DE69303786T2 - Kryogenische Flüssigkeitsabgabegerät und Verfahren - Google Patents
Kryogenische Flüssigkeitsabgabegerät und VerfahrenInfo
- Publication number
- DE69303786T2 DE69303786T2 DE69303786T DE69303786T DE69303786T2 DE 69303786 T2 DE69303786 T2 DE 69303786T2 DE 69303786 T DE69303786 T DE 69303786T DE 69303786 T DE69303786 T DE 69303786T DE 69303786 T2 DE69303786 T2 DE 69303786T2
- Authority
- DE
- Germany
- Prior art keywords
- liquid coolant
- dispensing
- dispensing passage
- flow
- passage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 11
- 239000012530 fluid Substances 0.000 title 1
- 239000007788 liquid Substances 0.000 claims description 123
- 239000002826 coolant Substances 0.000 claims description 120
- 238000010438 heat treatment Methods 0.000 claims description 28
- 238000009835 boiling Methods 0.000 claims description 23
- 238000005191 phase separation Methods 0.000 claims description 16
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000002706 hydrostatic effect Effects 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 230000003252 repetitive effect Effects 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000002470 thermal conductor Substances 0.000 description 13
- 239000000523 sample Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 238000012546 transfer Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-NJFSPNSNSA-N nitrogen-16 Chemical compound [16NH3] QGZKDVFQNNGYKY-NJFSPNSNSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000005931 tert-butyloxycarbonyl group Chemical group [H]C([H])([H])C(OC(*)=O)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17D—PIPE-LINE SYSTEMS; PIPE-LINES
- F17D1/00—Pipe-line systems
- F17D1/08—Pipe-line systems for liquids or viscous products
- F17D1/082—Pipe-line systems for liquids or viscous products for cold fluids, e.g. liquefied gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/006—Adding fluids for preventing deformation of filled and closed containers or wrappers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/021—Special adaptations of indicating, measuring, or monitoring equipment having the height as the parameter
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/03—Thermal insulations
- F17C2203/0304—Thermal insulations by solid means
- F17C2203/0329—Foam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0612—Wall structures
- F17C2203/0626—Multiple walls
- F17C2203/0629—Two walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0123—Mounting arrangements characterised by number of vessels
- F17C2205/013—Two or more vessels
- F17C2205/0149—Vessel mounted inside another one
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
- F17C2205/0326—Valves electrically actuated
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/014—Nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0304—Heat exchange with the fluid by heating using an electric heater
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/03—Control means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/03—Control means
- F17C2250/032—Control means using computers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0404—Parameters indicated or measured
- F17C2250/0408—Level of content in the vessel
- F17C2250/0417—Level of content in the vessel with electrical means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/02—Improving properties related to fluid or fluid transfer
- F17C2260/024—Improving metering
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- Water Supply & Treatment (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Loading And Unloading Of Fuel Tanks Or Ships (AREA)
- Pipeline Systems (AREA)
- Monitoring And Testing Of Nuclear Reactors (AREA)
- Sampling And Sample Adjustment (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/936,429 US5272881A (en) | 1992-08-27 | 1992-08-27 | Liquid cryogen dispensing apparatus and method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69303786D1 DE69303786D1 (de) | 1996-08-29 |
| DE69303786T2 true DE69303786T2 (de) | 1996-11-28 |
Family
ID=25468619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69303786T Expired - Fee Related DE69303786T2 (de) | 1992-08-27 | 1993-08-09 | Kryogenische Flüssigkeitsabgabegerät und Verfahren |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5272881A (enExample) |
| EP (1) | EP0589562B1 (enExample) |
| JP (1) | JPH06193800A (enExample) |
| KR (1) | KR940003836A (enExample) |
| CN (1) | CN1034760C (enExample) |
| AU (1) | AU665263B2 (enExample) |
| CA (1) | CA2103615C (enExample) |
| DE (1) | DE69303786T2 (enExample) |
| NZ (1) | NZ248480A (enExample) |
| PL (1) | PL172549B1 (enExample) |
| TW (1) | TW255952B (enExample) |
| ZA (1) | ZA935810B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2696152B1 (fr) * | 1992-09-29 | 1994-10-28 | Air Liquide | Procédé et dispositif de distribution de doses de liquide, notamment de gaz liquéfié. |
| GB9309637D0 (en) * | 1993-05-11 | 1993-06-23 | Boc Group Plc | Cryogenic liquid dispensers |
| US5385025A (en) * | 1994-03-04 | 1995-01-31 | Mg Industries | Apparatus and method for dispensing droplets of a cryogenic liquid |
| US5557924A (en) * | 1994-09-20 | 1996-09-24 | Vacuum Barrier Corporation | Controlled delivery of filtered cryogenic liquid |
| DE102007016712A1 (de) * | 2007-04-04 | 2008-10-09 | Air Liquide Deutschland Gmbh | Verfahren und Vorrichtung zum Kühlen einer Flüssigkeit |
| TWI334043B (en) | 2007-05-09 | 2010-12-01 | Au Optronics Corp | Direct-type backlight module and lamp holder thereof |
| DE102009023320B3 (de) * | 2009-05-29 | 2010-12-09 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Vorrichtungen und Verfahren zur Zuführung eines verflüssigten Gases in ein Gefäß |
| US20120159969A1 (en) * | 2009-07-22 | 2012-06-28 | Lo Solutions Gmbh | Method for charging evaporators with cryogenically liquefied gases, and a device for carrying out said method |
| US20110179667A1 (en) * | 2009-09-17 | 2011-07-28 | Lee Ron C | Freeze drying system |
| US9618257B2 (en) * | 2010-06-09 | 2017-04-11 | Quantum Design International, Inc. | Gas-flow cryostat for dynamic temperature regulation using a fluid level sensor |
| JP5529190B2 (ja) | 2012-03-02 | 2014-06-25 | 株式会社コスモライフ | ウォーターサーバー |
| EP2915624A1 (en) * | 2014-03-05 | 2015-09-09 | 5Me Ip, Llc | Method for subcooling liquid cryogen used by cutting tools |
| DE102024114205A1 (de) * | 2024-05-21 | 2025-11-27 | Krones Aktiengesellschaft | Vorrichtung und Verfahren zum Abgeben eines verflüssigten Fluids in ein Behältnis |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE399753B (sv) * | 1976-06-01 | 1978-02-27 | Aga Ab | Anordning for att fylla en vetska fran en forradsbehallare till ett kerl |
| FR2396920A1 (fr) * | 1977-07-05 | 1979-02-02 | Air Liquide | Dispositif d'injection controlee de fluide cryogenique |
| DE3402292C2 (de) * | 1984-01-24 | 1986-01-23 | Messer Griesheim Gmbh, 6000 Frankfurt | Verfahren und Vorrichtung zum Dosieren kleiner Mengen eines tiefsiedenden, verflüssigten Gases |
| US4608831A (en) * | 1984-10-24 | 1986-09-02 | Gustafson Keith W | Self-pressurizing container for cryogenic fluids |
| US4715187A (en) * | 1986-09-29 | 1987-12-29 | Vacuum Barrier Corporation | Controlled cryogenic liquid delivery |
| US4791788A (en) * | 1987-08-24 | 1988-12-20 | Quantum Design, Inc. | Method for obtaining improved temperature regulation when using liquid helium cooling |
| GB2215446B (en) * | 1988-02-29 | 1992-09-30 | Air Prod & Chem | Dispenser for dispensing cryogenic fluid |
| US4854128A (en) * | 1988-03-22 | 1989-08-08 | Zeamer Corporation | Cryogen supply system |
| US5060481A (en) * | 1989-07-20 | 1991-10-29 | Helix Technology Corporation | Method and apparatus for controlling a cryogenic refrigeration system |
| US5018358A (en) * | 1990-03-20 | 1991-05-28 | The Boc Group, Inc. | Cryogen delivery apparatus |
| DE4030546A1 (de) * | 1990-09-27 | 1992-04-02 | Linde Ag | Vorrichtung zum dosieren von tiefsiedenden verfluessigten gasen |
| CN107949909B (zh) * | 2015-08-31 | 2020-06-16 | 爱信艾达株式会社 | 半导体装置、芯片模块及半导体模块 |
-
1992
- 1992-08-27 US US07/936,429 patent/US5272881A/en not_active Expired - Fee Related
-
1993
- 1993-07-30 TW TW082106103A patent/TW255952B/zh active
- 1993-08-09 DE DE69303786T patent/DE69303786T2/de not_active Expired - Fee Related
- 1993-08-09 CA CA002103615A patent/CA2103615C/en not_active Expired - Fee Related
- 1993-08-09 EP EP93306262A patent/EP0589562B1/en not_active Expired - Lifetime
- 1993-08-10 ZA ZA935810A patent/ZA935810B/xx unknown
- 1993-08-20 AU AU44784/93A patent/AU665263B2/en not_active Ceased
- 1993-08-24 NZ NZ248480A patent/NZ248480A/en unknown
- 1993-08-25 PL PL93300192A patent/PL172549B1/pl unknown
- 1993-08-26 KR KR1019930016733A patent/KR940003836A/ko not_active Ceased
- 1993-08-27 JP JP5212707A patent/JPH06193800A/ja active Pending
- 1993-08-27 CN CN93109920A patent/CN1034760C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ZA935810B (en) | 1994-06-10 |
| PL172549B1 (pl) | 1997-10-31 |
| DE69303786D1 (de) | 1996-08-29 |
| CA2103615C (en) | 1996-11-05 |
| CA2103615A1 (en) | 1994-02-28 |
| AU665263B2 (en) | 1995-12-21 |
| EP0589562B1 (en) | 1996-07-24 |
| US5272881A (en) | 1993-12-28 |
| JPH06193800A (ja) | 1994-07-15 |
| TW255952B (enExample) | 1995-09-01 |
| NZ248480A (en) | 1994-12-22 |
| CN1034760C (zh) | 1997-04-30 |
| CN1084819A (zh) | 1994-04-06 |
| KR940003836A (ko) | 1994-03-12 |
| EP0589562A1 (en) | 1994-03-30 |
| AU4478493A (en) | 1994-03-03 |
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