831/94A patent/AU678062B2/en not_active Ceased
- 1994-09-19 DE DE69403090T patent/DE69403090T2/de not_active Expired - Fee Related
- 1994-09-19 JP JP7509562A patent/JPH09503758A/ja active Pending
-
1995
- 1995-04-05 US US08/417,481 patent/US5519152A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2172064C (en) | 2005-06-14 |
| TW314512B (enExample) | 1997-09-01 |
| SG59960A1 (en) | 1999-02-22 |
| DE69403090D1 (de) | 1997-06-12 |
| EP0720606B1 (en) | 1997-05-07 |
| CA2172064A1 (en) | 1995-03-30 |
| WO1995008545A1 (en) | 1995-03-30 |
| AU678062B2 (en) | 1997-05-15 |
| JPH09503758A (ja) | 1997-04-15 |
| US5519152A (en) | 1996-05-21 |
| AU7783194A (en) | 1995-04-10 |
| CN1131419A (zh) | 1996-09-18 |
| ES2102886T3 (es) | 1997-08-01 |
| EP0720606A1 (en) | 1996-07-10 |
| KR100354431B1 (ko) | 2002-12-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |