DE69314058T2 - Hochwirksame, wasserstoffbetriebene kühlvorrichtung - Google Patents
Hochwirksame, wasserstoffbetriebene kühlvorrichtungInfo
- Publication number
- DE69314058T2 DE69314058T2 DE69314058T DE69314058T DE69314058T2 DE 69314058 T2 DE69314058 T2 DE 69314058T2 DE 69314058 T DE69314058 T DE 69314058T DE 69314058 T DE69314058 T DE 69314058T DE 69314058 T2 DE69314058 T2 DE 69314058T2
- Authority
- DE
- Germany
- Prior art keywords
- heat
- working medium
- reaction
- catalyst
- organic hydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000001816 cooling Methods 0.000 title claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 58
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 48
- 150000004678 hydrides Chemical class 0.000 claims description 46
- 239000003054 catalyst Substances 0.000 claims description 44
- 239000012530 fluid Substances 0.000 claims description 37
- 239000007789 gas Substances 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- 238000004891 communication Methods 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 238000002485 combustion reaction Methods 0.000 claims description 13
- 229910052697 platinum Inorganic materials 0.000 claims description 11
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052703 rhodium Inorganic materials 0.000 claims description 10
- 229910052707 ruthenium Inorganic materials 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229910052702 rhenium Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000003990 capacitor Substances 0.000 claims 2
- 230000005587 bubbling Effects 0.000 claims 1
- 239000000047 product Substances 0.000 description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 6
- 230000001143 conditioned effect Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 238000005057 refrigeration Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229910001510 metal chloride Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229910019891 RuCl3 Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910020427 K2PtCl4 Inorganic materials 0.000 description 1
- 229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- DHCWLIOIJZJFJE-UHFFFAOYSA-L dichlororuthenium Chemical compound Cl[Ru]Cl DHCWLIOIJZJFJE-UHFFFAOYSA-L 0.000 description 1
- 101150109949 endou gene Proteins 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B27/00—Machines, plants or systems, using particular sources of energy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/035,812 US5291735A (en) | 1993-03-23 | 1993-03-23 | High efficiency, hydrogen-driven cooling device |
| PCT/US1993/011037 WO1994021974A1 (en) | 1993-03-23 | 1993-11-15 | High efficiency, hydrogen-driven cooling device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69314058D1 DE69314058D1 (de) | 1997-10-23 |
| DE69314058T2 true DE69314058T2 (de) | 1998-04-09 |
Family
ID=21884921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69314058T Expired - Fee Related DE69314058T2 (de) | 1993-03-23 | 1993-11-15 | Hochwirksame, wasserstoffbetriebene kühlvorrichtung |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5291735A (enExample) |
| EP (1) | EP0688418B1 (enExample) |
| JP (1) | JPH08507360A (enExample) |
| KR (1) | KR960701345A (enExample) |
| BR (1) | BR9307828A (enExample) |
| CA (1) | CA2158971A1 (enExample) |
| DE (1) | DE69314058T2 (enExample) |
| ES (1) | ES2108414T3 (enExample) |
| TW (1) | TW241329B (enExample) |
| WO (1) | WO1994021974A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4410914C2 (de) * | 1994-03-29 | 1996-03-28 | Daimler Benz Aerospace Ag | Vorrichtung zum Abführen von Wärme |
| RU2159396C1 (ru) * | 1999-12-03 | 2000-11-20 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная система с регенерацией топлива |
| RU2168680C1 (ru) * | 2000-02-28 | 2001-06-10 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная установка |
| RU2169319C1 (ru) * | 2000-05-25 | 2001-06-20 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергоустановка с двигателем стирлинга и водородосодержащим топливом |
| RU2166706C1 (ru) * | 2000-05-25 | 2001-05-10 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная система |
| US7186396B2 (en) * | 2003-11-26 | 2007-03-06 | Asemblon, Inc. | Method for hydrogen storage and delivery |
| US7181919B2 (en) * | 2004-03-31 | 2007-02-27 | Denso Corporation | System utilizing waste heat of internal combustion engine |
| US7574870B2 (en) * | 2006-07-20 | 2009-08-18 | Claudio Filippone | Air-conditioning systems and related methods |
| CL2009000917A1 (es) * | 2008-04-17 | 2010-07-02 | K Sortore Christopher | Una maquina que comprende un rotor con una pluralidad de imanes permanentes de tierras raras,retenidos en el rotor por medio de un casquillo cilindrico, el casquillo es retenido por medio de una banda que posee una pluralidad apilada de laminaciones de arandelas, estando cada laminacion aislada electricamente. |
| MX2010011348A (es) | 2008-04-18 | 2011-05-23 | Synchrony Inc | Cojinete de empuje magnetico con elementos electronicos integrados. |
| US9583991B2 (en) * | 2009-06-24 | 2017-02-28 | Synchrony, Inc. | Systems, devices, and/or methods for managing magnetic bearings |
| WO2011163456A1 (en) | 2010-06-23 | 2011-12-29 | Synchrony, Inc. | Split magnetic thrust bearing |
| JP5602698B2 (ja) * | 2011-09-22 | 2014-10-08 | 株式会社日立製作所 | 動力変換システム |
| KR101360003B1 (ko) * | 2012-04-25 | 2014-02-24 | 한국수력원자력 주식회사 | 발열 및 흡열을 동시에 제어할 수 있는 수소저장용기 |
| KR101569677B1 (ko) | 2015-02-04 | 2015-11-17 | 한국기계연구원 | 고희박연소를 이용한 트라이젠 시스템 및 그 제어방법 |
| IT201700098472A1 (it) * | 2017-09-01 | 2019-03-01 | Angelantoni Test Tech S R L In Breve Att S R L | Dispositivo di refrigerazione. |
| US11111448B1 (en) | 2018-01-18 | 2021-09-07 | Reaction Systems Inc. | Decahydronaphthalene as an endothermic fuel for hypersonic vehicles |
| US11697780B1 (en) * | 2018-01-18 | 2023-07-11 | Reaction Systems, Inc. | Decahydronaphthalene as an endothermic fuel for hypersonic vehicles |
| FR3097218B1 (fr) * | 2019-06-14 | 2022-05-06 | Alagy Serge Zareh | Procede et systeme de recuperation d’energie pour dispositif consommateur de dihydrogene |
| IT202300015141A1 (it) * | 2023-07-19 | 2025-01-19 | Nuovo Pignone Tecnologie Srl | Processo e sistema di produzione di idrogeno senza ossidi di carbonio |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2034412B (en) * | 1978-09-20 | 1982-11-10 | Chatwin F | Combined gas and steam turbine engine |
| US4347711A (en) * | 1980-07-25 | 1982-09-07 | The Garrett Corporation | Heat-actuated space conditioning unit with bottoming cycle |
| US4346752A (en) * | 1981-01-19 | 1982-08-31 | United Technologies Corporation | Self-driven chemical heat pipe |
| US4476918A (en) * | 1982-06-28 | 1984-10-16 | United Technologies Corporation | Method and apparatus for a temperature-shifted chemical heat pipe |
| US4478814A (en) * | 1982-09-30 | 1984-10-23 | United Technologies Corporation | Gas transporting system |
| US4567033A (en) * | 1984-10-25 | 1986-01-28 | United Technologies Corporation | Low-energy method for freeing chemically bound hydrogen |
| US4614176A (en) * | 1985-10-23 | 1986-09-30 | United Technologies Corporation | Catalytic metal hydride space heater |
| ES2018470B3 (es) * | 1986-03-25 | 1991-04-16 | Mitsui Shipbuilding Eng | Bomba de calor, metodo de recuperacion de energia y metodo para reducir la potencia de accionamiento del compresor en la bomba de carlor. |
| AU7396287A (en) * | 1986-05-19 | 1987-12-22 | Yamato Kosan Co., Ltd. | Heat exchanging system |
| US4712610A (en) * | 1986-11-28 | 1987-12-15 | United Technologies Corporation | Chemical heat pipe employing self-driven chemical pump based on a molar increase |
| US4754607A (en) * | 1986-12-12 | 1988-07-05 | Allied-Signal Inc. | Power generating system |
| US4942733A (en) * | 1987-03-26 | 1990-07-24 | Sundstrand Corporation | Hot gas generator system |
| US4999993A (en) * | 1987-11-25 | 1991-03-19 | Fluor Corporation | Reactor expander topping cycle |
| US4850859A (en) * | 1988-09-30 | 1989-07-25 | United Technologies Corporation | Liquid fueled hydrogen heater |
| SE468910B (sv) * | 1989-04-18 | 1993-04-05 | Gen Electric | Kraftaggregat, vid vilket halten av skadliga foeroreningar i avgaserna minskas |
| US5129236A (en) * | 1990-09-06 | 1992-07-14 | Solomon Fred D | Heat pump system |
| US5136854A (en) * | 1991-01-25 | 1992-08-11 | Abdelmalek Fawzy T | Centrifugal gas compressor - expander for refrigeration |
-
1993
- 1993-03-23 US US08/035,812 patent/US5291735A/en not_active Expired - Fee Related
- 1993-11-15 WO PCT/US1993/011037 patent/WO1994021974A1/en not_active Ceased
- 1993-11-15 CA CA002158971A patent/CA2158971A1/en not_active Abandoned
- 1993-11-15 BR BR9307828A patent/BR9307828A/pt not_active Application Discontinuation
- 1993-11-15 JP JP6514575A patent/JPH08507360A/ja active Pending
- 1993-11-15 EP EP94901495A patent/EP0688418B1/en not_active Expired - Lifetime
- 1993-11-15 ES ES94901495T patent/ES2108414T3/es not_active Expired - Lifetime
- 1993-11-15 KR KR1019950704046A patent/KR960701345A/ko not_active Withdrawn
- 1993-11-15 DE DE69314058T patent/DE69314058T2/de not_active Expired - Fee Related
- 1993-11-19 TW TW082109759A patent/TW241329B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0688418A1 (en) | 1995-12-27 |
| WO1994021974A1 (en) | 1994-09-29 |
| CA2158971A1 (en) | 1994-09-29 |
| TW241329B (enExample) | 1995-02-21 |
| KR960701345A (ko) | 1996-02-24 |
| ES2108414T3 (es) | 1997-12-16 |
| BR9307828A (pt) | 1995-11-14 |
| EP0688418B1 (en) | 1997-09-17 |
| JPH08507360A (ja) | 1996-08-06 |
| DE69314058D1 (de) | 1997-10-23 |
| US5291735A (en) | 1994-03-08 |
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