DE69224728T2 - Verfahren und Zusammensetzung zur Förderung von Hydrosilylierungsreaktionen unter Verwendung sterisch gehinderter Stickstoff- und phosphorhaltiger Verbindungen - Google Patents

Verfahren und Zusammensetzung zur Förderung von Hydrosilylierungsreaktionen unter Verwendung sterisch gehinderter Stickstoff- und phosphorhaltiger Verbindungen

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Publication number
DE69224728T2
DE69224728T2 DE69224728T DE69224728T DE69224728T2 DE 69224728 T2 DE69224728 T2 DE 69224728T2 DE 69224728 T DE69224728 T DE 69224728T DE 69224728 T DE69224728 T DE 69224728T DE 69224728 T2 DE69224728 T2 DE 69224728T2
Authority
DE
Germany
Prior art keywords
carbon atoms
arylalkyl
derivative
alkyl
promoter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69224728T
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English (en)
Other versions
DE69224728D1 (de
Inventor
Kunj Ramalal Mehta
James Dale Reedy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
OSI Specialties Inc
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Filing date
Publication date
Application filed by OSI Specialties Inc filed Critical OSI Specialties Inc
Publication of DE69224728D1 publication Critical patent/DE69224728D1/de
Application granted granted Critical
Publication of DE69224728T2 publication Critical patent/DE69224728T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0801—General processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/14—Preparation thereof from optionally substituted halogenated silanes and hydrocarbons hydrosilylation reactions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Silicon Polymers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69224728T 1991-12-30 1992-12-29 Verfahren und Zusammensetzung zur Förderung von Hydrosilylierungsreaktionen unter Verwendung sterisch gehinderter Stickstoff- und phosphorhaltiger Verbindungen Expired - Lifetime DE69224728T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/815,821 US5191103A (en) 1991-12-30 1991-12-30 Process and composition for promoting hydrosilylation reactions using sterically hindered nitrogen-containing and phosphorus-containing compounds

Publications (2)

Publication Number Publication Date
DE69224728D1 DE69224728D1 (de) 1998-04-16
DE69224728T2 true DE69224728T2 (de) 1998-07-02

Family

ID=25218936

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69224728T Expired - Lifetime DE69224728T2 (de) 1991-12-30 1992-12-29 Verfahren und Zusammensetzung zur Förderung von Hydrosilylierungsreaktionen unter Verwendung sterisch gehinderter Stickstoff- und phosphorhaltiger Verbindungen

Country Status (4)

Country Link
US (1) US5191103A (de)
EP (1) EP0550064B1 (de)
AT (1) ATE163935T1 (de)
DE (1) DE69224728T2 (de)

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GB9223335D0 (en) * 1992-11-06 1992-12-23 Dow Corning Hydrosilylation process
JPH08143778A (ja) * 1994-11-18 1996-06-04 Kanegafuchi Chem Ind Co Ltd ヒドロシリル化法及びそれを利用した硬化剤の製造方法
US5449802A (en) * 1994-12-27 1995-09-12 Dow Corning Corporation Acetylenic alcohols and ethers as accelerators for hydrosilation
JP2978435B2 (ja) * 1996-01-24 1999-11-15 チッソ株式会社 アクリロキシプロピルシランの製造方法
US5856369A (en) * 1996-07-30 1999-01-05 Osi Specialties, Inc. Polyethers and polysiloxane copolymers manufactured with double metal cyanide catalysts
US6071977A (en) * 1996-10-31 2000-06-06 Ck Witco Corporation Hydrosilation in high boiling natural vegetable oils
US5986122A (en) * 1996-11-18 1999-11-16 Witco Corporation Treatment of polyethers prior to hydrosilylation
US6103847A (en) * 1997-05-27 2000-08-15 Witco Corporation Siloxane-polyether copolymers with unsaturated functionalities, and process for making them
US6013711A (en) * 1997-06-18 2000-01-11 Ck Witco Corporation Hydrophilic polysiloxane compositions
US5986022A (en) 1998-04-01 1999-11-16 Witco Corporation Continuous manufacture of silicone coploymers
US5922895A (en) * 1998-04-17 1999-07-13 Dow Corning Corporation Amine borane complexes and phosphineborane complexes as catalyst for hydrosilation
US6372874B1 (en) * 1998-12-04 2002-04-16 Crompton Corporation Process for the preparation of siloxane-oxyalkylene copolymers
US6346583B1 (en) 1999-08-25 2002-02-12 General Electric Company Polar solvent compatible polyethersiloxane elastomers
US6797742B2 (en) 1999-08-25 2004-09-28 General Electric Company Polar solvent compatible polyethersiloxane elastomers
EP1230292B1 (de) * 1999-08-25 2008-03-26 General Electric Company Mit polarem lösemittel verträgliche polyethersiloxanelastomere
US6590117B1 (en) 2001-11-15 2003-07-08 Crompton Corporation Promoted hydrosilation reactions
US20040053810A1 (en) * 2002-08-16 2004-03-18 Tully Jo Anne Liquid laundry compositions comprising silicone additives
US6897280B2 (en) 2002-09-23 2005-05-24 General Electric Company Continuous manufacture of silicone copolymers via multi-stage blade-mixed plug flow tubular reactor
DE10359589A1 (de) * 2003-12-18 2005-07-28 Wacker-Chemie Gmbh Verfahren zur Herstellung von Organosiliciumverbindungen
US8008407B2 (en) 2006-03-31 2011-08-30 Dow Corning Corporation Process for preparing silicone polyethers
US7259220B1 (en) * 2006-07-13 2007-08-21 General Electric Company Selective hydrosilylation method
US20080033136A1 (en) * 2006-07-13 2008-02-07 Rinard Chauncey J Selective hydrosilylation conditions
US7569645B2 (en) * 2007-06-27 2009-08-04 Momentive Performance Materials Inc. Curable silyl-containing polymer composition containing paint adhesion additive
JP5459280B2 (ja) * 2011-09-12 2014-04-02 信越化学工業株式会社 オルガノキシシリル基又はシロキシ基含有エチルノルボルネン化合物の製造方法
EP2828337B1 (de) 2012-03-22 2023-08-02 Momentive Performance Materials Inc. Hydrophile makromere und hydrogele damit
CN104321352B (zh) 2012-03-22 2017-09-26 莫门蒂夫性能材料股份有限公司 可聚合的含酰胺基的有机硅化合物、含硅聚合物以及由其制备的生物医学装置
CN104321365B (zh) 2012-03-22 2018-06-05 莫门蒂夫性能材料股份有限公司 亲水有机硅单体、其制备方法和含有所述单体的薄膜
WO2014123956A1 (en) 2013-02-06 2014-08-14 Momentive Performance Materials Inc. (meth)acryloxy-containing trisiloxane, siloxane-containing polymers and biomedical devices therefrom
EP3415547B1 (de) 2017-06-13 2020-03-25 Evonik Operations GmbH Verfahren zur herstellung sic-verknüpfter polyethersiloxane
EP3415548B1 (de) 2017-06-13 2020-03-25 Evonik Operations GmbH Verfahren zur herstellung sic-verknüpfter polyethersiloxane
CN109867790B (zh) * 2018-12-24 2021-07-13 南京美思德新材料有限公司 一种有机硅聚醚共聚物及其制备方法

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Also Published As

Publication number Publication date
ATE163935T1 (de) 1998-03-15
EP0550064B1 (de) 1998-03-11
EP0550064A2 (de) 1993-07-07
DE69224728D1 (de) 1998-04-16
EP0550064A3 (en) 1993-09-22
US5191103A (en) 1993-03-02

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